MOF-on-MOF复合材料制备与光催化性能的研究进展

doi:10.16085/j.issn.1000-6613.2024-0413

摘要/Abstract

摘要：

人类的可持续发展正面临着环境污染和能源危机两大挑战，因此，高效利用和转化绿色能源（太阳能）引起了广泛关注。金属-有机框架（MOF）材料凭借其高比表面积、可调孔径和丰富活性位点等特点而逐渐成为光催化领域中一种热门材料。近年来，MOF-on-MOF复合材料成为纳米材料领域的研究热点，其重点是由两种或多种不同结构和形态的同质或异质MOF组装。与单一MOF相比，MOF-on-MOF复合材料表现出更加良好的可调性、更加丰富的活性位点和协同作用，在光催化领域中展现出了巨大的应用潜力。因此，本文主要从光催化CO₂还原、光催化水分解、光催化降解污染物和光催化有机转化这四个方面简述了MOF-on-MOF复合材料光催化性能的研究进展，介绍了MOF-on-MOF复合材料的合成策略，包括外延生长、表面活性剂辅助生长、配体/金属离子交换和成核动力学引导生长等，回顾了各种策略展现出的特点；分析了MOF-on-MOF复合材料在光催化方面的优势，阐述了影响其光催化性能的关键因素。指出需进一步提升高复杂性MOF-on-MOF的精确控制和操纵，探究了明确的MOF-on-MOF光催化反应途径和机理，拓展了MOF-on-MOF光催化应用领域，为MOF-on-MOF的工业应用奠定基础。

关键词: 金属-有机框架, 构效关系, 复合材料, 异质结, 光催化

Abstract:

Sustainable development is facing two major challenges: environmental pollution and energy crisis. Solar energy is a sustainable, clean and inexpensive green energy source. Therefore, the efficient use and conversion of solar energy have attracted widespread attention. Metal-organic frameworks (MOF) have gained extensive explorations as a highly versatile platform for functional applications in many research fields. Moreover, Heterostructured MOF-on-MOF composites are recently becoming a research hotspot, which are assembled by two or more different MOF with various structures and morphologies. Compared with single MOF, MOF-on-MOF composites display unprecedented tunability, richer active sites and synergistic effects, which exhibit great application potential in photocatalysis. Therefore, the article mainly reviewed the research progress on the preparation and photocatalytic performance of MOF-on-MOF composites from three aspects: photocatalytic CO₂ reduction, photocatalytic water splitting, photocatalytic degradation of organic pollutants and photocatalytic organic transformation. The synthesis strategies of MOF-on-MOF composites were summarized, including epitaxial growth, surfactant assistant growth, ligand/metal ion exchange and nucleation kinetic guided growth. The characteristics of various strategies were discussed. The advantages of MOF-on-MOF composites were analyzed in photocatalysis. It was pointed out that it was necessary to further improve the precise control and manipulation of MOF-on-MOF with high complexity, explore the clear photocatalytic reaction path and mechanism of MOF-on-MOF, expand the photocatalytic application field of MOF-on-MOF and lay a foundation for the industrial application of MOF-on-MOF.

Key words: metal?organic frameworks, structure-activity relationship, composites, heterostructures, photocatalysis

中图分类号:

O6-1

马晓宇, 张岩, 周阿武, 李涵冰, 杨飞华, 李建荣. MOF-on-MOF复合材料制备与光催化性能的研究进展[J]. 化工进展, 2025, 44(3): 1417-1431.

MA Xiaoyu, ZHANG Yan, ZHOU Awu, LI Hanbing, YANG Feihua, LI Jianrong. Research progress on preparation and photocatalytic performance of MOF-on-MOF heterojunctions[J]. Chemical Industry and Engineering Progress, 2025, 44(3): 1417-1431.

图/表 8

参考文献 21

22	MA Dou, LI Ping, DUAN Xiangyu, et al. A hydrolytically stable vanadium(Ⅳ) metal-organic framework with photocatalytic bacteriostatic activity for autonomous indoor humidity control[J]. Angewandte Chemie International Edition, 2020, 59(10): 3905-3909.
23	QIAN Yongteng, ZHANG Fangfang, PANG Huan. A review of MOFs and their composites-based photocatalysts: Synthesis and applications[J]. Advanced Functional Materials, 2021, 31(27): 2104231.
24	LIU Xiaoge, ZHANG Yi, GUO Xiaotian, et al. Electrospun metal-organic framework nanofiber membranes for energy storage and environmental protection[J]. Advanced Fiber Materials, 2022, 4(6): 1463-1485.
25	WEI Zihao, SONG Shaojia, GU Hongfei, et al. Enhancing the photocatalytic activity of zirconium-based metal-organic frameworks through the formation of mixed-valence centers[J]. Advanced Science, 2023, 10(29): e2303206.
26	YAN Yu, ABAZARI Reza, YAO Juming, et al. Recent strategies to improve the photoactivity of metal-organic frameworks[J]. Dalton Transactions, 2021, 50(7): 2342-2349.
27	LI Xinran, YANG Xinchun, XUE Huaiguo, et al. Metal-organic frameworks as a platform for clean energy applications[J]. EnergyChem, 2020, 2(2): 100027.
28	HAN Cheng, ZHANG Xiaodeng, HUANG Shengsheng, et al. MOF-on-MOF-derived hollow Co₃O₄/In₂O₃ nanostructure for efficient photocatalytic CO₂ reduction[J]. Advanced Science, 2023, 10(19): 2300797.
29	CHAI Lulu, PAN Junqing, HU Yue, et al. Rational design and growth of MOF-on-MOF heterostructures[J]. Small, 2021, 17(36): e2100607.
30	SEPEHRMANSOURIE Hassan, ALAMGHOLILOO Hassan, ZOLFIGOL Mohammad ALI, et al. Nanoarchitecting a dual Z-scheme Zr-MOF/Ti-MOF/g-C₃N₄ heterojunction for boosting gomberg-buchmann-hey reactions under visible light conditions[J]. ACS Sustainable Chemistry & Engineering, 2023, 11(8): 3182-3193.
31	LIU Chao, WANG Jing, WAN Jingjing, et al. MOF-on-MOF hybrids: Synthesis and applications[J]. Coordination Chemistry Reviews, 2021, 432: 213743.
32	LI Jiaxin, BAO Tong, ZHANG Chaoqi, et al. A general strategy for direct growth of yolk-shell MOF-on-MOF hybrids[J]. Chemical Engineering Journal, 2023, 472: 144926.
33	YAO Mingshui, XIU Jingwei, HUANG Qingqing, et al. Van der Waals heterostructured MOF-on-MOF thin films: Cascading functionality to realize advanced chemiresistive sensing[J]. Angewandte Chemie International Edition, 2019, 58(42): 14915-14919.
34	LEE Gihyun, LEE Sujeong, Sojin OH, et al. Tip-to-middle anisotropic MOF-on-MOF growth with a structural adjustment[J]. Journal of the American Chemical Society, 2020, 142(6): 3042-3049.
35	PARK Kyo Sung, NI Zheng, CÔTÉ Adrien P, et al. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks[J]. Proceedings of the National Academy of Sciences of the United States of America, 2006, 103(27): 10186-10191.
36	JIANG Yuanjuan, CHEN Tsung-Yi, CHEN Jeng-Lung, et al. Heterostructured bimetallic MOF-on-MOF architectures for efficient oxygen evolution reaction[J]. Advanced Materials, 2024, 36(8): e2306910.
37	JIANG Xin, FAN Ruiqing, ZHANG Jian, et al. Sequentially epitaxial growth multi-guest encapsulation strategy in MOF-on-MOF platform: Biogenic amine detection and systematic white light adjustment[J]. Chemical Engineering Journal, 2022, 436: 135236.
38	Junsu HA, MOON Hoi Ri. Synthesis of MOF-on-MOF architectures in the context of interfacial lattice matching[J]. CrystEngComm, 2021, 23(12): 2337-2354.
39	WANG Zhengbang, LIU Jinxuan, LUKOSE Binit, et al. Nanoporous designer solids with huge lattice constant gradients: Multiheteroepitaxy of metal-organic frameworks[J]. Nano Letters, 2014, 14(3): 1526-1529.
40	LIU Jinxuan, LUKOSE Binit, SHEKHAH Osama, et al. A novel series of isoreticular metal organic frameworks: Realizing metastable structures by liquid phase epitaxy[J]. Scientific Reports, 2012, 2: 921.
41	KIM Dooyoung, LEE Gihyun, Sojin OH, et al. Unbalanced MOF-on-MOF growth for the production of a lopsided core-shell of MIL-88B@MIL-88A with mismatched cell parameters[J]. Chemical Communications, 2018, 55(1): 43-46.
42	DE SOLER-ILLIA Galo J A A, SANCHEZ Clément, LEBEAU Bénédicte, et al. Chemical strategies of design textured materials: From microporous and mesoporous oxides to nanonetworks and hierarchichal structures[J]. Chemical Reviews, 2002, 102(11): 4093-4138.
43	ZHAO Dongyuan, HUO Qisheng, FENG Jianglin, et al. Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures[J]. Journal of the American Chemical Society, 1998, 120(24): 6024-6036.
44	XIANG Quanjun, YU Jiaguo, JARONIEC Mietek. Graphene-based semiconductor photocatalysts[J]. Chemical Society Reviews, 2012, 41(2): 782-796.
45	GU Yifan, WU Yinan, LI Liangchun, et al. Controllable modular growth of hierarchical MOF-on-MOF architectures[J]. Angewandte Chemie International Edition, 2017, 56(49): 15658-15662.
46	ZHAO Meiting, YUAN Kuo, WANG Yun, et al. Metal-organic frameworks as selectivity regulators for hydrogenation reactions[J]. Nature, 2016, 539(7627): 76-80.
47	DAI Shan, TISSOT Antoine, SERRE Christian. Recent progresses in metal-organic frameworks based core-shell composites[J]. Advanced Energy Materials, 2022, 12(4): 2100061.
48	DONG Chengjun, TIAN Ruonan, ZHANG Yanlin, et al. MOF-on-MOF nanoarchitecturing of Fe₂O₃@ZnFe₂O₄ radial-heterospindles towards multifaceted superiorities for acetone detection[J]. Chemical Engineering Journal, 2022, 442: 136094.
49	CHAI Huining, YU Kun, ZHAO Yiming, et al. MOF-on-MOF dual enzyme-mimic nanozyme with enhanced cascade catalysis for colorimetric/chemiluminescent dual-mode aptasensing[J]. Analytical Chemistry International Edition, 2023, 95(28): 10785-10794.
50	ZHAO Jun, LIU Xiang, WU Yapan, et al. Surfactants as promising media in the field of metal-organic frameworks[J]. Coordination Chemistry Reviews, 2019, 391: 30-43.
51	YU Meihui, GENG Lin, CHANG Ze, et al. Coordination bonding directed molecular assembly toward functional metal-organic frameworks: From structural regulation to properties modulation[J]. Accounts of Materials Research, 2023, 4(10): 839-853.
52	JEOUNG Sungeun, KIM Seongwoo, KIM Min, et al. Pore engineering of metal-organic frameworks with coordinating functionalities[J]. Coordination Chemistry Reviews, 2020, 420: 213377.
53	XIAO Xiao, ZHANG Guangxun, XU Yuxia, et al. A new strategy for the controllable growth of MOF@PBA architectures[J]. Journal of Materials Chemistry A, 2019, 7(29): 17266-17271.
54	ZHANG Hua, CHEN Anran, BI Zenghui, et al. MOF-on-MOF-derived ultrafine Fe₂P-Co₂P heterostructures for high-efficiency and durable anion exchange membrane water electrolyzers[J]. ACS Nano, 2023, 17(23): 24070-24079.
55	MA Yan, FANG Huixue, CHEN Rong, et al. 2D-MOF/2D-MOF heterojunctions with strong hetero-interface interaction for enhanced photocatalytic hydrogen evolution[J]. Rare Metals, 2023, 42(12): 3993-4004.
56	BROZEK C K, DINCĂ M. Cation exchange at the secondary building units of metal-organic frameworks[J]. Chemical Society Reviews, 2014, 43(16): 5456-5467.
57	ABEDNATANZI Sara, DERAKHSHANDEH Parviz Gohari, DEPAUW Hannes, et al. Mixed-metal metal-organic frameworks[J]. Chemical Society Reviews, 2019, 48(9): 2535-2565.
58	KIM Min, CAHILL John F, FEI Honghan, et al. Postsynthetic ligand and cation exchange in robust metal-organic frameworks[J]. Journal of the American Chemical Society, 2012, 134(43): 18082-18088.
59	ZHANG Wuxiang, SONG Hao, CHENG Yan, et al. Core-shell Prussian blue analogs with compositional heterogeneity and open cages for oxygen evolution reaction[J]. Advanced Science, 2019, 6(7): 1801901.
60	WANG Yawen, HE Jiating, LIU Cuicui, et al. Thermodynamics versus kinetics in nanosynthesis[J]. Angewandte Chemie International Edition, 2015, 54(7): 2022-2051.
61	SONG Hao, AHMAD NOR Yusilawati, YU Meihua, et al. Silica nanopollens enhance adhesion for long-term bacterial inhibition[J]. Journal of the American Chemical Society, 2016, 138(20): 6455-6462.
62	ZHANG Hongwei, NOONAN Owen, HUANG Xiaodan, et al. Surfactant-free assembly of mesoporous carbon hollow spheres with large tunable pore sizes[J]. ACS Nano, 2016, 10(4): 4579-4586.
63	LIU Yi, QIU Guangyao, LIU Yongfeng, et al. Fabrication of CoFe-MOF materials by different methods and adsorption properties for Congo red[J]. Journal of Molecular Liquids, 2022, 360: 119405.
64	YANG Xinyu, YUAN Shuai, ZOU Lanfang, et al. One-step synthesis of hybrid core-shell metal-organic frameworks[J]. Angewandte Chemie International Edition, 2018, 57(15): 3927-3932.
65	SONG Jiangyan, YU Yongyi, HAN Xiaoshuai, et al. Novel MOF(Zr)-on-MOF(Ce) adsorbent for elimination of excess fluoride from aqueous solution[J]. Journal of Hazardous Materials, 2024, 463: 132843.
66	WANG Lei, JIN Pengxia, DUAN Shuhua, et al. In-situ incorporation of Copper(Ⅱ) porphyrin functionalized zirconium MOF and TiO₂ for efficient photocatalytic CO₂ reduction[J]. Science Bulletin, 2019, 64(13): 926-933.
67	SU Yuqun, XU Haitao, WANG Jiajia, et al. Nanorattle Au@PtAg encapsulated in ZIF-8 for enhancing CO₂ photoreduction to CO[J]. Nano Research, 2019, 12(3): 625-630.
68	JIANG Haopeng, WANG Lele, YU Xiaohui, et al. Precise regulation of built-in electric field over NH₂-MIL-125-Ti/WO_3- _x S-scheme heterojunction for achieving simultaneous formation of CO and H₂O₂ from CO₂ and H₂O[J]. Chemical Engineering Journal, 2023, 466: 143129.
69	SHI Li, WANG Tao, ZHANG Huabin, et al. Electrostatic self-assembly of nanosized carbon nitride nanosheet onto a zirconium metal-organic framework for enhanced photocatalytic CO₂ reduction[J]. Advanced Functional Materials, 2015, 25(33): 5360-5367.
70	DONG Wenwen, JIA Jing, WANG Ye, et al. Visible-light-driven solvent-free photocatalytic CO₂ reduction to CO by Co-MOF/Cu₂O heterojunction with superior selectivity[J]. Chemical Engineering Journal, 2022, 438: 135622.
71	HUANG Haibo, FANG Zhibin, WANG Rui, et al. Engineering hierarchical architecture of metal-organic frameworks for highly efficient overall CO₂ photoreduction[J]. Small, 2022, 18(16): 2200407.
72	KONG Nan, DU Huiling, LI Zhuo, et al. Nano heterojunction of double MOFs for improved CO₂ photocatalytic reduction performance[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 663: 131005.
73	LI Jian, YU Xinmiao, XUE Wenjuan, et al. Engineering the direct Z-scheme systems over lattice intergrown of MOF-on-MOF for selective CO₂ photoreduction to CO[J]. AIChE Journal, 2023, 69(3): e17906.
74	HE Bing, WANG Yingjie, BAI Xuefeng, et al. Rational construction of MOF-on-MOF heterojunction with an array of flexible two-dimensional microsheets for efficient CO₂ photoreduction[J]. Chemical Engineering Journal, 2024, 482: 149000.
75	KAMPOURI Stavroula, EBRAHIM Fatmah M, FUMANAL Maria, et al. Enhanced visible-light-driven hydrogen production through MOF/MOF heterojunctions[J]. ACS Applied Materials & Interfaces, 2021, 13(12): 14239-14247.
76	CHEN Yao, YANG Dong, XIN Xin, et al. Multi-stepwise charge transfer via MOF@MOF/TiO₂ dual-heterojunction photocatalysts towards hydrogen evolution[J]. Journal of Materials Chemistry A, 2022, 10(17): 9717-9725.
77	JIN Fei, YANG Bolin, WANG Xuanpu, et al. Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (C _n H₂ _n_-2) electron transport layer[J]. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198.
78	Li Shiuan NG, MOGAN Tharishinny Raja, LEE Jinn-Kye, et al. Surface-degenerate semiconductor photocatalysis for efficient water splitting without sacrificial agents via a reticular chemistry approach[J]. Angewandte Chemie International Edition, 2023, 62(47): e202313695.
79	MELILLO Arianna, María CABRERO-ANTONINO, FERRER Belén, et al. MOF-on-MOF composites with UiO-66-based materials as photocatalysts for the overall water splitting under sunlight irradiation[J]. Energy & Fuels, 2023, 37(7): 5457-5468.
80	WANG He, ZHANG Xiyuan, ZHANG Wei, et al. Heteroatom-doped Ag₂₅ nanoclusters encapsulated in metal-organic frameworks for photocatalytic hydrogen production[J]. Angewandte Chemie International Edition, 2024, 63(17): e202401443.
81	XIAO Juanding, SHANG Qichao, XIONG Yujie, et al. Boosting photocatalytic hydrogen production of a metal-organic framework decorated with platinum nanoparticles: The platinum location matters[J]. Angewandte Chemie International Edition, 2016, 55(32): 9389-9393.
82	TENG Pingping, LIU Ying, SUN Zhongqiao, et al. Co-adsorption and Fenton-like oxidation in the efficient removal of methylene blue by MIL-88B@UiO-66 nanoflowers[J]. Dalton Transactions, 2023, 52(30): 10472-10480.
83	ALKHATIB Ismail Issa, GARLISI Corrado, PAGLIARO Mario, et al. Metal-organic frameworks for photocatalytic CO₂ reduction under visible radiation: A review of strategies and applications[J]. Catalysis Today, 2020, 340: 209-224.
84	XU Mengyang, SUN Chao, ZHAO Xiaoxue, et al. Fabricated hierarchical CdS/Ni-MOF heterostructure for promoting photocatalytic reduction of CO₂ [J]. Applied Surface Science, 2022, 576: 151792.
85	LEE Yeob, KIM Sangjun, KANG Jeung Ku, et al. Photocatalytic CO₂ reduction by a mixed metal (Zr/Ti), mixed ligand metal-organic framework under visible light irradiation[J]. Chemical Communications, 2015, 51(26): 5735-5738.
86	NABGAN Walid, TUAN ABDULLAH Tuan Amran, Ramli MAT, et al. Renewable hydrogen production from bio-oil derivative via catalytic steam reforming: An overview[J]. Renewable and Sustainable Energy Reviews, 2017, 79: 347-357.
87	MIYOSHI Akinobu, NISHIOKA Shunta, MAEDA Kazuhiko. Water splitting on rutile TiO₂-based photocatalysts[J]. Chemistry, 2018, 24(69): 18204-18219.
88	NAMI-ANA Seyedeh Fatemeh, ZEINALI Sedigheh. Synthesis of a novel one-dimensional ternary MOF-on-MOF in form of direct and carbonization derived structure towards promising catalytic efficiency of HER[J]. Applied Energy, 2023, 350: 121755.
89	RAMEZANALIZADEH Hamed, MANTEGHI Faranak. Synthesis of a novel MOF/CuWO₄ heterostructure for efficient photocatalytic degradation and removal of water pollutants[J]. Journal of Cleaner Production, 2018, 172: 2655-2666.
90	Shahnawaz KHAN M, LI Yixiang, LI Dongsheng, et al. A review of metal-organic framework (MOF) materials as an effective photocatalyst for degradation of organic pollutants[J]. Nanoscale Advances, 2023, 5(23): 6318-6348.
91	ANDRADE Pedro H M, PALHARES Hugo, VOLKRINGER Christophe, et al. State of the art in visible-light photocatalysis of aqueous pollutants using metal-organic frameworks[J]. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2023, 57: 100635.
92	ZHAO Yunkun, ZHANG Yu, CAO Xungu, et al. Synthesis of MOF on MOF photocatalysts using PCN-134 as seed through epitaxial growth strategy towards nizatidine degradation[J]. Chemical Engineering Journal, 2023, 465: 143000.
93	YU Linling, CAO Wen, WU Shichuan, et al. Removal of tetracycline from aqueous solution by MOF/graphite oxide pellets: Preparation, characteristic, adsorption performance and mechanism[J]. Ecotoxicology and Environmental Safety, 2018, 164: 289-296.
94	DONG Yonghao, WANG Xudong, SUN Han, et al. Construction of a 0D/3D AgI/MOF-808 photocatalyst with a one-photon excitation pathway for enhancing the degradation of tetracycline hydrochloride: Mechanism, degradation pathway and DFT calculations[J]. Chemical Engineering Journal, 2023, 460: 141842.
95	GAO Tian, ZHANG Hua, ZHAO Xiang, et al. Efficient removal of tetracycline from MOF-on-MOF heterojunctions driven by visible light: Evaluation of photocatalytic mechanisms and degradation pathway[J]. Applied Surface Science, 2024, 651: 159227.
96	YUAN Ling, ZHANG Chaoqi, ZOU Yingying, et al. A S-scheme MOF-on-MOF heterostructure[J]. Advanced Functional Materials, 2023, 33(20): 2214627.
97	PATEL Manvendra, KUMAR Rahul, KISHOR Kamal, et al. Pharmaceuticals of emerging concern in aquatic systems: Chemistry, occurrence, effects, and removal methods[J]. Chemical Reviews, 2019, 119(6): 3510-3673.
98	XIE Ruzhen, MENG Xiaoyang, SUN Peizhe, et al. Electrochemical oxidation of ofloxacin using a TiO₂-based SnO₂-Sb/polytetrafluoroethylene resin-PbO₂ electrode: Reaction kinetics and mass transfer impact[J]. Applied Catalysis B: Environmental, 2017, 203: 515-525.
99	YANG Xiuru, CHEN Zhi, ZHAO Wan, et al. Recent advances in photodegradation of antibiotic residues in water[J]. Chemical Engineering Journal, 2021, 405: 126806.
100	SEPEHRMANSOURIE Hassan, ALAMGHOLILOO Hassan, NOROOZI PESYAN Nader, et al. A MOF-on-MOF strategy to construct double Z-scheme heterojunction for high-performance photocatalytic degradation[J]. Applied Catalysis B: Environmental, 2023, 321: 122082.
101	GOHIL Jay, PATEL Jay, CHOPRA Jay, et al. Advent of big data technology in environment and water management sector[J]. Environmental Science and Pollution Research International, 2021, 28(45): 64084-64102.
102	TIAN Jiayue, Wenchao LYU, SHEN Aosong, et al. Construction of the copper metal-organic framework (MOF)-on-indium MOF Z-scheme heterojunction for efficiently photocatalytic reduction of Cr(Ⅵ)[J]. Separation and Purification Technology, 2023, 327: 124903.
103	YANG Xue, ZHANG Suyuan, LI Peixian, et al. Visible-light-driven photocatalytic selective organic oxidation reactions[J]. Journal of Materials Chemistry A, 2020, 8(40): 20897-20924.
104	FENG Liang, YUAN Shuai, LI Jialuo, et al. Uncovering two principles of multivariate hierarchical metal-organic framework synthesis via retrosynthetic design[J]. ACS Central Science, 2018, 4(12): 1719-1726.
1	QUADRELLI Roberta, PETERSON Sierra. The energy-climate challenge: Recent trends in CO₂ emissions from fuel combustion[J]. Energy Policy, 2007, 35(11): 5938-5952.
2	USMAN Muhammad, Zonish ZEB, ULLAH Habib, et al. A review of metal-organic frameworks/graphitic carbon nitride composites for solar-driven green H₂ production, CO₂ reduction, and water purification[J]. Journal of Environmental Chemical Engineering, 2022, 10(3): 107548.
3	XIAO Juanding, LI Rui, JIANG Hailong. Metal-organic framework-based photocatalysis for solar fuel production[J]. Small Methods, 2023, 7(1): e2201258.
4	GE T S, WANG R Z, XU Z Y, et al. Solar heating and cooling: Present and future development[J]. Renewable Energy, 2018, 126: 1126-1140.
5	XU Jinghang, SHEN Jun, JIANG Haopeng, et al. Progress and challenges in full spectrum photocatalysts: Mechanism and photocatalytic applications[J]. Journal of Industrial and Engineering Chemistry, 2023, 119: 112-129.
6	FRANCIS Angel, SHANMUGA Priya S, HARISH KUMAR S, et al. A review on recent developments in solar photoreactors for carbon dioxide conversion to fuels[J]. Journal of CO₂ Utilization, 2021, 47: 101515.
7	FUJISHIMA Akira, HONDA Kenichi. Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972, 238(5358): 37-38.
8	CHENG Lei, XIANG Quanjun, LIAO Yulong, et al. CdS-based photocatalysts[J]. Energy & Environmental Science, 2018, 11(6): 1362-1391.
9	MA Ran, ZHANG Sai, WEN Tao, et al. A critical review on visible-light-response CeO₂-based photocatalysts with enhanced photooxidation of organic pollutants[J]. Catalysis Today, 2019, 335: 20-30.
10	Chin Boon ONG, Law Yong NG, MOHAMMAD Abdul Wahab. A review of ZnO nanoparticles as solar photocatalysts: Synthesis, mechanisms and applications[J]. Renewable and Sustainable Energy Reviews, 2018, 81: 536-551.
11	XU Yuxia, LI Qing, XUE Huaiguo, et al. Metal-organic frameworks for direct electrochemical applications[J]. Coordination Chemistry Reviews, 2018, 376: 292-318.
12	YUAN Shuai, QIN Junsheng, LI Jialuo, et al. Retrosynthesis of multi-component metal-organic frameworks[J]. Nature Communications, 2018, 9(1): 808.
13	Won-Tae KOO, JANG Ji-Soo, KIM Il-Doo. Metal-organic frameworks for chemiresistive sensors[J]. Chem, 2019, 5(8): 1938-1963.
14	ZHOU Awu, ZHAO Chen, ZHOU Jianchi, et al. Tailoring the electronic structure of In₂O₃/C photocatalysts for enhanced CO₂ reduction[J]. Journal of Materials Chemistry A, 2023, 11(24): 12950-12957.
15	ZHANG Chenxi, LEI Da, XIE Chenfan, et al. Piezo-photocatalysis over metal-organic frameworks: Promoting photocatalytic activity by piezoelectric effect[J]. Advanced Materials, 2021, 33(51): 2106308.
16	LI Yongzhi, WANG Gangding, MA Lina, et al. Multiple functions of gas separation and vapor adsorption in a new MOF with open tubular channels[J]. ACS Applied Materials & Interfaces, 2021, 13(3): 4102-4109.
17	GAO Cun, MU Xiaobing, YUAN Wenyu, et al. Construction of new multi-cage-based MOFs using flexible triangular ligands for efficient gas adsorption and separation[J]. Journal of Solid State Chemistry, 2023, 322: 123994.
18	MA Teng, LI Huibo, MA Jiangong, et al. Application of MOF-based materials in electrochemical sensing[J]. Dalton Transactions, 2020, 49(47): 17121-17129.
19	CAO Jian, LI Xuejiao, TIAN Hongqi. Metal-organic framework (MOF)-based drug delivery[J]. Current Medicinal Chemistry, 2020, 27(35): 5949-5969.
20	WU Mingxue, YANG Yingwei. Metal-organic framework (MOF)-based drug/cargo delivery and cancer therapy[J]. Advanced Materials, 2017, 29(23): 1606134.
21	XIAO Juanding, JIANG Hailong. Metal-organic frameworks for photocatalysis and photothermal catalysis[J]. Accounts of Chemical Research, 2019, 52(2): 356-366.

应用	催化剂	光源	反应条件	主要产物	产率/μmol·g^-1·h^-1	参考文献
光催化CO₂还原	CuTCPP/UiO-66/TiO₂	300W氙灯	100mg催化剂，2mL水	一氧化碳	31.32	[66]
	Au@ZIF-8	500W氙灯	20mg催化剂，0.5mL水	一氧化碳	13.2	[67]
	MIL-125-Ti/WO_3-_x	300W氙灯	20mg催化剂，50mL水	一氧化碳	12.5	[68]
	UiO-66/CNSS	300W氙灯	100mg催化剂，4mL三乙醇胺，1mL水	一氧化碳	9.9	[69]
	Co-MOF/Cu₂O	300W氙灯	20mg催化剂，1mL水	一氧化碳	3.83	[70]
	PCN-222-Ni@UiO-67-NH₂	300W氙灯	5mg催化剂，3mL水	甲酸	146	[71]
	NH₂-UiO-66@MIL-101(Cr)	300W氙灯	30mg催化剂，15mL水	一氧化碳	267.9	[72]
	UiO-66-NH₂@MIL-88B(Fe)	300W氙灯	10mg催化剂，5mL水	一氧化碳	2.26	[73]
	NH₂-MIL-125@Ni-BDC	300W氙灯	1mg催化剂，0.1mL 三乙醇胺，0.1mL水	一氧化碳	41.38	[74]
光催化水分解	MIL-167/MIL-125-NH₂	300W氙灯	17mg催化剂，13.4mL 乙腈，2.8mL 三乙胺，0.8mL水	氢气	455	[75]
	NM@OM/TiO₂	300W氙灯	8mg催化剂，15mL 乙腈，3mL 三乙醇胺，0.3mL水	氢气	7108	[76]
	ZIF-9(Co)/Cu₃BTC₂	300W氙灯	10mg催化剂，4.5mL 三乙醇胺，25.5mL水	氢气	1126	[77]
	CdS@ZIF	100W LED灯	2.6mg催化剂，3mL水	氢气	519	[78]
	UiO-66(Zr)-NH₂@UiO-66(Ce)	150W氙灯	10mg催化剂，20mL水	氢气	32.2	[79]
	AuAg₂₄@UiO-66-NH₂	300W氙灯	5mg催化剂，18mL 乙腈，1mL 三乙胺，0.5mL 水	氢气	3600	[80]

应用	催化剂	光源	反应条件	主要产物	产率/μmol·g^-1·h^-1	参考文献
光催化CO₂还原	CuTCPP/UiO-66/TiO₂	300W氙灯	100mg催化剂，2mL水	一氧化碳	31.32	[66]
	Au@ZIF-8	500W氙灯	20mg催化剂，0.5mL水	一氧化碳	13.2	[67]
	MIL-125-Ti/WO_3-_x	300W氙灯	20mg催化剂，50mL水	一氧化碳	12.5	[68]
	UiO-66/CNSS	300W氙灯	100mg催化剂，4mL三乙醇胺，1mL水	一氧化碳	9.9	[69]
	Co-MOF/Cu₂O	300W氙灯	20mg催化剂，1mL水	一氧化碳	3.83	[70]
	PCN-222-Ni@UiO-67-NH₂	300W氙灯	5mg催化剂，3mL水	甲酸	146	[71]
	NH₂-UiO-66@MIL-101(Cr)	300W氙灯	30mg催化剂，15mL水	一氧化碳	267.9	[72]
	UiO-66-NH₂@MIL-88B(Fe)	300W氙灯	10mg催化剂，5mL水	一氧化碳	2.26	[73]
	NH₂-MIL-125@Ni-BDC	300W氙灯	1mg催化剂，0.1mL 三乙醇胺，0.1mL水	一氧化碳	41.38	[74]
光催化水分解	MIL-167/MIL-125-NH₂	300W氙灯	17mg催化剂，13.4mL 乙腈，2.8mL 三乙胺，0.8mL水	氢气	455	[75]
	NM@OM/TiO₂	300W氙灯	8mg催化剂，15mL 乙腈，3mL 三乙醇胺，0.3mL水	氢气	7108	[76]
	ZIF-9(Co)/Cu₃BTC₂	300W氙灯	10mg催化剂，4.5mL 三乙醇胺，25.5mL水	氢气	1126	[77]
	CdS@ZIF	100W LED灯	2.6mg催化剂，3mL水	氢气	519	[78]
	UiO-66(Zr)-NH₂@UiO-66(Ce)	150W氙灯	10mg催化剂，20mL水	氢气	32.2	[79]
	AuAg₂₄@UiO-66-NH₂	300W氙灯	5mg催化剂，18mL 乙腈，1mL 三乙胺，0.5mL 水	氢气	3600	[80]

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