二维纳米材料在渗透汽化脱盐膜中的应用

doi:10.16085/j.issn.1000-6613.2022-0967

化工进展 ›› 2023, Vol. 42 ›› Issue (3): 1437-1447.DOI: 10.16085/j.issn.1000-6613.2022-0967

二维纳米材料在渗透汽化脱盐膜中的应用

陈仪¹(), 郭耀励¹^,², 叶海星³, 李宇璇¹, 牛青山¹()

^1.深圳大学高等研究院，广东深圳 518000
^2.中国石油大学(华东)重质油国家重点实验室，山东青岛 266580
^3.中国石油大学(华东)材料科学与工程学院，山东青岛 266580

收稿日期:2022-05-24 修回日期:2022-08-10 出版日期:2023-03-15 发布日期:2023-04-10
通讯作者: 牛青山
作者简介:陈仪（1998—），女，硕士研究生，研究方向为渗透汽化脱盐。E-mail：2016101054@email.szu.edu.cn。
基金资助:
国家自然基金委联合基金重点项目(U2006230);深圳市科创委基础研究面上项目(JCYJ20210324095202008)

Application of two-dimensional nanomaterials in pervaporation desalination membrane

CHEN Yi¹(), GUO Yaoli¹^,², YE Haixing³, LI Yuxuan¹, NIU Q.Jason¹()

^1.Institute of Advance Study, Shenzhen University, Shenzhen 518000, Guangdong, China
^2.State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao 266580, Shandong, China
^3.School of Materials Science andEngineering, China University of Petroleum (East China), Qingdao 266580, Shandong, China

Received:2022-05-24 Revised:2022-08-10 Online:2023-03-15 Published:2023-04-10
Contact: NIU Q.Jason

摘要/Abstract

摘要：

渗透汽化（PV）具有预处理要求低，截留率及水回收率高、抗污染性强等优势，在水处理尤其是高盐废水处理方面具有巨大的应用前景。但目前PV脱盐技术的分离效率较低、稳定性差、抗污染性能欠佳的劣势限制了PV膜在分离膜技术的应用和认可。新型膜材料如二维纳米材料的引入使得PV膜从材料到性能都有了较大提升，被认为是提高PV膜脱盐性能的有效手段。本文首先介绍了PV脱盐技术的分离机理，并从3个方面综述了二维纳米材料在制备PV脱盐膜中的应用现状：二维纳米材料的分类与合成方法、PV复合脱盐膜的制备途径与稳定性提高策略以及二维纳米材料对PV膜特性及脱盐性能的影响。文中指出现有的PV传质模型存在较大局限性且新型二维纳米材料的合成方法较难，为了进一步提高PV复合膜的性能并降低制备成本，还需完善PV复合膜的传质机制并优化二维纳米材料的制备工艺。

关键词: 渗透汽化, 二维纳米材料, 脱盐, 膜, 复合材料

Abstract:

Pervaporation (PV) possesses advantages such as the low requirement for feed water, high rejection and water recovery rate, and strong fouling resistance. Therefore, PV desalination can be competitive with other desalination technologies, especially for high-salinity brine. Current applications of PV desalination however are limited due to its relatively low separation efficiency, stability and fouling resistance. The introduction of novel membrane materials such as two-dimensional (2D) nanomaterials is considered to be an effective means to improve both the material properties and performance of PV desalination membranes. In this paper, a brief introduction to PV desalination technology is initially given. Then, the research status of two-dimensional nanomaterials in the field of PV desalination is reviewed from three perspectives: the properties and synthesis methods of nanomaterials, the preparation and modification strategies of nanocomposite membranes, and the influence of 2D nanomaterials on the properties and desalination performance of PV membranes. It is pointed out that the existing PV mass transfer model had great limitations and the synthesis of new two-dimensional nanomaterials faced great difficulty. To further improve the performance of PV compositemembranes and reduce the preparation cost, it is necessary to clarify the mass transfer mechanism of PV composite membrane and optimize the fabrication method of two-dimensional nanomaterials. In general, two-dimensional PV nanocomposite membranes with excellent separation performance and physicochemical properties will play an important role in the field of desalination.

Key words: pervaporation, 2D nanomaterials, desalination, membrane, composites

中图分类号:

TQ028.8

陈仪, 郭耀励, 叶海星, 李宇璇, 牛青山. 二维纳米材料在渗透汽化脱盐膜中的应用[J]. 化工进展, 2023, 42(3): 1437-1447.

CHEN Yi, GUO Yaoli, YE Haixing, LI Yuxuan, NIU Q.Jason. Application of two-dimensional nanomaterials in pervaporation desalination membrane[J]. Chemical Industry and Engineering Progress, 2023, 42(3): 1437-1447.

图/表 8

参考文献 58

1	WERBER J R, OSUJI C O, ELIMELECH M. Materials for next-generation desalination and water purification membranes[J]. Nature Reviews Materials, 2016, 1: 16018.
2	CULLMANN J, DILLEY M, EGERTON P, et al. 2021 state of climate services: Water[R/OL]. WMO, 2021. ,climate%20adaptation%2C%20sustainable%20development%20and%20disaster%20risk%20reduction.
3	蒙俊权.聚乙烯醇渗透汽化脱盐复合膜的制备及性能研究[D]. 北京: 北京化工大学, 2021.
	MENG Junquan. Study on preparation and performance of polyvinyl alcohol pervaporation desalination composite membranes[D]. Beijing: Beijing University of Chemical Technology, 2021.
4	LEE A, ELAM J W, DARLING S B. Membrane materials for water purification: design, development, and application[J]. Environmental Science: Water Research & Technology, 2016, 2(1): 17-42.
5	邱柯卫, 苏伟, 孙志猛, 等. 渗透蒸发脱盐技术研究进展[J]. 膜科学与技术, 2020, 40(6): 133-140.
	QIU Kewei, SU Wei, SUN Zhimeng, et al. Review on desalination technology by pervaporation[J]. Membrane Science and Technology, 2020, 40(6): 133-140.
6	CASTRO-MUÑOZ R. Breakthroughs on tailoring pervaporation membranes for water desalination: a review[J]. Water Research, 2020, 187: 116428.
7	WANG Q Z, LI N, BOLTO B, et al. Desalination by pervaporation: a review[J]. Desalination, 2016, 387: 46-60.
8	KAMINSKI W, MARSZALEK J, TOMCZAK E. Water desalination by pervaporation—comparison of energy consumption[J]. Desalination, 2018, 433: 89-93.
9	PRIHATININGTYAS I, VAN DER BRUGGEN B. Nanocompositepervaporation membrane for desalination[J]. Chemical Engineering Research and Design, 2020, 164: 147-161.
10	TEOW Y H, MOHAMMAD A W. New generation nanomaterials for water desalination: a review[J]. Desalination, 2019, 451: 2-17.
11	李胄彦, 戴若彬, 李洋, 等. 基于二维纳米材料的水处理功能膜研究进展[J]. 化工进展, 2021, 40(8): 4117-4126.
	LI Zhouyan, DAI Ruobin, LI Yang, et al. Research progress of functional membranes based on two-dimensional nanomaterials for water treatment[J]. Chemical Industry and Engineering Progress, 2021, 40(8): 4117-4126.
12	LIU Gongping, JIN Wanqin, XU Nanping. Graphene-based membranes[J]. Chemical Society Reviews, 2015, 44(15): 5016-5030.
13	万武波, 纪冉, 何锋. 石墨烯基分离膜研究进展[J]. 化学进展, 2017, 29(8): 833-845.
	WAN Wubo, JI Ran, HE Feng. Recent advances in graphene based separation membranes[J]. Progress in Chemistry, 2017, 29(8): 833-845.
14	LIU Yi. Beyond graphene oxides: emerging 2D molecular sieve membranes for efficient separation[J]. Chinese Journal of Chemical Engineering, 2019, 27(6): 1257-1271.
15	CASTRO-MUÑOZ R, CRUZ-CRUZ A, ALFARO-SOMMERS Y, et al. Reviewing the recent developments of using graphene-based nanosized materials in membrane separations[J]. Critical Reviews in Environmental Science and Technology, 2022, 52(19): 3415-3452.
16	芦瑛, 张林, 李明, 等. 氧化石墨烯基水处理膜研究进展[J]. 科技导报, 2015, 33(14): 32-35.
	LU Ying, ZHANG Lin, LI Ming, et al. Research progress of graphene oxide based membrane in water treatment[J]. Science & Technology Review, 2015, 33(14): 32-35.
17	张晴, 任文才, 成会明. 石墨烯基分离膜研究进展[J]. 中国材料进展, 2019, 38(9): 887-896.
	ZHANG Qing, REN Wencai, CHENG Huiming. Research progress of graphene-based separation membranes[J]. Materials China, 2019, 38(9): 887-896.
18	SUN Pengzhan, WANG Kunlin, ZHU Hongwei. Recent developments in graphene-based membranes: structure, mass-transport mechanism and potential applications[J]. Advanced Materials, 2016, 28(12): 2287-2310.
19	NAIR R R, WU H A, JAYARAM P N, et al. Unimpeded permeation of water through helium-leak-tight graphene-based membranes[J]. Science, 2012, 335(6067): 442-444.
20	ABRAHAM J, VASU K S, WILLIAMS C D, et al. Tunable sieving of ions using graphene oxide membranes[J]. Nat Nanotechnol, 2017, 12(6): 546-550.
21	LIANG Bin, ZHAN Wu, QI Genggeng, et al. High performance graphene oxide/polyacrylonitrile composite pervaporation membranes for desalination applications[J]. Journal of Materials Chemistry A, 2015, 3(9): 5140-5147.
22	HALAKOO E, FENG X S. Layer-by-layer assembly of polyethyleneimine/graphene oxide membranes for desalination of high-salinity water via pervaporation[J]. Separation and Purification Technology, 2020, 234: 116077.
23	YANG Guang, XIE Zongli, CRAN Ma, et al. Functionalizing graphene oxide framework membranes with sulfonic acid groups for superior aqueous mixture separation[J]. Journal of Materials Chemistry A, 2019, 7(34): 19682-19690.
24	XU Kai, FENG Bo, ZHOU Chen, et al. Synthesis of highly stable graphene oxide membranes on polydopamine functionalized supports for seawater desalination[J]. Chemical Engineering Science, 2016, 146: 159-165.
25	QIAN Yunlong, ZHOU Chen, HUANG Aisheng. Cross-linking modification with diamine monomers to enhance desalination performance of graphene oxide membranes[J]. Carbon, 2018, 136: 28-37.
26	CHENG Cheng, SHEN Lingdi, YU Xufeng, et al. Robust construction of a graphene oxide barrier layer on a nanofibrous substrate assisted by the flexible poly(vinylalcohol) for efficient pervaporation desalination[J]. Journal of Materials Chemistry A, 2017, 5(7): 3558-3568.
27	FENG Bo, XU Kai, HUANG Aisheng. Synthesis of graphene oxide/polyimide mixed matrix membranes for desalination[J]. RSC Advances, 2017, 7(4): 2211-2217.
28	HUANG Aisheng, FENG Bo. Synthesis of novel graphene oxide-polyimide hollow fiber membranes for seawater desalination[J]. Journal of Membrane Science, 2018, 548: 59-65.
29	QIAN Xiaowei, LI Na, WANG Qinzhuo, et al. Chitosan/graphene oxide mixed matrix membrane with enhanced water permeability for high-salinity water desalination by pervaporation[J]. Desalination, 2018, 438: 83-96.
30	ALMARZOOQI K, ASHRAFI M, KANTHAN T, et al. Graphene oxide membranes for high salinity, produced water separation by pervaporation[J]. Membranes, 2021, 11(7): 475.
31	CHING K, LIAN B Y, LESLIE G, et al. Metal-cation-modified graphene oxide membranes for water permeation[J]. Carbon, 2020, 170: 646-657.
32	ZHAO Xiaoying, TONG Ziqiang, LIU Xiufeng, et al. Facile preparation of polyamide-graphene oxide composite membranes for upgrading pervaporation desalination performances of hypersaline solutions[J]. Industrial & Engineering Chemistry Research, 2020, 59(26): 12232-12238.
33	CHA-UMPONG W, DONG G X, RAZMJOU A, et al. Effect of oscillating temperature and crystallization on graphene oxide composite pervaporation membrane for inland brine desalination[J]. Journal of Membrane Science, 2019, 588: 117210.
34	CHA-UMPONG W, MAYYAS M, RAZMJOU A, et al. Modification of GO-based pervaporation membranes to improve stability in oscillating temperature operation[J]. Desalination, 2021, 516: 115215.
35	WYATT B C, ROSENKRANZ A, ANASORI B. 2D MXenes: tunable mechanical and tribologicalproperties[J]. Advanced Materials, 2021, 33(17): e2007973.
36	VAHIDMOHAMMADI A, ROSEN J, GOGOTSI Y. The world of two-dimensional carbides and nitrides (MXenes)[J]. Science, 2021, 372(6547): eabf1581.
37	郑伟, 孙正明, 张培根, 等. 二维纳米材料MXene的研究进展[J]. 材料导报, 2017, 31(9): 1-14.
	ZHENG Wei, SUN Zhengming, ZHANG Peigen, et al. Research progress on MXene, two dimensional nano-materials[J]. Materials Review, 2017, 31(9): 1-14.
38	曾广勇, 王彬, 张俊, 等. 二维MXene膜的构筑及在水处理应用中的研究进展[J]. 复合材料学报, 2021, 38(7): 2078-2091.
	ZENG Guangyong, WANG Bin, ZHANG Jun, et al. Construction of two-dimensional MXene membrane and its research progress of application in water treatment[M]. Acta Materiae Compositae Sinica, 2021, 38(7): 2078-2091
39	RASOOL K, PANDEY R P, RASHEED P A, et al. Water treatment and environmental remediation applications of two-dimensional metal carbides (MXenes)[J]. Materials Today, 2019, 30: 80-102.
40	WEI Y, ZHANG P, SOOMRO R A, et al. Advances in the synthesis of 2D MXenes[J]. Advanced Materials, 2021, 33(39): e2103148.
41	LIU Guozhen, SHEN Jie, LIU Quan, et al. Ultrathin two-dimensional MXene membrane for pervaporationdesalination[J]. Journal of Membrane Science, 2018, 548: 548-558.
42	YANG G, XIE Z L, THORNTON A W, et al. Ultrathin poly(vinyl alcohol)/MXenenanofilm composite membrane with facile intrusion-free construction for pervaporative separations[J]. Journal of Membrane Science, 2020, 614: 118490.
43	DING Mingmei, XU Hang, CHEN Wei, et al. 2D laminar maleic acid-crosslinkedMXene membrane with tunable nanochannels for efficient and stable pervaporationdesalination[J]. Journal of Membrane Science, 2020, 600: 117871.
44	何磊, 么秋香, 孙鸣, 等. 二维(2D)沸石与三维(3D)沸石的制备及催化研究进展[J]. 化学学报, 2022, 80(2): 180-198.
	HE Lei, YAO Qiuxiang, SUN Ming, et al. Progress in preparation and catalysis of two-dimensional(2D) and three-dimensional(3D) zeolites[J]. ActaChimicaSinica, 2022, 80(2): 180-198.
45	LI Yi, YU Jihong. Emerging applications of zeolites in catalysis, separation and host-guest assembly[J]. Nature Reviews Materials, 2021, 6(12): 1156-1174.
46	PŘECH J, PIZARRO P, SERRANO D P, et al. From 3D to 2D zeolite catalytic materials[J]. Chemical Society Reviews, 2018, 47(22): 8263-8306.
47	黄阳环, 张宏斌, 唐颐. 二维沸石及其在大分子催化转化领域的研究进展[J]. 大学化学, 2017, 32(2): 1-8.
	HUANG Yanghuan, ZHANG Hongbin, TANG Yi. Progress of two-dimensional zeolites and their applications in bulky molecule catalytic conversion[J]. University Chemistry, 2017, 32(2): 1-8.
48	ROTH W J, NACHTIGALL P, MORRIS R E, et al. Two-dimensional zeolites: current status and perspectives[J]. Chemical Reviews, 2014, 114(9): 4807-4837.
49	CAO Zishu, ZENG Shixuan, XU Zhi, et al. Ultrathin ZSM-5 zeolite nanosheet laminated membrane for high-flux desalination of concentrated brines[J]. Science Advances, 2018, 4(11): eaau8634.
50	CAO Z S, ISKHAKOVA L, SUN X H, et al. ZSM-5 zeolite nanosheet-based membranes on porous polyvinylidene fluoride for high-flux desalination[J]. ACS Applied Nano Materials, 2021, 4(3): 2895-2902.
51	KORDE A, MIN B, GANESAN A, et al. AEL zeolite nanosheet-polyamide nanocomposite membranes on α-alumina hollow fibers with enhanced pervaporationproperties[J]. Industrial & Engineering Chemistry Research, 2020, 59(33): 14789-14796.
52	FENG Bo, XU Kai, HUANG Aisheng. Covalent synthesis of three-dimensional graphene oxide framework (GOF) membrane for seawater desalination[J]. Desalination, 2016, 394: 123-130.
53	LI Lin, HOU Jingwei, YE Yun, et al. Suppressing salt transport through composite pervaporation membranes for brine desalination[J]. Applied Sciences, 2017, 7(8): 856.
54	NIGIZ F U. Preparation of high-performance graphenenanoplate incorporated polyether block amide membrane and application for seawater desalination[J]. Desalination, 2018, 433: 164-171.
55	QIAN Yunlong, ZHANG Xiaoling, LIU Chuanyao, et al. Tuning interlayer spacing of graphene oxide membranes with enhanced desalination performance[J].Desalination, 2019, 460: 56-63.
56	LI L, HOU J W, CHEN V. Pinning down the water transport mechanism in graphene oxide pervaporation desalination membranes[J]. Industrial & Engineering Chemistry Research, 2019, 58(10): 4231-4239.
57	NIGIZ F U. Graphene oxide‑sodium alginate membrane for seawater desalination through pervaporation[J]. Desalination, 2020, 485: 114465.
58	SUN Jiawei, QIAN Xiaowei, WANG Ziheng, et al. Tailoring the microstructure of poly(vinyl alcohol)-intercalated graphene oxide membranes for enhanced desalination performance of high-salinity water by pervaporation[J]. Journal of Membrane Science, 2020, 599: 117838.

PV脱盐膜	制备方法	NaCl浓度 /g·L^-1	实验条件	渗透通量 /L∙m^-2∙h^-1	截留率 /%	参考文献
GO/聚丙烯腈	真空抽滤法	3.5	90℃，真空0.1kPa	65.1	99.8	[21]
GO/多巴胺-α-氧化铝	真空抽滤法	3.5	90℃，真空	48.4	99.7	[24]
氧化石墨烯骨架（GOF）/对苯二异氰酸酯-α-氧化铝	真空抽滤法	3.5	90℃，真空	11.4	99.9	[52]
GO-聚乙烯醇/聚丙烯腈	真空抽滤法	3.5	70℃，真空0.1kPa	69.1	99.9	[28]
GO-聚乙烯醇/聚偏氟乙烯（PVDF）	溶液铸膜法	10	65℃，真空24kPa	28	99.9	[53]
GO-聚酰亚胺	相转化法	3.5	90℃，真空100kPa	36.1	99.9	[29]
GO-壳聚糖	溶液铸膜法	5	81℃，真空6kPa	30	99.9	[31]
GO-聚酰亚胺纤维	相转化法	3.5	90℃，真空100kPa	15.6	99.9	[30]
纳米石墨烯材料(GNPs)-聚醚嵌段酰胺/聚四氟乙烯	相转化法	马尔马拉海水	35℃，真空0.1kPa	2.5	99.8	[54]
GOF/多巴胺-α-氧化铝	真空抽滤法	3.5	90℃，真空	20.1	99.9	[55]
二胺分子交联 GO/多巴胺(PDA)-α-氧化铝	真空抽滤法	3.5	90℃，真空	19.7	99.9	[25]
GO/聚碳酸酯	抽滤涂层法	10	70℃，真空3kPa	42.4	99.9	[56]
GOF-磺基琥珀酸/尼龙底膜	真空抽滤法	3.5	70℃，真空0.13kPa	80.1	99.9	[23]
GO/聚丙烯中空纤维膜	真空抽滤法	3.321	70℃，真空	11.5	99.9	[33]
GO/海藻酸钠/聚甲基丙烯酸甲酯	溶液铸膜法	3	60℃，真空0.1kPa	8.11	99.41	[57]
GO-聚醚酰亚胺/聚酰胺	层层组装法	5	65℃，真空1.7kPa	13	99.9	[22]
GO-聚乙烯醇/混合纤维素膜	压力辅助抽滤法	10	85℃，真空6kPa	98	99.9	[58]
聚酰胺/GO/聚丙烯腈	压力辅助抽滤法	3.5	70℃，真空0.2kPa	26.7	99.9	[32]
阳离子交联-GO膜	真空抽滤法	纯水	20~25℃，真空2.8kPa	16.16	—	[27]
壳聚糖-氧化石墨烯(CGO)-二甲基苯磺酸/聚丙烯	压力辅助抽滤法	1.752	70℃，真空-95kPa	30.5	99.9	[34]
GO-Zn²⁺/聚醚砜	真空抽滤法	3	60℃，真空-100kPa	47.8	99.9	[26]
MXene/聚丙烯腈	真空抽滤法	3.5	65℃，真空0.4kPa	85.4	99.5	[41]
MXene-马来酸/尼龙底膜	真空抽滤法	3.5	65℃，真空0.1kPa	70	99	[43]
MXene-聚乙烯醇/聚四氟乙烯	溶液铸膜法	3.5	30℃，真空0.13kPa	62.2	99.8	[42]
ZSM-5/α-氧化铝	浸涂法	24	80℃，真空1kPa	6.4	99.5	[49]
AEL-聚酰胺/α-氧化铝	真空抽滤法	3.6	25℃，真空	3.3	99.9	[50]
ZSM-5/聚偏氟乙烯	真空抽滤法	22（混合盐）	73℃±2℃，真空	11	99.9	[51]

PV脱盐膜	制备方法	NaCl浓度 /g·L^-1	实验条件	渗透通量 /L∙m^-2∙h^-1	截留率 /%	参考文献
GO/聚丙烯腈	真空抽滤法	3.5	90℃，真空0.1kPa	65.1	99.8	[21]
GO/多巴胺-α-氧化铝	真空抽滤法	3.5	90℃，真空	48.4	99.7	[24]
氧化石墨烯骨架（GOF）/对苯二异氰酸酯-α-氧化铝	真空抽滤法	3.5	90℃，真空	11.4	99.9	[52]
GO-聚乙烯醇/聚丙烯腈	真空抽滤法	3.5	70℃，真空0.1kPa	69.1	99.9	[28]
GO-聚乙烯醇/聚偏氟乙烯（PVDF）	溶液铸膜法	10	65℃，真空24kPa	28	99.9	[53]
GO-聚酰亚胺	相转化法	3.5	90℃，真空100kPa	36.1	99.9	[29]
GO-壳聚糖	溶液铸膜法	5	81℃，真空6kPa	30	99.9	[31]
GO-聚酰亚胺纤维	相转化法	3.5	90℃，真空100kPa	15.6	99.9	[30]
纳米石墨烯材料(GNPs)-聚醚嵌段酰胺/聚四氟乙烯	相转化法	马尔马拉海水	35℃，真空0.1kPa	2.5	99.8	[54]
GOF/多巴胺-α-氧化铝	真空抽滤法	3.5	90℃，真空	20.1	99.9	[55]
二胺分子交联 GO/多巴胺(PDA)-α-氧化铝	真空抽滤法	3.5	90℃，真空	19.7	99.9	[25]
GO/聚碳酸酯	抽滤涂层法	10	70℃，真空3kPa	42.4	99.9	[56]
GOF-磺基琥珀酸/尼龙底膜	真空抽滤法	3.5	70℃，真空0.13kPa	80.1	99.9	[23]
GO/聚丙烯中空纤维膜	真空抽滤法	3.321	70℃，真空	11.5	99.9	[33]
GO/海藻酸钠/聚甲基丙烯酸甲酯	溶液铸膜法	3	60℃，真空0.1kPa	8.11	99.41	[57]
GO-聚醚酰亚胺/聚酰胺	层层组装法	5	65℃，真空1.7kPa	13	99.9	[22]
GO-聚乙烯醇/混合纤维素膜	压力辅助抽滤法	10	85℃，真空6kPa	98	99.9	[58]
聚酰胺/GO/聚丙烯腈	压力辅助抽滤法	3.5	70℃，真空0.2kPa	26.7	99.9	[32]
阳离子交联-GO膜	真空抽滤法	纯水	20~25℃，真空2.8kPa	16.16	—	[27]
壳聚糖-氧化石墨烯(CGO)-二甲基苯磺酸/聚丙烯	压力辅助抽滤法	1.752	70℃，真空-95kPa	30.5	99.9	[34]
GO-Zn²⁺/聚醚砜	真空抽滤法	3	60℃，真空-100kPa	47.8	99.9	[26]
MXene/聚丙烯腈	真空抽滤法	3.5	65℃，真空0.4kPa	85.4	99.5	[41]
MXene-马来酸/尼龙底膜	真空抽滤法	3.5	65℃，真空0.1kPa	70	99	[43]
MXene-聚乙烯醇/聚四氟乙烯	溶液铸膜法	3.5	30℃，真空0.13kPa	62.2	99.8	[42]
ZSM-5/α-氧化铝	浸涂法	24	80℃，真空1kPa	6.4	99.5	[49]
AEL-聚酰胺/α-氧化铝	真空抽滤法	3.6	25℃，真空	3.3	99.9	[50]
ZSM-5/聚偏氟乙烯	真空抽滤法	22（混合盐）	73℃±2℃，真空	11	99.9	[51]

[1]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[2]	胡喜, 王明珊, 李恩智, 黄思鸣, 陈俊臣, 郭秉淑, 于博, 马志远, 李星. 二硫化钨复合材料制备与储钠性能研究进展[J]. 化工进展, 2023, 42(S1): 344-355.
[3]	张祚群, 高扬, 白超杰, 薛立新. 二次界面聚合同步反扩散原位生长ZIF-8纳米粒子制备聚酰胺混合基质反渗透（RO）膜[J]. 化工进展, 2023, 42(S1): 364-373.
[4]	林晓鹏, 肖友华, 管奕琛, 鲁晓东, 宗文杰, 傅深渊. 离子聚合物-金属复合材料（IPMC）柔性电极的研究进展[J]. 化工进展, 2023, 42(9): 4770-4782.
[5]	徐杰, 夏隆博, 罗平, 邹栋, 仲兆祥. 面向膜蒸馏过程的全疏膜制备及其应用进展[J]. 化工进展, 2023, 42(8): 3943-3955.
[6]	李雪佳, 李鹏, 李志霞, 晋墩尚, 郭强, 宋旭锋, 宋芃, 彭跃莲. 亲水和疏水改性膜的抗结垢和润湿能力的对比[J]. 化工进展, 2023, 42(8): 4458-4464.
[7]	潘宜昌, 周荣飞, 邢卫红. 高效分离同碳数烃的先进微孔膜：现状与挑战[J]. 化工进展, 2023, 42(8): 3926-3942.
[8]	王报英, 王皝莹, 闫军营, 汪耀明, 徐铜文. 聚合物包覆膜在金属分离回收中的研究进展[J]. 化工进展, 2023, 42(8): 3990-4004.
[9]	单雪影, 张濛, 张家傅, 李玲玉, 宋艳, 李锦春. 阻燃型环氧树脂的燃烧数值模拟[J]. 化工进展, 2023, 42(7): 3413-3419.
[10]	陆诗建, 刘苗苗, 杨菲, 张俊杰, 陈思铭, 刘玲, 康国俊, 李清方. 改良型CO₂湿壁塔内气液两相流动规律及传质特性[J]. 化工进展, 2023, 42(7): 3457-3467.
[11]	冯江涵, 宋钫. 阴离子交换膜电解池的研究进展[J]. 化工进展, 2023, 42(7): 3501-3509.
[12]	于志庆, 黄文斌, 王晓晗, 邓开鑫, 魏强, 周亚松, 姜鹏. B掺杂Al₂O₃@C负载CoMo型加氢脱硫催化剂性能[J]. 化工进展, 2023, 42(7): 3550-3560.
[13]	陈香李, 李倩倩, 张甜, 李彪, 李康康. 自愈合油水分离膜的研究进展[J]. 化工进展, 2023, 42(7): 3600-3610.
[14]	杨竞莹, 施万胜, 黄振兴, 谢利娟, 赵明星, 阮文权. 改性纳米零价铁材料制备的研究进展[J]. 化工进展, 2023, 42(6): 2975-2986.
[15]	许春树, 姚庆达, 梁永贤, 周华龙. 氧化石墨烯/碳纳米管对几种典型高分子材料的性能影响[J]. 化工进展, 2023, 42(6): 3012-3028.

二维纳米材料在渗透汽化脱盐膜中的应用

Application of two-dimensional nanomaterials in pervaporation desalination membrane

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 8

参考文献 58

相关文章 15

编辑推荐

Metrics

本文评价