高级氧化技术降解典型抗生素的研究进展

doi:10.16085/j.issn.1000-6613.2024-0959

化工进展 ›› 2025, Vol. 44 ›› Issue (7): 4169-4189.DOI: 10.16085/j.issn.1000-6613.2024-0959

• 资源与环境化工 • 上一篇

高级氧化技术降解典型抗生素的研究进展

罗司玲¹(), 艾建平¹^,³(), 李文魁¹, 王翼¹, 程丽红¹, 万芸¹, 黄隆¹, 李喜宝²()

^1.江西科技师范大学材料与能源学院，江西南昌 330038
^2.南昌航空大学材料科学与工程学院，江西南昌 330063
^3.江西科技师范大学材料表面工程江西省重点实验室，江西南昌 330038

收稿日期:2024-06-14 修回日期:2024-08-16 出版日期:2025-07-25 发布日期:2025-08-04
通讯作者: 艾建平,李喜宝
作者简介:罗司玲（1998—），女，硕士研究生，研究方向为非均相催化降解有机污染物。E-mail：lsl981211@163.com。
基金资助:
国家自然科学基金(52102101);国家自然科学基金(22262024);国家自然科学基金(52267001);江西省重点学科学术技术带头人项目(20232BCJ22008);江西自然科学基金重点项目(20232ACB204007);江西省研究生创新专项基金(YC2023-S882);材料表面工程江西省重点实验室平台基金(2024SSY05071)

Research progress on degradation of typical antibiotics by advanced oxidation processes

LUO Siling¹(), AI Jianping¹^,³(), LI Wenkui¹, WANG Yi¹, CHENG Lihong¹, WAN Yun¹, HUANG Long¹, LI Xibao²()

^1.School of Materials and Energy, Jiangxi Science & Technology Normal University, Nanchang 330038, Jiangxi, China
^2.School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, Jiangxi, China
^3.Jiangxi Province Key Laboratory of Surface Engineering, Jiangxi Science & Technology Normal University, Nanchang 330038, Jiangxi, China

Received:2024-06-14 Revised:2024-08-16 Online:2025-07-25 Published:2025-08-04
Contact: AI Jianping, LI Xibao

摘要/Abstract

摘要：

抗生素是水环境中一类典型的新兴微污染有机物，具有难降解、高风险、潜在未知毒性和普遍残留等特性。基于羟基自由基、超氧自由基、硫酸根自由基等活性物种的高级氧化技术，因其高效快速、适用范围广等特点，已成为抗生素废水处理领域的研究热点。本文从抗生素的结构特征出发，结合密度泛函理论，首次系统剖析了不同活性物种对常见五大类抗生素的攻击位点和降解机理。同时，综述了电催化法、光催化法、臭氧氧化法、芬顿及类芬顿法四种高级氧化技术在处理抗生素废水方面的优势及适用范围，并展望了未来的发展方向及趋势。

关键词: 高级氧化技术, 抗生素, 催化氧化, 废水处理, 降解机理

Abstract:

As an important emerging organic pollutant in water environment, antibiotics have low biodegradability and potentially unknown toxicity. Advanced oxidation processes (AOPs) as a kind of chemical technology have attracted growing attention for the treatment of antibiotic wastewater due to the generation of reactive species (such as hydroxyl radicals, superoxide radicals and sulfate radicals). Based on the structural characteristics of antibiotics and density functional theory, this article reviewed key publications on the attack sites and degradation mechanisms of classical antibiotics for the first time. In addition, this article reviewed key publications on the electrocatalysis, photocatalysis, ozonation process and Fenton/Fenton-like reactions used to remove antibiotics from the aquatic environment. We further provided perspectives on the key opportunities and challenges associated with catalysts in AOPs, recommending further exploration for enhanced applications in future studies.

Key words: advanced oxidation processes, antibiotics, acatalytic oxidation, wastewater treatment, degradation mechanism

中图分类号:

TQ460.9

罗司玲, 艾建平, 李文魁, 王翼, 程丽红, 万芸, 黄隆, 李喜宝. 高级氧化技术降解典型抗生素的研究进展[J]. 化工进展, 2025, 44(7): 4169-4189.

LUO Siling, AI Jianping, LI Wenkui, WANG Yi, CHENG Lihong, WAN Yun, HUANG Long, LI Xibao. Research progress on degradation of typical antibiotics by advanced oxidation processes[J]. Chemical Industry and Engineering Progress, 2025, 44(7): 4169-4189.

图/表 17

图1 (a)不同ROS的氧化还原电位；(b)ZnO/CuCo2O4/PMS、CuCo2O4/PMS和ZnO/PMS体系中DMPO-·OH和DMPO-·SO4-的EPR谱图；(c)ZnO/CuCo2O4/PMS、CuCo2O4/PMS和ZnO/PMS体系中DMPO-·O2-的EPR谱图；(d)ZnO/CuCo2O4/PMS、CuCo2O4/PMS和ZnO/PMS体系中TEMP-·O2的EPR谱图[16]

图2 电催化法降解抗生素原理

图3 (a)BDD/SS体系电催化降解SMX的可能降解途径；(b)优化后的SMX结构；(c)SMX的HOMO图；(d)SMX的LUMO图；(e)SMX的ESP图[47]

图4 Ti/SnO2-Sb/Er-PbO2体系电催化降解SMX和Ac-SMX的可能降解途径

图5 光催化降解抗生素的基本原理

图6 (a) BPQDs/Bi2WO6体系光催化降解AMX的可能途径；(b)、(c)AMX的HOMO和LUMO轨道图像[81]；(d)AMX化学结构（红色部分表示容易受到ROS攻击）；(e)AMX的福井指数[82]；(f)~(h)AMX福井指数分布

图7 (a)SNCN光催化降解OFL的可能途径；(b)OFL化学结构及福井指数分布；(c)OFL的ESP分布图像；(d)OFL的HOMO轨道图像；(e)OFL的LUMO轨道图像[85]

图8 臭氧氧化法降解抗生素原理

图9 磁性g-C3N4/Fe-MCM-48体系光-臭氧氧化降解AZY可能的降解途径

表1 臭氧氧化法对不同抗生素的降解

抗生素种类	催化体系	最优反应条件	降解效能	参考文献
头孢氨苄	Mn@ZN	[CLX]=1.0mg/L [O₃]=0.20mg/L pH=9.12	97% （2min）	[97]
环丙沙星	Mn-CeO _x @γ-Al₂O₃	[CIP]=80g/L [O₃]=14mg/L pH=8~9	100% （60min）	[105]
诺氟沙星	RuO₂/Ti电极（电催化-O₃氧化）	[NOR]=10mg/L [O₃]=10mg/L J=3mA/cm² pH=11	100% （40min）	[106]
磺胺嘧啶	Fe-H-Beta-25-EIM Cu-H-Beta-150-DP	VN₂=0.0025L/min VO₂=445mL/min	100% （1min）	[107]
甲硝唑	锂掺杂Mg(OH)₂的纳米片	[MTZ]=50g/L [O₃]=14mg/L t=25℃	100% （10min）	[108]
四环素	(MgMnO)₃(SCOP)	[TC]=50g/L [O₃]=2.0mg/L	88.4% （80min）（矿化率）	[109]

图10 (a)O3/H2O2体系氧化SSZ的反应途径；(b)优化后的SSZ球棍模型；(c)SSZ上亲核（P-k ）和亲电（P+k ）值；(d)DFT模拟的N̿ N键裂解机理的势能曲线[110]

图11 芬顿及类芬顿法降解抗生素原理

图12 (a)CIP在g-C3N4/Fe3O4@MIL-100(Fe)/H2O2/vis体系中的可能降解途径；(b)CIP的化学结构；(c)CIP的HOMO和LUMO轨道图像；(d)CIP的福井指数分布图像[127]

图13 PMS和PDS通过电子和能量转移过程的活化128]

图14 (a)CoP/CoO x /PMS氧化体系中TC可能的降解途径；(b)TC的的化学结构；(c)TC的HOMO和LUMO轨道分布；(d)TC的福井指数分布图；(e)TC的福井指数[137]

图15 (a)Fe7S8@HC/PMS氧化体系中DXC可能的降解途径；(b)DXC分子优化后的结构；(c)DXC的ESP分布图；(d)DXC的福井指数和CDD值分布[144]；(e)DXC的HOMO和LUMO分布图；(f)DXC的福井指数和CDD值

表2 4种AOP处理抗生素废水的优缺点及适用范围

处理技术	主要ROS	优点	适用范围	存在问题
电催化法	·OH	成本低、操作简便且对环境友好	小流量含高浓度抗生素和COD的有机废水	运营成本较高，处理流量必须控制在较小范围内
光催化法	e^-/h⁺、·OH和·O₂^-	能源来源简单，成本较低	透光性能够达到处理标准的有机废水	量子效率低，催化剂价格昂贵，难以回收
臭氧氧化法	·OH、O₃	反应快速高效、稳定性好	水质和水量变化时可用能耗、设备成本及维修费用高，适用于难降解有机废水	能耗、设备成本及维修费用高
芬顿及类芬顿法	·OH、·SO₄^-、·O₂^-和¹O₂	成本低、水溶性好、氧化性强，活化方式多样	光敏感化合物废水和COD浓度较低的水体	易受pH、温度、H₂O₂浓度和目标物浓度影响

参考文献 147

[1]	LIU Yurong, VAN DER HEIJDEN Marcel G A, RIEDO Judith, et al. Soil contamination in nearby natural areas mirrors that in urban greenspaces worldwide[J]. Nature Communications, 2023, 14: 1706.
[2]	LI Xi, WANG Shiwen, CHEN Pei, et al. ZIF-derived non-bonding Co/Zn coordinated hollow carbon nitride for enhanced removal of antibiotic contaminants by peroxymonosulfate activation: Performance and mechanism[J]. Applied Catalysis B: Environmental, 2023, 325: 122401.
[3]	吴文瞳, 张玲玲, 李子富, 等. 高级氧化技术降解抗生素及去除耐药性的研究进展[J]. 化工进展, 2021, 40(8): 4551-4561.
	WU Wentong, ZHANG Lingling, LI Zifu, et al. Research progress of advanced oxidation technology in degradation of antibiotics and removal of antibiotic resistance[J]. Chemical Industry and Engineering Progress, 2021, 40(8): 4551-4561.
[4]	XIE Zhihui, HE Chuanshu, PEI Danni, et al. Review of characteristics, generation pathways and detection methods of singlet oxygen generated in advanced oxidation processes (AOPs)[J]. Chemical Engineering Journal, 2023, 468: 143778.
[5]	XIE Zhihui, ZHOU Hongyu, HE Chuanshu, et al. Synthesis, application and catalytic performance of layered double hydroxide based catalysts in advanced oxidation processes for wastewater decontamination: A review[J]. Chemical Engineering Journal, 2021, 414: 128713.
[6]	DONG Guihua, CHEN Bing, LIU Bo, et al. Advanced oxidation processes in microreactors for water and wastewater treatment: Development, challenges, and opportunities[J]. Water Research, 2022, 211: 118047.
[7]	RAYAROTH Manoj P, ARAVINDAKUMAR Charuvila T, SHAH Noor S, et al. Advanced oxidation processes (AOPs) based wastewater treatment—Unexpected nitration side reactions—A serious environmental issue: A review[J]. Chemical Engineering Journal, 2022, 430: 133002.
[8]	GLAZE William H, KANG Joon-Wun, CHAPIN Douglas H. The chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation[J]. Ozone: Science & Engineering, 1987, 9(4): 335-352.
[9]	LIU Hongzhi, SHU Xiaoxuan, HUANG Mingjie, et al. Tailoring d-band center of high-valent metal-oxo species for pollutant removal via complete polymerization[J]. Nature Communications, 2024, 15: 2327.
[10]	YAN Huijie, PENG Yuan, HUANG Yuyan, et al. Enhancing photosynthesis efficiency of hydrogen peroxide by modulating side chains to facilitate water oxidation at low-energy barrier sites[J]. Advanced Materials, 2024, 36(18): 2311535.
[11]	CHEN Yidi, REN Wei, MA Tianyi, et al. Transformative removal of aqueous micropollutants into polymeric products by advanced oxidation processes[J]. Environmental Science & Technology, 2024, 58(11): 4844-4851.
[12]	LU Gonggong, LI Xiang, LI Wei, et al. Thermo-activated periodate oxidation process for tetracycline degradation: Kinetics and byproducts transformation pathways[J]. Journal of Hazardous Materials, 2024, 461: 132696.
[13]	ZHANG Xinyi, WEI Jian, WANG Chen, et al. Recent advance of Fe-based bimetallic persulfate activation catalysts for antibiotics removal: Performance, mechanism, contribution of the key ROSs and degradation pathways[J]. Chemical Engineering Journal, 2024, 487: 150514.
[14]	LI Bo, XU Huanyan, LIU Yulong, et al. Unveiling the structure-activity relationships of ofloxacin degradation by Co₃O₄-activated peroxymonosulfate: From microstructures to exposed facets[J]. Chemical Engineering Journal, 2023, 467: 143396.
[15]	XIE Zhihui, HE Chuanshu, HE Yongli, et al. Peracetic acid activation via the synergic effect of Co and Fe in CoFe-LDH for efficient degradation of pharmaceuticals in hospital wastewater[J]. Water Research, 2023, 232: 119666.
[16]	LI Junjing, CHENG Xiuwen, ZHANG Huixuan, et al. Insights into performance and mechanism of ZnO/CuCo₂O₄ composite as heterogeneous photoactivator of peroxymonosulfate for enrofloxacin degradation[J]. Journal of Hazardous Materials, 2023, 448: 130946.
[17]	LI Ning, YE Jingya, DAI Haoxi, et al. A critical review on correlating active sites, oxidative species and degradation routes with persulfate-based antibiotics oxidation[J]. Water Research, 2023, 235: 119926.
[18]	WANG Yaobin, LI Dong, GE Xinlei, et al. Anchored cobalt nanoparticles on layered perovskites for rapid peroxymonosulfate activation in antibiotic degradation[J]. Advanced Materials, 2024, 36(27): 2402935.
[19]	CHEN Xiaojuan, YAO Liang, HE Juhua, et al. Enhanced degradation of tetracycline under natural sunlight through the synergistic effect of Ag₃PO₄/MIL-101(Fe) photocatalysis and Fenton catalysis: Mechanism, pathway, and toxicity assessment[J]. Journal of Hazardous Materials, 2023, 449: 131024.
[20]	WANG Chen, LIU Huanran, SUN Peng, et al. A novel peroxymonosulfate activation process by single-atom iron catalyst from waste biomass for efficient singlet oxygen-mediated degradation of organic pollutants[J]. Journal of Hazardous Materials, 2023, 453: 131333.
[21]	REN Tengfei, YIN Mengxi, CHEN Shuning, et al. Single-atom Fe-N₄ sites for catalytic ozonation to selectively induce a nonradical pathway toward wastewater purification[J]. Environmental Science & Technology, 2023, 57(9): 3623-3633.
[22]	ZHAO Ranran, WANG Tianyu, WANG Zhaowei, et al. Activation of peroxymonosulfate with natural pyrite-biochar composite for sulfamethoxazole degradation in soil: Organic matter effects and free radical conversion[J]. Journal of Hazardous Materials, 2024, 469: 133895.
[23]	WU Suqing, HU Yunhang. A comprehensive review on catalysts for electrocatalytic and photoelectrocatalytic degradation of antibiotics[J]. Chemical Engineering Journal, 2021, 409: 127739.
[24]	GU Hongbo, XIE Wenhao, DU Ai, et al. Overview of electrocatalytic treatment of antibiotic pollutants in wastewater[J]. Catalysis Reviews, 2023, 65(2): 569-619.
[25]	YUAN Qingbin, QU Siyao, LI Rong, et al. Degradation of antibiotics by electrochemical advanced oxidation processes (EAOPs): Performance, mechanisms, and perspectives[J]. Science of the Total Environment, 2023, 856: 159092.
[26]	ORIMOLADE Benjamin O, OLADIPO Adewale O, IDRIS Azeez O, et al. Advancements in electrochemical technologies for the removal of fluoroquinolone antibiotics in wastewater: A review[J]. Science of the Total Environment, 2023, 881: 163522.
[27]	LIU Hao, ZHAI Luwei, WANG Pengqi, et al. Ti/PbO₂ electrode efficiency in catalytic chloramphenicol degradation and its effect on antibiotic resistance genes[J]. International Journal of Environmental Research and Public Health, 2022, 19(23): 15632.
[28]	LIU Haiyang, CHEN Haijun, ADDISON Francis, et al. Insights into electrocatalytic oxidation of aqueous ampicillin: Degradation mechanism and potential toxicity from intermediates[J]. Journal of Environmental Chemical Engineering, 2022, 10(6): 108673.
[29]	ZENG Junling, XIE Wenhao, GUO Ying, et al. Magnetic field facilitated electrocatalytic degradation of tetracycline in wastewater by magnetic porous carbonized phthalonitrile resin[J]. Applied Catalysis B: Environmental, 2024, 340: 123225.
[30]	YANG Chao, SHANG Shanshan, LI Xiaoyan. Oxygen-vacancy-enriched substrate-less SnO _x /La-Sb anode for high-performance electrocatalytic oxidation of antibiotics in wastewater[J]. Journal of Hazardous Materials, 2022, 436: 129212.
[31]	MD ISHAK Nurul Atiqah Izzati, KAMARUDIN Siti Kartom, MANSOR Muliani, et al. Effect of tunable composition-shape of bio-inspired Pt NPs electrocatalyst in direct methanol fuel cell: Process optimization and kinetic studies[J]. Journal of Cleaner Production, 2024, 440: 140637.
[32]	Natalia ORMENO-CANO, RADJENOVIC Jelena. Electrochemical degradation of antibiotics using flow-through graphene sponge electrodes[J]. Journal of Hazardous Materials, 2022, 431: 128462.
[33]	Hao HAI, XING Xuan, LI Si, et al. Electrochemical oxidation of sulfamethoxazole in BDD anode system: Degradation kinetics, mechanisms and toxicity evaluation[J]. Science of the Total Environment, 2020, 738: 139909.
[34]	WANG Chong, ZHANG Tianai, LUO Jinlin, et al. Synergistic enhancement of piezocatalysis and electrochemical oxidation for the degradation of ciprofloxacin by PbO₂ intercalation material[J]. Separation and Purification Technology, 2022, 297: 121528.
[35]	SUN Qi, LI Xinhao, WANG Kaixue, et al. Inorganic non-carbon supported Pt catalysts and synergetic effects for oxygen reduction reaction[J]. Energy & Environmental Science, 2023, 16(5): 1838-1869.
[36]	LI Xiaotian, SHEN Peng, LI Xingchuan, et al. Sub-nm RuO _x clusters on Pd metallene for synergistically enhanced nitrate electroreduction to ammonia[J]. ACS Nano, 2023, 17(2): 1081-1090.
[37]	BRITO Laysa R D, GANIYU Soliu O, DOS SANTOS Elisama V, et al. Removal of antibiotic rifampicin from aqueous media by advanced electrochemical oxidation: Role of electrode materials, electrolytes and real water matrices[J]. Electrochimica Acta, 2021, 396: 139254.
[38]	ZHANG Jian, JIANG Yuting, WANG Ziyi, et al. Preparation of Pd/PANI/ITO composite electrode and its degradation of tetracycline wastewater[J]. Journal of Applied Polymer Science, 2021, 138(47): 51400.
[39]	LI Ping, HUANG Yuqi, OUYANG Xiao, et al. Unusual hcp Ni with metal and non-metal dual doping modulation to realize boosted urea oxidation[J]. Chemical Engineering Journal, 2023, 464: 142570.
[40]	ZHAO Hailing, REN Yi, LIU Chao, et al. In-depth insights into Fe(Ⅲ)-doped g-C₃N₄ activated peracetic acid: Intrinsic reactive species, catalytic mechanism and environmental application[J]. Journal of Hazardous Materials, 2023, 459: 132117.
[41]	YANG Qiang, CHU Longgang, WU Tongliang, et al. Investigation of dual-functional carbon cathode catalysts from agricultural wastes in the heterogeneous electro-Fenton process[J]. Applied Catalysis B: Environmental, 2023, 337: 123018.
[42]	LI Shuaishuai, ZHOU Minghua, WU Huizhong, et al. High-efficiency degradation of carbamazepine by the synergistic electro-activation and bimetals (FeCo@NC) catalytic-activation of peroxymonosulfate[J]. Applied Catalysis B: Environmental, 2023, 338: 123064.
[43]	SHI Guodong, LIU Haiyang, CHEN Haijun, et al. Nitrogen self-doped Chlorella biochar as a peroxydisulfate activator for sulfamethazine degradation: The dominant role of electron transfer[J]. Journal of Cleaner Production, 2024, 440: 140951.
[44]	GAO Yifan, LIANG Shuai, LIU Biming, et al. Subtle tuning of nanodefects actuates highly efficient electrocatalytic oxidation[J]. Nature Communications, 2023, 14: 2059.
[45]	翟重渊, 赵丹荻, 何亚鹏, 等. 掺硼金刚石阳极电催化降解新兴抗生素类污染物研究进展[J]. 化工进展, 2022, 41(12): 6615-6626.
	ZHAI Chongyuan, ZHAO Dandi, HE Yapeng, et al. Recent development on boron-doped diamond anodes in electrochemical degradation of emerging antibiotic pollutants[J]. Chemical Industry and Engineering Progress, 2022, 41(12): 6615-6626.
[46]	SHEN Linan, YU Xinyi, LI Mingxue, et al. The in situ generation of ClO• by single- and dual-atom catalysis of chloride ions to degrade sulfonamide antibiotics: A DFT study[J]. Chemical Engineering Journal, 2024, 485: 149719.
[47]	MA Yongfei, CHEN Xi, TANG Jiayi, et al. An in situ electrogenerated persulfate and its activation by functionalized sludge biochar for efficient degradation of sulfamethoxazole[J]. Journal of Cleaner Production, 2023, 423: 138768.
[48]	LIU Tong, WANG Qi, LI Chenxuan, et al. Synthesizing and characterizing Fe₃O₄ embedded in N-doped carbon nanotubes-bridged biochar as a persulfate activator for sulfamethoxazole degradation[J]. Journal of Cleaner Production, 2022, 353: 131669.
[49]	HE Yapeng, ZHAO Dandi, LIN Haibo, et al. Design of diamond anodes in electrochemical degradation of organic pollutants[J]. Current Opinion in Electrochemistry, 2022, 32: 100878.
[50]	DOS SANTOS Alexsandro J, FORTUNATO Guilherme V, KRONKA Matheus S, et al. Electrochemical oxidation of ciprofloxacin in different aqueous matrices using synthesized boron-doped micro and nano-diamond anodes[J]. Environmental Research, 2022, 204: 112027.
[51]	YANG Wanlin, TAN Jilin, CHEN Yinhao, et al. Relationship between substrate type and BDD electrode structure, performance and antibiotic tetracycline mineralization[J]. Journal of Alloys and Compounds, 2022, 890: 161760.
[52]	WANG Yanping, ZHOU Chengzhi, WU Jinhua, et al. Insights into the electrochemical degradation of sulfamethoxazole and its metabolite by Ti/SnO₂-Sb/Er-PbO₂ anode[J]. Chinese Chemical Letters, 2020, 31(10): 2673-2677.
[53]	HAN Xiao, ZHOU Chenliang, CHEN Yongjing, et al. Preparation of Yb-Sb co-doped Ti/SnO₂ electrode for electrocatalytic degradation of sulfamethoxazole (SMX)[J]. Chemosphere, 2023, 339: 139633.
[54]	DIAO Yuan, SHAN Rui, LI Mei, et al. Magnetized algae catalyst by endogenous N to effectively trigger peroxodisulfate activation for ultrafast degraded sulfathiazole: Radical evolution and electron transfer[J]. Chemosphere, 2023, 342: 140205.
[55]	QIAO Jing, XIONG Yuzhu. Electrochemical oxidation technology: A review of its application in high-efficiency treatment of wastewater containing persistent organic pollutants[J]. Journal of Water Process Engineering, 2021, 44: 102308.
[56]	YANG Yang, LI Xin, ZHOU Chengyun, et al. Recent advances in application of graphitic carbon nitride-based catalysts for degrading organic contaminants in water through advanced oxidation processes beyond photocatalysis: A critical review[J]. Water Research, 2020, 184: 116200.
[57]	HUA Xiuyi, CHEN Haijun, RONG Chang, et al. Visible-light-driven photocatalytic degradation of tetracycline hydrochloride by Z-scheme Ag₃PO₄/1T@2H-MoS₂ heterojunction: Degradation mechanism, toxicity assessment, and potential applications[J]. Journal of Hazardous Materials, 2023, 448: 130951.
[58]	REN Haitao, QI Fan, LABIDI Abdelkader, et al. Chemically bonded carbon quantum dots/Bi₂WO₆ S-scheme heterojunction for boosted photocatalytic antibiotic degradation: Interfacial engineering and mechanism insight[J]. Applied Catalysis B: Environmental, 2023, 330: 122587.
[59]	张申平, 王艺蒙, 葛宇, 等. 基于孔材料的多元复合光催化剂降解抗生素[J]. 化工进展, 2021, 40(6): 3287-3299.
	ZHANG Shenping, WANG Yimeng, GE Yu, et al. Degradation of antibiotics by porous composite photocatalyst[J]. Chemical Industry and Engineering Progress, 2021, 40(6): 3287-3299.
[60]	SUN Pengfei, LIU Yi, MO Fan, et al. Efficient photocatalytic degradation of high-concentration moxifloxacin over dodecyl benzene sulfonate modified graphitic carbon nitride: Enhanced photogenerated charge separation and pollutant enrichment[J]. Journal of Cleaner Production, 2023, 393: 136320.
[61]	ZHAO Wenfeng, DUAN Jieli, JI Bang, et al. Novel formation of large area N-TiO₂/graphene layered materials and enhanced photocatalytic degradation of antibiotics[J]. Journal of Environmental Chemical Engineering, 2020, 8(1): 102206.
[62]	ABDULLAH Muneeb, IQBAL Javed, REHMAN Muhammad Saif UR, et al. Removal of ceftriaxone sodium antibiotic from pharmaceutical wastewater using an activated carbon based TiO₂ composite: Adsorption and photocatalytic degradation evaluation[J]. Chemosphere, 2023, 317: 137834.
[63]	ZHANG Zhiquan, LIANG Jianli, ZHANG Wei, et al. Modified-pollen confined hybrid system: A promising union for visible-light-driven photocatalytic antibiotic degradation[J]. Applied Catalysis B: Environmental, 2023, 330: 122621.
[64]	LI Xibao, XIONG Jie, GAO Xiaoming, et al. Novel BP/BiOBr S-scheme nano-heterojunction for enhanced visible-light photocatalytic tetracycline removal and oxygen evolution activity[J]. Journal of Hazardous Materials, 2020, 387: 121690.
[65]	LI Shijie, CAI Mingjie, WANG Chunchun, et al. Ta₃N₅/CdS core-shell S-scheme heterojunction nanofibers for efficient photocatalytic removal of antibiotic tetracycline and Cr(Ⅵ): Performance and mechanism insights[J]. Advanced Fiber Materials, 2023, 5(3): 994-1007.
[66]	HASIJA Vasudha, SINGH Pardeep, THAKUR Sourbh, et al. O and S co-doping induced N-vacancy in graphitic carbon nitride towards photocatalytic peroxymonosulfate activation for sulfamethoxazole degradation[J]. Chemosphere, 2023, 320: 138015.
[67]	CHEN Jinfeng, ZHANG Xiaodong, SHI Xiaoyu, et al. Synergistic effects of octahedral TiO₂-MIL-101(Cr) with two heterojunctions for enhancing visible-light photocatalytic degradation of liquid tetracycline and gaseous toluene[J]. Journal of Colloid and Interface Science, 2020, 579: 37-49.
[68]	QUYEN Vu Thi, KIM Ji Tae, PARK Poong-Mo, et al. Enhanced the visible light photocatalytic decomposition of antibiotic pollutant in wastewater by using Cu doped WO₃ [J]. Journal of Environmental Chemical Engineering, 2021, 9(1): 104737.
[69]	LIU Tianyu, SHEN Hailin, WANG Min, et al. Fabrication of ZnIn₂S₄ nanosheets decorated hollow CdS nanostructure for efficient photocatalytic H₂-evolution and antibiotic removal performance[J]. Separation and Purification Technology, 2023, 315: 123698.
[70]	WEN Chenghui, LI Daguang, ZHONG Jiapeng, et al. In situ synthesis of S-scheme AgBr/BiOBr for efficient degradation of sulfonamide antibiotics: Synergistic effects of oxygen vacancies and heterojunctions promote exciton dissociation[J]. Chemical Engineering Journal, 2022, 450: 138075.
[71]	LI Xibao, HAN Tao, ZHOU Yingtang, et al. Boosting photoelectrocatalytic hydrogen evolution of Bi@OV-BiOBr/Cu₃P high-low heterojunction with dual-channel charge transfer[J]. Applied Catalysis B: Environment and Energy, 2024, 350: 123913.
[72]	LI Xibao, HU Yan, DONG Fan, et al. Non-noble-metallic Ni₂P nanoparticles modified OV-BiOBr with boosting photoelectrochemical hydrogen evolution without sacrificial agent[J]. Applied Catalysis B: Environmental, 2023, 325: 122341.
[73]	PHAM Viet Van, TRUONG Thao Kim, Le Viet HAI, et al. S-scheme α-Fe₂O₃/g-C₃N₄ nanocomposites as heterojunction photocatalysts for antibiotic degradation[J]. ACS Applied Nano Materials, 2022, 5(3): 4506-4514.
[74]	FENG Xiaofang, YU Zongxue, SUN Yuxi, et al. 3D MXene/Ag₂S material as Schottky junction catalyst with stable and enhanced photocatalytic activity and photocorrosion resistance[J]. Separation and Purification Technology, 2021, 266: 118606.
[75]	SHEN Shishi, LI Xibao, ZHOU Yingtang, et al. Novel BiOBr/Bi₂S₃ high-low junction prepared by molten salt method for boosting photocatalytic degradation and H₂O₂ production[J]. Journal of Materials Science & Technology, 2023, 155: 148-159.
[76]	ZAN Zhongqi, LI Xibao, GAO Xiaoming, et al. 0D/2D carbon nitride quantum dots (CNQDs)/BiOBr S-scheme heterojunction for robust photocatalytic degradation and H₂O₂ production[J]. Acta Physico Chimica Sinica, 2023, 39(6): 2209016.
[77]	NI Jiaxin, LIU Dongmei, WANG Wei, et al. Hierarchical defect-rich flower-like BiOBr/Ag nanoparticles/ultrathin g-C₃N₄ with transfer channels plasmonic Z-scheme heterojunction photocatalyst for accelerated visible-light-driven photothermal-photocatalytic oxytetracycline degradation[J]. Chemical Engineering Journal, 2021, 419: 129969.
[78]	CHEN Lijun, WANG Chenguang, LIU Guozhao, et al. Anchoring black phosphorous quantum dots on Bi₂WO₆ porous hollow spheres: A novel 0D/3D S-scheme photocatalyst for efficient degradation of amoxicillin under visible light[J]. Journal of Hazardous Materials, 2023, 443: 130326.
[79]	SARKAR Poulomi, NEOGI Sudarsan, DE Sirshendu. Accelerated radical generation from visible light driven peroxymonosulfate activation by Bi₂MoO₆/doped gCN S-scheme heterojunction towards Amoxicillin mineralization: Elucidation of the degradation mechanism[J]. Journal of Hazardous Materials, 2023, 451: 131102.
[80]	GRAIMED Bassim H, JABBAR Zaid H, ALSUNBULI Maye M, et al. Decoration of 0D Bi₃NbO₇ nanoparticles onto 2D BiOIO₃ nanosheets as visible-light responsive S-scheme photocatalyst for photo-oxidation of antibiotics in wastewater[J]. Environmental Research, 2024, 243: 117854.
[81]	MA Qiansu, MING Jie, SUN Xiang, et al. Photocatalytic degradation of multiple-organic-pollutant under visible light by graphene oxide modified composite: Degradation pathway, DFT calculation and mechanism[J]. Journal of Environmental Management, 2023, 347: 119128.
[82]	LU Jiani, WANG Yinan, LI Hongda, et al. Bi₂MoS _x O_6- _x /α-CoS crystalline/amorphous S-scheme heterojunction for visible light-driven targeted photo-decomposition of amoxicillin[J]. Chemical Engineering Journal, 2023, 470: 144294.
[83]	FANG Siyuan, Xingyi LYU, TONG Tian, et al. Turning dead leaves into an active multifunctional material as evaporator, photocatalyst, and bioplastic[J]. Nature Communications, 2023, 14: 1203.
[84]	JI Haodong, DU Penghui, ZHAO Dongye, et al. 2D/1D graphitic carbon nitride/titanate nanotubes heterostructure for efficient photocatalysis of sulfamethazine under solar light: Catalytic “hot spots” at the rutile-anatase-titanate interfaces[J]. Applied Catalysis B: Environmental, 2020, 263: 118357.
[85]	ZHANG Dandan, QI Juanjuan, JI Haodong, et al. Photocatalytic degradation of ofloxacin by perovskite-type NaNbO₃ nanorods modified g-C₃N₄ heterojunction under simulated solar light: Theoretical calculation, ofloxacin degradation pathways and toxicity evolution[J]. Chemical Engineering Journal, 2020, 400: 125918.
[86]	WANG Ruobing, YU Weili, FANG Ningjie, et al. Constructing fast charge separation of ZnIn₂S₄@CuCo₂S₄ p-n heterojunction for efficient photocatalytic hydrogen energy recovery from quinolone antibiotic wastewater[J]. Applied Catalysis B: Environmental, 2024, 341: 123284.
[87]	WANG Zhenzhou, WANG Danqi, DENG Fang, et al. Ag quantum dots decorated ultrathin g-C₃N₄ nanosheets for boosting degradation of pharmaceutical contaminants: Insight from interfacial electric field induced by local surface plasma resonance[J]. Chemical Engineering Journal, 2023, 463: 142313.
[88]	ZOU Jinru, LIU Yongze, HAN Qi, et al. Importance of chain length in propagation reaction on ·OH formation during ozonation of wastewater effluent[J]. Environmental Science & Technology, 2023, 57(47): 18811-18824.
[89]	WANG Jingjing, YUAN Shijie, DAI Xiaohu, et al. Application, mechanism and prospects of Fe-based/Fe-biochar catalysts in heterogenous ozonation process: A review[J]. Chemosphere, 2023, 319: 138018.
[90]	ZHUANG Wei, ZHENG Ying, XIANG Junying, et al. Enhanced Hydraulic-driven piezoelectric ozonation performance by CNTs/BaTiO₃ nanocatalyst for ibuprofen removal[J]. Chemical Engineering Journal, 2023, 454: 139928.
[91]	TANG Yingcai, WEN Qinxue, CHEN Zhiqiang, et al. Different mobile counter ion types of magnetic ion-exchange resin coupling with ozonation treatment of the organic matter, antibiotic resistance genes, and pathogens in secondary effluent[J]. Chemical Engineering Journal, 2024, 485: 149962.
[92]	高雨飞, 鲁金凤. 非均相催化臭氧氧化作用机理研究进展[J]. 化工进展, 2023, 42(S1): 430-438.
	GAO Yufei, LU Jinfeng. Research progress on mechanism of heterogeneous catalytic ozone oxidation[J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 430-438.
[93]	Sungeun LIM, SHI Jiaming Lily, VON GUNTEN Urs, et al. Ozonation of organic compounds in water and wastewater: A critical review[J]. Water Research, 2022, 213: 118053.
[94]	LONG Jingfei, GUO Yang, YU Gang, et al. Evaluation of the effect of catalysts on ozone mass transfer and pollutant abatement during laboratory catalytic ozonation experiments: Implications for practical water and wastewater treatment[J]. ACS ES&T Engineering, 2023, 3(3): 387-397.
[95]	WANG Zhiyong, LI Kuiling, GUO Jingjing, et al. Enhanced mass transfer of ozone and emerging pollutants through a gas-solid-liquid reaction interface for efficient water decontamination[J]. Environmental Science & Technology, 2023, 57(47): 18647-18657.
[96]	YU Haidong, WANG Mingxi, YAN Jiabao, et al. Complete mineralization of phenolic compounds in visible-light-driven photocatalytic ozonation with single-crystal WO₃ nanosheets: Performance and mechanism investigation[J]. Journal of Hazardous Materials, 2022, 433: 128811.
[97]	ZENG Yaxiong, ZHUO Qizheng, DAI Liyan, et al. Mn anchored zeolite molecular nest for enhanced catalytic ozonation of cephalexin[J]. Chemosphere, 2023, 335: 139058.
[98]	ADAMEK Ewa, BARAN Wojciech. Degradation of veterinary antibiotics by the ozonation process: Product identification and ecotoxicity assessment[J]. Journal of Hazardous Materials, 2024, 469: 134026.
[99]	WANG Yujue, YU Gang. Challenges and pitfalls in the investigation of the catalytic ozonation mechanism: A critical review[J]. Journal of Hazardous Materials, 2022, 436: 129157.
[100]	CHEN Cong, LIU Pengfei, LI Yubao, et al. Electro-peroxone enables efficient Cr removal and recovery from Cr(Ⅲ) complexes and inhibits intermediate Cr(Ⅵ) generation in wastewater: Performance and mechanism[J]. Water Research, 2022, 218: 118502.
[101]	YANG Bochen, GUAN Baohong. Synergistic catalysis of ozonation and photooxidation by sandwich structured MnO₂-NH₂/GO/p-C₃N₄ on cephalexin degradation[J]. Journal of Hazardous Materials, 2022, 439: 129540.
[102]	BEIN Emil, SEIWERT Bettina, REEMTSMA Thorsten, et al. Advanced oxidation processes for removal of monocyclic aromatic hydrocarbon from water: Effects of O₃/H₂O₂ and UV/H₂O₂ treatment on product formation and biological post-treatment[J]. Journal of Hazardous Materials, 2023, 450: 131066.
[103]	LING Yu, LIU Hai, LI Biqing, et al. Efficient photocatalytic ozonation of azithromycin by three-dimensional g-C₃N₄ nanosheet loaded magnetic Fe-MCM-48 under simulated solar light[J]. Applied Catalysis B: Environmental, 2023, 324: 122208.
[104]	KUMAR Amit, RANA Anamika, GUO Changsheng, et al. Acceleration of photo-reduction and oxidation capabilities of Bi₄O₅I₂/SPION@calcium alginate by metallic Ag: Wide spectral removal of nitrate and azithromycin[J]. Chemical Engineering Journal, 2021, 423: 130173.
[105]	LIU Haibao, GAO Yue, WANG Jie, et al. Catalytic ozonation performance and mechanism of Mn-CeO _x @γ-Al₂O₃/O₃ in the treatment of sulfate-containing hypersaline antibiotic wastewater[J]. Science of the Total Environment, 2022, 807: 150867.
[106]	WANG Hui, CHENG Zhaowen, ZHU Nanwen, et al. pH-dependent norfloxacin degradation by E⁺-ozonation: Radical reactivities and intermediates identification[J]. Journal of Cleaner Production, 2020, 265: 121722.
[107]	Matilda KRÅKSTRÖM, SAEID Soudabeh, TOLVANEN Pasi, et al. Catalytic ozonation of the antibiotic sulfadiazine: Reaction kinetics and transformation mechanisms[J]. Chemosphere, 2020, 247: 125853.
[108]	WU Jun, SUN Qi, LU Jian. Catalytic ozonation of antibiotics by using Mg(OH)₂ nanosheet with dot-sheet hierarchical structure as novel nanoconfined catalyst[J]. Chemosphere, 2022, 302: 134835.
[109]	LU Jiang, SUN Jingxiang, CHEN Xixi, et al. Efficient mineralization of aqueous antibiotics by simultaneous catalytic ozonation and photocatalysis using MgMnO₃ as a bifunctional catalyst[J]. Chemical Engineering Journal, 2019, 358: 48-57.
[110]	PELALAK Rasool, ALIZADEH Reza, GHARESHABANI Eslam, et al. Degradation of sulfonamide antibiotics using ozone-based advanced oxidation process: Experimental, modeling, transformation mechanism and DFT study[J]. Science of the Total Environment, 2020, 734: 139446.
[111]	SHAHMAHDI Najmeh, DEHGHANZADEH Reza, ASLANI Hassan, et al. Performance evaluation of waste iron shavings (Fe₀) for catalytic ozonation in removal of sulfamethoxazole from municipal wastewater treatment plant effluent in a batch mode pilot plant[J]. Chemical Engineering Journal, 2020, 383: 123093.
[112]	WU Yaohua, LI Yulian, HE Junyong, et al. Nano-hybrids of needle-like MnO₂ on graphene oxide coupled with peroxymonosulfate for enhanced degradation of norfloxacin: A comparative study and probable degradation pathway[J]. Journal of Colloid and Interface Science, 2020, 562: 1-11.
[113]	KIM Soyeon, TANG Cheng, PARK Yuri, et al. Unveiling the adsorption mechanism of beta-blockers and sulfonamides in aqueous environment using disulfide-linked polymer[J]. Separation and Purification Technology, 2024, 333: 125897.
[114]	HACHEM Kadda, JADE CATALAN OPULENCIA Maria, KAMAL ABDELBASSET Walid, et al. RETRACTED: Anti-inflammatory effect of functionalized sulfasalazine boron nitride nanocages on cardiovascular disease and breast cancer: An in-silico simulation[J]. Journal of Molecular Liquids, 2022, 356: 119030.
[115]	EISENHAUER Hugh R. Oxidation of phenolic wastes[J]. Water Pollution Control Federation, 1964, 36(9): 1116-1128.
[116]	GHASEMI Homa, MOZAFFARI Saeed, MOUSAVI Seyed Hesam, et al. Decolorization of wastewater by heterogeneous Fenton reaction using MnO₂-Fe₃O₄/CuO hybrid catalysts[J]. Journal of Environmental Chemical Engineering, 2021, 9(2): 105091.
[117]	ZHANG Nuanqin, XUE Chengjie, WANG Kuang, et al. Efficient oxidative degradation of fluconazole by a heterogeneous Fenton process with Cu-V bimetallic catalysts[J]. Chemical Engineering Journal, 2020, 380: 122516.
[118]	LIU Yong, WANG Jianlong. Multivalent metal catalysts in Fenton/Fenton-like oxidation system: A critical review[J]. Chemical Engineering Journal, 2023, 466: 143147.
[119]	JIANG Yu, RAN Jiabing, MAO Kang, et al. Recent progress in Fenton/Fenton-like reactions for the removal of antibiotics in aqueous environments[J]. Ecotoxicology and Environmental Safety, 2022, 236: 113464.
[120]	LIU Chongchong, WANG Peifang, HUANG Peilin, et al. Photo-induced heterogeneous regeneration of Fe(Ⅱ) in Fenton reaction for efficient polycyclic antibiotics removal and in-depth charge transfer mechanism[J]. Journal of Colloid and Interface Science, 2023, 638: 768-777.
[121]	JIA Wenqiang, SONG Jiaying, WANG Jian, et al. Fenton oxidation treatment of oxytetracycline fermentation residues: Harmless performance and bioresource properties[J]. Chemosphere, 2023, 336: 139201.
[122]	XU Jing, LIANG Puying, SHEN Xuancheng, et al. High-efficiency removal of organic pollutants, antibiotic resistant bacteria and resistance genes by a photocatalysis-self-Fenton system based on S, K co-doped g-C₃N₄ nanosheets[J]. Separation and Purification Technology, 2024, 339: 126734.
[123]	ZHANG Shiyu, WANG Rupeng, WANG Ke, et al. Aeration-free in situ Fenton-like reaction: Specific adsorption and activation of oxygen on heterophase oxygen vacancies[J]. Environmental Science & Technology, 2024, 58(4): 1921-1933.
[124]	FURIA Francesco, MINELLA Marco, GOSETTI Fabio, et al. Elimination from wastewater of antibiotics reserved for hospital settings, with a Fenton process based on zero-valent iron[J]. Chemosphere, 2021, 283: 131170.
[125]	WANG Xinhao, XIONG Zhaokun, SHI Hongle, et al. Switching the reaction mechanisms and pollutant degradation routes through active center size-dependent Fenton-like catalysis[J]. Applied Catalysis B: Environmental, 2023, 329: 122569.
[126]	HE Wenjuan, JIA Hongping, LI Zuopeng, et al. Magnetic recyclable g-C₃N₄/Fe₃O₄@MIL-100(Fe) ternary catalyst for photo-Fenton degradation of ciprofloxacin[J]. Journal of Environmental Chemical Engineering, 2022, 10(6): 108698.
[127]	JIANG Wenxuan, HAN Jiangang, GUO He. Highlight the plasma-generated reactive oxygen species (ROSs) dominant to degradation of emerging contaminants based on experiment and density functional theory[J]. Separation and Purification Technology, 2024, 330: 125309.
[128]	HONARMANDRAD Zhila, SUN Xun, WANG Zhaohui, et al. Activated persulfate and peroxymonosulfate based advanced oxidation processes (AOPs) for antibiotics degradation—A review[J]. Water Resources and Industry, 2023, 29: 100194.
[129]	齐亚兵. 活化过硫酸盐高级氧化法降解抗生素的研究进展[J]. 化工进展, 2022, 41(12): 6627-6643.
	QI Yabing. Research progress on degradation of antibiotics by activated persulfate oxidation[J]. Chemical Industry and Engineering Progress, 2022, 41(12): 6627-6643.
[130]	段毅, 邹烨, 周书葵, 等. 过渡金属单原子催化剂活化H₂O₂/PMS/PDS降解有机污染物的研究进展[J]. 化工进展, 2022, 41(8): 4147-4158.
	DUAN Yi, ZOU Ye, ZHOU Shukui, et al. Progress in the degradation of organic pollutants by H₂O₂/PMS/PDS activated by transition metal single-atom catalysts[J]. Chemical Industry and Engineering Progress, 2022, 41(8): 4147-4158.
[131]	KOHANTORABI Mona, MOUSSAVI Gholamreza, GIANNAKIS Stefanos. A review of the innovations in metal- and carbon-based catalysts explored for heterogeneous peroxymonosulfate (PMS) activation, with focus on radical vs. non-radical degradation pathways of organic contaminants[J]. Chemical Engineering Journal, 2021, 411: 127957.
[132]	CHEN Meiqing, HUANG Zhiyan, LIANG Shuling, et al. Immobilized Co²⁺ and Cu²⁺ induced structural change of layered double hydroxide for efficient heterogeneous degradation of antibiotic[J]. Journal of Hazardous Materials, 2021, 403: 123554.
[133]	LI Yinghao, ZHU Wenjie, GUO Qian, et al. Highly efficient degradation of sulfamethoxazole (SMX) by activating peroxymonosulfate (PMS) with CoFe₂O₄ in a wide pH range[J]. Separation and Purification Technology, 2021, 276: 119403.
[134]	LIU Fan, ZHOU Hongyu, PAN Zhicheng, et al. Degradation of sulfamethoxazole by cobalt-nickel powder composite catalyst coupled with peroxymonosulfate: Performance, degradation pathways and mechanistic consideration[J]. Journal of Hazardous Materials, 2020, 400: 123322.
[135]	LIU Zhanmeng, GAO Zhimin, WU Qin. Activation of persulfate by magnetic zirconium-doped manganese ferrite for efficient degradation of tetracycline[J]. Chemical Engineering Journal, 2021, 423: 130283.
[136]	LIU Yingying, ZOU Haiyan, MA Hanyu, et al. Highly efficient activation of peroxymonosulfate by MOF-derived CoP/CoO _x heterostructured nanoparticles for the degradation of tetracycline[J]. Chemical Engineering Journal, 2022, 430: 132816.
[137]	ZHANG Binbin, BAI Changwei, CHEN Xinjia, et al. 2D/2D heterojunctions for rapid and self-cleaning removal of antibiotics via visible light-assisted peroxymonosulfate activation: Efficiency, synergistic effects, and applications[J]. Journal of Hazardous Materials, 2024, 468: 133816.
[138]	WANG Hanlin, CHEN Tianhu, CHEN Dong, et al. Sulfurized oolitic hematite as a heterogeneous Fenton-like catalyst for tetracycline antibiotic degradation[J]. Applied Catalysis B: Environmental, 2020, 260: 118203.
[139]	WAN Zhonghao, CAO Yang, XU Zibo, et al. Revealing intrinsic relations between Cu scales and radical/nonradical oxidations to regulate nucleophilic/electrophilic catalysis[J]. Advanced Functional Materials, 2023, 33(12): 2212227.
[140]	LI Shuo, YANG Yalun, ZHENG Heshan, et al. Introduction of oxygen vacancy to manganese ferrite by Co substitution for enhanced peracetic acid activation and ¹O₂ dominated tetracycline hydrochloride degradation under microwave irradiation[J]. Water Research, 2022, 225: 119176.
[141]	DOU Jibo, TANG Yao, LU Zhijiang, et al. Neglected but efficient electron utilization driven by biochar-coactivated phenols and peroxydisulfate: Polyphenol accumulation rather than mineralization[J]. Environmental Science & Technology, 2023, 57(14): 5703-5713.
[142]	LIU Xinru, QIN Hehe, XING Siyang, et al. Selective removal of organic pollutants in groundwater and surface water by persulfate-assisted advanced oxidation: The role of electron-donating capacity[J]. Environmental Science & Technology, 2023, 57(36): 13710-13720.
[143]	YANG Bowen, KANG Haisu, Young-Jin KO, et al. Persulfate activation by nanodiamond-derived carbon Onions: Effect of phase transformation of the inner diamond core on reaction kinetics and mechanisms[J]. Applied Catalysis B: Environmental, 2021, 293: 120205.
[144]	JIANG Zijian, WEI Jia, NIU Xiruo, et al. Highly dispersed Fe₇S₈ anchored on sp²/sp³ hybridized carbon boosting peroxymonosulfate activation for enhanced EOCs elimination though singlet oxygen-dominated nonradical pathway[J]. Journal of Hazardous Materials, 2024, 461: 132607.
[145]	XU Huan, ZHU Kairuo, ALHARBI Njud S, et al. Mechanisms and degradation pathways of doxycycline hydrochloride by Fe₃O₄ nanoparticles anchored nitrogen-doped porous carbon microspheres activated peroxymonosulfate[J]. Chemosphere, 2023, 333: 138917.
[146]	WANG Aiwen, DU Meng, NI Jiaxin, et al. Enhanced and synergistic catalytic activation by photoexcitation driven S-scheme heterojunction hydrogel interface electric field[J]. Nature Communications, 2023, 14: 6733.
[147]	CUI Xueru, WEI Jia, JIANG Zijian, et al. Highly efficient elimination of organic contaminants by boron-doped biochar modified dual-cathode electro-Fenton system[J]. Separation and Purification Technology, 2024, 342: 126996.

高级氧化技术降解典型抗生素的研究进展

Research progress on degradation of typical antibiotics by advanced oxidation processes

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