基于固体前体构建集成催化剂及CO2加氢研究进展

doi:10.16085/j.issn.1000-6613.2023-1584

摘要/Abstract

摘要：

针对催化剂活性位点和微观结构不可控的问题，采用固体前体作为缓释的金属离子源制备微观结构可控、活性位点空间位置明确的金属基集成催化剂有望解决该问题，并实现催化剂的定制化设计。本文介绍了4类固体前体材料用于制备CO₂热催化加氢反应的催化剂，包括过渡金属层状硅酸盐、层状双金属氢氧化物、金属有机骨架材料以及钒酸铋材料。总结了这4类集成催化材料的制备过程机制及其在CO₂热催化加氢中的应用实例，并对固体前体制备多组分集成催化剂的研究前景进行了展望。

关键词: 催化, 二氧化碳, 加氢, 纳米材料, 固体前体, 集成催化剂

Abstract:

To overcome the problems of uncontrollable active sites and microstructures of catalysts, the utilization of solid precursor as a controlled-release source of metal ions has emerged as a promising approach for fabricating metal-based integrated catalysts with precise microstructures and well-defined spatial configuration of active sites, therefore realizing the rational design of catalysts. This review highlights four types of solid precursor materials, namely transition metal phyllosilicates, layered double hydroxides, metal-organic frameworks, and bismuth vanadate materials, for the preparation of catalysts for thermal catalytic hydrogenation of CO₂. The review provides an overview of preparation mechanisms and application examples of these four integrated catalyst materials, along with an outlook on the research direction of developing multi-component integrated catalysts based on solid precursors.

Key words: catalysis, carbon dioxide, hydrogenation, nanomaterials, solid precursor, integrated catalyst

中图分类号:

TQ426

卢欣欣, 蔡东仁, 詹国武. 基于固体前体构建集成催化剂及CO₂加氢研究进展[J]. 化工进展, 2024, 43(5): 2786-2802.

LU Xinxin, CAI Dongren, ZHAN Guowu. Research progress in the construction of integrated catalysts based on solid precursors and their application in CO₂ hydrogenation[J]. Chemical Industry and Engineering Progress, 2024, 43(5): 2786-2802.

图/表 8

图1 基于固体前体构建用于CO2热催化加氢反应的金属基催化剂示意图[22-24]TCPP(M)—去质子金属卟啉；LDO—层状双金属氧化物

图2 基于过渡金属层状硅酸盐制备双金属催化剂的衍生过程示意图[27]

图3 在280℃的H2还原气氛下不同区域硅酸铜随时间演变的TEM图和还原后的Cu粒径统计[28]

图4 LDHs和LDOs的结构及记忆效应机制示意图[63]

图5 离子交换法制备TCPP(M)@LDO催化剂的流程示意图[23]

图6 不同尺寸Zn-Cu-BTC晶体热分解前后的扫描电镜、透射电镜、光学显微镜图[93]

图7 Co基集成催化剂结构示意图及表征结果[101-102]

图8 不同晶体体系BiVO4的晶体结构示意图[111]（键长的单位为Å；红色为V、紫色为Bi、灰色为O）

参考文献 121

1	International Energy Agency. CO₂emissions in 2023[EB/OL]. , 2024.
2	TOLLEFSON Jeff, WEISS Kenneth R. Nations approve historic global climate accord[J]. Nature, 2015, 528(7582): 315-316.
3	张凡, 王树众, 李艳辉, 等. 中国制造业碳排放问题分析与减排对策建议[J]. 化工进展, 2022, 41(3): 1645-1653.
	ZHANG Fan, WANG Shuzhong, LI Yanhui, et al. Analysis of CO₂ emission and countermeasures and suggestions for emission reduction in Chinese manufacturing[J]. Chemical Industry and Engineering Progress, 2022, 41(3): 1645-1653.
4	HEPBURN Cameron, ADLEN Ella, BEDDINGTON John, et al. The technological and economic prospects for CO₂ utilization and removal[J]. Nature, 2019, 575(7781): 87-97.
5	张育新, 王灿, 舒文祥. 二氧化碳的还原及其利用研究进展[J]. 化工进展, 2023, 42(2): 944-956.
	ZHANG Yuxin, WANG Can, SHU Wenxiang. Research progress of carbon dioxide reduction and utilization[J]. Chemical Industry and Engineering Progress, 2023, 42(2): 944-956.
6	JIANG Xiao, NIE Xiaowa, GUO Xinwen, et al. Recent advances in carbon dioxide hydrogenation to methanol via heterogeneous catalysis[J]. Chemical Reviews, 2020, 120(15): 7984-8034.
7	成康, 张庆红, 康金灿, 等. 二氧化碳直接制备高值化学品中的接力催化方法[J]. 中国科学: 化学, 2020, 50(7): 743-755.
	CHENG Kang, ZHANG Qinghong, KANG Jincan, et al. Relay catalysis in the direct conversion of carbon dioxide to high-value chemicals[J]. Scientia Sinica Chimica, 2020, 50(7): 743-755.
8	WANG Wei, WANG Shengping, MA Xinbin, et al. Recent advances in catalytic hydrogenation of carbon dioxide[J]. Chemical Society Reviews, 2011, 40(7): 3703-3727.
9	徐海成, 戈亮. 二氧化碳加氢逆水汽变换反应的研究进展[J]. 化工进展, 2016, 35(10): 3180-3189.
	XU Haicheng, GE Liang. Progress on the catalytic hydrogenation of CO₂ via reverse water gas shift reaction[J]. Chemical Industry and Engineering Progress, 2016, 35(10): 3180-3189.
10	POROSOFF Marc D, YAN Binhang, CHEN Jingguang G. Catalytic reduction of CO₂ by H₂ for synthesis of CO, methanol and hydrocarbons: Challenges and opportunities[J]. Energy & Environmental Science, 2016, 9(1): 62-73.
11	CHEN Linxiao, KOVARIK Libor, János SZANYI. Temperature-dependent communication between Pt/Al₂O₃ catalysts and anatase TiO₂ dilutant: The effects of metal migration and carbon transfer on the reverse water-gas shift reaction[J]. ACS Catalysis, 2021, 11(19): 12058-12067.
12	刘昌俊, 郭秋婷, 叶静云, 等. 二氧化碳转化催化剂研究进展及相关问题思考[J]. 化工学报, 2016, 67(1): 6-13.
	LIU Changjun, GUO Qiuting, YE Jingyun, et al. Perspective on catalyst investigation for CO₂ conversion and related issues[J]. CIESC Journal, 2016, 67(1): 6-13.
13	贾晨喜, 邵敬爱, 白小薇, 等. 二氧化碳加氢制甲醇铜基催化剂性能的研究进展[J]. 化工进展, 2020, 39(9): 3658-3668.
	JIA Chenxi, SHAO Jingai, BAI Xiaowei, et al. Review on Cu-based catalysts for CO₂ hydrogenation to methanol[J]. Chemical Industry and Engineering Progress, 2020, 39(9): 3658-3668.
14	蔡中杰, 田盼, 黄忠亮, 等. 基于生物模板制备二氧化碳加氢反应的Cu/ZnO催化剂[J]. 化工学报, 2021, 72(7): 3668-3679.
	CAI Zhongjie, TIAN Pan, HUANG Zhongliang, et al. Preparation of Cu/ZnO nanocatalysts based on bio-templates for CO₂ hydrogenation[J]. CIESC Journal, 2021, 72(7): 3668-3679.
15	李雯, 詹国武, 黄加乐, 等. 基于金属有机骨架和稻谷壳前体构筑ZnZrO _x &bio-SAPO-34双功能催化剂及CO₂加氢制低碳烯烃[J]. 化工进展, 2022, 41(3): 1298-1308.
	LI Wen, ZHAN Guowu, HUANG Jiale, et al. Synthesis of ZnZrO _x &bio-SAPO-34 bifunctional catalysts derived from metal organic frameworks and rice husk template for CO₂ hydrogenation to light olefins[J]. Chemical Industry and Engineering Progress, 2022, 41(3): 1298-1308.
16	WANG Yuhao, KATTEL Shyam, GAO Wengui, et al. Exploring the ternary interactions in Cu-ZnO-ZrO₂ catalysts for efficient CO₂ hydrogenation to methanol[J]. Nature Communications, 2019, 10: 1166.
17	ZHANG Xiao, LI Xueqian, ZHANG Du, et al. Product selectivity in plasmonic photocatalysis for carbon dioxide hydrogenation[J]. Nature Communications, 2017, 8: 14542.
18	ZHANG Yaping, XU Jixiang, ZHOU Jie, et al. Metal-organic framework-derived multifunctional photocatalysts[J]. Chinese Journal of Catalysis, 2022, 43(4): 971-1000.
19	KONNERTH Hannelore, MATSAGAR Babasaheb M, CHEN Season S, et al. Metal-organic framework (MOF)-derived catalysts for fine chemical production[J]. Coordination Chemistry Reviews, 2020, 416: 213319.
20	YANG Liu, ZENG Xiaofei, WANG Wenchuan, et al. Recent progress in MOF-derived, heteroatom-doped porous carbons as highly efficient electrocatalysts for oxygen reduction reaction in fuel cells[J]. Advanced Functional Materials, 2018, 28(7): 1704537.
21	LIU Da, GU Wenyi, ZHOU Liang, et al. Recent advances in MOF-derived carbon-based nanomaterials for environmental applications in adsorption and catalytic degradation[J]. Chemical Engineering Journal, 2022, 427: 131503.
22	LIU Sihan, SONG Miaomiao, Xingwen CHA, et al. Nickel phyllosilicates functionalized with graphene oxide to boost CO selectivity in CO₂ hydrogenation[J]. Separation and Purification Technology, 2022, 287: 120555.
23	ZHAO Feigang, ZHAN Guowu, ZHOU Shufeng. Intercalation of laminar Cu-Al LDHs with molecular TCPP(M) (M = Zn, Co, Ni, and Fe) towards high-performance CO₂ hydrogenation catalysts[J]. Nanoscale, 2020, 12(24): 13145-13156.
24	YU Jiahui, FENG Bingge, LIU Shuai, et al. Highly active Ni/Al₂O₃ catalyst for CO₂ methanation by the decomposition of Ni-MOF@Al₂O₃ precursor via cold plasma[J]. Applied Energy, 2022, 315: 119036.
25	SHENG Yuan, ZENG Huachun. Monodisperse aluminosilicate spheres with tunable Al/Si ratio and hierarchical macro-meso-microporous structure[J]. ACS Applied Materials & Interfaces, 2015, 7(24): 13578-13589.
26	WANG Meiling, QIAN Xiaoqi, XIE Liqiang, et al. Synthesis of a Ni phyllosilicate with controlled morphology for deep hydrogenation of polycyclic aromatic hydrocarbons[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(2): 1989-1997.
27	SONG Miaomiao, HUANG Zhongliang, CHEN Bin, et al. Reduction treatment of nickel phyllosilicate supported Pt nanocatalysts determining product selectivity in CO₂ hydrogenation[J]. Journal of CO₂ Utilization, 2021, 52: 101674.
28	VAN DEN BERG Roy, ELKJAER Christian F, GOMMES Cedric J, et al. Revealing the formation of copper nanoparticles from a homogeneous solid precursor by electron microscopy[J]. Journal of the American Chemical Society, 2016, 138(10): 3433-3442.
29	SIVAIAH M V, PETIT S, BEAUFORT M F, et al. Nickel based catalysts derived from hydrothermally synthesized 1∶1 and 2∶1 phyllosilicates as precursors for carbon dioxide reforming of methane[J]. Microporous and Mesoporous Materials, 2011, 140(1/2/3): 69-80.
30	LIU Hua, CHAI Mengqian, PEI Guangxian, et al. Effect of IB-metal on Ni/SiO₂ catalyst for selective hydrogenation of acetylene[J]. Chinese Journal of Catalysis, 2020, 41(7): 1099-1108.
31	WEN Xueying, XU Leilei, CHEN Mindong, et al. Exploring the influence of nickel precursors on constructing efficient Ni-based CO₂ methanation catalysts assisted with in-situ technologies[J]. Applied Catalysis B: Environmental, 2021, 297: 120486.
32	YANG Meihua, JIN Peng, FAN Yinrui, et al. Ammonia-assisted synthesis towards a phyllosilicate-derived highly-dispersed and long-lived Ni/SiO₂ catalyst[J]. Catalysis Science & Technology, 2015, 5(12): 5095-5099.
33	ZHAO Yujun, LI Siming, WANG Yue, et al. Efficient tuning of surface copper species of Cu/SiO₂ catalyst for hydrogenation of dimethyl oxalate to ethylene glycol[J]. Chemical Engineering Journal, 2017, 313: 759-768.
34	LI Fengjiao, WANG Liguo, HAN Xiao, et al. Selective hydrogenation of ethylene carbonate to methanol and ethylene glycol over Cu/SiO₂ catalysts prepared by ammonia evaporation method[J]. International Journal of Hydrogen Energy, 2017, 42(4): 2144-2156.
35	CHEN Liangfeng, GUO Pingjun, QIAO Minghua, et al. Cu/SiO₂ catalysts prepared by the ammonia-evaporation method: Texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol[J]. Journal of Catalysis, 2008, 257(1): 172-180.
36	CHE Michel, CHENG Zheng xing, LOUIS Catherine. Nucleation and particle growth processes involved in the preparation of silica-supported nickel materials by a two-step procedure[J]. Journal of the American Chemical Society, 1995, 117: 2008-2018.
37	BURATTIN Paolo, CHE Michel, LOUIS Catherine. Molecular approach to the mechanism of deposition-precipitation of the Ni(Ⅱ) phase on silica[J]. Journal of Physical Chemistry B, 1998, 102: 2722-2732.
38	BURATTIN Paolo, CHE Michel, LOUIS Catherine. Metal particle size in Ni/SiO₂ materials prepared by deposition- precipitation: Influence of the nature of the Ni(Ⅱ) phase and of its interaction with the support[J]. Journal of Physical Chemistry B, 1999, 103: 6171-6178.
39	BURATTIN Paolo, CHE Michel, LOUIS Catherine. Characterization of the Ni(Ⅱ) phase formed on silica upon deposition- precipitation[J]. Journal of Physical Chemistry B, 1997, 101: 7060-7074.
40	BURATTIN Paolo, CHE Michel, LOUIS Catherine. Ni/SiO₂ materials prepared by deposition-precipitation: Influence of the reduction conditions and mechanism of formation of metal particles[J]. Journal of Physical Chemistry B, 2020, 104(45): 10482-10489.
41	VAN DER GRIFT C J G, ELBERSE P A, MULDER A, et al. Preparation of silica-supported copper catalysts by means of deposition-precipitation[J]. Applied Catalysis, 1990, 59: 275-289.
42	BIAN Zhoufeng, KAWI Sibudjing. Preparation, characterization and catalytic application of phyllosilicate: A review[J]. Catalysis Today, 2020, 339: 3-23.
43	SIVAIAH M V, PETIT S, BARRAULT J, et al. CO₂ reforming of CH₄ over Ni-containing phyllosilicates as catalyst precursors[J]. Catalysis Today, 2010, 157(1/2/3/4): 397-403.
44	李静, 靳博晗, 岳海荣, 等. 氨铜比对蒸氨法Cu/SiO₂催化剂活性组分演变及二氧化碳加氢性能的影响[J]. 应用化工 2016, 45(11): 2005-2012.
	LI Jing, JIN Bohan, YUE Hairong, et al. Effect of ammonia copper ratio on the structural evolution and catalytic activity of Cu/SiO₂ catalysts prepared by ammonia evaporation method in CO₂ hydrogenation reaction[J]. Applied Chemical Industry, 2016, 45(11): 2005-2012.
45	WANG Zhiqiang, XU Zhongning, PENG Siyan, et al. High-performance and long-lived Cu/SiO₂ nanocatalyst for CO₂ hydrogenation[J]. ACS Catalysis, 2015, 5(7): 4255-4259.
46	YE Runping, GONG Weibo, SUN Zhao, et al. Enhanced stability of Ni/SiO₂ catalyst for CO₂ methanation: Derived from nickel phyllosilicate with strong metal-support interactions[J]. Energy, 2019, 188: 116059.
47	Juhwan IM, SHIN Hyeyoung, JANG Haeyoun, et al. Maximizing the catalytic function of hydrogen spillover in platinum-encapsulated aluminosilicates with controlled nanostructures[J]. Nature Communications, 2014, 5: 3370.
48	ZUO Jiachang, CHEN Kun, ZHENG Jianwei, et al. Enhanced CO₂ hydrogenation to methanol over La oxide-modified Cu nanoparticles socketed on Cu phyllosilicate nanotubes[J]. Journal of CO₂ Utilization, 2021, 52: 101699.
49	吕翰林, 胡兵, 刘国亮, 等. ZnO逆修饰小尺寸Cu/SiO₂催化剂及其在CO₂加氢制甲醇中的应用[J]. 物理化学学报, 2020, 36(11): 1911008.
	Hanlin LYU, HU Bing, LIU Guoliang, et al. Inverse decoration of ZnO on small-sized Cu/SiO₂ with controllable Cu-ZnO interaction for CO₂ hydrogenation to produce methanol[J]. Acta Physico-Chimica Sinica, 2020, 36(11): 1911008.
50	ZHANG Tengfei, LIU Qing. Lanthanum-modified MCF-derived nickel phyllosilicate catalyst for enhanced CO₂ methanation: A comprehensive study[J]. ACS Applied Materials & Interfaces, 2020, 12(17): 19587-19600.
51	ZHANG Yang, DUAN Hongchang, Zhaoyang LYU, et al. Which is the better catalyst for CO₂ methanation-nanotubular or supported Ni phyllosilicate?[J]. International Journal of Hydrogen Energy, 2021, 46(80): 39903-39911.
52	LIU J, ZHANG Y, CHEN Y, et al. Controllable synthesis of yolk-shell nickel phyllosilicate for CO₂ methanation: Identifying effect of pore structure of silica sacrificial template[J]. Materials Today Nano, 2022, 18: 100208.
53	NGUYEN H T, NGUYEN A T Q, TRANG T T VU, et al. Potassium in silicon-rich biomass wastes: A perspective of slow-release potassium sources[J]. Biofuels, Bioproducts and Biorefining, 2022, 16(5): 1159-1164.
54	CHEN Yaqi, LIU Qing. Synthesis and regeneration of Ni-phyllosilicate catalysts using a versatile double accelerator method: A comprehensive study[J]. ACS Catalysis, 2021, 11(20): 12570-12584.
55	ZHANG Shouwei, GAO Huihui, LI Jiaxing, et al. Rice husks as a sustainable silica source for hierarchical flower-like metal silicate architectures assembled into ultrathin nanosheets for adsorption and catalysis[J]. Journal of Hazardous Materials, 2017, 321: 92-102.
56	宋苗苗, 郭梅婷, 蔡东仁, 等. 基于稻谷壳模板制备层状硅酸盐催化剂用于CO₂加氢反应[J]. 化学反应工程与工艺, 2022, 38(4): 318-347.
	SONG Miaomiao, GUO Meiting, CAI Dongren, et al. Preparation of phyllosilicate catalysts using rice husk as template for CO₂ hydrogenation[J]. Chemical Reaction Engineering and Technology, 2022, 38(4): 318-347.
57	YANG Zhongzhu, WEI Jingjing, ZENG Guangming, et al. A review on strategies to LDH-based materials to improve adsorption capacity and photoreduction efficiency for CO₂ [J]. Coordination Chemistry Reviews, 2019(386): 154-182.
58	张栋强, 王园园, 贾倩, 等. 层状双氢氧化物的制备及其摩擦学性能研究进展[J]. 中国表面工程, 2022, 35(2): 91-101.
	ZHANG Dongqiang, WANG Yuanyuan, JIA Qian, et al. Review on preparation and tribological properties of layered double hydroxides[J]. China Surface Engineering, 2022, 35(2): 91-101.
59	谢博尧, 张纪梅, 郝帅帅, 等. 层状双氢氧化物析氧催化剂的研究进展[J]. 材料工程, 2020, 48(1): 1-9.
	XIE Boyao, ZHANG Jimei, HAO Shuaishuai, et al. Research progress in layered double hydroxides catalysts for oxygen evolution reaction[J]. Journal of Materials Engineering, 2020, 48(1): 1-9.
60	ZHANG Luhong, XIONG Zhigang, LI Li, et al. Uptake and degradation of orange Ⅱ by zinc aluminum layered double oxides[J]. Journal of Colloid and Interface Science, 2016, 469: 224-230.
61	FANG Xin, CHEN Chuang, JIA He, et al. Progress in adsorption enhanced hydrogenation of CO₂ on layered double hydroxide (LDH) derived catalysts[J]. Journal of Industrial and Engineering Chemistry, 2021, 95: 16-27.
62	CAVANI F, TRIFIRÒ F, VACCARI A. Hydrotalcite-type anionic clays: Preparation, properties and applications[J]. Catalysis Today, 1991, 11: 173-301.
63	JIN Li, ZHOU Xiaoyuan, WANG Fang, et al. Insights into memory effect mechanisms of layered double hydroxides with solid-state NMR spectroscopy[J]. Nature Communications, 2022, 13(1): 6093.
64	TEIXEIRA Mariana A, MAGESTE Aparecida B, DIAS Anderson, et al. Layered double hydroxides for remediation of industrial wastewater containing manganese and fluoride[J]. Journal of Cleaner Production, 2018, 171: 275-284.
65	MIYATA Shigeo. Physico-chemical properties of synthetic hydrotalcites in relation to composition[J]. Clays and Clay Minerals, 1980, 28(1): 50-56.
66	WANG Qiang, Hui huang TAY, JIA WEI NG Desmond, et al. The effect of trivalent cations on the performance of Mg-M-CO₃ layered double hydroxides for high-temperature CO₂ capture[J]. ChemSusChem, 2010, 3(8): 965-973.
67	HE Lei, HUANG Yanqiang, WANG Aiqin, et al. A noble-metal-free catalyst derived from Ni-Al hydrotalcite for hydrogen generation from N₂H₄·H₂O decomposition[J]. Angewandte Chemie-International Edition, 2012, 51(25): 6191-6195.
68	HE Lei, LIN Qingquan, LIU Yu, et al. Unique catalysis of Ni-Al hydrotalcite derived catalyst in CO₂ methanation: Cooperative effect between Ni nanoparticles and a basic support[J]. Journal of Energy Chemistry, 2014, 23(5): 587-592.
69	Yuhan MEN, FANG Xin, GU Qinfen, et al. Synthesis of Ni₅Ga₃ catalyst by hydrotalcite-like compound (HTlc) precursors for CO₂ hydrogenation to methanol[J]. Applied Catalysis B: Environmental, 2020, 275: 119067.
70	LIU Zhihao, GAO Xinhua, LIU Bo, et al. Highly stable and selective layered Co-Al-O catalysts for low-temperature CO₂ methanation[J]. Applied Catalysis B: Environmental, 2022, 310: 121303.
71	LAN HUYNH Huong, MEKONNEN TUCHO Wakshum, YU Zhixin. Structured NiFe catalysts derived from in-situ grown layered double hydroxides on ceramic monolith for CO₂ methanation[J]. Green Energy & Environment, 2020, 5(4): 423-432.
72	HANIF Aamir, DASGUPTA Soumen, DIVEKAR Swapnil, et al. A study on high temperature CO₂ capture by improved hydrotalcite sorbents[J]. Chemical Engineering Journal, 2014, 236: 91-99.
73	HANIF Aamir, SUN Mingzhe, SHANG Shanshan, et al. Exfoliated Ni-Al LDH 2D nanosheets for intermediate temperature CO₂ capture[J]. Journal of Hazardous Materials, 2019, 374: 365-371.
74	MIGUEL C V, SORIA M A, MENDES A, et al. A sorptive reactor for CO₂ capture and conversion to renewable methane[J]. Chemical Engineering Journal, 2017, 322: 590-602.
75	FANG Xin, Yuhan MEN, WU Fan, et al. Promoting CO₂ hydrogenation to methanol by incorporating adsorbents into catalysts: Effects of hydrotalcite[J]. Chemical Engineering Journal, 2019, 378: 122052.
76	ZHANG Ruihong, AI Yuejie, LU Zhanhui. Application of multifunctional layered double hydroxides for removing environmental pollutants: Recent experimental and theoretical progress[J]. Journal of Environmental Chemical Engineering, 2020, 8(4): 103908.
77	HE Feng, ZHUANG Jiahao, LU Bin, et al. Ni-based catalysts derived from Ni-Zr-Al ternary hydrotalcites show outstanding catalytic properties for low-temperature CO₂ methanation[J]. Applied Catalysis B: Environmental, 2021, 293: 120218.
78	ZHAO Feigang, FAN Longlong, XU Kaiji, et al. Hierarchical sheet-like Cu/Zn/Al nanocatalysts derived from LDH/MOF composites for CO₂ hydrogenation to methanol[J]. Journal of CO₂ Utilization, 2019, 33: 222-232.
79	LI Molly M J, CHEN Chunping, AYVALI Tuğçe, et al. CO₂ hydrogenation to methanol over catalysts derived from single cationic layer CuZnGa LDH precursors[J]. ACS Catalysis, 2018, 8(5): 4390-4401.
80	OREGE Joshua Iseoluwa, KIFLE Ghebretensae Aron, YU Yang, et al. Emerging spinel ferrite catalysts for driving CO₂ hydrogenation to high-value chemicals[J]. Matter, 2023, 6(5): 1404-34.
81	JOUTSUKA Tatsuya, HAMAMURA Ryu, FUJIWARA Kakeru, et al. Understanding the structure of Cu-doped MgAl₂O₄ for CO₂ hydrogenation catalyst precursor using experimental and computational approaches[J]. International Journal of Hydrogen Energy, 2022, 47(50): 21369-21374.
82	LIU Tangkang, XU Di, WU Dengdeng, et al. Spinel ZnFe₂O₄ regulates copper sites for CO₂ hydrogenation to methanol[J]. ACS Sustainable Chemistry Engineering, 2021, 9(11): 4033-41.
83	Yonggyun BAE, HONG Jongsup. Enhancement of surface morphology and catalytic kinetics of NiAl₂O₄ spinel-derived Ni catalyst to promote dry reforming of methane at low temperature for the direct application to a solid oxide fuel cell[J]. Chemical Engineering Journal, 2022, 446: 136978.
84	WANG Lingxiang, WANG Liang, ZHANG Jian, et al. Selective hydrogenation of CO₂ to ethanol over cobalt catalysts[J]. Angewandte Chemie International Edition, 2018, 57(21): 6104-6108.
85	AN Kang, ZHANG Siran, WANG Hong, et al. Co⁰-Co ^δ ⁺ active pairs tailored by Ga-Al-O spinel for CO₂-to-ethanol synthesis[J]. Chemical Engineering Journal, 2022, 433: 134606.
86	KHAN Nazmul Abedin, HASAN Zubair, JHUNG Sung Hwa. Beyond pristine metal-organic frameworks: Preparation and application of nanostructured, nanosized, and analogous MOFs[J]. Coordination Chemistry Reviews, 2018, 376: 20-45.
87	QIAN Yongteng, ZHANG Fangfang, PANG Huan. A review of MOFs and their composites based photocatalysts: Synthesis and applications[J]. Advanced Functional Materials, 2021, 31(37): 2104231.
88	WANG Kecheng, LI Yaping, XIE Linhua, et al. Construction and application of base stable MOFs: A critical review[J]. Chemical Society Reviews, 2022, 51(15): 6417-6441.
89	KHALIL Islam E, FONSECA Javier, REITHOFER Michael R, et al. Tackling orientation of metal-organic frameworks (MOFs): The quest to enhance MOF performance[J]. Coordination Chemistry Reviews, 2023, 481: 215043.
90	REN Jianwei, DYOSIBA Xoliswa, MUSYOKA Nicholas M, et al. Review on the current practices and efforts towards pilot-scale production of metal-organic frameworks (MOFs)[J]. Coordination Chemistry Reviews, 2017, 352: 187-219.
91	周程, 南永永, 查飞, 等. 金属有机骨架材料在二氧化碳加氢中的应用[J]. 燃料化学学报, 2021, 49(10): 1444-1457.
	ZHOU Chen, Yongyong NAN, ZHA Fei, et al. Application of metal-organic frameworks in CO₂ hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2021, 49(10): 1444-1457.
92	CHEN Bin, ZENG Xiaoli, LIU Yiping, et al. Thermal decomposition kinetics of M-BTC (M = Cu, Co, Zn, and Ce) and M-BTC/Pt composites under oxidative and reductive environments[J]. Chemical Engineering Journal, 2022, 450: 138470.
93	ZHANG Jingzheng, AN Bing, HONG Yahui, et al. Pyrolysis of metal-organic frameworks to hierarchical porous Cu/Zn-nanoparticle@carbon materials for efficient CO₂ hydrogenation[J]. Materials Chemistry Frontiers, 2017, 1(11): 2405-2409.
94	WEI Xijun, LI Yanhong, PENG Huarong, et al. A novel functional material of Co₃O₄/Fe₂O₃ nanocubes derived from a MOF precursor for high-performance electrochemical energy storage and conversion application[J]. Chemical Engineering Journal, 2019, 355: 336-340.
95	WANG Sha, GAO Zhimin, SONG Guoshuai, et al. Copper oxide hierarchical morphology derived from MOF precursors for enhancing ethanol vapor sensing performance[J]. Journal of Materials Chemistry C, 2020, 8(28): 9671-9677.
96	HU Yating, SONG Chi, LI Changjian, et al. Two-step pyrolysis of Mn MIL-100 MOF into MnO nanoclusters/carbon and the effect of N-doping[J]. Journal of Materials Chemistry A, 2022, 10(15): 8172-8177.
97	CHEN Xi, CHEN Xi, YU Enqi, et al. In situ pyrolysis of Ce-MOF to prepare CeO₂ catalyst with obviously improved catalytic performance for toluene combustion[J]. Chemical Engineering Journal, 2018, 344: 469-479.
98	CHEN Xi, CHEN Xi, CAI Songcai, et al. Catalytic combustion of toluene over mesoporous Cr₂O₃-supported platinum catalysts prepared by in situ pyrolysis of MOFs[J]. Chemical Engineering Journal, 2018, 334: 768-779.
99	ZHAN Guowu, ZENG Huachun. Synthesis and functionalization of oriented metal-organic-framework nanosheets: Toward a series of 2D catalysts[J]. Advanced Functional Materials, 2016, 26(19): 3268-3281.
100	LIPPI R, HOWARD S C, BARRON H, et al. Highly active catalyst for CO₂ methanation derived from a metal organic framework template[J]. Journal of Materials Chemistry A, 2017, 5(25): 12990-12997.
101	ZHAN Guowu, ZENG Huachun. ZIF-67 derived nanoreactors for controlling product selectivity in CO₂ hydrogenation[J]. ACS Catalysis, 2017, 7(11): 7509-7519.
102	HUANG Zhongliang, FAN Longling, ZHAO Feigang, et al. Rational engineering of multilayered Co₃O₄/ZnO nanocatalysts through chemical transformations from matryoshka-type ZIFs[J]. Advanced Functional Materials, 2019, 29(42): 1903774.
103	YUE Yihua, HUANG Zhongliang, CAI Dongren, et al. Fabrication of multi-layered Co₃O₄/ZnO nanocatalysts for spectroscopic visualization: Effect of spatial positions on CO₂ hydrogenation performance[J]. Fuel, 2022, 321: 124042.
104	CUI Wengang, ZHANG Qiang, ZHOU Lei, et al. Hybrid MOF template-directed construction of hollow-structured In₂O₃@ZrO₂ heterostructure for enhancing hydrogenation of CO₂ to methanol[J]. Small, 2023, 19(1): 2204914.
105	CAI Zhongjie, DAI Jiajun, LI Wen, et al. Pd supported on MIL-68(In) derived In₂O₃ nanotubes as superior catalysts to boost CO₂ hydrogenation to methanol[J]. ACS Catalysis, 2020, 10(22): 13275-13289.
106	GUTTEROD Emil S, LAZZARINI Andrea, FJERMESTAD Torstein, et al. Hydrogenation of CO₂ to methanol by Pt nanoparticles encapsulated in UiO-67: Deciphering the role of the metal organic framework[J]. Journal of the American Chemical Society, 2020, 142(2): 999-1009.
107	LI Wen, WANG Kuncan, HUANG Jiale, et al. M _x O _y -ZrO₂ (M = Zn, Co, Cu) solid solutions derived from schiff base-bridged UiO-66 composites as high-performance catalysts for CO₂ hydrogenation[J]. ACS Applied Materials & Interfaces, 2019, 11(36): 33263-33272.
108	CAI Zhongjie, HUANG Meng, DAI Jiajun, et al. Fabrication of Pd/In₂O₃ nanocatalysts derived from MIL-68(In) loaded with molecular metalloporphyrin (TCPP(Pd)) toward CO₂ hydrogenation to methanol[J]. ACS Catalysis, 2021, 12(1): 709-723.
109	KIM Jin Hyun, LEE Jae Sung. Elaborately modified BiVO₄ photoanodes for solar water splitting[J]. Advanced Materials, 2019, 31(20): 1806938.
110	LU Xinxin, XIAO Jingran, PENG Lingling, et al. Enhancement in the photoelectrochemical performance of BiVO₄ photoanode with high (040) facet exposure[J]. Journal of Colloid and Interface Science, 2022, 628: 726-735.
111	PARK Yiseul, MCDONALD Kenneth J, CHOI Kyoung Shin. Progress in bismuth vanadate photoanodes for use in solar water oxidation[J]. Chemical Society Reviews, 2013, 42(6): 2321-2337.
112	GAO Shan, GU Bingchuan, JIAO Xingchen, et al. Highly efficient and exceptionally durable CO₂ photoreduction to methanol over freestanding defective single unit cell bismuth vanadate layers[J]. Journal of the American Chemical Society, 2017, 139(9): 3438-3445.
113	ZHAO Lina, BIAN Ji, ZHANG Xianfa, et al. Construction of ultrathin S-scheme heterojunctions of single Ni atom immobilized Ti-MOF and BiVO₄ for CO₂ photoconversion of nearly 100% to CO by pure water[J]. Advanced Materials, 2022, 34(41): 2205303.
114	BRITO Juliana F de, CORRADINI Patricia G, ZANONI Maria Valnice B, et al. The influence of metallic Bi in BiVO₄ semiconductor for artificial photosynthesis[J]. Journal of Alloys and Compounds, 2021, 851: 156912.
115	LIU Lixia, FU Jiaju, JIANG Liping, et al. Highly efficient photoelectrochemical reduction of CO₂ at low applied voltage using 3D Co-Pi/BiVO₄/SnO₂ nanosheet array photoanodes[J]. ACS Applied Materials & Interfaces, 2019, 11(29): 26024-26031.
116	KIM Chang Woo, KANG Myung Jong, JI Sohyun, et al. Artificial photosynthesis for formaldehyde production with 85% of faradaic efficiency by tuning the reduction potential[J]. ACS Catalysis, 2018, 8(2): 968-974.
117	MA Wenxiu, BU Jun, LIU Zhenpeng, et al. Monoclinic scheelite bismuth vanadate derived bismuthene nanosheets with rapid kinetics for electrochemically reducing carbon dioxide to formate [J]. Advanced Functional Materials, 2020, 31(4): 2006704.
118	JING Qifeng, FENG Xinyan, PAN Jiangling, et al. Facile synthesis of Bi/BiVO₄ composite ellipsoids with high photocatalytic activity[J]. Dalton Transactions, 2018, 47(8): 2602-2609.
119	XU Xiaofeng, KOU Shufang, GUO Xia, et al. The enhanced photocatalytic properties for water oxidation over Bi/BiVO₄/V₂O₅ Composite[J]. The Journal of Physical Chemistry C, 2017, 121(30): 16257-16265.
120	Bartose TRAWIŃSKI, BOCHENTYN Beata, KUSZ Boguslaw. A study of a reduction of a micro- and nanometric bismuth oxide in hydrogen atmosphere[J]. Thermochimica Acta, 2018, 669: 99-108.
121	JIANG Feng, WANG Shanshan, XU Yuebing, et al. Catalytic activity for CO₂ hydrogenation is linearly dependent on generated oxygen vacancies over CeO₂-supported Pd catalysts[J]. ChemCatChem, 2022, 14: e202200422.

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基于固体前体构建集成催化剂及CO₂加氢研究进展

Research progress in the construction of integrated catalysts based on solid precursors and their application in CO₂ hydrogenation

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