单宁酸-纳米协同改性胶原纤维多孔材料的制备及其油水分离性能

doi:10.16085/j.issn.1000-6613.2023-1085

化工进展 ›› 2024, Vol. 43 ›› Issue (8): 4624-4629.DOI: 10.16085/j.issn.1000-6613.2023-1085

• 资源与环境化工 • 上一篇

单宁酸-纳米协同改性胶原纤维多孔材料的制备及其油水分离性能

石佳博(), 张宇轩, 陈雪峰, 谭蕉君

陕西科技大学轻工科学与工程学院，轻化工程国家级实验教学示范中心，陕西西安 710021

收稿日期:2023-06-30 修回日期:2023-08-02 出版日期:2024-08-15 发布日期:2024-09-02
通讯作者: 石佳博
作者简介:石佳博（1989—），男，副教授，硕士生导师，研究方向为生物质材料与化学。E-mail：shijiabo@sust.edu.cn。
基金资助:
国家自然科学基金青年基金(22208201);四川省科技成果转移转化示范项目(2024ZHCG0082);中国博士后科学基金(2023M743106);绵阳市中央引导地方科技发展资金项目(2023ZYDF037);大学生创新创业训练计划(202210708033);广西清洁化制浆造纸与污染控制重点实验室开放基金(KF201904);陕西省重点研发计划一般项目(2023-YBGY-474)

Preparation and oil-water separation property of tannic acid-nanoclay synergistically modified collagen fiber-based porous materials

SHI Jiabo(), ZHANG Yuxuan, CHEN Xuefeng, TAN Jiaojun

College of Bioresources Chemical and Materials Engineering and National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science & Technology, Xi’an 710021, Shaanxi, China

Received:2023-06-30 Revised:2023-08-02 Online:2024-08-15 Published:2024-09-02
Contact: SHI Jiabo

摘要/Abstract

摘要：

以胶原纤维为代表的生物质基多孔材料因其具有可再生、储量丰富等特点且保留胶原纤维独特的多尺度孔隙结构以及具有优异的分离能力、可重复使用和可生物降解等优势，近年在含油废水处理等领域备受关注。针对胶原纤维多孔材料存在着油水分离效率低等问题，本文利用单宁酸与金属离子（铝和锆）掺杂锂藻土纳米片的协同交联体系来改性胶原纤维，制备了一种具有油水分离性能的胶原纤维基多孔材料。结果表明：该协同交联体系可提高胶原纤维多孔材料的自支撑性、成型性和多孔性，同时未改变胶原的三股螺旋构象并可起到稳定胶原微结构的作用；协同交联改性后胶原纤维多孔材料的收缩温度提升至90℃以上，接触角提升至98°以上，油水分离效率提升至68%以上，表明其热稳定性、疏水性以及油水分离性能均得以改善。

关键词: 生物质, 胶原纤维, 多孔材料, 协同交联, 油水分离, 纳米材料

Abstract:

In recent years, owing to their advantages of being renewable and abundant, retaining unique multi-scale pore structure, and exhibiting excellent separation ability, reusability and biodegradability, biomass-based porous materials represented by collagen fibers have attracted much attention in the fields of oil-containing wastewater treatment. To address the problems of low oil-water separation efficiency of collagen fiber porous materials, a novel collagen fiber-based porous material with oil-water separation performance was prepared by modification of collagen fibers using a synergistic cross-linking system of tannic acid and metal ion (aluminum and zirconium) doped Laponite nanoplatelets. The results showed that the synergistic cross-linking system improved the self-standing, formability and porosity of the porous material without altering the triple-helix conformation of the collagen and stabilizing the collagen microstructures. Moreover, after the synergistic cross-linking modification, the shrinkage temperature, water contact angle and oil-water separation efficiency of the collagen fiber porous material network were increased to over 90℃, 98° and 68%, respectively, indicating that the thermal stability, hydrophobicity and oil-water separation properties were improved.

Key words: biomass, collagen fibers, porous materials, synergistic crosslinking, oil-water separation, nanomaterials

中图分类号:

X506

石佳博, 张宇轩, 陈雪峰, 谭蕉君. 单宁酸-纳米协同改性胶原纤维多孔材料的制备及其油水分离性能[J]. 化工进展, 2024, 43(8): 4624-4629.

SHI Jiabo, ZHANG Yuxuan, CHEN Xuefeng, TAN Jiaojun. Preparation and oil-water separation property of tannic acid-nanoclay synergistically modified collagen fiber-based porous materials[J]. Chemical Industry and Engineering Progress, 2024, 43(8): 4624-4629.

图/表 7

图1 不同多孔材料的数码照片

图2 不同多孔材料的SEM图

图3 不同多孔材料的平均孔径和孔隙率

图4 LAP纳米片以及不同多孔材料的XRD谱图

图5 不同多孔材料的收缩温度

图6 不同多孔材料的水接触角和对应照片

图7 不同多孔材料分别对菜籽油的分离过程及CFs-TA-Al/LAP和CFs-TA-Zr/LAP多孔材料对菜籽油的分离机制

参考文献 26

1	左继浩, 陈嘉慧, 文秀芳, 等. 用于分离油水乳液的先进材料[J]. 化学进展, 2019, 31(10): 1440-1458.
	ZUO Jihao, CHEN Jiahui, WEN Xiufang, et al. Advanced materials for separation of oil/water emulsion[J]. Progress in Chemistry, 2019, 31(10): 1440-1458.
2	CHILVERS B L, MORGAN K J, WHITE B J. Sources and reporting of oil spills and impacts on wildlife 1970—2018[J]. Environmental Science and Pollution Research, 2021, 28(1): 754-762.
3	辛玥, 宋爽, 张芝蕾, 等. 鳞片状BiVO₄不锈钢网涂层的制备及其在油水分离中的应用[J]. 化工进展, 2021, 40(6): 3536-3542.
	XIN Yue, SONG Shuang, ZHANG Zhilei, et al. Preparation of scale-like BiVO₄ coated mesh and its application in oil-water separation[J]. Chemical Industry and Engineering Progress, 2021, 40(6): 3536-3542.
4	戴国琛, 张泽天, 高文伟, 等. 油水乳液分离吸附材料的分离原理、构建方法和分离性能[J]. 化工进展, 2019, 38(4): 1785-1793.
	DAI Guochen, ZHANG Zetian, GAO Wenwei, et al. Separation principle, fabrication strategies and performance of sorbents for oil-water emulsions[J]. Chemical Industry and Engineering Progress, 2019, 38(4): 1785-1793.
5	ZHANG Wanqi, LIU Yiting, TAO Fengbin, et al. An overview of biomass-based oil/water separation materials[J]. Separation and Purification Technology, 2023, 316: 123767.
6	ZHENG Weiwei, HUANG Jianying, LI Shuhui, et al. Advanced materials with special wettability toward intelligent oily wastewater remediation[J]. ACS Applied Materials & Interfaces, 2021, 13(1): 67-87.
7	董哲勤, 王宝娟, 许振良, 等. 油水分离功能膜制备技术研究进展[J]. 化工进展, 2017, 36(1): 1-9.
	DONG Zheqin, WANG Baojuan, XU Zhenliang, et al. Recent progress on fabrication technology of functional membranes for oil/water separation[J]. Chemical Industry and Engineering Progress, 2017, 36(1): 1-9.
8	BAIG U, FAIZAN M, DASTAGEER M A. Polyimide based super-wettable membranes/materials for high performance oil/water mixture and emulsion separation: A review[J]. Advances in Colloid and Interface Science, 2021, 297: 102525.
9	FU Ye, GUO Zhiguang. Natural polysaccharide-based aerogels and their applications in oil-water separations: A review[J]. Journal of Materials Chemistry A, 2022, 10(15): 8129-8158.
10	PEI Ying, WANG Lu, TANG Keyong, et al. Biopolymer nanoscale assemblies as building blocks for new materials: A review[J]. Advanced Functional Materials, 2021, 31(15): 2008552.
11	TIAN Na, WU Shaohua, HAN Guangting, et al. Biomass-derived oriented neurovascular network-like superhydrophobic aerogel as robust and recyclable oil droplets captor for versatile oil/water separation[J]. Journal of Hazardous Materials, 2022, 424: 127393.
12	HUANG Lei, LUO Zhixuan, HUANG Xuexia, et al. Applications of biomass-based materials to remove fluoride from wastewater: A review[J]. Chemosphere, 2022, 301: 134679.
13	WU Ren, BAO Agula. Preparation of cellulose carbon material from cow dung and its CO₂ adsorption performance[J]. Journal of CO₂ Utilization, 2023, 68: 102377.
14	Barbara SZCZĘŚNIAK, PHURIRAGPITIKHON Jenjira, CHOMA Jerzy, et al. Recent advances in the development and applications of biomass-derived carbons with uniform porosity[J]. Journal of Materials Chemistry A, 2020, 8(36): 18464-18491.
15	WEI Gang, ZHANG Jianming, USUELLI Mattia, et al. Biomass vs inorganic and plastic-based aerogels: Structural design, functional tailoring, resource-efficient applications and sustainability analysis[J]. Progress in Materials Science, 2022, 125: 100915.
16	YANG Yang, JIANG Xiaofeng, Kheng Lim GOH, et al. The separation of oily water using low-cost natural materials: Review and development[J]. Chemosphere, 2021, 285: 131398.
17	XIAO Hanzhong, WANG Yujia, HAO Baicun, et al. Collagen fiber-based advanced separation materials: Recent developments and future perspectives[J]. Advanced Materials, 2022, 34(46): e2107891.
18	SORUSHANOVA Anna, DELGADO Luis M, WU Zhuning, et al. The collagen suprafamily: From biosynthesis to advanced biomaterial development[J]. Advanced Materials, 2019, 31(1): e1801651.
19	ORGEL Joseph P R O, IRVING Thomas C, MILLER Andrew, et al. Microfibrillar structure of type Ⅰ collagen in situ [J]. Proceedings of the National Academy of Sciences of the United States of America, 2006, 103(24): 9001-9005.
20	CHEN Guangyan, WANG Yanan, WANG Yujia, et al. Collagen fibers with tuned wetting properties for dual separation of oil-in-water and water-in-oil emulsion[J]. Journal of Materials Chemistry A, 2020, 8(46): 24388-24392.
21	SHI Jiabo, WANG Chunhua, NGAI To, et al. Diffusion and binding of Laponite clay nanoparticles into collagen fibers for the formation of leather matrix[J]. Langmuir, 2018, 34(25): 7379-7385.
22	LI Nan, YU Li, XIAO Zhiqun, et al. Biofouling mitigation effect of thin film nanocomposite membranes immobilized with Laponite mediated metal ions[J]. Desalination, 2020, 473: 114162.
23	SHI Jiabo, ZHANG Ruizhen, MI Zhiyuan, et al. Engineering a sustainable chrome-free leather processing based on novel lightfast wet-white tanning system towards eco-leather manufacture[J]. Journal of Cleaner Production, 2021, 282: 124504.
24	WU Bo, MU Changdao, ZHANG Guangzhao, et al. Effects of Cr³⁺ on the structure of collagen fiber[J]. Langmuir, 2009, 25(19): 11905-11910.
25	LOTSCH Bettina V, OZIN Geoffrey A. All-clay photonic crystals[J]. Journal of the American Chemical Society, 2008, 130(46): 15252-15253.
26	SHI Jiabo, ZHANG Ruizhen, YANG Na, et al. Hierarchical incorporation of surface-functionalized laponite clay nanoplatelets with type Ⅰ collagen matrix[J]. Biomacromolecules, 2021, 22(2): 504-513.

[1]	胡婷霞, 赵立欣, 姚宗路, 霍丽丽, 贾吉秀, 谢腾. 双金属催化剂在生物质焦油催化蒸汽重整领域的研究进展[J]. 化工进展, 2024, 43(8): 4354-4365.
[2]	任国瑜, 妥云, 郑文杰, 谯泽庭, 任壮壮, 赵娅莉, 尚军飞, 陈晓东, 高祥虎. 超疏水纳米涂层技术研究进展及应用[J]. 化工进展, 2024, 43(8): 4450-4463.
[3]	张子杭, 王树荣. 生物质热解转化与产物低碳利用研究进展[J]. 化工进展, 2024, 43(7): 3692-3708.
[4]	王颖杰, 祝新利. 溶胶-凝胶法制备高分散Ni-Cu/SiO₂ 促进间甲酚直接脱氧制甲苯[J]. 化工进展, 2024, 43(7): 3824-3833.
[5]	王丽娜, 武金升. 共价有机框架材料的合成与应用研究进展[J]. 化工进展, 2024, 43(7): 3834-3856.
[6]	赵伟刚, 张倩倩, 蓝钰玲, 闫雯, 周晓剑, 范毜仔, 杜官本. 真空绝热板芯材的研究进展与展望[J]. 化工进展, 2024, 43(7): 3910-3922.
[7]	江慧珍, 罗凯, 王艳, 费华, 吴登科, 叶卓铖, 曹雄金. 废弃生物质复合相变材料的构建与应用[J]. 化工进展, 2024, 43(7): 3934-3945.
[8]	何世坤, 张文豪, 冯君锋, 潘晖. 负载金属型固体酸催化木质纤维生物质定向转化为乙酰丙酸甲酯[J]. 化工进展, 2024, 43(6): 3042-3050.
[9]	龚雪梅, 蒋军, 王超, 梅长彤. 纳米纤维素疏水改性及其功能化应用研究进展[J]. 化工进展, 2024, 43(6): 3187-3198.
[10]	闫哲, 刘畅, 王丰旭, 周宏旺, 刘樨, 赵雪冰. 耦合生物质氧化转化的CO₂电化学还原[J]. 化工进展, 2024, 43(6): 3310-3321.
[11]	谢国平, 谭雪松, 刘鹏, 苗长林, 许光文, 庄新姝. 基于生物基衍生有机溶剂的木质纤维素预处理研究进展[J]. 化工进展, 2024, 43(6): 3347-3358.
[12]	卢欣欣, 蔡东仁, 詹国武. 基于固体前体构建集成催化剂及CO₂加氢研究进展[J]. 化工进展, 2024, 43(5): 2786-2802.
[13]	韩伟, 韩恒文, 程薇, 汤玮健. 碳中和目标驱动下生物质燃料技术研究进展[J]. 化工进展, 2024, 43(5): 2463-2474.
[14]	黄坤, 许明, 吴秀娟, 裴思佳, 刘大伟, 马晓迅, 徐龙. 生物质活性炭的制备与微结构特性调控研究进展[J]. 化工进展, 2024, 43(5): 2475-2493.
[15]	石鎏, 胡振中, 李显, 孙一鸣, 童珊, 刘显哲, 郭丽, 刘豪, 彭冰, 李硕, 罗光前, 姚洪. 生物质气压烘焙技术研究进展[J]. 化工进展, 2024, 43(5): 2494-2511.

单宁酸-纳米协同改性胶原纤维多孔材料的制备及其油水分离性能

Preparation and oil-water separation property of tannic acid-nanoclay synergistically modified collagen fiber-based porous materials

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 26

相关文章 15

编辑推荐

Metrics

本文评价