锰基催化剂催化氧化甲苯的研究进展

doi:10.16085/j.issn.1000-6613.2023-0896

化工进展 ›› 2024, Vol. 43 ›› Issue (11): 6129-6139.DOI: 10.16085/j.issn.1000-6613.2023-0896

• 工业催化 • 上一篇

锰基催化剂催化氧化甲苯的研究进展

崔维怡¹^,²(), 谭乃迪²(), 霍其雷³, 李伟⁴

^1.吉林化工学院化工清洁生产技术吉林省高校重点实验室，吉林吉林 132022
^2.吉林化工学院化学与制药工程学院，吉林吉林 132022
^3.中国石油吉林石化公司乙烯厂，吉林吉林 132022
^4.中国石油吉林石化公司化肥厂，吉林吉林 132021

收稿日期:2023-05-30 修回日期:2023-08-03 出版日期:2024-11-15 发布日期:2024-12-07
通讯作者: 谭乃迪
作者简介:崔维怡（1977—），女，副教授，研究方向为环境催化。E-mail：cuiweiyi0119@163.com。
基金资助:
国家自然科学基金(51805207);吉林省科技发展计划(YDZJ202401378ZYTS)

Research progress in catalytic oxidation of toluene over Mn-based catalysts

CUI Weiyi¹^,²(), TAN Naidi²(), HUO Qilei³, LI Wei⁴

^1.The Key Laboratory of Chemical Cleaner Production Technology of Jilin Province, Jilin Institute of Chemical Technology, Jilin 132022, Jilin, China
^2.College of Chemical and Pharmaceutical Engineering, Jilin Institute of Chemical and Technology, Jilin 132022, Jilin, China
^3.Ethylene Plant of Jilin Petrochemical Company, PetroChina, Jilin 132022, Jilin, China
^4.Fertilizer Plant of Jilin Petrochemical Company，PetroChina, Jilin 132021, Jilin, China

Received:2023-05-30 Revised:2023-08-03 Online:2024-11-15 Published:2024-12-07
Contact: TAN Naidi

摘要/Abstract

摘要：

甲苯是一种来源广泛的芳香族化合污染物，对人体健康及环境都产生强烈的危害。锰氧化物具有形貌可控、晶体结构多样、价态可变等特点，被认为是最具有应用潜力的甲苯氧化催化剂。本文综述了近年来锰基催化剂催化氧化甲苯的研究进展，主要介绍了单一锰氧化物和复合锰氧化物，讨论了形貌、晶型结构、氧空位、金属-载体相互作用等因素对甲苯催化氧化性能的影响，并归纳了一部分甲苯催化氧化的反应机理。最后，提出开发简单的合成工艺以构建MnO _x 纳米催化剂或Mn基复合纳米催化剂，研究实际的工业尾气影响催化剂行为的因素等是该领域未来的研究方向。

关键词: 甲苯催化氧化, 锰氧化物, 活性, 氧物种

Abstract:

Toluene is an aromatic pollutant coming from a wide range of sources, which causes strong harm to human health and environment. Manganese oxide is considered as the most potential catalyst for oxidation of toluene due to its controllable morphology, diverse crystal structure and variable valence state. In this paper, the research progress of catalytic oxidation of toluene by manganese-based catalysts in recent years was reviewed, including single manganese oxide and composite manganese oxide. The effects of morphology, crystal structure, oxygen vacancy, metal-carrier interaction and other factors on the catalytic oxidation performance of toluene were discussed. The catalytic reaction mechanisms of toluene oxidation were also summarized. Finally, it is suggested that developing a simple synthesis process to construct MnO _x or Mn-based composite nano-catalyst, and studying the actual factors affecting the catalyst behavior for industrial exhaust are the future research directions in this field.

Key words: toluene catalytic oxidation, manganese oxide, activity, oxygen species

中图分类号:

TQ426

崔维怡, 谭乃迪, 霍其雷, 李伟. 锰基催化剂催化氧化甲苯的研究进展[J]. 化工进展, 2024, 43(11): 6129-6139.

CUI Weiyi, TAN Naidi, HUO Qilei, LI Wei. Research progress in catalytic oxidation of toluene over Mn-based catalysts[J]. Chemical Industry and Engineering Progress, 2024, 43(11): 6129-6139.

图/表 8

图1 花状MnO2空心微球的形成过程[11]

图2 MnO2扫描电镜图片[17](a) β-MnO2; (b) α-MnO2; (c) γ-MnO2; (d) δ-MnO2-1; (e) δ-MnO2-2; (f) δ-MnO2-3

图3 T-0.5 MnO2-Mn2O3界面上甲苯的氧化机理[25]

图4 CM-X催化剂合成过程[35]

图5 10%-MnO2@CeO2催化剂上甲苯氧化活性优异的影响因素[42]

图6 尖晶石CoMn2O4上甲苯降解途径机制[57]

图7 甲苯在α-MnO2上的催化氧化反应机理[63]

图8 甲苯在Pt/CuMnO x 催化剂上的催化氧化反应途径[67]

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锰基催化剂催化氧化甲苯的研究进展

Research progress in catalytic oxidation of toluene over Mn-based catalysts

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