链状MFI型分子筛的合成与应用

doi:10.16085/j.issn.1000-6613.2023-1140

摘要/Abstract

摘要：

链状MFI型分子筛是由大小均一的晶粒沿b轴方向通过表面羟基缩合而成，在保留传统分子筛独特的三维孔道结构、耐酸性、水热稳定性、高催化活性的同时，具有较高的孔道择形性，在吸附、分离、催化等领域展现出独特的性能。本文系统介绍了链状MFI型分子筛合成及其应用领域的最新研究进展，重点综述了常规水热合成与微波辅助水热合成两种方法，深入分析了链状MFI型分子筛的形成机理，对诱导表面羟基缩合的各种因素进行了详细阐述，总结了其在物理吸附及催化方面的优异性能。最后对链状MFI型分子筛的绿色合成及潜在应用进行了展望，提出硅配位环境的动态变化过程分析对于揭示其合成机理至关重要，将为拓展链状MFI型分子筛的应用奠定重要理论基础。

关键词: 链状, MFI型分子筛, 合成, 催化

Abstract:

Chainlike MFI type zeolites were formed by the condensation of uniformly sized crystals along the b-axis direction through surface hydroxyl groups, which not only maintianed traditional zeolites' unique three-dimensional pore structure, acid resistance, hydrothermal stability, and high catalytic activity, but also showed higher shape selectivity, endowing them with unique properties in many fields such as adsorption, separation and catalysis. This paper systematically presented the current research development on the synthesis of chainlike MFI type zeolites and their application, focusing on the two synthesis methods of conventional hydrothermal and microwave-assisted hydrothermal synthesis. In addition, it analyzed the formation mechanism of chainlike MFI type zeolites in depth, elaborated on the various factors inducing the condensation of Si—OH groups, and then concluded the excellent catalytic and adsorptive performance of chainlike MFI type zeolites. Finally, an outlook on the green synthesis and potential application about chainlike MFI type zeolites was given, and the analysis on the evolution of silicon coordination environment was proposed as an important direction for further exploring their synthesis mechanism, which would lay an essential theoretical foundation for expanding the application of chainlike MFI type zeolites in the future.

Key words: chainlike morphology, MFI type zeolites, synthesis, catalysis

中图分类号:

TQ426.65

张叶素, 权燕红, 丁欣欣, 任军. 链状MFI型分子筛的合成与应用[J]. 化工进展, 2024, 43(8): 4382-4392.

ZHANG Yesu, QUAN Yanhong, DING Xinxin, REN Jun. Synthesis and application of chainlike MFI type zeolites[J]. Chemical Industry and Engineering Progress, 2024, 43(8): 4382-4392.

图/表 9

参考文献 61

1	徐如人, 庞文琴, 于吉红, 等. 分子筛与多孔材料化学[M]. 北京: 科学出版社, 2004.
	XU Ruren, PANG Wenqin, YU Jihong, et al. Molecular sieves and porous materials chemistry[M]. Beijing: Science Press, 2004.
2	OLSON D H, KOKOTAILO G T, LAWTON S L, et al. Crystal structure and structure-related properties of ZSM-5[J]. The Journal of Physical Chemistry, 1981, 85(15): 2238-2243.
3	权燕红. 链形ZSM-5分子筛的控制合成及取向生长机理研究[D]. 北京: 中国科学院大学, 2017.
	QUAN Yanhong. Study on the controllable synthesis and oriented growth mechanism of chainlike ZSM-5 zeolite[D]. Beijing: University of Chinese Academy of Sciences, 2017.
4	ARGAUER R J, LANDOLT G R. Crystallization zeolite ZSM-5 and method of preparing the same: US3702886[P]. 1972-11-14.
5	KOKOTAILO G T, LAWTON S L, OLSON D H, et al. Structure of synthetic zeolite ZSM-5[J]. Nature, 1978, 272: 437-438.
6	TARAMASSO Marco, PEREGO Giovanni, NOTARI Bruno. Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides: US4410501[P]. 1983-10-18.
7	ZHAO Tingting, LI Fuwei, YU Hongchang, et al. Synthesis of mesoporous ZSM-5 zeolites and catalytic cracking of ethanol and oleic acid into light olefins[J]. Applied Catalysis A: General, 2019, 575: 101-110.
8	张春梅, 付廷俊, 邵娟, 等. 介孔结构和助剂Zn对不同晶粒大小ZSM-5催化甲醇制芳烃反应性能的影响[J]. 化工进展, 2019, 38(4): 1758-1767.
	ZHANG Chunmei, FU Tingjun, SHAO Juan, et al. Effects of mesoporous structure and Zn promoter on methanol to aromatics performance over different crystal sized ZSM-5 catalysts[J]. Chemical Industry and Engineering Progress, 2019, 38(4): 1758-1767.
9	崔生航, 张君涛, 申志兵. 多级孔道ZSM-5分子筛的合成及其催化应用[J]. 化工进展, 2015, 34(9): 3311-3316, 3336.
	CUI Shenghang, ZHANG Juntao, SHEN Zhibing. Hierarchical ZSM-5 zeolite: Synthesis and catalytic applications[J]. Chemical Industry and Engineering Progress, 2015, 34(9): 3311-3316, 3336.
10	QUAN Yanhong, LI Shiying, WANG Sen, et al. Synthesis of chainlike ZSM-5 zeolites: Determination of synthesis parameters, mechanism of chainlike morphology formation, and their performance in selective adsorption of xylene isomers[J]. ACS Applied Materials & Interfaces, 2017, 9(17): 14899-14910.
11	黄世勇, 任育宏, 黄尚顺, 等. 不同形貌ZSM-5分子筛的合成及甲醇制汽油催化性能[J]. 广西大学学报(自然科学版), 2020, 45(2): 414-420.
	HUANG Shiyong, REN Yuhong, HUANG Shangshun, et al. Synthesis of ZSM-5 zeolites with different morphology and the catalytic performance for methanol to gasoline (MTG) reaction[J]. Journal of Guangxi University (Natural Science Edition), 2020, 45(2): 414-420.
12	ZHOU Zihan, JIANG Rongli, CHEN Xueshuai, et al. One-step synthesis of hierarchical lamellar H-ZSM-5 zeolite and catalytic performance of methanol to olefin[J]. Journal of Solid State Chemistry, 2021, 298: 122132.
13	TANG Guoqiang, LI Yichuan, WANG Yu, et al. A review on the synthesis, structural modification and application of two-dimensional MFI zeolite[J]. Journal of Porous Materials, 2022, 29(6): 1649-1666.
14	PARK Sang-Eon, CHANG Jong-San, HWANG Young Kyu, et al. Supramolecular interactions and morphology control in microwave synthesis of nanoporous materials[J]. Catalysis Surveys from Asia, 2004, 8(2): 91-110.
15	Afsaneh SHIRZADEH-GHARACHEH, Masoud RAHBARI-SISAKHT. Polyvinylidene fluoride hollow fiber mixed matrix membrane contactor incorporating modified ZSM-5 zeolite for carbon dioxide absorption[J]. RSC Advances, 2016, 6(82): 78865-78874.
16	DAI Weijiong, KOUVATAS Cassandre, TAI Wenshu, et al. Platelike MFI crystals with controlled crystal faces aspect ratio[J]. Journal of the American Chemical Society, 2021, 143(4): 1993-2004.
17	邵秀丽, 王驷骐, 张轩, 等. 纳米片层结构MFI分子筛的合成及应用[J]. 化学进展, 2022, 34(12): 2651-2666.
	SHAO Xiuli, WANG Siqi, ZHANG Xuan, et al. Fabrication and application of MFI zeolite nanosheets[J]. Progress in Chemistry, 2022, 34(12): 2651-2666.
18	HAO Jing, XU Shuman, CHENG Dangguo, et al. Synthesis of nanosheet epitaxial growth ZSM-5 zeolite with increased diffusivity and its catalytic cracking performance[J]. Catalysis Science & Technology, 2022, 12(12): 3912-3920.
19	姜健准, 张明森, 柯丽, 等. 超细ZSM-5分子筛的制备及其形貌表征[J]. 化工进展, 2012, 31(9): 1980-1984.
	JIANG Jianzhun, ZHANG Mingsen, KE Li, et al. Synthesis and characterization of ultra-fine ZSM-5 zeolite[J]. Chemical Industry and Engineering Progress, 2012, 31(9): 1980-1984.
20	MA Tong, ZHANG Luoming, SONG Yu, et al. A comparative synthesis of ZSM-5 with ethanol or TPABr template: Distinction of Brønsted/Lewis acidity ratio and its impact on n-hexane cracking[J]. Catalysis Science & Technology, 2018, 8(7): 1923-1935.
21	童伟益, 宋家庆, 赵昱. 原位合成球花形貌多级孔ZSM-5及其催化甲醇制丙烯性能[J]. 化学反应工程与工艺, 2021, 37(6): 505-512.
	TONG Weiyi, SONG Jiaqing, ZHAO Yu. Synthesis and methanol to propylene properties of flowerlike spheroidal morphology hierarchical ZSM-5[J]. Chemical Reaction Engineering and Technology, 2021, 37(6): 505-512.
22	刘文婷. 具有介孔的链状MFI型分子筛的合成、表征及催化性能初探[D]. 长春: 吉林大学, 2010.
	LIU Wenting. Synthesis, characterization and catalytic properties of mesoporous MFI zeolite with self-stacked morphology[D].Changchun: Jilin University, 2010.
23	HE Wen, LI Fuwei, GU Yufei, et al. Synthesis of chainlike ZSM-5 with a polyelectrolyte as a second template for oleic acid and ethanol cracking into light olefins[J]. ACS Omega, 2022, 7(44): 40520-40531.
24	JIN Lijun, XIE Tong, LIU Sibao, et al. Controllable synthesis of chainlike hierarchical ZSM-5 templated by sucrose and its catalytic performance[J]. Catalysis Communications, 2016, 75: 32-36.
25	JIANG Jinlong, JI Shoupeng, DUANMU Chuansong, et al. Self-assembly of fibrous ZSM-5 zeolites in the presence of sodium alginate[J]. Particuology, 2017, 33: 55-62.
26	侯慧琳, 蒋荣立, 陈学帅, 等. ZSM-5分子筛的合成与应用研究进展[J]. 天然气化工(C1化学与化工), 2021, 46(5): 7-12.
	HOU Huilin, JIANG Rongli, CHEN Xueshuai, et al. Research progress in synthesis and application of ZSM-5 zeolites[J]. Natural Gas Chemical Industry, 2021, 46(5): 7-12.
27	BARRER R M, BAYNHAM J W, BULTITUDE F W, et al. 36. Hydrothermal chemistry of the silicates. Part Ⅷ. Low-temperature crystal growth of aluminosilicates, and of some gallium and germanium analogues[J]. Journal of the Chemical Society (Resumed), 1959(0): 195-208.
28	LI Shiying, LI Junfen, DONG Mei, et al. Strategies to control zeolite particle morphology[J]. Chemical Society Reviews, 2019, 48(3): 885-907.
29	刘春燕. ZSM-5沸石水热合成中的晶粒度调控[D]. 大连: 大连理工大学, 2014.
	LIU Chunyan. Crystal size control during the hydrothermal synthesis of ZSM-5 zeolite[D]. Dalian: Dalian University of Technology, 2014.
30	MEI Changsong, LIU Zhicheng, WEN Pengyu, et al. Regular HZSM-5 microboxes prepared via a mild alkaline treatment[J]. Journal of Materials Chemistry, 2008, 18(29): 3496-3500.
31	王晔, 李家栋, 林晓. 自堆积纤维状TS-1分子筛的常规水热合成[J]. 无机化学学报, 2010, 26(9): 1711-1714.
	WANG Ye, LI Jiadong, LIN Xiao. Self-stacked TS-1 zeolite with fibrous morphology prepared by conventional hydrothermal method[J]. Chinese Journal of Inorganic Chemistry, 2010, 26(9): 1711-1714.
32	牛世军, 王晔, 林晓. 纤维状形貌TS-1分子筛的形成[J]. 南京工业大学学报(自然科学版), 2012, 34(4): 65-68, 73.
	NIU Shijun, WANG Ye, LIN Xiao. Formation of TS-1 zeolite with fibrous morphology[J]. Journal of Nanjing University of Technology (Natural Science Edition), 2012, 34(4): 65-68, 73.
33	AOKI Kensuke, MANN Stephen. Polyelectrolyte-mediated synthesis and self-assembly of silicalite nanocrystals into linear chain superstructures[J]. Journal of Materials Chemistry, 2005, 15(1): 111-113.
34	WANG Runwei, LIU Wenting, DING Shuang, et al. Mesoporous MFI zeolites with self-stacked morphology templated by cationic polymer[J]. Chemical Communications, 2010, 46(39): 7418-7420.
35	刘斯宝, 靳立军, 栾珊, 等. 以蔗糖为模板合成链状多级孔道ZSM-5[C]//第六届全国化学工程与生物化工年会论文集. 2010: 1-4.
	LIU Sibao, JIN Lijun, LUAN Shan, et al. Chainlike hierarchical ZSM-5 synthesis templated by sucrose[C]//Proceedings of the Sixth Annual National Conference on Chemical Engineering and Biochemistry. 2010: 1-4.
36	LIU Xiuru, SUN Yiqing. Effect of ethanol on the morphology and textual properties of ZSM-5 zeolite[J]. Catalysts, 2020, 10(2): 198.
37	田晓帅. 水热合成低硅铝比纳米ZSM-5沸石的研究[D]. 大连: 大连理工大学, 2013.
	TIAN Xiaoshuai. Hydrothermal synthesis of nano-ZSM-5 with low SiO₂/Al₂O₃ molar ratio[D]. Dalian: Dalian University of Technology, 2013.
38	MA Zhe, DENG Hua, LI Lin, et al. Fluoride-free and seed-free microwave-assisted hydrothermal synthesis of nanosized high-silica Beta zeolites for effective VOCs adsorption[J]. Chemical Science, 2023, 14(8): 2131-2138.
39	王达锐, 孙洪敏, 薛明伟, 等. 微波法高效合成全结晶ZSM-5分子筛催化剂及其催化性能[J]. 化工进展, 2023, 42(7): 3582-3588.
	WANG Darui, SUN Hongmin, XUE Mingwei, et al. Efficient synthesis of fully crystalline ZSM-5 zeolite catalyst by microwave method and its catalytic performance[J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3582-3588.
40	PARK Sang-Eon, CHOI Kwang-Min. Green catalysis by microwave synthesized nanostructured materials[J]. Journal of Physics and Chemistry of Solids, 2008, 69(5/6): 1501-1504.
41	ARAFAT A, JANSEN J C, EBAID A R, et al. Microwave preparation of zeolite Y and ZSM-5[J]. Zeolites, 1993, 13(3): 162-165.
42	HWANG Young Kyu, CHANG Jong-San, PARK Sang-Eon, et al. Microwave fabrication of MFI zeolite crystals with a fibrous morphology and their applications[J]. Angewandte Chemie International Edition, 2005, 44(4): 556-560.
43	JIN Hailian, JIANG Nanzhe, PARK Sang-Eon. Nanoarchitectured synthesis of TS-1 depending on microwave power[J]. Journal of Physics and Chemistry of Solids, 2008, 69(5/6): 1136-1138.
44	CHEN Xiaoxin, YAN Wenfu, SHEN Wanling, et al. Morphology control of self-stacked silicalite-1 crystals using microwave-assisted solvothermal synthesis[J]. Microporous and Mesoporous Materials, 2007, 104(1/2/3): 296-304.
45	JIN Taihuan, HWANG Young Kyu, HONG Do-Young, et al. Microwave synthesis, characterization and catalytic properties of titanium-incorporated ZSM-5 zeolite[J]. Research on Chemical Intermediates, 2007, 33(6): 501-512.
46	XU Chenghua, JIN Taihuan, JHUNG Sung Hwa, et al. Hydrophobicity and catalytic properties of Ti-MFI zeolites synthesized by microwave and conventional heating[J]. Catalysis Today, 2006, 111(3/4): 366-372.
47	赵杉林, 张扬建, 孙桂大, 等. ZSM-5沸石分子筛的微波辐射法合成与表征[J]. 石油学报(石油加工), 1999, 15(3): 89-91.
	ZHAO Shanlin, ZHANG Yangjian, SUN Guida, et al. Characterization and synthesis of zeolite ZSM 5 by microwave radiation[J]. Acta Petrolei Sinica (Petroleum Processing Section), 1999, 15(3): 89-91.
48	舒静, 任丽丽, 张铁珍, 等. 微波辐射在催化剂制备中的应用[J]. 化工进展, 2008, 27(3): 352-357.
	SHU Jing, REN Lili, ZHANG Tiezhen, et al. Application of microwave irradiation in the preparation of catalyst[J]. Chemical Industry and Engineering Progress, 2008, 27(3): 352-357.
49	SHAN Zhichao, WANG Hong, MENG Xiangju, et al. Designed synthesis of TS-1 crystals with controllable b-oriented length[J]. Chemical Communications, 2011, 47(3): 1048-1050.
50	彭涵, 张纪梅, 王学铭, 等. 杂原子沸石分子筛的合成及应用研究进展[J]. 山东化工, 2019, 48(3): 44-46, 48.
	PENG Han, ZHANG Jimei, WANG Xueming, et al. Advances in synthesis and application of heteroatom-containing zeolites[J]. Shandong Chemical Industry, 2019, 48(3): 44-46, 48.
51	SAKIZCI Meryem, ERDOĞAN ALVER Burcu, Ertuğrul YÖRÜKOĞULLARI. Influence of the exchangeable cations on SO₂ adsorption capacities of clinoptilolite-rich natural zeolite[J]. Adsorption, 2011, 17(4): 739-745.
52	WANG Chuanfu, ZHANG Lei, HUANG Xin, et al. Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene[J]. Nature Communications, 2019, 10(1): 4348.
53	TIAN Peng, WEI Yingxu, YE Mao, et al. Methanol to olefins (MTO): From fundamentals to commercialization[J]. ACS Catalysis, 2015, 5(3): 1922-1938.
54	YARULINA Irina, CHOWDHURY Abhishek Dutta, MEIRER Florian, et al. Recent trends and fundamental insights in the methanol-to-hydrocarbons process[J]. Nature Catalysis, 2018, 1: 398-411.
55	潘红艳, 田敏, 何志艳, 等. 甲醇制烯烃用ZSM-5分子筛的研究进展[J]. 化工进展, 2014, 33(10): 2625-2633.
	PAN Hongyan, TIAN Min, HE Zhiyan, et al. Advances in research on modified ZSM-5 molecular sieves for conversion of methanol to olefins[J]. Chemical Industry and Engineering Progress, 2014, 33(10): 2625-2633.
56	杨秀娜, 姜阳, 齐慧敏. 多级孔ZSM-5分子筛的制备及其催化甲醇芳构化反应性能[J]. 化工进展, 2016, 35(11): 3536-3541.
	YANG Xiuna, JIANG Yang, QI Huimin. Synthesis of hierarchical ZSM-5 molecular sieves and evaluation of their catalytic performance in methanol aromatization[J]. Chemical Industry and Engineering Progress, 2016, 35(11): 3536-3541.
57	WANG Ting, YANG Chengguang, GAO Peng, et al. ZnZrO _x integrated with chain-like nanocrystal HZSM-5 as efficient catalysts for aromatics synthesis from CO₂ hydrogenation[J]. Applied Catalysis B: Environmental, 2021, 286: 119929.
58	XU Xianglong, WEN Chengyan, JIN Ke, et al. Chain-like ZSM-5 zeolite coupled with Cu-Fe₃O₄ for CO₂ hydrogenation to light aromatics[J]. Journal of Fuel Chemistry and Technology, 2022, 50(9): 1183-1190.
59	LIU Shuang, YANG Shuang, HE Jing, et al. Efficient synthesis of chain-like ZSM-5 zeolite for the m-xylene isomerization reaction[J]. Inorganic Chemistry Communications, 2021, 128: 108564.
60	QUAN Yanhong, PENG Lulu, JIN Yuting, et al. Highly effective chainlike Ni/CZ5-x catalysts for catalytic reduction of p-nitrophenol: Effect of Si/Al ratio of ZSM-5 support[J]. Journal of Environmental Chemical Engineering, 2023, 11(6): 111402.
61	JIN Yuting, QUAN Yanhong, LI Yan, et al. Probing synergistic effect of active Cu⁰ species and surface acidity of chainlike ZSM-5 supported copper catalysts in methanol dehydrogenation to methyl formate[J]. Fuel, 2024, 355: 129546.

合成方法	MFI型分子筛	模板剂	Si/Al或Si/Ti	比表面积 /m²·g^-1	总孔容 /cm³·g^-1	特征与优势	应用	参考文献
水热合成法
模板法	ZSM-5	TPAOH	70	315	0.47	中空、介孔结构	催化裂解	[30]
		TPAOH	63	313	0.28	介孔结构	异构化	[59]
		TPAOH	83	398.8	—	链长适当	CO₂加氢制芳烃	[58]
助剂辅助法	ZSM-5	TPAOH、PDDA	90	470	0.27	介孔结构	甲醇制烯烃	[22]
		TPAOH、PDDA	50	538.7	0.77	介孔结构	催化裂解	[23]
		TPAOH、蔗糖	136	397	0.36	介孔结构	甲基化	[24]
		TPAOH、SA	16~64	410	0.25	—	—	[25]
		TPAOH、乙醇	50	370.7	0.63	—	—	[36]
微波合成法	TS-1	TPAOH	70~230	423	0.21	长而直的孔道、较强的疏水性	吸附分离	[42]
		TPAOH	71	329	0.23	适当的酸性	环氧化	[40]
	ZSM-5	TPAOH	70~90	451	0.37	—	—	[45]

合成方法	MFI型分子筛	模板剂	Si/Al或Si/Ti	比表面积 /m²·g^-1	总孔容 /cm³·g^-1	特征与优势	应用	参考文献
水热合成法
模板法	ZSM-5	TPAOH	70	315	0.47	中空、介孔结构	催化裂解	[30]
		TPAOH	63	313	0.28	介孔结构	异构化	[59]
		TPAOH	83	398.8	—	链长适当	CO₂加氢制芳烃	[58]
助剂辅助法	ZSM-5	TPAOH、PDDA	90	470	0.27	介孔结构	甲醇制烯烃	[22]
		TPAOH、PDDA	50	538.7	0.77	介孔结构	催化裂解	[23]
		TPAOH、蔗糖	136	397	0.36	介孔结构	甲基化	[24]
		TPAOH、SA	16~64	410	0.25	—	—	[25]
		TPAOH、乙醇	50	370.7	0.63	—	—	[36]
微波合成法	TS-1	TPAOH	70~230	423	0.21	长而直的孔道、较强的疏水性	吸附分离	[42]
		TPAOH	71	329	0.23	适当的酸性	环氧化	[40]
	ZSM-5	TPAOH	70~90	451	0.37	—	—	[45]

[1]	胡婷霞, 赵立欣, 姚宗路, 霍丽丽, 贾吉秀, 谢腾. 双金属催化剂在生物质焦油催化蒸汽重整领域的研究进展[J]. 化工进展, 2024, 43(8): 4354-4365.
[2]	吴泽亮, 管琦卉, 陈世霞, 王珺. 炔烃选择性加氢制烯烃反应的研究进展[J]. 化工进展, 2024, 43(8): 4366-4381.
[3]	刘文津, 张玉明, 李家州, 张炜, 陈哲文. 典型石油热加工技术发展现状及展望[J]. 化工进展, 2024, 43(7): 3534-3550.
[4]	张子杭, 王树荣. 生物质热解转化与产物低碳利用研究进展[J]. 化工进展, 2024, 43(7): 3692-3708.
[5]	龚德成, 沈倩, 朱贤青, 黄云, 夏奡, 张敬苗, 朱恂, 廖强. 微藻超临界水气化制取富氢合成气的研究进展[J]. 化工进展, 2024, 43(7): 3709-3728.
[6]	郭鹏, 李红伟, 李贵贤, 季东, 王东亮, 赵新红. 直接甲醇燃料电池阳极催化剂的失活机制及应对策略[J]. 化工进展, 2024, 43(7): 3812-3823.
[7]	王颖杰, 祝新利. 溶胶-凝胶法制备高分散Ni-Cu/SiO₂ 促进间甲酚直接脱氧制甲苯[J]. 化工进展, 2024, 43(7): 3824-3833.
[8]	王丽娜, 武金升. 共价有机框架材料的合成与应用研究进展[J]. 化工进展, 2024, 43(7): 3834-3856.
[9]	罗丛佳, 豆义波, 卫敏. 水滑石光催化剂结构调控用于二氧化碳还原的研究进展[J]. 化工进展, 2024, 43(7): 3891-3909.
[10]	龚勇, 潘忠文, 谢纯, 崔瑾, 王鲜. 碳酸钠催化制备纳米碳纤维[J]. 化工进展, 2024, 43(7): 3980-3986.
[11]	张世蕊, 范朕连, 宋慧平, 张丽娜, 高宏宇, 程淑艳, 程芳琴. 粉煤灰负载光催化材料的研究进展[J]. 化工进展, 2024, 43(7): 4043-4058.
[12]	何弈雪, 秦先超, 马伟芳. 过硫酸盐高级氧化原位修复地下水中卤代烃污染研究进展[J]. 化工进展, 2024, 43(7): 4072-4088.
[13]	杨昕, 钟承韡, 杨志山, 朱韦韦, 王文浩, 余江. 人工仿真菱铁矿及其衍生材料催化修复PAHs污染土壤[J]. 化工进展, 2024, 43(7): 4118-4127.
[14]	蓝瑞嵩, 刘丽华, 张倩, 陈博彦, 洪俊明. 硫掺杂石墨烯作为MFC阴极性能和生物毒性检测[J]. 化工进展, 2024, 43(6): 3430-3439.
[15]	朱连燕, 周幸福. 锰掺杂DSA电极及其对印染废水处理的过程优化[J]. 化工进展, 2024, 43(6): 3459-3467.