化工进展 ›› 2023, Vol. 42 ›› Issue (10): 5373-5380.DOI: 10.16085/j.issn.1000-6613.2022-2084

• 材料科学与技术 • 上一篇    下一篇

环糊精原位改性MoS2管式陶瓷复合膜的制备及性能

王妍1(), 秦振平1, 刘越2, 张文海1(), 郭红霞2()   

  1. 1.北京工业大学环境与生命学部,北京 100124
    2.北京工业大学材料与制造学部,北京 100124
  • 收稿日期:2022-11-08 修回日期:2022-12-11 出版日期:2023-10-15 发布日期:2023-11-11
  • 通讯作者: 张文海,郭红霞
  • 作者简介:王妍(1998—),女,硕士研究生,研究方向为膜分离科学与技术。E-mail:wyan@emails.bjut.edu.cn
  • 基金资助:
    国家自然科学基金面上项目(21878003);北京工业大学国际合作种子基金(22178007)

Preparation and properties of β-cyclodextrin in-situ modified MoS2 tubular ceramic composite membrane

WANG Yan1(), QIN Zhenping1, LIU Yue2, ZHANG Wenhai1(), GUO Hongxia2()   

  1. 1.Faculty of Environmental and Life, Beijing University of Technology, Beijing 10024, China
    2.Faculty of Material and Manufacturing, Beijing University of Technology, Beijing 10024, China
  • Received:2022-11-08 Revised:2022-12-11 Online:2023-10-15 Published:2023-11-11
  • Contact: ZHANG Wenhai, GUO Hongxia

摘要:

在氧化铝陶瓷管基体上原位水热法制备二硫化钼(MoS2)陶瓷膜的过程中,将β-环糊精(β-CD)作为添加剂加入前体溶液,得到环糊精改性的MoS2/β-CD管式陶瓷复合纳滤膜。采用扫描电子显微镜、X射线衍射仪、X射线光电子能谱、水接触角和zeta电位等研究了膜的表面形貌、结构、化学组成、亲水性以及荷电性。探究了不同β-CD添加量对复合膜纳滤性能的影响,考察了膜的抗压性和长期运行稳定性。结果表明,β-CD固有的空腔结构提供了更多的水分子传输通道,提高了MoS2/β-CD陶瓷复合膜的渗透性能。当添加质量分数为2.4%的β-CD时,制备的陶瓷复合纳滤膜水通量最高为325L/(m2·h·MPa),对伊文思蓝(EB)的截留率达98.6%;对铬黑T(EBT)、二甲酚橙(XO)染料的截留率均在90%以上;且该陶瓷复合纳滤膜在0.2~0.8MPa的压力下运行,显示优异的抗压性,在错流纳滤操作体系中连续运行7天,表现出良好的长期运行稳定性。

关键词: MoS2陶瓷复合膜, β-环糊精, 原位水热法, 纳滤, 染料分离

Abstract:

The β‍-cyclodextrin modified MoS2 tubular ceramic composite membrane was prepared by in-situ hydrothermal method on the surface of alumina ceramic substrate with β‍-cyclodextrin (β‍-CD) as an additive into precursor solution. The surface morphology, structure, chemical composition, hydrophilicity and charge of the membrane were well investigated by search engine marketing, X-raydiffraction, X-ray photoelectron spectroscopy, water contact angle and zeta potential techniques. The effect of different β-CD amount on the membrane nanofiltration performance as well as the pressure resistance and long-term stability of the membranes were studied. The results indicated that the permeability of the membrane was greatly increased due to that the cavity-related structure of β‍-CD provided additional fast transport channels for water molecules. When the amount of β‍-CD was 2.4%, the water permeability of the membrane was highest as 325L/(m2·h·MPa) along with 98.6% rejection of Evans blue (EB), and more than 90% rejection for chrome Black T (EBT) and Xylenol orange (XO). The prepared membrane showed an excellent pressure resistance at 0.2—0.8MPa pressure and displayed a great long-term stability.

Key words: MoS2 ceramic composite membrane, β?-cyclodextrin, in-situ hydrothermal method, nanofiltration, dye separation

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