质子交换膜燃料电池气体扩散层结构与设计研究进展

doi:10.16085/j.issn.1000-6613.2023-1102

摘要/Abstract

摘要：

气体扩散层（GDL）在质子交换膜燃料电池（PEMFC）中起到支撑催化层、传输反应气体和排出反应过程中产生的水的作用，设计和优化GDL的结构对提升燃料电池的性能有重要作用。本文首先介绍了氢燃料电池应用前景，简述了PEMFC的结构和工作原理，指出了目前GDL的气液传输能力不足的问题，分析了孔结构、碳材料、微孔层微观结构、润湿性和耐久性五个因素对GDL性能的影响，并归纳了当前的研究进展，同时还涵盖了与GDL内传质过程相关的建模方法。最后总结了影响GDL性能的各种因素，并对质子交换膜燃料电池内的GDL发展进行了展望，指出用新型金属泡沫材料代替传统碳材料构建气体扩散层-双极板集成结构从而缩短传质路径并降低传质阻力，提出利用新兴的3D打印技术去构建高精度具有复杂结构的气体扩散层。本综述对未来优化GDL结构、提高燃料电池性能具有一定的指导意义。

关键词: 燃料电池, 气液两相流, 优化设计, 传质, 数值模拟

Abstract:

Gas diffusion layer (GDL) plays an important role in supporting the catalytic layer and providing the transmission access of gas and water in proton exchange membrane fuel cell (PEMFC). Designing and optimizing the structure of GDL significantly influence the performance of fuel cell. In this paper, the application prospect of hydrogen fuel cell and the structure and working principle of PEMFC are briefly introduced. The problem of insufficient gas-liquid transmission capacity of GDL is pointed out and the effects of pore structure, carbon material, and microstructure of microporous layer, wettability and durability on the performance of GDL are analyzed. This review also summarizes the current research progress of GDL including the modeling studies. Finally, various factors affecting the performance of GDL are summarized, and the development of PEMFC is prospected. It is pointed out that novel metal foam materials could replace the traditional carbon materials to construct the GDL-BP integrated structure with shorter transmission path and smaller mass transfer resistance. It is also proposed to use the emerging 3D printing technology to construct GDL with high precision and complex structure. This review has certain guiding significance for future work in optimizing the gas diffusion layer structure and improving the fuel cell performance.

Key words: fuel cells, gas-liquid flow, optional design, mass transfer, numerical simulation

中图分类号:

TQ028.8

陈匡胤, 李蕊兰, 童杨, 沈建华. 质子交换膜燃料电池气体扩散层结构与设计研究进展[J]. 化工进展, 2023, 42(S1): 246-259.

CHEN Kuangyin, LI Ruilan, TONG Yang, SHEN Jianhua. Structure design of gas diffusion layer in proton exchange membrane fuel cell[J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 246-259.

图/表 13

图1 气体扩散层的结构示意图

图2 GDL的厚度和孔隙率对GDL传质的影响

图3 具有不同微孔层结构的GDL结构示意图[31]

图4 用于研究蒸汽渗透性的装置示意图和含有在碳纸上原位生长的CNTs的GDL电子显微镜图像[34]

图5 表面裂纹类型对GDL水传输的影响[37]

图6 裂缝对GDL水传输的影响[38]

图7 PTFE质量分数10%的GDL表面出现液滴

图8 不同CNT含量对燃料电池性能的影响

图9 中子照相法测量改性 GDL 的毛细管压力实验及在不同毛细管压力作用下选定区域的水厚度和饱和度[水出现的位置：(1) 0mbar，(2) 10mbar，(3) 20mbar，(4) 40mbar，(5) 50mbar。1mbar=102Pa]

图10 不同亲水图案对燃料电池性能的影响[56]

图11 GDL中不同的FEP含量对燃料电池耐久性的影响

图12 微孔层表面的裂缝对GDL耐久性的影响[60]

图13 有限元模拟水和氧气在GDL中的分布[56]

参考文献 62

63	HUANG Xiang, HE Yinwu, ZHOU Wei, et al. Pore network modeling of fibrous porous media of uniform and gradient porosity[J]. Powder Technology, 2019, 343: 350-361.
64	NIU Zhiqiang, BAO Zhiming, WU Jingtian, et al. Two-phase flow in the mixed-wettability gas diffusion layer of proton exchange membrane fuel cells[J]. Applied Energy, 2018, 232: 443-450.
65	PARK Jae Wan, JIAO Kui, LI Xianguo. Numerical investigations on liquid water removal from the porous gas diffusion layer by reactant flow[J]. Applied Energy, 2010, 87(7): 2180-2186.
66	WANG C Y, CHENG P. A multiphase mixture model for multiphase, multicomponent transport in capillary porous media—Ⅰ. Model development[J]. International Journal of Heat and Mass Transfer, 1996, 39(17): 3607-3618.
67	CHENG P, WANG C Y. A multiphase mixture model for multiphase, multicomponent transport in capillary porous media—Ⅱ. Numerical simulation of the transport of organic compounds in the subsurface[J]. International Journal of Heat and Mass Transfer, 1996, 39(17): 3619-3632.
68	HE Wensheng, YI Jung S, VAN NGUYEN Trung. Two-phase flow model of the cathode of PEM fuel cells using interdigitated flow fields[J]. AIChE Journal, 2000, 46(10): 2053-2064.
69	NATARAJAN Dilip, VAN NGUYEN Trung. Three-dimensional effects of liquid water flooding in the cathode of a PEM fuel cell[J]. Journal of Power Sources, 2003, 115(1): 66-80.
70	Jin Hyun NAM, KAVIANY Massoud. Effective diffusivity and water-saturation distribution in single- and two-layer PEMFC diffusion medium[J]. International Journal of Heat and Mass Transfer, 2003, 46(24): 4595-4611.
71	WEBER Adam Z, DARLING Robert M, NEWMAN John. Modeling two-phase behavior in PEFCs[J]. Journal of the Electrochemical Society, 2004, 151(10): A1715.
72	NATARAJAN Dilip, VAN NGUYEN Trung. A two-dimensional, two-phase, multicomponent, transient model for the cathode of a proton exchange membrane fuel cell using conventional gas distributors[J]. Journal of the Electrochemical Society, 2001, 148(12): A1324.
73	SIEGEL N P, ELLIS M W, NELSON D J, et al. A two-dimensional computational model of a PEMFC with liquid water transport[J]. Journal of Power Sources, 2004, 128(2): 173-184.
74	MUKHERJEE Partha P, KANG Qinjun, WANG Chaoyang. Pore-scale modeling of two-phase transport in polymer electrolyte fuel cells—Progress and perspective[J]. Energy & Environmental Science, 2011, 4(2): 346-369.
1	ILBEYGI Hamid, GHASEMI Mostafa, EMADZADEH D, et al. Power generation and wastewater treatment using a novel SPEEK nanocomposite membrane in a dual chamber microbial fuel cell[J]. International Journal of Hydrogen Energy, 2015, 40(1): 477-487.
2	LIU Jiao, YU Haiyang, ZHANG Tianheng, et al. Honeycomb-like self-supported Co-N-C catalysts with an ultrastable structure: Highly efficient electrocatalysts toward oxygen reduction reaction in alkaline and acidic solutions[J]. ACS Applied Energy Materials, 2021, 4(3): 2522-2530.
3	ZHU Mengzhao, ZHAO Chao, LIU Xiaokang, et al. Single atomic cerium sites with a high coordination number for efficient oxygen reduction in proton-exchange membrane fuel cells[J]. ACS Catalysis, 2021, 11(7): 3923-3929.
4	ABDELKAREEM Mohammad ALI, ELSAID Khaled, WILBERFORCE Tabbi, et al. Environmental aspects of fuel cells: A review[J]. Science of the Total Environment, 2021, 752: 141803.
5	ELWAN Hosni Ahmed, MAMLOUK Mohamed, SCOTT Keith. A review of proton exchange membranes based on protic ionic liquid/polymer blends for polymer electrolyte membrane fuel cells[J]. Journal of Power Sources, 2021, 484: 229197.
6	LUCIANI Sara, TONOLI Andrea. Control strategy assessment for improving PEM fuel cell system efficiency in fuel cell hybrid vehicles[J]. Energies, 2022, 15(6): 2004.
7	BELZ S. A synergetic use of hydrogen and fuel cells in human spaceflight power systems[J]. Acta Astronautica, 2016, 121: 323-331.
8	YAN Mei, LI Guotong, LI Menglin, et al. Hierarchical predictive energy management of fuel cell buses with launch control integrating traffic information[J]. Energy Conversion and Management, 2022, 256: 115397.
9	氢云链. 中国首款量产氢轿车：长安深蓝C385[J]. 上海节能, 2022(6): 725.
	QING Yunlian. China’s first mass-produced hydrogen car: Changan Deep Blue C385[J]. Shanghai Energy Conservation, 2022(6): 725.
10	JIAO Kui, XUAN Jin, DU Qing, et al. Designing the next generation of proton-exchange membrane fuel cells[J]. Nature, 2021, 595(7867): 361-369.
11	JEON Dong Hyup, KIM Kwang Nam, BAEK Seung Man, et al. The effect of relative humidity of the cathode on the performance and the uniformity of PEM fuel cells[J]. International Journal of Hydrogen Energy, 2011, 36(19): 12499-12511.
12	Željko PENGA, BERGBREITER Christian, BARBIR Frano, et al. Numerical and experimental analysis of liquid water distribution in PEM fuel cells[J]. Energy Conversion and Management, 2019, 189: 167-183.
13	杨景帅. 燃料电池用新型耐高温质子交换膜的制备与性能研究[D]. 沈阳: 东北大学, 2013.
	YANG Jingshuai. Preparation and investigation of novel high temperature proton exchange membranes for fuel cell applications[D]. Shenyang: Northeastern University, 2013.
14	WANG Yun, RUIZ DIAZ Daniela Fernanda, CHEN Ken S, et al. Materials, technological status, and fundamentals of PEM fuel cells—A review[J]. Materials Today, 2020, 32: 178-203.
15	XING Lei, SHI Weidong, SU Huaneng, et al. Membrane electrode assemblies for PEM fuel cells: A review of functional graded design and optimization[J]. Energy, 2019, 177: 445-464.
16	PARK Sehkyu, LEE Jong-Won, POPOV Branko N. A review of gas diffusion layer in PEM fuel cells: Materials and designs[J]. International Journal of Hydrogen Energy, 2012, 37(7): 5850-5865.
17	WU Rui, ZHU Xun, LIAO Qiang, et al. A pore network study on the role of micro-porous layer in control of liquid water distribution in gas diffusion layer[J]. International Journal of Hydrogen Energy, 2010, 35(14): 7588-7593.
18	NANADEGANI Fereshteh Salimi, LAY Ebrahim Nemati, SUNDEN Bengt. Effects of an MPL on water and thermal management in a PEMFC[J]. International Journal of Energy Research, 2019, 43(1): 274-296.
19	FISHMAN Z, BAZYLAK A. Heterogeneous through-plane porosity distributions for treated PEMFC GDLs Ⅰ. PTFE effect[J]. Journal of the Electrochemical Society, 2011, 158(8): B841.
20	OMRANI Reza, SHABANI Bahman. Gas diffusion layer modifications and treatments for improving the performance of proton exchange membrane fuel cells and electrolysers: A review[J]. International Journal of Hydrogen Energy, 2017, 42(47): 28515-28536.
21	Vikalp JHA, HARIHARAN R, KRISHNAMURTHY Balaji. A 3 dimensional numerical model to study the effect of GDL porosity on high temperature PEM fuel cells[J]. International Journal of Heat and Mass Transfer, 2020, 161: 120311.
22	XIA Lingchao, NI Meng, HE Qijiao, et al. Optimization of gas diffusion layer in high temperature PEMFC with the focuses on thickness and porosity[J]. Applied Energy, 2021, 300: 117357.
23	Prince ABRAHAM B, Kalidasa MURUGAVEL K. Influence of catalyst layer and gas diffusion layer porosity in proton exchange membrane fuel cell performance[J]. Electrochimica Acta, 2021, 389: 138793.
24	KONG Chang sun, KIM Do-Young, LEE Han-Kyu, et al. Influence of pore-size distribution of diffusion layer on mass-transport problems of proton exchange membrane fuel cells[J]. Journal of Power Sources, 2002, 108(1/2): 185-191.
25	TANG Haolin, WANG Shenlong, PAN Mu, et al. Porosity-graded micro-porous layers for polymer electrolyte membrane fuel cells[J]. Journal of Power Sources, 2007, 166(1): 41-46.
26	Donggun KO, Seungwoo DOH, PARK Hyun Sun, et al. The effect of through plane pore gradient GDL on the water distribution of PEMFC[J]. International Journal of Hydrogen Energy, 2018, 43(4): 2369-2380.
27	OKONKWO Paul C, OTOR Clement. A review of gas diffusion layer properties and water management in proton exchange membrane fuel cell system[J]. International Journal of Energy Research, 2021, 45(3): 3780-3800.
28	MASAYOSHI Yuasa, AKIKO Koga, TETSUYA Kida, et al. Structural optimization of gas diffusion electrodes loaded with LaMnO₃ electrocatalysts[J]. Journal of Applied Electrochemistry, 2010, 40(3): 675-681.
29	WANG Xiaoli, ZHANG Huamin, ZHANG Jianlu, et al. A bi-functional micro-porous layer with composite carbon black for PEM fuel cells[J]. Journal of Power Sources, 2006, 162(1): 474-479.
30	CHEN Honghua, CHANG Min-Hsing. Effect of cathode microporous layer composition on proton exchange membrane fuel cell performance under different air inlet relative humidity[J]. Journal of Power Sources, 2013, 232: 306-309.
31	LIN Guangyi, LIU Shouyi, YU Boquan, et al. Preparation of graded microporous layers for enhanced water management in fuel cells[J]. Journal of Applied Polymer Science, 2020, 137(47): e49564.
32	LIN Shengyan, CHANG Min-Hsing. Effect of microporous layer composed of carbon nanotube and acetylene black on polymer electrolyte membrane fuel cell performance[J]. International Journal of Hydrogen Energy, 2015, 40(24): 7879-7885.
33	XIE Zhiyong, CHEN Guofen, YU Xiao, et al. Carbon nanotubes grown in situ on carbon paper as a microporous layer for proton exchange membrane fuel cells[J]. International Journal of Hydrogen Energy, 2015, 40(29): 8958-8965.
34	LEE J, BANERJEE R, GEORGE M G, et al. Multiwall carbon nanotube-based microporous layers for polymer electrolyte membrane fuel cells[J]. Journal of the Electrochemical Society, 2017, 164(12): F1149-F1157.
35	OWEJAN Jon P, OWEJAN Jeanette E, GU Wenbin, et al. Water transport mechanisms in PEMFC gas diffusion layers[J]. Journal of the Electrochemical Society, 2010, 157(10): B1456.
36	ZHOU Chong, GUO Lingyi, CHEN Li, et al. Pore-scale modeling of air–water two phase flow and oxygen transport in gas diffusion layer of proton exchange membrane fuel cell[J]. Energies, 2021, 14(13): 3812.
37	SHI Xin, JIAO Daokuan, BAO Zhiming, et al. Liquid transport in gas diffusion layer of proton exchange membrane fuel cells: Effects of micro-porous layer cracks[J]. International Journal of Hydrogen Energy, 2022, 47(9): 6247-6258.
38	SASABE Takashi, DEEVANHXAY Phengxay, TSUSHIMA Shohji, et al. Soft X-ray visualization of the liquid water transport within the cracks of micro porous layer in PEMFC[J]. Electrochemistry Communications, 2011, 13(6): 638-641.
39	MARKÖTTER H, MANKE I, KRÜGER P, et al. Investigation of 3D water transport paths in gas diffusion layers by combined in situ synchrotron X-ray radiography and tomography[J]. Electrochemistry Communications, 2011, 13(9): 1001-1004.
40	ALRWASHDEH S S, MARKÖTTER H, HAUßMANN J, et al. Investigation of water transport dynamics in polymer electrolyte membrane fuel cells based on high porous micro porous layers[J]. Energy, 2016, 102: 161-165.
41	YANG Tien-Fu, HSUEH Ching-Yi, CHEN Bolin, et al. Effects of fluorinated ethylene propylene contents in a novel gas diffusion layer on cell performance of a proton exchange membrane fuel cell[J]. International Journal of Energy Research, 2022, 46(2): 1553-1564.
42	BOTTINO Aldo, CAPANNELLI Gustavo, COMITE Antonio, et al. Microporous layers based on poly(vinylidene fluoride) and sulfonated poly(vinylidene fluoride)[J]. International Journal of Hydrogen Energy, 2015, 40(42): 14690-14698.
43	ZHOU Ke, LI Tianya, HAN Yufen, et al. Optimizing the hydrophobicity of GDL to improve the fuel cell performance[J]. RSC Advances, 2021, 11(4): 2010-2019.
44	LI Linbo, CHEN Jun, MOSALI Venkata Sai Sriram, et al. Hydrophobicity graded gas diffusion layer for stable electrochemical reduction of CO₂ [J]. Angewandte Chemie International Edition, 2022, 61(39): e202208534.
45	FERREIRA Rui B, FALCÃO D S, OLIVEIRA V B, et al. Experimental study on the membrane electrode assembly of a proton exchange membrane fuel cell: Effects of microporous layer, membrane thickness and gas diffusion layer hydrophobic treatment[J]. Electrochimica Acta, 2017, 224: 337-345.
46	MORTAZAVI Mehdi, TAJIRI Kazuya. Effect of the PTFE content in the gas diffusion layer on water transport in polymer electrolyte fuel cells (PEFCs)[J]. Journal of Power Sources, 2014, 245: 236-244.
47	SCHWEISS R, STEEB M, WILDE P M. Mitigation of water management in PEM fuel cell cathodes by hydrophilic wicking microporous layers[J]. Fuel Cells, 2010, 10(6): 1176-1180.
75	HINEBAUGH James, FISHMAN Zachary, BAZYLAK A. Unstructured pore network modeling with heterogeneous PEMFC GDL porosity distributions[J]. Journal of the Electrochemical Society, 2010, 157(11): B1651.
76	SINHA Puneet K, WANG Chaoyang. Pore-network modeling of liquid water transport in gas diffusion layer of a polymer electrolyte fuel cell[J]. Electrochimica Acta, 2007, 52(28): 7936-7945.
77	SINHA Puneet K, MUKHERJEE Partha P, WANG Chaoyang. Impact of GDL structure and wettability on water management in polymer electrolyte fuel cells[J]. Journal of Materials Chemistry, 2007, 17(30): 3089-3103.
78	FAZELI Mohammadreza, HINEBAUGH James, BAZYLAK Aimy. Investigating inlet condition effects on PEMFC GDL liquid water transport through pore network modeling[J]. ECS Transactions, 2014, 64(3): 593-602.
79	SAKAIDA Satoshi, TABE Yutaka, CHIKAHISA Takemi. Large scale simulation of liquid water transport in a gas diffusion layer of polymer electrolyte membrane fuel cells using the lattice Boltzmann method[J]. Journal of Power Sources, 2017, 361: 133-143.
80	YANG Mingyang, JIANG Y, LIU Jinling, et al. Lattice Boltzmann method modeling and experimental study on liquid water characteristics in the gas diffusion layer of proton exchange membrane fuel cells[J]. International Journal of Hydrogen Energy, 2022, 47(18): 10366-10380.
81	RAMA Pratap, LIU Yu, CHEN Rui, et al. An X-ray tomography based lattice boltzmann simulation study on gas diffusion layers of polymer electrolyte fuel cells[J]. Journal of Fuel Cell Science and Technology, 2010, 7(3): 1.
82	RAMA P, LIU Y, CHEN R, et al. Simulation of liquid water breakthrough in a nanotomography reconstruction of a carbon paper gas-diffusion layer[J]. AIChE Journal, 2012, 58(2): 646-655.
48	KITAHARA Tatsumi, NAKAJIMA Hironori, OKAMURA Kosuke. Gas diffusion layers coated with a microporous layer containing hydrophilic carbon nanotubes for performance enhancement of polymer electrolyte fuel cells under both low and high humidity conditions[J]. Journal of Power Sources, 2015, 283: 115-124.
49	SPERNJAK Dusan, MUKUNDAN Rangachary, BORUP Rodney L, et al. Enhanced water management of polymer electrolyte fuel cells with additive-containing microporous layers[J]. ACS Applied Energy Materials, 2018, 1(11): 6006-6017.
50	KORESAWA Ryo, UTAKA Yoshio. Improvement of oxygen diffusion characteristic in gas diffusion layer with planar-distributed wettability for polymer electrolyte fuel cell[J]. Journal of Power Sources, 2014, 271: 16-24.
51	GUO Feng, YANG Xiaoling, JIANG Haibo, et al. An ultrasonic atomization spray strategy for constructing hydrophobic and hydrophilic synergistic surfaces as gas diffusion layers for proton exchange membrane fuel cells[J]. Journal of Power Sources, 2020, 451: 227784.
52	GERTEISEN D, HEILMANN T, ZIEGLER C. Enhancing liquid water transport by laser perforation of a GDL in a PEM fuel cell[J]. Journal of Power Sources, 2008, 177(2): 348-354.
53	MANAHAN M P, HATZELL M C, KUMBUR E C, et al. Laser perforated fuel cell diffusion media. Part I: Related changes in performance and water content[J]. Journal of Power Sources, 2011, 196(13): 5573-5582.
54	Antoni FORNER-CUENCA, BIESDORF Johannes, GUBLER Lorenz, et al. Engineered water highways in fuel cells: Radiation grafting of gas diffusion layers[J]. Advanced Materials, 2015, 27(41): 6317-6322.
55	UTAKA Yoshio, KORESAWA Ryo. Effect of wettability-distribution pattern of the gas diffusion layer with a microgrooved separator on polymer electrolyte fuel cell performance[J]. Journal of Power Sources, 2017, 363: 227-233.
56	ZHANG Wenhui, GUO Feng, ZHOU Yingjie, et al. Gas diffusion layer with a regular hydrophilic structure boosts the power density of proton exchange membrane fuel cells via the construction of water highways[J]. ACS Applied Materials & Interfaces, 2022, 14(15): 17578-17584.
57	HIRAMITSU Yusuke, SATO Hitoshi, KOBAYASHI Kenji, et al. Controlling gas diffusion layer oxidation by homogeneous hydrophobic coating for polymer electrolyte fuel cells[J]. Journal of Power Sources, 2011, 196(13): 5453-5469.
58	YU Shuchun, HAO Jinkai, LI Jin, et al. Effect of distribution of polytetrafluoroethylene on durability of gas diffusion backing in proton exchange membrane fuel cell[J]. Materials Research Bulletin, 2020, 122: 110684.
59	LATORRATA Saverio, GALLO STAMPINO Paola, CRISTIANI Cinzia, et al. Performance evaluation and durability enhancement of FEP-based gas diffusion media for PEM fuel cells[J]. Energies, 2017, 10(12): 2063.
60	CHUN Jeong Hwan, Dong Hyun JO, KIM Sang Gon, et al. Improvement of the mechanical durability of micro porous layer in a proton exchange membrane fuel cell by elimination of surface cracks[J]. Renewable Energy, 2012, 48: 35-41.
61	WANG Z H, WANG C Y, CHEN K S. Two-phase flow and transport in the air cathode of proton exchange membrane fuel cells[J]. Journal of Power Sources, 2001, 94(1): 40-50.
62	ZHAO Benzhong, MACMINN Christopher W, PRIMKULOV Bauyrzhan K, et al. Comprehensive comparison of pore-scale models for multiphase flow in porous media[J]. Proceedings of the National Academy of Sciences of the United States of America, 2019, 116(28): 13799-13806.

[1]	许家珩, 李永胜, 罗春欢, 苏庆泉. 甲醇水蒸气重整工艺的优化[J]. 化工进展, 2023, 42(S1): 41-46.
[2]	孙玉玉, 蔡鑫磊, 汤吉海, 黄晶晶, 黄益平, 刘杰. 反应精馏合成甲基丙烯酸甲酯工艺优化及节能[J]. 化工进展, 2023, 42(S1): 56-63.
[3]	郭强, 赵文凯, 肖永厚. 增强流体扰动强化变压吸附甲硫醚/氮气分离的数值模拟[J]. 化工进展, 2023, 42(S1): 64-72.
[4]	邵博识, 谭宏博. 锯齿波纹板对挥发性有机物低温脱除过程强化模拟分析[J]. 化工进展, 2023, 42(S1): 84-93.
[5]	王太, 苏硕, 李晟瑞, 马小龙, 刘春涛. 交流电场中贴壁气泡的动力学行为[J]. 化工进展, 2023, 42(S1): 133-141.
[6]	盛维武, 程永攀, 陈强, 李小婷, 魏嘉, 李琳鸽, 陈险峰. 微气泡和微液滴双强化脱硫反应器操作分析[J]. 化工进展, 2023, 42(S1): 142-147.
[7]	赵晨, 苗天泽, 张朝阳, 洪芳军, 汪大海. 负压状态窄缝通道乙二醇水溶液传热特性[J]. 化工进展, 2023, 42(S1): 148-157.
[8]	黄益平, 李婷, 郑龙云, 戚傲, 陈政霖, 史天昊, 张新宇, 郭凯, 胡猛, 倪泽雨, 刘辉, 夏苗, 主凯, 刘春江. 三级环流反应器中气液流动与传质规律[J]. 化工进展, 2023, 42(S1): 175-188.
[9]	杨寒月, 孔令真, 陈家庆, 孙欢, 宋家恺, 王思诚, 孔标. 微气泡型下向流管式气液接触器脱碳性能[J]. 化工进展, 2023, 42(S1): 197-204.
[10]	刘炫麟, 王驿凯, 戴苏洲, 殷勇高. 热泵中氨基甲酸铵分解反应特性及反应器结构优化[J]. 化工进展, 2023, 42(9): 4522-4530.
[11]	赵曦, 马浩然, 李平, 黄爱玲. 错位碰撞型微混合器混合性能的模拟分析与优化设计[J]. 化工进展, 2023, 42(9): 4559-4572.
[12]	张启, 赵红, 荣峻峰. 质子交换膜燃料电池中氧还原反应抗毒性电催化剂研究进展[J]. 化工进展, 2023, 42(9): 4677-4691.
[13]	王晨, 白浩良, 康雪. 大功率UV-LED散热与纳米TiO₂光催化酸性红26耦合系统性能[J]. 化工进展, 2023, 42(9): 4905-4916.
[14]	卜治丞, 焦波, 林海花, 孙洪源. 脉动热管计算流体力学模型与研究进展[J]. 化工进展, 2023, 42(8): 4167-4181.
[15]	李洞, 王倩倩, 张亮, 李俊, 付乾, 朱恂, 廖强. 非水系纳米流体热再生液流电池串联堆性能特性[J]. 化工进展, 2023, 42(8): 4238-4246.