木材在电化学中的应用研究进展

doi:10.16085/j.issn.1000-6613.2021-1233

摘要/Abstract

摘要：

木材具有发达的孔道结构和良好的机械性能，用木材制备的电极和电解质材料具备优异的电化学性能，成为了当下的研究热点。本文综述了近年来木材在电化学领域的研究进展，着重介绍了木材基电极和电解质材料的制备方法以及在电化学传感器、超级电容器和电池中的应用情况；分析了木材提高电极和电解质材料电化学性能的机理，指出木材发达的孔道结构能够有效吸附和传输电解质离子，是赋予材料优异电化学性能的关键。最后总结了木材在电化学领域中应用存在的问题，提出今后应加深对木材孔结构、孔形貌的设计和研究，高效利用木材的微观结构，丰富木材的改性方案。

关键词: 木材, 生物质, 电化学, 电化学传感器, 超级电容器, 电池, 电极, 电解质

Abstract:

Wood has developed pore structure and good mechanical properties. The electrode and electrolyte materials prepared from wood have excellent electrochemical properties, which has become a research hotspot. In this paper, the research progress of wood in the field of electrochemistry in recent years was reviewed, with emphasis on the preparation methods of wood-based electrode and electrolyte materials and their applications in electrochemical sensors, supercapacitors and batteries. The mechanism of wood improving the electrochemical properties of electrode and electrolyte materials is analyzed. It is pointed out that the developed pore structure of wood can effectively adsorb and transport electrolyte ions, which is the key to endow the materials with excellent electrochemical properties. Finally, the problems existing in the application of wood in the field of electrochemistry are summarized, and it is proposed that we should deepen the design and research of wood pore structure and pore morphology, make efficient use of wood microstructure and enrich wood modification schemes in the future.

Key words: wood, biomass, electrochemistry, electrochemical sensor, supercapacitor, battery, electrodes, electrolytes

中图分类号:

TB324

高晨祥, 张珂, 刘春媛, 冯鑫, 霍鹏飞. 木材在电化学中的应用研究进展[J]. 化工进展, 2021, 40(S2): 203-210.

GAO Chenxiang, ZHANG Ke, LIU Chunyuan, FENG Xin, HUO Pengfei. Research progress on the application of wood in electrochemistry[J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 203-210.

图/表 1

参考文献 45

1	涂平涛. 木材与建筑[J]. 人造板通讯, 2003(9): 3-4, 9.
	TU Pingtao. Wood and architecture[J]. China Wood-Based Panels, 2003(9): 3-4, 9.
2	WIMMERS G. Wood: a construction material for tall buildings[J]. Nature Reviews Materials, 2017, 2(12): 17051.
3	CHEN Chaoji, HU Liangbing. Nanocellulose toward advanced energy storage devices: structure and electrochemistry[J]. Accounts of Chemical Research, 2018, 51(12): 3154-3165.
4	CHEN Chaoji, KUANG Yudi, ZHU Shuze, et al. Structure-property-function relationships of natural and engineered wood[J]. Nature Reviews Materials, 2020, 5(9): 642-666.
5	吴宇晖, 张少迪, 任自忠, 等. 植酸-三聚氰胺处理木材阻燃性能研究[J]. 北京林业大学学报, 2020, 42(4): 155-161.
	WU Yuhui, ZHANG Shaodi, REN Zizhong, et al. Flame retardant properties of phytic acid and melamine treated wood[J]. Journal of Beijing Forestry University, 2020, 42(4): 155-161.
6	GUAN Hao, CHENG Zhiyong, WANG Xiaoqing. Highly compressible wood sponges with a spring-like lamellar structure as effective and reusable oil absorbents[J]. ACS Nano, 2018, 12(10): 10365-10373.
7	GAN Wentao, CHEN Chaoji, GIROUX M, et al. Conductive wood for high-performance structural electromagnetic interference shielding[J]. Chemistry of Materials, 2020, 32(12): 5280-5289.
8	户桂涛, 范云场, 董兴, 等. 电化学传感器在食品分析中的应用进展[J]. 材料导报, 2015, 29(19): 40-45.
	HU Guitao, FAN Yunchang, DONG Xing, et al. Progress in application of electrochemical sensors in food analysis[J]. Materials Review, 2015, 29(19): 40-45.
9	HARPER A, ANDERSON M R. Electrochemical glucose sensors-developments using electrostatic assembly and carbon nanotubes for biosensor construction[J]. Sensors (Basel), 2010, 10(9): 8248-8274.
10	刘建国, 安振涛, 张倩. 新型电化学传感器的研究进展[J]. 传感器与微系统, 2013, 32(7): 1-3, 7.
	LIU Jianguo, AN Zhentao, ZHANG Qian. Research progress on novel electrochemical sensor [J]. Transducer and Microsystem Technologies, 2013, 32(7): 1-3, 7.
11	DONG Xiaoying, ZHUO Xiao, WEI Jie, et al. Wood-based nanocomposite derived by in-situ formation of organic-inorganic hybrid polymer within wood via a sol-gel method[J]. ACS Applied Materials & Interfaces, 2017, 9(10): 9070-9078.
12	NIE Kangchen, WANG Zhaosong, TANG Ruixin, et al. Anisotropic, flexible wood hydrogels and wrinkled, electrodeposited film electrodes for highly sensitive, wide-range pressure sensing[J]. ACS Applied Materials & Interfaces, 2020, 12(38): 43024-43031.
13	KONG Weiqing, WANG Chengwei, JIA Chao, et al. Muscle-inspired highly anisotropic, strong, ion-conductive hydrogels[J]. Advanced Materials, 2018, 30(39): 1801934.
14	CHEN Chuchu, WANG Yiren, WU Qijing, et al. Highly strong and flexible composite hydrogel reinforced by aligned wood cellulose skeleton via alkali treatment for muscle-like sensors[J]. Chemical Engineering Journal, 2020, 400: 125876.
15	HUANG Yan, CHEN Yun, FAN Xiangyu, et al. Wood derived composites for high sensitivity and wide linear-range pressure sensing[J]. Small, 2018, 14: 1801520.
16	GUAN Hao, MENG Junwang, CHENG Zhiyong, et al. Processing natural wood into a high-performance flexible pressure sensor[J]. ACS Applied Materials & Interfaces. 2020, 12(41): 46357-46365.
17	FU Qiliang, CHEN Yi, Sorieul M. Wood-based flexible electronics[J]. ACS Nano, 2020, 14(3): 3528-3538.
18	GONZALEZ A, GOIKOLEA E, BARRENA J A, et al. Review on supercapacitors: technologies and materials[J]. Renewable and Sustainable Energy Reviews, 2016, 58: 1189-1206.
19	PENG Huisheng. Fiber-shaped energy harvesting and storage devices[M]. Berlin: Springer Berlin Heidelberg, 2015.
20	LU Leilei, LU Yuyang, XIAO Zijian, et al. Wood-inspired high-performance ultrathick bulk battery electrodes[J]. Advanced Materials, 2018, 30(20): 1706545.
21	ZHANG Sen, WU Chenling, WU Wei, et al. High performance flexible supercapacitors based on porous wood carbon slices derived from Chinese fir wood scraps[J]. Journal of Power Sources, 2019, 424: 1-7.
22	MA Yu, YAO Dongxu, LIANG Hanqin, et al. Ultra-thick wood biochar monoliths with hierarchically porous structure from cotton rose for electrochemical capacitor electrodes[J]. Electrochimica Acta, 2020, 352: 136452.
23	LIU Mingquan, XU Min, XUE Yifei, et al. Efficient capacitive deionization using natural basswood-derived, freestanding, hierarchically porous carbon electrodes[J]. ACS Applied Materials & Interfaces, 2018, 10(37): 31260-31270.
24	MENG Qi, GE Huilin, YAO Weitang, et al. One-step synthesis of nitrogen-doped wood derived carbons as advanced electrodes for supercapacitor applications[J]. New Journal of Chemistry, 2019, 43(9): 3649-3652.
25	CHEN Chaoji, ZHANG Ying, LI Yiju, et al. All-wood, low tortuosity, aqueous, biodegradable supercapacitors with ultra-high capacitance[J]. Energy & Environmental Science, 2017, 10(2): 538-545.
26	CUI Mengxia, WANG Fang, ZHANG Zhengguo, et al. Polyaniline-filled carbonized wood membrane as an advanced self-supported electrode for superior pseudocapacitive energy storage[J]. Electrochimica Acta, 2020, 359: 136961.
27	XIN Fuen, JIA Yufeng, SUN Jie, et al. Enhancing the capacitive performance of carbonized wood by growing FeOOH nanosheets and PEDOT coating[J]. ACS Applied Materials & Interfaces, 2018, 10(38): 32192-32200.
28	WU Chenling, ZHANG Sen, WU Wei, et al. Carbon nanotubes grown on the inner wall of carbonized wood tracheids for high-performance supercapacitors[J]. Carbon, 2019, 150: 311-318.
29	李腾飞, 黄璐君, 闫旭东, 等. 碳化钛/椴木多孔碳复合材料用于超级电容器性能的研究(英文)[J]. 无机材料学报, 2020, 35(1): 126-130.
	LI Tengfei, HUANG Lujun, YAN Xudong, et al. Ti₃C₂T_x/wood carbon as high-areal-capacity electrodes for supercapacitors (English)[J]. Journal of Inorganic Materials, 2020, 35(1): 126-130.
30	WU Wei, WANG Xin, DENG Yuanyuan, et al. In situ synthesis of polyaniline/carbon nanotube composites in a carbonized wood scaffold for high performance supercapacitors[J]. Nanoscale, 2020, 12(34): 17738-17745.
31	ROY P, SRIVASTAVA S K. Nanostructured anode materials for lithium ion batteries[J]. Journal of Materials Chemistry A, 2015, 3(6):2454-2484.
32	孙仲振, 赵云. 锂离子电池组应用中存在的问题[J]. 化工设计通讯, 2021, 47(1): 82-85.
	SUN Zhongzhen, ZHAO Yun. The problems existing in the application of lithium-ion batteries pack[J]. Chemical Engineering Design Communications, 2021, 47(1): 82-85.
33	FENG Ningning, WANG Bingliang, YU Zhuo, et al. Mechanism-of-action elucidation of reversible Li-CO₂ batteries using the water-in-salt electrolyte[J]. ACS Applied Materials & Interfaces, 2021, 13(6): 7396-7404.
34	WOO H S, SON H B, MIN Jiyun, et al. Ionic liquid-based gel polymer electrolyte containing zwitterion for lithium-oxygen batteries[J]. Electrochimica Acta, 2020, 345: 136248.
35	郑凌云, 吴双双, 王傲楠, 等. Li-CO₂电池电化学机理研究进展[J]. 山东化工, 2019, 48(19): 60-61, 64.
	ZHENG Lingyun, WU Shuangshuang, WANG Aonan, et al. Recent advances in electrochemical mechanism of Li-CO₂ batteries[J]. Shandong Chemical Industry, 2019, 48(19): 60-61, 64.
36	SHI Baohui, SHANG Yuanyuan, PEI Yong, et al. Low tortuous, highly conductive, and high-areal-capacity battery electrodes enabled by through-thickness aligned carbon fiber framework[J]. Nano Lett., 2020, 20(7): 5504-5512.
37	WANG Jun, YAO Hongyan, DU Chunya, et al. Polyimide schiff base as a high-performance anode material for lithium-ion batteries[J]. Journal of Power Sources, 2021, 482: 228931.
38	SONG Huiyu, CHEN Xilong, ZHENG Guangli, et al. Dendrite-free composite Li anode assisted by Ag nanoparticles in a wood-derived carbon frame[J]. ACS Applied Materials & Interfaces, 2019, 11(20): 18361-18367.
39	SONG Huiyu, XU Shaomao, LI Yiju, et al. Hierarchically porous, ultrathick, “breathable”wood-derived cathode for lithium-oxygen batteries[J]. Advanced Energy Materials, 2018, 8(4): 1701203.
40	XU Shaomao, CHEN Chaiji, KUANG Yudi, et al. Flexible lithium-CO₂ battery with ultrahigh capacity and stable cycling[J]. Energy & Environmental Science, 2018, 11(11): 3231-3237.
41	CHEN Minfeng, ZHOU Weijun, CHEN Jizhang, et al. Rendering wood veneers flexible and electrically conductive through delignification and electroless Ni plating[J]. Materials (Basel), 2019, 12(19): 3198.
42	郭晋芝, 万放, 吴兴隆, 等. 钠离子电池工作原理及关键电极材料研究进展[J]. 分子科学学报, 2016, 32(4): 265-279.
	GUO Jinzhi, WAN Fang, WU Xinglong, et al. Sodium-ion batteries: work mechanism and the research progress of key electrode materials [J]. Journal of Molecular Science, 2016, 32(4): 265-279.
43	HAN Longfei, WANG Junling, MU Xiaowei, et al. Anisotropic, low-tortuosity and ultra-thick red P@C-wood electrodes for sodium-ion batteries[J]. Nanoscale, 2020, 12(27): 14642-14650.
44	JIA Chao, LI Tian, CHEN Chaoji, et al. Scalable, anisotropic transparent paper directly from wood for light management in solar cells[J]. Nano Energy, 2017, 36: 366-373.
45	LI Yuanyuan, CHENG Ming, JUNGSTEDT E, et al. Optically transparent wood substrate for perovskite solar cells[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(6): 6061-6067.

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