添加剂改性固态胺吸附剂用于碳捕集的研究进展

doi:10.16085/j.issn.1000-6613.2023-1831

化工进展 ›› 2024, Vol. 43 ›› Issue (5): 2739-2759.DOI: 10.16085/j.issn.1000-6613.2023-1831

• 二氧化碳捕集与资源化利用 • 上一篇

添加剂改性固态胺吸附剂用于碳捕集的研究进展

苗诒贺¹(), 王耀祖¹, 刘雨杭¹, 朱炫灿², 李佳³, 于立军¹()

^1.上海交通大学智慧能源创新学院，上海 200240
^2.上海交通大学机械与动力工程学院，上海 200240
^3.香港科技大学（广州）碳中和与气候变化学域，广东广州 200240

收稿日期:2023-10-18 修回日期:2024-02-27 出版日期:2024-05-15 发布日期:2024-06-15
通讯作者: 于立军
作者简介:苗诒贺（1993—），男，助理研究员，研究方向为吸附法二氧化碳捕集。E-mail：miaoyihe@sjtu.edu.cn。
基金资助:
国家博士后研究人员资助计划(GZC20231557);上海市“科技创新行动计划”科技支撑碳达峰碳中和专项(21DZ1206200);国家重点研发计划(2022YFB4101702)

Research progress on the improving effect of additives on supported amine adsorbents for carbon capture

MIAO Yihe¹(), WANG Yaozu¹, LIU Yuhang¹, ZHU Xuancan², LI Jia³, YU Lijun¹()

^1.College of Smart Energy, Shanghai Jiao Tong University, Shanghai 200240, China
^2.School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
^3.Carbon Neutrality and Climate Change Thrust, Society Hub, The Hong Kong University of Science and Technology (Guangzhou), Guangzhou 511400, Guangdong, China

Received:2023-10-18 Revised:2024-02-27 Online:2024-05-15 Published:2024-06-15
Contact: YU Lijun

摘要/Abstract

摘要：

固态胺是固体吸附CO₂捕集技术路线中的研究热点，是烟气碳捕集和直接空气碳捕集技术中最有应用前景的吸附剂材料，近年来受到广泛关注。目前，固态胺吸附剂的吸脱附性能以及热化学稳定性仍有较大提升空间。本文综述了近年来表面活性剂、胺类和无机物类，以及环氧化物、螯合剂和含硫化合物等添加剂对固态胺吸附剂吸附能力增强和热化学稳定性提升的研究成果。在此基础上，进一步介绍了不同种类添加剂对固态胺吸附剂的改性机理，总结了在不同碳捕集工况下添加剂对固态胺吸附剂的改性特点。尽管现有研究已经取得了一些进展，但添加剂改性固态胺吸附剂仍然面临挑战，尤其是目前尚未能充分实现增强固态胺吸附剂的吸附能力和热化学稳定性的双重目标。此外，鉴于不同碳捕集工况下气体成分显著不同，未来研究需要更加明晰不同碳捕集工况下添加剂对固态胺吸附剂吸脱附热力学、动力学以及热化学稳定性的影响，并根据具体碳捕集工况有针对性地设计添加剂改性方案。

关键词: 二氧化碳捕集, 吸附剂, 稳定性, 添加剂, 表面活性剂, 混合

Abstract:

Supported amine adsorbents are a prominent subject of research within the realm of solid adsorption techniques for CO₂ capture, representing an area of considerable interest and applicability in the field of flue gas carbon capture and direct air capture technologies, and have received extensive attention. Nevertheless, there exists substantial room for improvement regarding the adsorption-desorption performance and thermochemical stability of supported amine adsorbents. This review focused on the study of the performance improvement of supported amine adsorbents through introducing additives. It provided a review of recent research on enhancing the adsorption performance of supported amine adsorbents through the utilization of additives, encompassing surfactants, amine-based additives and inorganic additives. Additionally, it delved into the achievements of research efforts aimed at enhancing the thermochemical stability of supported amine adsorbents through the application of epoxides, chelators and sulfur-containing additives. Furthermore, this review elucidated the underlying mechanisms governing the performance improvement of supported amine adsorbents via various categories of additives and summarized the performance improvement characteristics of distinct types of additives for supported amine adsorbents under different carbon capture conditions. Despite some progress in research, the performance improvement of supported amine adsorbents through additives still faced challenges. Presently, research had not fully achieved the dual objectives of enhancing the adsorption performance and thermochemical stability of supported amine adsorbents. Moreover, given the significant variation in gas composition under different carbon capture conditions, future research needed to clarify the impact of additives on the thermodynamics, kinetics and thermochemical stability of supported amine adsorbents under different carbon capture scenarios, and design additive modification strategies accordingly.

Key words: CO₂ capture, adsorbents, stability, additives, surfactants, mixing

中图分类号:

TQ028

苗诒贺, 王耀祖, 刘雨杭, 朱炫灿, 李佳, 于立军. 添加剂改性固态胺吸附剂用于碳捕集的研究进展[J]. 化工进展, 2024, 43(5): 2739-2759.

MIAO Yihe, WANG Yaozu, LIU Yuhang, ZHU Xuancan, LI Jia, YU Lijun. Research progress on the improving effect of additives on supported amine adsorbents for carbon capture[J]. Chemical Industry and Engineering Progress, 2024, 43(5): 2739-2759.

图/表 14

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载体与模板剂	胺组分	吸附气体氛围	吸附温度 /℃	脱附温度 /℃	脱附方式	测定方法	CO₂吸附量 /mmol·g^-1	胺效率 (CO₂/N)	参考文献
SBA-15	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	3.23	NA	[19]
SBA-15+P123	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	3.27	NA	[19]
MCM-41	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	3.27	NA	[21]
MCM-41+CTAB	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	4.80	NA	[21]
MCM-41+DTAB	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	3.50	NA	[21]
PE -MCM-41	55% PEI	纯CO₂	75	75	N₂吹扫	TGA	约4.38	NA	[22]
PE -MCM-41+CTAB	55% PEI	纯CO₂	75	75	N₂吹扫	TGA	约10.06	NA	[22]
KIT-1	50% TEPA	纯CO₂	75	100	N₂吹扫	TGA	2.71	0.21	[23]
KIT-1+CTAB	50% TEPA	纯CO₂	75	100	N₂吹扫	TGA	4.19	0.36	[23]
KIT-1	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约2.3	约0.18	[23]
KIT-1+CTAB	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约3.1	约0.27	[23]
MCM-48	40% PEI	纯CO₂	25	100	N₂吹扫	TGA	2.16	0.22	[24]
MCM-48+CTAB	40% PEI	纯CO₂	25	100	N₂吹扫	TGA	2.59	0.30	[24]
MCM-48	40% PEI	15% CO₂/N₂	50	100	N₂吹扫	固定床+质谱	1.01	0.10	[24]
MCM-48+CTAB	40% PEI	15% CO₂/N₂	50	100	N₂吹扫	固定床+质谱	1.54	0.18	[24]
MMSN	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	3.08	0.18	[25]
MMSN+CTAC	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	4.55	0.25	[25]
MMSN	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约3.4	N/A	[25]
MMSN+CTAC	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约4.6	N/A	[25]
MMSN	50% TEPA	0.04% CO₂/N₂	25	100	N₂吹扫	TGA	约2.5	N/A	[25]
MMSN+CTAC	50% TEPA	0.04% CO₂/N₂	25	100	N₂吹扫	TGA	3.68	N/A	[25]
MMON	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	2.46	0.20	[26]
MMON+CTAC	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	2.78	0.22	[26]
MMON+CTAC+BTES	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	4.04	0.33	[26]
MMON	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约2.4	N/A	[26]
MMON+CTAC	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约2.6	N/A	[26]
MMON+CTAC+BTES	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约3.6	N/A	[26]

载体与模板剂	胺组分	吸附气体氛围	吸附温度 /℃	脱附温度 /℃	脱附方式	测定方法	CO₂吸附量 /mmol·g^-1	胺效率 (CO₂/N)	参考文献
SBA-15	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	3.23	NA	[19]
SBA-15+P123	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	3.27	NA	[19]
MCM-41	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	3.27	NA	[21]
MCM-41+CTAB	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	4.80	NA	[21]
MCM-41+DTAB	50% TEPA	纯CO₂	75	100	He吹扫	固定床+气相色谱	3.50	NA	[21]
PE -MCM-41	55% PEI	纯CO₂	75	75	N₂吹扫	TGA	约4.38	NA	[22]
PE -MCM-41+CTAB	55% PEI	纯CO₂	75	75	N₂吹扫	TGA	约10.06	NA	[22]
KIT-1	50% TEPA	纯CO₂	75	100	N₂吹扫	TGA	2.71	0.21	[23]
KIT-1+CTAB	50% TEPA	纯CO₂	75	100	N₂吹扫	TGA	4.19	0.36	[23]
KIT-1	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约2.3	约0.18	[23]
KIT-1+CTAB	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约3.1	约0.27	[23]
MCM-48	40% PEI	纯CO₂	25	100	N₂吹扫	TGA	2.16	0.22	[24]
MCM-48+CTAB	40% PEI	纯CO₂	25	100	N₂吹扫	TGA	2.59	0.30	[24]
MCM-48	40% PEI	15% CO₂/N₂	50	100	N₂吹扫	固定床+质谱	1.01	0.10	[24]
MCM-48+CTAB	40% PEI	15% CO₂/N₂	50	100	N₂吹扫	固定床+质谱	1.54	0.18	[24]
MMSN	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	3.08	0.18	[25]
MMSN+CTAC	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	4.55	0.25	[25]
MMSN	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约3.4	N/A	[25]
MMSN+CTAC	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约4.6	N/A	[25]
MMSN	50% TEPA	0.04% CO₂/N₂	25	100	N₂吹扫	TGA	约2.5	N/A	[25]
MMSN+CTAC	50% TEPA	0.04% CO₂/N₂	25	100	N₂吹扫	TGA	3.68	N/A	[25]
MMON	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	2.46	0.20	[26]
MMON+CTAC	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	2.78	0.22	[26]
MMON+CTAC+BTES	50% TEPA	纯CO₂	25	100	N₂吹扫	TGA	4.04	0.33	[26]
MMON	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约2.4	N/A	[26]
MMON+CTAC	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约2.6	N/A	[26]
MMON+CTAC+BTES	50% TEPA	15% CO₂/N₂	75	100	N₂吹扫	TGA	约3.6	N/A	[26]

载体	胺与添加剂组分	吸附气体氛围	吸附温度 /℃	脱附温度 /℃	脱附方式	测定方法	CO₂吸附量 /mmol·g^-1	胺效率（CO₂/N）	参考文献
MCM-41	30% PEI	纯CO₂	75	100	N₂吹扫	TGA	1.56	N/A	[27]
	30% PEI+20% PEG	纯CO₂	75	100	N₂吹扫	TGA	1.75	N/A	[27]
SBA-15	30% PEI	纯CO₂	70	100	N₂吹扫	TGA	约2	约0.27	[28]
	30% PEI+10% PEG200	纯CO₂	70	100	N₂吹扫	TGA	约2.68	约0.35	[28]
	20% PEI	纯CO₂	70	100	N₂吹扫	TGA	约1.36	约0.29	[28]
	20% PEI+20% PEG200	纯CO₂	70	100	N₂吹扫	TGA	约2.22	约0.43	[28]
	40% PEI	纯CO₂	70	100	N₂吹扫	TGA	约2.27	约0.27	[28]
SiO₂	25% TEPA	纯CO₂	25	100	真空	固定床	1.23	0.18	[18]
	25% TEPA+25% PEG200	纯CO₂	25	100	真空	固定床	2.44	0.37	[18]
	25% TEPA+25% PEG600	纯CO₂	25	100	真空	固定床	1.81	0.27	[18]
MSU-F	70% TEPA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	4.17	0.23	[40]
	40% TEPA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	3.13	0.30	[40]
	40% TEPA+30% PEG	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	3.32	0.31	[40]
SiO₂	TEPA	15% CO₂/Ar	55	115	Ar吹扫	固定床+质谱	2.09	N/A	[29]
	TEPA+PEG200	15% CO₂/Ar	55	115	Ar吹扫	固定床+质谱	1.11	N/A	[29]
SiO₂	40% PEI	10% CO₂/He	25	95	He吹扫	固定床+质谱	1.58	N/A	[31]
	36% PEI+4% PEG200	10% CO₂/He	25	95	He吹扫	固定床+质谱	1.46	N/A	[31]
多孔SiO₂	30% TEPA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	1.89	约0.25	[41]
	40% TEPA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	2.81	约0.26	[41]
	50% TEPA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	1.42	约0.11	[41]
	30% TEPA+20%PEG4000	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	1.78	约0.24	[41]
	30% TEPA+20% PEG400	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	2.5	约0.34	[41]
多孔氧化硅(HPS)	65% PEI	纯CO₂	75	110	N₂吹扫	TGA	3.93	N/A	[32]
	65% PEI+5% DTAB	纯CO₂	75	110	N₂吹扫	TGA	4.32	N/A	[32]
	65% PEI+5% CTAB	纯CO₂	75	110	N₂吹扫	TGA	4.35	N/A	[32]
	65% PEI+5% SATB	纯CO₂	75	110	N₂吹扫	TGA	4.59	N/A	[32]
	65% PEI+ 5% SDBS	纯CO₂	75	110	N₂吹扫	TGA	4.39	N/A	[32]
	65% PEI+ 5% SDS	纯CO₂	75	110	N₂吹扫	TGA	4.20	N/A	[32]
	65% PEI+ 5% PC	纯CO₂	75	110	N₂吹扫	TGA	4.37	N/A	[32]
	65% PEI+ 5% F127	纯CO₂	75	110	N₂吹扫	TGA	4.36	N/A	[32]
	65% PEI+ 5% P123	纯CO₂	75	110	N₂吹扫	TGA	4.24	N/A	[32]
	65% PEI+ 5% Span80	纯CO₂	75	110	N₂吹扫	TGA	4.61	N/A	[32]
介孔碳	60% PEI	纯CO₂	30	110	N₂吹扫	TGA	3.82	N/A	[33]
	60% PEI+5% DTAB	纯CO₂	30	110	N₂吹扫	TGA	约4.35	N/A	[33]
	60% PEI+5% CTAB	纯CO₂	30	110	N₂吹扫	TGA	约4.32	N/A	[33]
	60% PEI+5% SATB	纯CO₂	30	110	N₂吹扫	TGA	约4.20	N/A	[33]
	60% PEI+5% SDS	纯CO₂	30	110	N₂吹扫	TGA	4.67	N/A	[33]
	60% PEI+5% PC	纯CO₂	30	110	N₂吹扫	TGA	约4.32	N/A	[33]
	60% PEI+5% Span 80	纯CO₂	30	110	N₂吹扫	TGA	约4.35	N/A	[33]
	60% PEI+5% F127	纯CO₂	30	110	N₂吹扫	TGA	约4.35	N/A	[33]
	60% PEI+5% X100	纯CO₂	30	110	N₂吹扫	TGA	约4.13	N/A	[33]
介孔碳	50% PEI（M_n≈10000）	15% CO₂/ N₂	75	110	N₂吹扫	TGA	约2.39	N/A	[36]
	50% PEI（M_n≈10000）+ 20% PEG（M_n≈6000）	15% CO₂/ N₂	75	110	N₂吹扫	TGA	约3.07	N/A	[36]
树脂 (HP2MGL)	50% PEI	0.5% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.13	N/A	[35]
	50% PEI+5% Span 80	0.5% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.81	N/A	[35]
	50% PEI+5% CTAB	0.5% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.82	N/A	[35]
	50% PEI+5% PEG	0.5% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.64	N/A	[35]
	50% PEI	0.04% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约1.90	N/A	[35]
	50% PEI+5% Span 80	0.04% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.08	N/A	[35]
	50% PEI+5% CTAB	0.04% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.08	N/A	[35]
	50% PEI+5% PEG	0.04% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约1.99	N/A	[35]
介孔碳	55% PEI	0.5% CO₂/N₂	25	110	N₂吹扫	固定床+气相色谱	2.53	NA	[34]
	55% PEI+ 5% Span 80	0.5% CO₂/N₂	25	110	N₂吹扫	固定床+气相色谱	3.34	NA	[34]
	55% PEI	0.04% CO₂/N₂	25	110	N₂吹扫	固定床+气相色谱	约1.5	NA	[34]
	55% PEI+ 5% Span 80	0.04% CO₂/N₂	25	110	N₂吹扫	固定床+气相色谱	2.25	NA	[34]
SBA-15	PEI	0.04% CO₂/He	30	110	He吹扫	TGA	0.63	0.10	[37]
	PEI+CTAB	0.04% CO₂/He	30	110	He吹扫	TGA	0.55	0.10	[37]
	PEI+PEG200	0.04% CO₂/He	30	110	He吹扫	TGA	0.73	0.10	[37]
	PEI+PEG1000	0.04% CO₂/He	30	110	He吹扫	TGA	0.71	0.10	[37]
SBA-15	40% TEPA	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.74	0.17	[38]
	40% TEPA+10% PEG200	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	2.03	0.22	[38]
	40% TEPA+10% P123	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.60	0.18	[38]
	40% TEPA+10% Span80	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.42	0.17	[38]
	40% TEPA+10% SDS	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.52	0.17	[38]
	40% TEPA+10% CTAB	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.39	0.15	[38]
	40% TEPA+10% PC	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.56	1.75	[38]
SBA-15	45% PEI	9.5% CO₂/ N₂	75	105	N₂吹扫	固定床+CO₂分析仪	约1.80	约0.17	[39]
	45% PEI+5% TEP	9.5% CO₂/ N₂	75	105	N₂吹扫	固定床+CO₂分析仪	约1.90	约0.20	[39]
	45% PEI+5% BEP	9.5% CO₂/ N₂	75	105	N₂吹扫	固定床+CO₂分析仪	约1.70	NA	[39]

载体	胺与添加剂组分	吸附气体氛围	吸附温度 /℃	脱附温度 /℃	脱附方式	测定方法	CO₂吸附量 /mmol·g^-1	胺效率（CO₂/N）	参考文献
MCM-41	30% PEI	纯CO₂	75	100	N₂吹扫	TGA	1.56	N/A	[27]
	30% PEI+20% PEG	纯CO₂	75	100	N₂吹扫	TGA	1.75	N/A	[27]
SBA-15	30% PEI	纯CO₂	70	100	N₂吹扫	TGA	约2	约0.27	[28]
	30% PEI+10% PEG200	纯CO₂	70	100	N₂吹扫	TGA	约2.68	约0.35	[28]
	20% PEI	纯CO₂	70	100	N₂吹扫	TGA	约1.36	约0.29	[28]
	20% PEI+20% PEG200	纯CO₂	70	100	N₂吹扫	TGA	约2.22	约0.43	[28]
	40% PEI	纯CO₂	70	100	N₂吹扫	TGA	约2.27	约0.27	[28]
SiO₂	25% TEPA	纯CO₂	25	100	真空	固定床	1.23	0.18	[18]
	25% TEPA+25% PEG200	纯CO₂	25	100	真空	固定床	2.44	0.37	[18]
	25% TEPA+25% PEG600	纯CO₂	25	100	真空	固定床	1.81	0.27	[18]
MSU-F	70% TEPA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	4.17	0.23	[40]
	40% TEPA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	3.13	0.30	[40]
	40% TEPA+30% PEG	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	3.32	0.31	[40]
SiO₂	TEPA	15% CO₂/Ar	55	115	Ar吹扫	固定床+质谱	2.09	N/A	[29]
	TEPA+PEG200	15% CO₂/Ar	55	115	Ar吹扫	固定床+质谱	1.11	N/A	[29]
SiO₂	40% PEI	10% CO₂/He	25	95	He吹扫	固定床+质谱	1.58	N/A	[31]
	36% PEI+4% PEG200	10% CO₂/He	25	95	He吹扫	固定床+质谱	1.46	N/A	[31]
多孔SiO₂	30% TEPA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	1.89	约0.25	[41]
	40% TEPA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	2.81	约0.26	[41]
	50% TEPA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	1.42	约0.11	[41]
	30% TEPA+20%PEG4000	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	1.78	约0.24	[41]
	30% TEPA+20% PEG400	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	2.5	约0.34	[41]
多孔氧化硅(HPS)	65% PEI	纯CO₂	75	110	N₂吹扫	TGA	3.93	N/A	[32]
	65% PEI+5% DTAB	纯CO₂	75	110	N₂吹扫	TGA	4.32	N/A	[32]
	65% PEI+5% CTAB	纯CO₂	75	110	N₂吹扫	TGA	4.35	N/A	[32]
	65% PEI+5% SATB	纯CO₂	75	110	N₂吹扫	TGA	4.59	N/A	[32]
	65% PEI+ 5% SDBS	纯CO₂	75	110	N₂吹扫	TGA	4.39	N/A	[32]
	65% PEI+ 5% SDS	纯CO₂	75	110	N₂吹扫	TGA	4.20	N/A	[32]
	65% PEI+ 5% PC	纯CO₂	75	110	N₂吹扫	TGA	4.37	N/A	[32]
	65% PEI+ 5% F127	纯CO₂	75	110	N₂吹扫	TGA	4.36	N/A	[32]
	65% PEI+ 5% P123	纯CO₂	75	110	N₂吹扫	TGA	4.24	N/A	[32]
	65% PEI+ 5% Span80	纯CO₂	75	110	N₂吹扫	TGA	4.61	N/A	[32]
介孔碳	60% PEI	纯CO₂	30	110	N₂吹扫	TGA	3.82	N/A	[33]
	60% PEI+5% DTAB	纯CO₂	30	110	N₂吹扫	TGA	约4.35	N/A	[33]
	60% PEI+5% CTAB	纯CO₂	30	110	N₂吹扫	TGA	约4.32	N/A	[33]
	60% PEI+5% SATB	纯CO₂	30	110	N₂吹扫	TGA	约4.20	N/A	[33]
	60% PEI+5% SDS	纯CO₂	30	110	N₂吹扫	TGA	4.67	N/A	[33]
	60% PEI+5% PC	纯CO₂	30	110	N₂吹扫	TGA	约4.32	N/A	[33]
	60% PEI+5% Span 80	纯CO₂	30	110	N₂吹扫	TGA	约4.35	N/A	[33]
	60% PEI+5% F127	纯CO₂	30	110	N₂吹扫	TGA	约4.35	N/A	[33]
	60% PEI+5% X100	纯CO₂	30	110	N₂吹扫	TGA	约4.13	N/A	[33]
介孔碳	50% PEI（M_n≈10000）	15% CO₂/ N₂	75	110	N₂吹扫	TGA	约2.39	N/A	[36]
	50% PEI（M_n≈10000）+ 20% PEG（M_n≈6000）	15% CO₂/ N₂	75	110	N₂吹扫	TGA	约3.07	N/A	[36]
树脂 (HP2MGL)	50% PEI	0.5% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.13	N/A	[35]
	50% PEI+5% Span 80	0.5% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.81	N/A	[35]
	50% PEI+5% CTAB	0.5% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.82	N/A	[35]
	50% PEI+5% PEG	0.5% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.64	N/A	[35]
	50% PEI	0.04% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约1.90	N/A	[35]
	50% PEI+5% Span 80	0.04% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.08	N/A	[35]
	50% PEI+5% CTAB	0.04% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约2.08	N/A	[35]
	50% PEI+5% PEG	0.04% CO₂/N₂	25	100	N₂吹扫	固定床+气相色谱	约1.99	N/A	[35]
介孔碳	55% PEI	0.5% CO₂/N₂	25	110	N₂吹扫	固定床+气相色谱	2.53	NA	[34]
	55% PEI+ 5% Span 80	0.5% CO₂/N₂	25	110	N₂吹扫	固定床+气相色谱	3.34	NA	[34]
	55% PEI	0.04% CO₂/N₂	25	110	N₂吹扫	固定床+气相色谱	约1.5	NA	[34]
	55% PEI+ 5% Span 80	0.04% CO₂/N₂	25	110	N₂吹扫	固定床+气相色谱	2.25	NA	[34]
SBA-15	PEI	0.04% CO₂/He	30	110	He吹扫	TGA	0.63	0.10	[37]
	PEI+CTAB	0.04% CO₂/He	30	110	He吹扫	TGA	0.55	0.10	[37]
	PEI+PEG200	0.04% CO₂/He	30	110	He吹扫	TGA	0.73	0.10	[37]
	PEI+PEG1000	0.04% CO₂/He	30	110	He吹扫	TGA	0.71	0.10	[37]
SBA-15	40% TEPA	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.74	0.17	[38]
	40% TEPA+10% PEG200	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	2.03	0.22	[38]
	40% TEPA+10% P123	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.60	0.18	[38]
	40% TEPA+10% Span80	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.42	0.17	[38]
	40% TEPA+10% SDS	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.52	0.17	[38]
	40% TEPA+10% CTAB	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.39	0.15	[38]
	40% TEPA+10% PC	0.04% CO₂/N₂	25	80	N₂吹扫	TGA	1.56	1.75	[38]
SBA-15	45% PEI	9.5% CO₂/ N₂	75	105	N₂吹扫	固定床+CO₂分析仪	约1.80	约0.17	[39]
	45% PEI+5% TEP	9.5% CO₂/ N₂	75	105	N₂吹扫	固定床+CO₂分析仪	约1.90	约0.20	[39]
	45% PEI+5% BEP	9.5% CO₂/ N₂	75	105	N₂吹扫	固定床+CO₂分析仪	约1.70	NA	[39]

载体	胺与添加剂组分	吸附气体氛围	吸附温度 /℃	脱附温度 /℃	脱附方式	测定方法	CO₂吸附量 /mmol·g^-1	胺效率（CO₂/N）	参考文献
SBA-15	50% TEPA	99.999% CO₂	75	100	N/A	固定床+气相色谱	3.23	约0.8	[44]
	30% TEPA+20% DEA	99.999% CO₂	75	100	N/A	固定床+气相色谱	3.70	约0.93	[44]
MSU-F	40% TEPA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	3.13	0.30	[40]
	70% TEPA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	4.17	0.23	[40]
	70% DEA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	3.38	0.51	[40]
	40% TEPA+30% DEA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	5.62	0.42	[40]
	40% TEPA+30% DEAP	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	5.13	0.41	[40]
	40% TEPA+30% MEA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	3.64	0.24	[40]
	40% TEPA+30% TEA	100kPa CO₂	40	N/A	真空脱附	CO₂吸附等温线	4.89	0.39	[40]
多孔SiO₂	30% TEPA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	1.89	约0.25	[41]
	50% TEPA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	1.42	约0.11	[41]
	30% TEPA+20% MEA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	2.74	约0.25	[41]
	30% TEPA+20% DEA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	3.75	约0.39	[41]
	30% TEPA+20% TEA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	3.25	约0.36	[41]
	30% TEPA+20% AMP	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	2.58	约0.26	[41]
	30%TEPA+20%AEEA	2% CO₂/Ar	25	80	Ar吹扫	固定床+气相色谱	2.89	约0.25	[41]
SBA-15	40% TEPA	0.04% CO₂	25	80	N/A	TGA	1.74	0.18	[38]
	40% TEPA+10% DEA	0.04% CO₂	25	80	N/A	TGA	2.24	0.22	[38]
SBA-15	50% PEI	0.04% CO₂	25	90	N/A	TGA	1.11	0.1	[48]
	25% PEI+25% DEA	0.04% CO₂	25	90	N/A	TGA	1.62	0.2	[48]
MCM-41	60% TEPA	15% CO₂/N₂	70	100	N₂吹扫	固定床+气相色谱	2.45	NA	[49]
	30% TEPA+30% AMP	15% CO₂/N₂	70	100	N₂吹扫	固定床+气相色谱	3.01	NA	[49]

添加剂改性固态胺吸附剂用于碳捕集的研究进展

Research progress on the improving effect of additives on supported amine adsorbents for carbon capture

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载体	胺与添加剂组分	吸附气体氛围	吸附温度 /℃	脱附温度 /℃	脱附方式	测定方法	CO₂吸附量 /mmol·g^-1	胺效率（CO₂/N）	参考文献
多孔氧化硅	50% PEI	0.04% CO₂/Ar	25	110	Ar吹扫	TGA	2.36	0.22	[50]
	50% PEI+APTES	0.04% CO₂/Ar	25	110	Ar吹扫	TGA	2.26	0.21	[50]
氧化硅	50% PEI	10% CO₂/He	60	105	He吹扫	固定床+质谱	3.2	0.29	[51]
	35% PEI+15% APTES	10% CO₂/He	60	105	He吹扫	固定床+质谱	2.9	0.33	[51]
	25% PEI+25% APTES	10% CO₂/He	60	105	He吹扫	固定床+质谱	2.8	0.37	[51]
	15% PEI+35% APTES	10% CO₂/He	60	105	He吹扫	固定床+质谱	2.2	0.37	[51]
MCF	70% PEI	纯CO₂	30	100	N₂吹扫	固定床+气相色谱	约0.8	约0.06	[52]
	50% PEI+20% APTMS	纯CO₂	30	100	N₂吹扫	固定床+气相色谱	约1.3	0.12	[52]
氧化硅	40% PEI800	85% CO₂/N₂	40	105	N₂吹扫	TGA	2.81	0.45	[54]
	12% PEI800+28% TMPED	85% CO₂/N₂	40	105	N₂吹扫	TGA	2.1	0.46	[54]
	20% PEI800+20% TMPED	85% CO₂/N₂	40	105	N₂吹扫	TGA	2.5	0.5	[54]
	28% PEI800+12% TMPED	85%CO₂/N₂	40	105	N₂吹扫	TGA	2.81	0.5	[54]
	40% PEI2000	83%CO₂/N₂	40	105	N₂吹扫	TGA	2.7	N/A	[53]
	20% PEI2000+20% TMPED	83%CO₂/N₂	40	105	N₂吹扫	TGA	2.4	N/A	[53]
孔增大SBA-15	30% TEPA	100kPa CO₂	45	N/A	N/A	等温吸附线	2.16	0.32	[55]
	30% (TEPA+APTMS)	100kPa CO₂	45	N/A	N/A	等温吸附线	3.16	0.40	[55]
	30% (TEPA+DT)	100kPa CO₂	45	N/A	N/A	等温吸附线	3.89	0.42	[55]
	50% TEPA	100kPa CO₂	45	N/A	N/A	等温吸附线	3.73	0.37	[55]
	50% (TEPA+APTMS)	100kPa CO₂	45	N/A	N/A	等温吸附线	4.89	0.45	[55]
	30% PEI	100kPa CO₂	45	N/A	N/A	等温吸附线	1.83	0.28	[55]
	30% (PEI+APTMS)	100kPa CO₂	45	N/A	N/A	等温吸附线	2.53	0.33	[55]
MCM-41	60% TEPA	15% CO₂/N₂	70	100	N₂吹扫	固定床+气相色谱	2.45	NA	[56]
	30% APTES+40% TEPA	15% CO₂/N₂	70	100	N₂吹扫	固定床+气相色谱	3.45	NA	[56]

载体	胺+添加剂组分	吸附气体氛围	吸附温度 /℃	脱附温度 /℃	脱附方式	测定方法	CO₂吸附量 /mmol·g^-1	胺效率（CO₂/N）	参考文献
气相氧化硅	40% PEI	15% CO₂/He	75	120	He吹扫	固定床+气相色谱	2.38	约0.26	[60]
	40% PEI+ 6% K₂CO₃	15% CO₂/He	75	120	He吹扫	固定床+气相色谱	2.64	约0.28	[60]
	40% PEI	15% CO₂, 4.5% O₂/N₂	75	120	He吹扫	固定床+气相色谱	2.07	约0.26	[60]
	40% PEI+ 6% K₂CO₃	15% CO₂, 4.5% O₂/ N₂	75	120	He吹扫	固定床+气相色谱	2.75	约0.30	[60]
	40% PEI	15% CO₂, 4.5% O₂/N₂+3% H₂O	75	120	He吹扫	固定床+气相色谱	2.36	约0.26	[60]
	40% PEI+ 6% K₂CO₃	15% CO₂, 4.5% O₂/N₂+3% H₂O	75	120	He吹扫	固定床+气相色谱	2.75	约0.30	[60]
SBA-15	50% TEPA	0.044% CO₂/Air (50% RH)	30	90	N₂吹扫	固定床+ CO₂分析仪	4.81	0.36	[61]
	+4.5% NaNO₃	0.044% CO₂/Air (50% RH)	30	90	N₂吹扫	固定床+ CO₂分析仪	6.28	NA	[61]
	+4.5% KNO₃	0.044% CO₂/Air (50% RH)	30	90	N₂吹扫	固定床+ CO₂分析仪	6.24	NA	[61]
	+4.5% Zr(NO₃)₄	0.044% CO₂/Air (50% RH)	30	90	N₂吹扫	固定床+ CO₂分析仪	6.10	NA	[61]
	+4.5% Al(NO₃)₃	0.044% CO₂/Air (50% RH)	30	90	N₂吹扫	固定床+ CO₂分析仪	约4.9	NA	[61]
	+4.5% Ca(NO₃)₃	0.044% CO₂/Air (50% RH)	30	90	N₂吹扫	固定床+ CO₂分析仪	约4.0	NA	[61]
	+4.5% Mg(NO₃)₂	0.044% CO₂/Air (50% RH)	30	90	N₂吹扫	固定床+ CO₂分析仪	约4.0	NA	[61]

载体	胺+添加剂组分	氧化条件	吸附条件	脱附条件	氧化稳定性评价	参考文献
二氧化硅微球	50% PEI（M_W≈1200）	20% O₂/N₂，120℃，24h	15% CO₂，3% H₂O，2% Ar/N₂，40˚C，30min	100% CO₂，120˚C，60min	吸附量损失81%	[69]
	50% (0.15 EB+PEI)	20% O₂/N₂，120℃，24h	15% CO₂，3% H₂O，2% Ar/N₂，40˚C，30min	100% CO₂，120˚C，60min	吸附量损失44%	[69]
	50% (0.37 EB+PEI)	20% O₂/N₂，120℃，24h	15% CO₂，3% H₂O，2% Ar/N₂，40˚C，30min	100% CO₂，120˚C，60min	吸附量损失20%	[69]
	50% (0.54 EB+PEI)	20% O₂/N₂，120℃，24h	15% CO₂，3% H₂O，2% Ar/N₂，40˚C，30min	100% CO₂，120˚C，60min	吸附量损失19%	[69]
二氧化硅微球	50% PEI (M_W≈1200)	3% O₂/N₂，110℃，24h	15% CO₂，10% H₂O，75% N₂，60℃，30min	100% CO₂，110℃，30min	吸附量损失52%	[70]
	50% (0.37 EB+PEI)	3% O₂/N₂，110℃，24h	15% CO₂，10% H₂O，75% N₂，60℃，30min	100% CO₂，110℃，30min	吸附量损失23%	[70]
氧化硅（Sipernat 50S）	50% TEPA	21% O₂/N₂，100℃，20h	95% CO₂/N₂，25/55/85℃，3h	N₂，110℃，30min	吸附量损失约90%	[72]
	TEPA-PO-1-2 (39% TEPA+22% PO)	21% O₂/N₂，100℃，20h	95% CO₂/N₂，25/55/85℃，3h	N₂，110℃，30min	吸附量分别损失16%（55℃），18%（85℃）	[72]
	50% PEHA	21% O₂/N₂，100℃，20h	95% CO₂/N₂，25/55/85℃，3h	N₂，110℃，30min	吸附量损失约90%	[72]
	PEHA-PO-1-2 (39% TEPA+22% PO)	21% O₂/N₂，100℃，20h	95% CO₂/N₂，25/55/85℃，3h	N₂，110℃，30min	吸附量分别损失16%（55℃），18%（85℃）	[72]

载体	胺	氧化条件	吸附条件	脱附条件	氧化稳定性评价	参考文献
MSU-F	30% TEPA	100% O₂，80℃，18~42h	100kPa CO₂，40℃	40℃，真空，6h	吸附量损失分别为54%（18h），79%（42h）	[75]
	30% TEPA+5% TDE	100% O₂，80℃，18~42h	100kPa CO₂，40℃	40℃，真空，6h	吸附量损失分别为约18%（18h），60%（42h）	[75]
	30% TEPA+5% HEDS	100% O₂，80℃，18~42h	100kPa CO₂，40℃	40℃，真空，6h	吸附量损失分别为约30%（18h），70%（42h）	[75]
	30% TEPA+5% DTDP	100% O₂，80℃，18~42h	100kPa CO₂，40℃	40℃，真空，6h	吸附量损失分别为约25%（18h），60%（42h）	[75]
MSU-F	30% PEI (M_n≈1200)	100% O₂，80℃，42h	100kPa CO₂，40℃	40℃，真空，6h	吸附量损失近60%	[75]
	30% PEI+5% TDE	100% O₂，80℃，42h	100kPa CO₂，40℃	40℃，真空，6h	吸附量损失近40%	[75]
	30% PEI+5% HEDS	100% O₂，80℃，42h	100kPa CO₂，40℃	40℃，真空，6h	吸附量损失近30%	[75]
	30% PEI+5% DTDP	100% O₂，80℃，42h	100kPa CO₂，40℃	40℃，真空，6h	吸附量损失近25%	[75]

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