化工进展 ›› 2024, Vol. 43 ›› Issue (5): 2739-2759.DOI: 10.16085/j.issn.1000-6613.2023-1831
• 二氧化碳捕集与资源化利用 • 上一篇
苗诒贺1(), 王耀祖1, 刘雨杭1, 朱炫灿2, 李佳3, 于立军1(
)
收稿日期:
2023-10-18
修回日期:
2024-02-27
出版日期:
2024-05-15
发布日期:
2024-06-15
通讯作者:
于立军
作者简介:
苗诒贺(1993—),男,助理研究员,研究方向为吸附法二氧化碳捕集。E-mail:miaoyihe@sjtu.edu.cn。
基金资助:
MIAO Yihe1(), WANG Yaozu1, LIU Yuhang1, ZHU Xuancan2, LI Jia3, YU Lijun1(
)
Received:
2023-10-18
Revised:
2024-02-27
Online:
2024-05-15
Published:
2024-06-15
Contact:
YU Lijun
摘要:
固态胺是固体吸附CO2捕集技术路线中的研究热点,是烟气碳捕集和直接空气碳捕集技术中最有应用前景的吸附剂材料,近年来受到广泛关注。目前,固态胺吸附剂的吸脱附性能以及热化学稳定性仍有较大提升空间。本文综述了近年来表面活性剂、胺类和无机物类,以及环氧化物、螯合剂和含硫化合物等添加剂对固态胺吸附剂吸附能力增强和热化学稳定性提升的研究成果。在此基础上,进一步介绍了不同种类添加剂对固态胺吸附剂的改性机理,总结了在不同碳捕集工况下添加剂对固态胺吸附剂的改性特点。尽管现有研究已经取得了一些进展,但添加剂改性固态胺吸附剂仍然面临挑战,尤其是目前尚未能充分实现增强固态胺吸附剂的吸附能力和热化学稳定性的双重目标。此外,鉴于不同碳捕集工况下气体成分显著不同,未来研究需要更加明晰不同碳捕集工况下添加剂对固态胺吸附剂吸脱附热力学、动力学以及热化学稳定性的影响,并根据具体碳捕集工况有针对性地设计添加剂改性方案。
中图分类号:
苗诒贺, 王耀祖, 刘雨杭, 朱炫灿, 李佳, 于立军. 添加剂改性固态胺吸附剂用于碳捕集的研究进展[J]. 化工进展, 2024, 43(5): 2739-2759.
MIAO Yihe, WANG Yaozu, LIU Yuhang, ZHU Xuancan, LI Jia, YU Lijun. Research progress on the improving effect of additives on supported amine adsorbents for carbon capture[J]. Chemical Industry and Engineering Progress, 2024, 43(5): 2739-2759.
载体与模板剂 | 胺组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
SBA-15 | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 3.23 | NA | [ |
SBA-15+P123 | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 3.27 | NA | [ |
MCM-41 | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 3.27 | NA | [ |
MCM-41+CTAB | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 4.80 | NA | [ |
MCM-41+DTAB | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 3.50 | NA | [ |
PE -MCM-41 | 55% PEI | 纯CO2 | 75 | 75 | N2吹扫 | TGA | 约4.38 | NA | [ |
PE -MCM-41+CTAB | 55% PEI | 纯CO2 | 75 | 75 | N2吹扫 | TGA | 约10.06 | NA | [ |
KIT-1 | 50% TEPA | 纯CO2 | 75 | 100 | N2吹扫 | TGA | 2.71 | 0.21 | [ |
KIT-1+CTAB | 50% TEPA | 纯CO2 | 75 | 100 | N2吹扫 | TGA | 4.19 | 0.36 | [ |
KIT-1 | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约2.3 | 约0.18 | [ |
KIT-1+CTAB | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约3.1 | 约0.27 | [ |
MCM-48 | 40% PEI | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 2.16 | 0.22 | [ |
MCM-48+CTAB | 40% PEI | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 2.59 | 0.30 | [ |
MCM-48 | 40% PEI | 15% CO2/N2 | 50 | 100 | N2吹扫 | 固定床+质谱 | 1.01 | 0.10 | [ |
MCM-48+CTAB | 40% PEI | 15% CO2/N2 | 50 | 100 | N2吹扫 | 固定床+质谱 | 1.54 | 0.18 | [ |
MMSN | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 3.08 | 0.18 | [ |
MMSN+CTAC | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 4.55 | 0.25 | [ |
MMSN | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约3.4 | N/A | [ |
MMSN+CTAC | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约4.6 | N/A | [ |
MMSN | 50% TEPA | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | TGA | 约2.5 | N/A | [ |
MMSN+CTAC | 50% TEPA | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | TGA | 3.68 | N/A | [ |
MMON | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 2.46 | 0.20 | [ |
MMON+CTAC | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 2.78 | 0.22 | [ |
MMON+CTAC+BTES | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 4.04 | 0.33 | [ |
MMON | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约2.4 | N/A | [ |
MMON+CTAC | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约2.6 | N/A | [ |
MMON+CTAC+BTES | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约3.6 | N/A | [ |
表1 表面活性剂(模板剂保留法)改性的固态胺吸附剂材料吸脱附性能汇总
载体与模板剂 | 胺组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
SBA-15 | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 3.23 | NA | [ |
SBA-15+P123 | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 3.27 | NA | [ |
MCM-41 | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 3.27 | NA | [ |
MCM-41+CTAB | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 4.80 | NA | [ |
MCM-41+DTAB | 50% TEPA | 纯CO2 | 75 | 100 | He吹扫 | 固定床+气相色谱 | 3.50 | NA | [ |
PE -MCM-41 | 55% PEI | 纯CO2 | 75 | 75 | N2吹扫 | TGA | 约4.38 | NA | [ |
PE -MCM-41+CTAB | 55% PEI | 纯CO2 | 75 | 75 | N2吹扫 | TGA | 约10.06 | NA | [ |
KIT-1 | 50% TEPA | 纯CO2 | 75 | 100 | N2吹扫 | TGA | 2.71 | 0.21 | [ |
KIT-1+CTAB | 50% TEPA | 纯CO2 | 75 | 100 | N2吹扫 | TGA | 4.19 | 0.36 | [ |
KIT-1 | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约2.3 | 约0.18 | [ |
KIT-1+CTAB | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约3.1 | 约0.27 | [ |
MCM-48 | 40% PEI | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 2.16 | 0.22 | [ |
MCM-48+CTAB | 40% PEI | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 2.59 | 0.30 | [ |
MCM-48 | 40% PEI | 15% CO2/N2 | 50 | 100 | N2吹扫 | 固定床+质谱 | 1.01 | 0.10 | [ |
MCM-48+CTAB | 40% PEI | 15% CO2/N2 | 50 | 100 | N2吹扫 | 固定床+质谱 | 1.54 | 0.18 | [ |
MMSN | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 3.08 | 0.18 | [ |
MMSN+CTAC | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 4.55 | 0.25 | [ |
MMSN | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约3.4 | N/A | [ |
MMSN+CTAC | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约4.6 | N/A | [ |
MMSN | 50% TEPA | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | TGA | 约2.5 | N/A | [ |
MMSN+CTAC | 50% TEPA | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | TGA | 3.68 | N/A | [ |
MMON | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 2.46 | 0.20 | [ |
MMON+CTAC | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 2.78 | 0.22 | [ |
MMON+CTAC+BTES | 50% TEPA | 纯CO2 | 25 | 100 | N2吹扫 | TGA | 4.04 | 0.33 | [ |
MMON | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约2.4 | N/A | [ |
MMON+CTAC | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约2.6 | N/A | [ |
MMON+CTAC+BTES | 50% TEPA | 15% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约3.6 | N/A | [ |
载体 | 胺与添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
MCM-41 | 30% PEI | 纯CO2 | 75 | 100 | N2吹扫 | TGA | 1.56 | N/A | [ |
30% PEI+20% PEG | 纯CO2 | 75 | 100 | N2吹扫 | TGA | 1.75 | N/A | [ | |
SBA-15 | 30% PEI | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约2 | 约0.27 | [ |
30% PEI+10% PEG200 | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约2.68 | 约0.35 | [ | |
20% PEI | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约1.36 | 约0.29 | [ | |
20% PEI+20% PEG200 | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约2.22 | 约0.43 | [ | |
40% PEI | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约2.27 | 约0.27 | [ | |
SiO2 | 25% TEPA | 纯CO2 | 25 | 100 | 真空 | 固定床 | 1.23 | 0.18 | [ |
25% TEPA+25% PEG200 | 纯CO2 | 25 | 100 | 真空 | 固定床 | 2.44 | 0.37 | [ | |
25% TEPA+25% PEG600 | 纯CO2 | 25 | 100 | 真空 | 固定床 | 1.81 | 0.27 | [ | |
MSU-F | 70% TEPA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 4.17 | 0.23 | [ |
40% TEPA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.13 | 0.30 | [ | |
40% TEPA+30% PEG | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.32 | 0.31 | [ | |
SiO2 | TEPA | 15% CO2/Ar | 55 | 115 | Ar吹扫 | 固定床+质谱 | 2.09 | N/A | [ |
TEPA+PEG200 | 15% CO2/Ar | 55 | 115 | Ar吹扫 | 固定床+质谱 | 1.11 | N/A | [ | |
SiO2 | 40% PEI | 10% CO2/He | 25 | 95 | He吹扫 | 固定床+质谱 | 1.58 | N/A | [ |
36% PEI+4% PEG200 | 10% CO2/He | 25 | 95 | He吹扫 | 固定床+质谱 | 1.46 | N/A | [ | |
多孔SiO2 | 30% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.89 | 约0.25 | [ |
40% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.81 | 约0.26 | [ | |
50% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.42 | 约0.11 | [ | |
30% TEPA+20%PEG4000 | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.78 | 约0.24 | [ | |
30% TEPA+20% PEG400 | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.5 | 约0.34 | [ | |
多孔氧化硅(HPS) | 65% PEI | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 3.93 | N/A | [ |
65% PEI+5% DTAB | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.32 | N/A | [ | |
65% PEI+5% CTAB | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.35 | N/A | [ | |
65% PEI+5% SATB | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.59 | N/A | [ | |
65% PEI+ 5% SDBS | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.39 | N/A | [ | |
65% PEI+ 5% SDS | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.20 | N/A | [ | |
65% PEI+ 5% PC | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.37 | N/A | [ | |
65% PEI+ 5% F127 | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.36 | N/A | [ | |
65% PEI+ 5% P123 | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.24 | N/A | [ | |
65% PEI+ 5% Span80 | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.61 | N/A | [ | |
介孔碳 | 60% PEI | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 3.82 | N/A | [ |
60% PEI+5% DTAB | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.35 | N/A | [ | |
60% PEI+5% CTAB | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.32 | N/A | [ | |
60% PEI+5% SATB | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.20 | N/A | [ | |
60% PEI+5% SDS | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 4.67 | N/A | [ | |
60% PEI+5% PC | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.32 | N/A | [ | |
60% PEI+5% Span 80 | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.35 | N/A | [ | |
60% PEI+5% F127 | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.35 | N/A | [ | |
60% PEI+5% X100 | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.13 | N/A | [ | |
介孔碳 | 50% PEI(Mn≈10000) | 15% CO2/ N2 | 75 | 110 | N2吹扫 | TGA | 约2.39 | N/A | [ |
50% PEI(Mn≈10000)+ 20% PEG(Mn≈6000) | 15% CO2/ N2 | 75 | 110 | N2吹扫 | TGA | 约3.07 | N/A | [ | |
树脂 (HP2MGL) | 50% PEI | 0.5% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.13 | N/A | [ |
50% PEI+5% Span 80 | 0.5% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.81 | N/A | [ | |
50% PEI+5% CTAB | 0.5% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.82 | N/A | [ | |
50% PEI+5% PEG | 0.5% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.64 | N/A | [ | |
50% PEI | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约1.90 | N/A | [ | |
50% PEI+5% Span 80 | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.08 | N/A | [ | |
50% PEI+5% CTAB | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.08 | N/A | [ | |
50% PEI+5% PEG | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约1.99 | N/A | [ | |
介孔碳 | 55% PEI | 0.5% CO2/N2 | 25 | 110 | N2吹扫 | 固定床+气相色谱 | 2.53 | NA | [ |
55% PEI+ 5% Span 80 | 0.5% CO2/N2 | 25 | 110 | N2吹扫 | 固定床+气相色谱 | 3.34 | NA | [ | |
55% PEI | 0.04% CO2/N2 | 25 | 110 | N2吹扫 | 固定床+气相色谱 | 约1.5 | NA | [ | |
55% PEI+ 5% Span 80 | 0.04% CO2/N2 | 25 | 110 | N2吹扫 | 固定床+气相色谱 | 2.25 | NA | [ | |
SBA-15 | PEI | 0.04% CO2/He | 30 | 110 | He吹扫 | TGA | 0.63 | 0.10 | [ |
PEI+CTAB | 0.04% CO2/He | 30 | 110 | He吹扫 | TGA | 0.55 | 0.10 | [ | |
PEI+PEG200 | 0.04% CO2/He | 30 | 110 | He吹扫 | TGA | 0.73 | 0.10 | [ | |
PEI+PEG1000 | 0.04% CO2/He | 30 | 110 | He吹扫 | TGA | 0.71 | 0.10 | [ | |
SBA-15 | 40% TEPA | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.74 | 0.17 | [ |
40% TEPA+10% PEG200 | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 2.03 | 0.22 | [ | |
40% TEPA+10% P123 | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.60 | 0.18 | [ | |
40% TEPA+10% Span80 | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.42 | 0.17 | [ | |
40% TEPA+10% SDS | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.52 | 0.17 | [ | |
40% TEPA+10% CTAB | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.39 | 0.15 | [ | |
40% TEPA+10% PC | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.56 | 1.75 | [ | |
SBA-15 | 45% PEI | 9.5% CO2/ N2 | 75 | 105 | N2吹扫 | 固定床+CO2分析仪 | 约1.80 | 约0.17 | [ |
45% PEI+5% TEP | 9.5% CO2/ N2 | 75 | 105 | N2吹扫 | 固定床+CO2分析仪 | 约1.90 | 约0.20 | [ | |
45% PEI+5% BEP | 9.5% CO2/ N2 | 75 | 105 | N2吹扫 | 固定床+CO2分析仪 | 约1.70 | NA | [ |
表2 表面活性剂(浸渍法)改性的固态胺吸附剂材料吸脱附性能汇总
载体 | 胺与添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
MCM-41 | 30% PEI | 纯CO2 | 75 | 100 | N2吹扫 | TGA | 1.56 | N/A | [ |
30% PEI+20% PEG | 纯CO2 | 75 | 100 | N2吹扫 | TGA | 1.75 | N/A | [ | |
SBA-15 | 30% PEI | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约2 | 约0.27 | [ |
30% PEI+10% PEG200 | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约2.68 | 约0.35 | [ | |
20% PEI | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约1.36 | 约0.29 | [ | |
20% PEI+20% PEG200 | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约2.22 | 约0.43 | [ | |
40% PEI | 纯CO2 | 70 | 100 | N2吹扫 | TGA | 约2.27 | 约0.27 | [ | |
SiO2 | 25% TEPA | 纯CO2 | 25 | 100 | 真空 | 固定床 | 1.23 | 0.18 | [ |
25% TEPA+25% PEG200 | 纯CO2 | 25 | 100 | 真空 | 固定床 | 2.44 | 0.37 | [ | |
25% TEPA+25% PEG600 | 纯CO2 | 25 | 100 | 真空 | 固定床 | 1.81 | 0.27 | [ | |
MSU-F | 70% TEPA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 4.17 | 0.23 | [ |
40% TEPA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.13 | 0.30 | [ | |
40% TEPA+30% PEG | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.32 | 0.31 | [ | |
SiO2 | TEPA | 15% CO2/Ar | 55 | 115 | Ar吹扫 | 固定床+质谱 | 2.09 | N/A | [ |
TEPA+PEG200 | 15% CO2/Ar | 55 | 115 | Ar吹扫 | 固定床+质谱 | 1.11 | N/A | [ | |
SiO2 | 40% PEI | 10% CO2/He | 25 | 95 | He吹扫 | 固定床+质谱 | 1.58 | N/A | [ |
36% PEI+4% PEG200 | 10% CO2/He | 25 | 95 | He吹扫 | 固定床+质谱 | 1.46 | N/A | [ | |
多孔SiO2 | 30% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.89 | 约0.25 | [ |
40% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.81 | 约0.26 | [ | |
50% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.42 | 约0.11 | [ | |
30% TEPA+20%PEG4000 | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.78 | 约0.24 | [ | |
30% TEPA+20% PEG400 | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.5 | 约0.34 | [ | |
多孔氧化硅(HPS) | 65% PEI | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 3.93 | N/A | [ |
65% PEI+5% DTAB | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.32 | N/A | [ | |
65% PEI+5% CTAB | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.35 | N/A | [ | |
65% PEI+5% SATB | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.59 | N/A | [ | |
65% PEI+ 5% SDBS | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.39 | N/A | [ | |
65% PEI+ 5% SDS | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.20 | N/A | [ | |
65% PEI+ 5% PC | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.37 | N/A | [ | |
65% PEI+ 5% F127 | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.36 | N/A | [ | |
65% PEI+ 5% P123 | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.24 | N/A | [ | |
65% PEI+ 5% Span80 | 纯CO2 | 75 | 110 | N2吹扫 | TGA | 4.61 | N/A | [ | |
介孔碳 | 60% PEI | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 3.82 | N/A | [ |
60% PEI+5% DTAB | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.35 | N/A | [ | |
60% PEI+5% CTAB | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.32 | N/A | [ | |
60% PEI+5% SATB | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.20 | N/A | [ | |
60% PEI+5% SDS | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 4.67 | N/A | [ | |
60% PEI+5% PC | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.32 | N/A | [ | |
60% PEI+5% Span 80 | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.35 | N/A | [ | |
60% PEI+5% F127 | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.35 | N/A | [ | |
60% PEI+5% X100 | 纯CO2 | 30 | 110 | N2吹扫 | TGA | 约4.13 | N/A | [ | |
介孔碳 | 50% PEI(Mn≈10000) | 15% CO2/ N2 | 75 | 110 | N2吹扫 | TGA | 约2.39 | N/A | [ |
50% PEI(Mn≈10000)+ 20% PEG(Mn≈6000) | 15% CO2/ N2 | 75 | 110 | N2吹扫 | TGA | 约3.07 | N/A | [ | |
树脂 (HP2MGL) | 50% PEI | 0.5% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.13 | N/A | [ |
50% PEI+5% Span 80 | 0.5% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.81 | N/A | [ | |
50% PEI+5% CTAB | 0.5% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.82 | N/A | [ | |
50% PEI+5% PEG | 0.5% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.64 | N/A | [ | |
50% PEI | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约1.90 | N/A | [ | |
50% PEI+5% Span 80 | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.08 | N/A | [ | |
50% PEI+5% CTAB | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约2.08 | N/A | [ | |
50% PEI+5% PEG | 0.04% CO2/N2 | 25 | 100 | N2吹扫 | 固定床+气相色谱 | 约1.99 | N/A | [ | |
介孔碳 | 55% PEI | 0.5% CO2/N2 | 25 | 110 | N2吹扫 | 固定床+气相色谱 | 2.53 | NA | [ |
55% PEI+ 5% Span 80 | 0.5% CO2/N2 | 25 | 110 | N2吹扫 | 固定床+气相色谱 | 3.34 | NA | [ | |
55% PEI | 0.04% CO2/N2 | 25 | 110 | N2吹扫 | 固定床+气相色谱 | 约1.5 | NA | [ | |
55% PEI+ 5% Span 80 | 0.04% CO2/N2 | 25 | 110 | N2吹扫 | 固定床+气相色谱 | 2.25 | NA | [ | |
SBA-15 | PEI | 0.04% CO2/He | 30 | 110 | He吹扫 | TGA | 0.63 | 0.10 | [ |
PEI+CTAB | 0.04% CO2/He | 30 | 110 | He吹扫 | TGA | 0.55 | 0.10 | [ | |
PEI+PEG200 | 0.04% CO2/He | 30 | 110 | He吹扫 | TGA | 0.73 | 0.10 | [ | |
PEI+PEG1000 | 0.04% CO2/He | 30 | 110 | He吹扫 | TGA | 0.71 | 0.10 | [ | |
SBA-15 | 40% TEPA | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.74 | 0.17 | [ |
40% TEPA+10% PEG200 | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 2.03 | 0.22 | [ | |
40% TEPA+10% P123 | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.60 | 0.18 | [ | |
40% TEPA+10% Span80 | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.42 | 0.17 | [ | |
40% TEPA+10% SDS | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.52 | 0.17 | [ | |
40% TEPA+10% CTAB | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.39 | 0.15 | [ | |
40% TEPA+10% PC | 0.04% CO2/N2 | 25 | 80 | N2吹扫 | TGA | 1.56 | 1.75 | [ | |
SBA-15 | 45% PEI | 9.5% CO2/ N2 | 75 | 105 | N2吹扫 | 固定床+CO2分析仪 | 约1.80 | 约0.17 | [ |
45% PEI+5% TEP | 9.5% CO2/ N2 | 75 | 105 | N2吹扫 | 固定床+CO2分析仪 | 约1.90 | 约0.20 | [ | |
45% PEI+5% BEP | 9.5% CO2/ N2 | 75 | 105 | N2吹扫 | 固定床+CO2分析仪 | 约1.70 | NA | [ |
载体 | 胺与添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率(CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
SBA-15 | 50% TEPA | 99.999% CO2 | 75 | 100 | N/A | 固定床+气相色谱 | 3.23 | 约0.8 | [ |
30% TEPA+20% DEA | 99.999% CO2 | 75 | 100 | N/A | 固定床+气相色谱 | 3.70 | 约0.93 | [ | |
MSU-F | 40% TEPA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.13 | 0.30 | [ |
70% TEPA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 4.17 | 0.23 | [ | |
70% DEA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.38 | 0.51 | [ | |
40% TEPA+30% DEA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 5.62 | 0.42 | [ | |
40% TEPA+30% DEAP | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 5.13 | 0.41 | [ | |
40% TEPA+30% MEA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.64 | 0.24 | [ | |
40% TEPA+30% TEA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 4.89 | 0.39 | [ | |
多孔SiO2 | 30% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.89 | 约0.25 | [ |
50% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.42 | 约0.11 | [ | |
30% TEPA+20% MEA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.74 | 约0.25 | [ | |
30% TEPA+20% DEA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 3.75 | 约0.39 | [ | |
30% TEPA+20% TEA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 3.25 | 约0.36 | [ | |
30% TEPA+20% AMP | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.58 | 约0.26 | [ | |
30%TEPA+20%AEEA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.89 | 约0.25 | [ | |
SBA-15 | 40% TEPA | 0.04% CO2 | 25 | 80 | N/A | TGA | 1.74 | 0.18 | [ |
40% TEPA+10% DEA | 0.04% CO2 | 25 | 80 | N/A | TGA | 2.24 | 0.22 | [ | |
SBA-15 | 50% PEI | 0.04% CO2 | 25 | 90 | N/A | TGA | 1.11 | 0.1 | [ |
25% PEI+25% DEA | 0.04% CO2 | 25 | 90 | N/A | TGA | 1.62 | 0.2 | [ | |
MCM-41 | 60% TEPA | 15% CO2/N2 | 70 | 100 | N2吹扫 | 固定床+气相色谱 | 2.45 | NA | [ |
30% TEPA+30% AMP | 15% CO2/N2 | 70 | 100 | N2吹扫 | 固定床+气相色谱 | 3.01 | NA | [ |
表3 烷醇胺添加剂(浸渍法引入)改性的固态胺吸附剂材料吸脱附性能汇总
载体 | 胺与添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率(CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
SBA-15 | 50% TEPA | 99.999% CO2 | 75 | 100 | N/A | 固定床+气相色谱 | 3.23 | 约0.8 | [ |
30% TEPA+20% DEA | 99.999% CO2 | 75 | 100 | N/A | 固定床+气相色谱 | 3.70 | 约0.93 | [ | |
MSU-F | 40% TEPA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.13 | 0.30 | [ |
70% TEPA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 4.17 | 0.23 | [ | |
70% DEA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.38 | 0.51 | [ | |
40% TEPA+30% DEA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 5.62 | 0.42 | [ | |
40% TEPA+30% DEAP | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 5.13 | 0.41 | [ | |
40% TEPA+30% MEA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 3.64 | 0.24 | [ | |
40% TEPA+30% TEA | 100kPa CO2 | 40 | N/A | 真空脱附 | CO2吸附等温线 | 4.89 | 0.39 | [ | |
多孔SiO2 | 30% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.89 | 约0.25 | [ |
50% TEPA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 1.42 | 约0.11 | [ | |
30% TEPA+20% MEA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.74 | 约0.25 | [ | |
30% TEPA+20% DEA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 3.75 | 约0.39 | [ | |
30% TEPA+20% TEA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 3.25 | 约0.36 | [ | |
30% TEPA+20% AMP | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.58 | 约0.26 | [ | |
30%TEPA+20%AEEA | 2% CO2/Ar | 25 | 80 | Ar吹扫 | 固定床+气相色谱 | 2.89 | 约0.25 | [ | |
SBA-15 | 40% TEPA | 0.04% CO2 | 25 | 80 | N/A | TGA | 1.74 | 0.18 | [ |
40% TEPA+10% DEA | 0.04% CO2 | 25 | 80 | N/A | TGA | 2.24 | 0.22 | [ | |
SBA-15 | 50% PEI | 0.04% CO2 | 25 | 90 | N/A | TGA | 1.11 | 0.1 | [ |
25% PEI+25% DEA | 0.04% CO2 | 25 | 90 | N/A | TGA | 1.62 | 0.2 | [ | |
MCM-41 | 60% TEPA | 15% CO2/N2 | 70 | 100 | N2吹扫 | 固定床+气相色谱 | 2.45 | NA | [ |
30% TEPA+30% AMP | 15% CO2/N2 | 70 | 100 | N2吹扫 | 固定床+气相色谱 | 3.01 | NA | [ |
载体 | 胺与添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
多孔氧化硅 | 50% PEI | 0.04% CO2/Ar | 25 | 110 | Ar吹扫 | TGA | 2.36 | 0.22 | [ |
50% PEI+APTES | 0.04% CO2/Ar | 25 | 110 | Ar吹扫 | TGA | 2.26 | 0.21 | [ | |
氧化硅 | 50% PEI | 10% CO2/He | 60 | 105 | He吹扫 | 固定床+质谱 | 3.2 | 0.29 | [ |
35% PEI+15% APTES | 10% CO2/He | 60 | 105 | He吹扫 | 固定床+质谱 | 2.9 | 0.33 | [ | |
25% PEI+25% APTES | 10% CO2/He | 60 | 105 | He吹扫 | 固定床+质谱 | 2.8 | 0.37 | [ | |
15% PEI+35% APTES | 10% CO2/He | 60 | 105 | He吹扫 | 固定床+质谱 | 2.2 | 0.37 | [ | |
MCF | 70% PEI | 纯CO2 | 30 | 100 | N2吹扫 | 固定床+气相色谱 | 约0.8 | 约0.06 | [ |
50% PEI+20% APTMS | 纯CO2 | 30 | 100 | N2吹扫 | 固定床+气相色谱 | 约1.3 | 0.12 | [ | |
氧化硅 | 40% PEI800 | 85% CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.81 | 0.45 | [ |
12% PEI800+28% TMPED | 85% CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.1 | 0.46 | [ | |
20% PEI800+20% TMPED | 85% CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.5 | 0.5 | [ | |
28% PEI800+12% TMPED | 85%CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.81 | 0.5 | [ | |
40% PEI2000 | 83%CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.7 | N/A | [ | |
20% PEI2000+20% TMPED | 83%CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.4 | N/A | [ | |
孔增大SBA-15 | 30% TEPA | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 2.16 | 0.32 | [ |
30% (TEPA+APTMS) | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 3.16 | 0.40 | [ | |
30% (TEPA+DT) | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 3.89 | 0.42 | [ | |
50% TEPA | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 3.73 | 0.37 | [ | |
50% (TEPA+APTMS) | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 4.89 | 0.45 | [ | |
30% PEI | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 1.83 | 0.28 | [ | |
30% (PEI+APTMS) | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 2.53 | 0.33 | [ | |
MCM-41 | 60% TEPA | 15% CO2/N2 | 70 | 100 | N2吹扫 | 固定床+气相色谱 | 2.45 | NA | [ |
30% APTES+40% TEPA | 15% CO2/N2 | 70 | 100 | N2吹扫 | 固定床+气相色谱 | 3.45 | NA | [ |
表4 氨基硅烷类添加剂改性的固态胺吸附剂材料吸脱附性能汇总
载体 | 胺与添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
多孔氧化硅 | 50% PEI | 0.04% CO2/Ar | 25 | 110 | Ar吹扫 | TGA | 2.36 | 0.22 | [ |
50% PEI+APTES | 0.04% CO2/Ar | 25 | 110 | Ar吹扫 | TGA | 2.26 | 0.21 | [ | |
氧化硅 | 50% PEI | 10% CO2/He | 60 | 105 | He吹扫 | 固定床+质谱 | 3.2 | 0.29 | [ |
35% PEI+15% APTES | 10% CO2/He | 60 | 105 | He吹扫 | 固定床+质谱 | 2.9 | 0.33 | [ | |
25% PEI+25% APTES | 10% CO2/He | 60 | 105 | He吹扫 | 固定床+质谱 | 2.8 | 0.37 | [ | |
15% PEI+35% APTES | 10% CO2/He | 60 | 105 | He吹扫 | 固定床+质谱 | 2.2 | 0.37 | [ | |
MCF | 70% PEI | 纯CO2 | 30 | 100 | N2吹扫 | 固定床+气相色谱 | 约0.8 | 约0.06 | [ |
50% PEI+20% APTMS | 纯CO2 | 30 | 100 | N2吹扫 | 固定床+气相色谱 | 约1.3 | 0.12 | [ | |
氧化硅 | 40% PEI800 | 85% CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.81 | 0.45 | [ |
12% PEI800+28% TMPED | 85% CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.1 | 0.46 | [ | |
20% PEI800+20% TMPED | 85% CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.5 | 0.5 | [ | |
28% PEI800+12% TMPED | 85%CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.81 | 0.5 | [ | |
40% PEI2000 | 83%CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.7 | N/A | [ | |
20% PEI2000+20% TMPED | 83%CO2/N2 | 40 | 105 | N2吹扫 | TGA | 2.4 | N/A | [ | |
孔增大SBA-15 | 30% TEPA | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 2.16 | 0.32 | [ |
30% (TEPA+APTMS) | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 3.16 | 0.40 | [ | |
30% (TEPA+DT) | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 3.89 | 0.42 | [ | |
50% TEPA | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 3.73 | 0.37 | [ | |
50% (TEPA+APTMS) | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 4.89 | 0.45 | [ | |
30% PEI | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 1.83 | 0.28 | [ | |
30% (PEI+APTMS) | 100kPa CO2 | 45 | N/A | N/A | 等温吸附线 | 2.53 | 0.33 | [ | |
MCM-41 | 60% TEPA | 15% CO2/N2 | 70 | 100 | N2吹扫 | 固定床+气相色谱 | 2.45 | NA | [ |
30% APTES+40% TEPA | 15% CO2/N2 | 70 | 100 | N2吹扫 | 固定床+气相色谱 | 3.45 | NA | [ |
载体 | 胺与添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
MSU-F | 70% TEPA | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 4.17 | 0.23 | [ |
40% TEPA+30% PZ | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 3.61 | NA | [ | |
40% TEPA+30% DBU | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 3.73 | NA | [ | |
40% TEPA+30% PEI | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 3.50 | NA | [ | |
硅胶 | 45% PEI | 10% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约2.80 | NA | [ |
45% PEI+5% PZ | 10% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约3.18 | NA | [ | |
MSU-F | 70% TEPA | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 4.17 | 0.24 | [ |
40% TEPA+30% 4MIm | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 4.88 | 0.46 | [ | |
MCF | 70% PEI | 纯CO2 | 30 | 100 | N2吹扫 | 固定床+气相色谱 | 约0.8 | 约0.06 | [ |
50% PEI+20% DETA | 纯CO2 | 30 | 100 | N2吹扫 | 固定床+气相色谱 | 约1.3 | 0.11 | [ |
表5 其他胺类添加剂(浸渍法引入)改性的固态胺吸附剂材料吸脱附性能汇总
载体 | 胺与添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
MSU-F | 70% TEPA | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 4.17 | 0.23 | [ |
40% TEPA+30% PZ | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 3.61 | NA | [ | |
40% TEPA+30% DBU | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 3.73 | NA | [ | |
40% TEPA+30% PEI | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 3.50 | NA | [ | |
硅胶 | 45% PEI | 10% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约2.80 | NA | [ |
45% PEI+5% PZ | 10% CO2/N2 | 75 | 100 | N2吹扫 | TGA | 约3.18 | NA | [ | |
MSU-F | 70% TEPA | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 4.17 | 0.24 | [ |
40% TEPA+30% 4MIm | 100kPa CO2 | 40 | NA | 真空脱附 | CO2吸附等温线 | 4.88 | 0.46 | [ | |
MCF | 70% PEI | 纯CO2 | 30 | 100 | N2吹扫 | 固定床+气相色谱 | 约0.8 | 约0.06 | [ |
50% PEI+20% DETA | 纯CO2 | 30 | 100 | N2吹扫 | 固定床+气相色谱 | 约1.3 | 0.11 | [ |
载体 | 胺+添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附 方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
气相氧化硅 | 40% PEI | 15% CO2/He | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.38 | 约0.26 | [ |
40% PEI+ 6% K2CO3 | 15% CO2/He | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.64 | 约0.28 | [ | |
40% PEI | 15% CO2, 4.5% O2/N2 | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.07 | 约0.26 | [ | |
40% PEI+ 6% K2CO3 | 15% CO2, 4.5% O2/ N2 | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.75 | 约0.30 | [ | |
40% PEI | 15% CO2, 4.5% O2/N2+3% H2O | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.36 | 约0.26 | [ | |
40% PEI+ 6% K2CO3 | 15% CO2, 4.5% O2/N2+3% H2O | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.75 | 约0.30 | [ | |
SBA-15 | 50% TEPA | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 4.81 | 0.36 | [ |
+4.5% NaNO3 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 6.28 | NA | [ | |
+4.5% KNO3 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 6.24 | NA | [ | |
+4.5% Zr(NO3)4 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 6.10 | NA | [ | |
+4.5% Al(NO3)3 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 约4.9 | NA | [ | |
+4.5% Ca(NO3)3 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 约4.0 | NA | [ | |
+4.5% Mg(NO3)2 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 约4.0 | NA | [ |
表6 无机物类添加剂改性的固态胺吸附剂材料吸脱附性能汇总
载体 | 胺+添加剂组分 | 吸附气体氛围 | 吸附温度 /℃ | 脱附温度 /℃ | 脱附 方式 | 测定方法 | CO2吸附量 /mmol·g-1 | 胺效率 (CO2/N) | 参考 文献 |
---|---|---|---|---|---|---|---|---|---|
气相氧化硅 | 40% PEI | 15% CO2/He | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.38 | 约0.26 | [ |
40% PEI+ 6% K2CO3 | 15% CO2/He | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.64 | 约0.28 | [ | |
40% PEI | 15% CO2, 4.5% O2/N2 | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.07 | 约0.26 | [ | |
40% PEI+ 6% K2CO3 | 15% CO2, 4.5% O2/ N2 | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.75 | 约0.30 | [ | |
40% PEI | 15% CO2, 4.5% O2/N2+3% H2O | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.36 | 约0.26 | [ | |
40% PEI+ 6% K2CO3 | 15% CO2, 4.5% O2/N2+3% H2O | 75 | 120 | He吹扫 | 固定床+气相色谱 | 2.75 | 约0.30 | [ | |
SBA-15 | 50% TEPA | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 4.81 | 0.36 | [ |
+4.5% NaNO3 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 6.28 | NA | [ | |
+4.5% KNO3 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 6.24 | NA | [ | |
+4.5% Zr(NO3)4 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 6.10 | NA | [ | |
+4.5% Al(NO3)3 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 约4.9 | NA | [ | |
+4.5% Ca(NO3)3 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 约4.0 | NA | [ | |
+4.5% Mg(NO3)2 | 0.044% CO2/Air (50% RH) | 30 | 90 | N2吹扫 | 固定床+ CO2分析仪 | 约4.0 | NA | [ |
载体 | 胺+添加剂组分 | 氧化条件 | 吸附条件 | 脱附条件 | 氧化稳定性评价 | 参考文献 |
---|---|---|---|---|---|---|
二氧化硅微球 | 50% PEI(MW≈1200) | 20% O2/N2,120℃,24h | 15% CO2,3% H2O,2% Ar/N2,40˚C,30min | 100% CO2,120˚C,60min | 吸附量损失81% | [ |
50% (0.15 EB+PEI) | 20% O2/N2,120℃,24h | 15% CO2,3% H2O,2% Ar/N2,40˚C,30min | 100% CO2,120˚C,60min | 吸附量损失44% | [ | |
50% (0.37 EB+PEI) | 20% O2/N2,120℃,24h | 15% CO2,3% H2O,2% Ar/N2,40˚C,30min | 100% CO2,120˚C,60min | 吸附量损失20% | [ | |
50% (0.54 EB+PEI) | 20% O2/N2,120℃,24h | 15% CO2,3% H2O,2% Ar/N2,40˚C,30min | 100% CO2,120˚C,60min | 吸附量损失19% | [ | |
二氧化硅微球 | 50% PEI (MW≈1200) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失52% | [ |
50% (0.37 EB+PEI) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失23% | [ | |
氧化硅 (Sipernat 50S) | 50% TEPA | 21% O2/N2,100℃,20h | 95% CO2/N2,25/55/85℃,3h | N2,110℃,30min | 吸附量损失约90% | [ |
TEPA-PO-1-2 (39% TEPA+22% PO) | 21% O2/N2,100℃,20h | 95% CO2/N2,25/55/85℃,3h | N2,110℃,30min | 吸附量分别损失16%(55℃),18%(85℃) | [ | |
50% PEHA | 21% O2/N2,100℃,20h | 95% CO2/N2,25/55/85℃,3h | N2,110℃,30min | 吸附量损失约90% | [ | |
PEHA-PO-1-2 (39% TEPA+22% PO) | 21% O2/N2,100℃,20h | 95% CO2/N2,25/55/85℃,3h | N2,110℃,30min | 吸附量分别损失16%(55℃),18%(85℃) | [ |
表7 环氧化物对固态胺吸附剂热化学稳定性的影响汇总
载体 | 胺+添加剂组分 | 氧化条件 | 吸附条件 | 脱附条件 | 氧化稳定性评价 | 参考文献 |
---|---|---|---|---|---|---|
二氧化硅微球 | 50% PEI(MW≈1200) | 20% O2/N2,120℃,24h | 15% CO2,3% H2O,2% Ar/N2,40˚C,30min | 100% CO2,120˚C,60min | 吸附量损失81% | [ |
50% (0.15 EB+PEI) | 20% O2/N2,120℃,24h | 15% CO2,3% H2O,2% Ar/N2,40˚C,30min | 100% CO2,120˚C,60min | 吸附量损失44% | [ | |
50% (0.37 EB+PEI) | 20% O2/N2,120℃,24h | 15% CO2,3% H2O,2% Ar/N2,40˚C,30min | 100% CO2,120˚C,60min | 吸附量损失20% | [ | |
50% (0.54 EB+PEI) | 20% O2/N2,120℃,24h | 15% CO2,3% H2O,2% Ar/N2,40˚C,30min | 100% CO2,120˚C,60min | 吸附量损失19% | [ | |
二氧化硅微球 | 50% PEI (MW≈1200) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失52% | [ |
50% (0.37 EB+PEI) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失23% | [ | |
氧化硅 (Sipernat 50S) | 50% TEPA | 21% O2/N2,100℃,20h | 95% CO2/N2,25/55/85℃,3h | N2,110℃,30min | 吸附量损失约90% | [ |
TEPA-PO-1-2 (39% TEPA+22% PO) | 21% O2/N2,100℃,20h | 95% CO2/N2,25/55/85℃,3h | N2,110℃,30min | 吸附量分别损失16%(55℃),18%(85℃) | [ | |
50% PEHA | 21% O2/N2,100℃,20h | 95% CO2/N2,25/55/85℃,3h | N2,110℃,30min | 吸附量损失约90% | [ | |
PEHA-PO-1-2 (39% TEPA+22% PO) | 21% O2/N2,100℃,20h | 95% CO2/N2,25/55/85℃,3h | N2,110℃,30min | 吸附量分别损失16%(55℃),18%(85℃) | [ |
载体 | 胺+添加剂组分 | 氧化条件 | 吸附条件 | 脱附条件 | 氧化稳定性 评价 | 参考 文献 |
---|---|---|---|---|---|---|
二氧化硅微球 | 50% PEI(MW≈1200) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失52% | [ |
50%(0.37 EB+PEI) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失23% | [ | |
2% Na3PO4+50% PEI | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约10% | [ | |
2% Na3PO4+50%(0.37 EB+PEI) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约4% | [ | |
50% PEI(MW≈1200) | 模拟烟气(15% CO2,3% O2,10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约100% | [ | |
50%(0.37 EB+PEI) | 模拟烟气(15% CO2,3% O2,and 10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约80% | [ | |
2% Na3PO4+50% PEI | 模拟烟气(15% CO2,3% O2,10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约80% | [ | |
2% Na3PO4+50%(0.37 EB+PEI) | 模拟烟气(15% CO2,3% O2,10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约8.5% | [ | |
二氧化硅微球 | 0.2mmol/g TEAH2PO4+50%(EB+PEI) | 20% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约1% | [ |
0.2mmol/g TMAH2PO4+50%(EB+PEI) | 20% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约2% | [ | |
0.2mmol/g NaH2PO4+50%(EB+PEI) | 20% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约10% | [ | |
0.2mmol/g LiH2PO4+50%(EB+PEI) | 20% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约15% | [ | |
0.2mmol/g TEAH2PO4+50% (EB+PEI) | 模拟烟气(15% CO2,3% O2,10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约14% | [ |
表8 螯合剂对固态胺吸附剂热化学稳定性的影响汇总
载体 | 胺+添加剂组分 | 氧化条件 | 吸附条件 | 脱附条件 | 氧化稳定性 评价 | 参考 文献 |
---|---|---|---|---|---|---|
二氧化硅微球 | 50% PEI(MW≈1200) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失52% | [ |
50%(0.37 EB+PEI) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失23% | [ | |
2% Na3PO4+50% PEI | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约10% | [ | |
2% Na3PO4+50%(0.37 EB+PEI) | 3% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约4% | [ | |
50% PEI(MW≈1200) | 模拟烟气(15% CO2,3% O2,10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约100% | [ | |
50%(0.37 EB+PEI) | 模拟烟气(15% CO2,3% O2,and 10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约80% | [ | |
2% Na3PO4+50% PEI | 模拟烟气(15% CO2,3% O2,10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约80% | [ | |
2% Na3PO4+50%(0.37 EB+PEI) | 模拟烟气(15% CO2,3% O2,10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约8.5% | [ | |
二氧化硅微球 | 0.2mmol/g TEAH2PO4+50%(EB+PEI) | 20% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约1% | [ |
0.2mmol/g TMAH2PO4+50%(EB+PEI) | 20% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约2% | [ | |
0.2mmol/g NaH2PO4+50%(EB+PEI) | 20% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约10% | [ | |
0.2mmol/g LiH2PO4+50%(EB+PEI) | 20% O2/N2,110℃,24h | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约15% | [ | |
0.2mmol/g TEAH2PO4+50% (EB+PEI) | 模拟烟气(15% CO2,3% O2,10% H2O/N2),110℃,30d | 15% CO2,10% H2O,75% N2,60℃,30min | 100% CO2,110℃,30min | 吸附量损失约14% | [ |
载体 | 胺 | 氧化条件 | 吸附条件 | 脱附条件 | 氧化稳定性评价 | 参考 文献 |
---|---|---|---|---|---|---|
MSU-F | 30% TEPA | 100% O2,80℃,18~42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失分别为54%(18h),79%(42h) | [ |
30% TEPA+5% TDE | 100% O2,80℃,18~42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失分别为约18%(18h),60%(42h) | [ | |
30% TEPA+5% HEDS | 100% O2,80℃,18~42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失分别为约30%(18h),70%(42h) | [ | |
30% TEPA+5% DTDP | 100% O2,80℃,18~42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失分别为约25%(18h),60%(42h) | [ | |
MSU-F | 30% PEI (Mn≈1200) | 100% O2,80℃,42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失近60% | [ |
30% PEI+5% TDE | 100% O2,80℃,42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失近40% | [ | |
30% PEI+5% HEDS | 100% O2,80℃,42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失近30% | [ | |
30% PEI+5% DTDP | 100% O2,80℃,42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失近25% | [ |
表9 含硫化合物添加剂对固态胺吸附剂热化学稳定性的影响汇总
载体 | 胺 | 氧化条件 | 吸附条件 | 脱附条件 | 氧化稳定性评价 | 参考 文献 |
---|---|---|---|---|---|---|
MSU-F | 30% TEPA | 100% O2,80℃,18~42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失分别为54%(18h),79%(42h) | [ |
30% TEPA+5% TDE | 100% O2,80℃,18~42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失分别为约18%(18h),60%(42h) | [ | |
30% TEPA+5% HEDS | 100% O2,80℃,18~42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失分别为约30%(18h),70%(42h) | [ | |
30% TEPA+5% DTDP | 100% O2,80℃,18~42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失分别为约25%(18h),60%(42h) | [ | |
MSU-F | 30% PEI (Mn≈1200) | 100% O2,80℃,42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失近60% | [ |
30% PEI+5% TDE | 100% O2,80℃,42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失近40% | [ | |
30% PEI+5% HEDS | 100% O2,80℃,42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失近30% | [ | |
30% PEI+5% DTDP | 100% O2,80℃,42h | 100kPa CO2,40℃ | 40℃,真空,6h | 吸附量损失近25% | [ |
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