二硫化钼纳米片基水处理纳滤/反渗透膜研究进展

doi:10.16085/j.issn.1000-6613.2020-2143

摘要/Abstract

摘要：

二硫化钼（MoS₂）纳米片的层内固有缺陷以及层间纳米限域通道的存在，有利于提高水处理纳滤/反渗透（NF/RO）膜的渗透选择性。本文首先介绍了MoS₂纳米片的“三明治”结构，其具有易功能化、高吸附容量和氧化还原去除能力、层间纳米限域通道的光滑性和稳定性及抗污染等特性；然后重点综述了MoS₂基纳米孔膜、层叠膜和混合基质膜的制备方法及膜性能的影响因素；最后总结了MoS₂纳米片基水处理NF/RO膜未来发展亟待解决的关键问题，主要包括研究大尺寸纳米片和均匀亚纳米孔的可控制备方法，开发超薄、高度有序的MoS₂分离层构建方法，探索层间纳米限域通道内分子和离子的传输行为和潜在的分离机理，开发增强与聚合物基质界面相容性的改性策略，对下一代高性能水处理NF/RO膜的研发具有启发意义。

关键词: 膜, 纳滤, 反渗透, 二硫化钼

Abstract:

The inherent defects in the molybdenum disulfide (MoS₂) nanosheets and the nano-confined channels between the nanosheets are beneficial to enhance the perm-selectivity of nanofiltration/reverse osmosis (NF/RO) membranes. In this paper, the sandwich structure of the MoS₂ nanosheets, and their merits of easy functionalization, high adsorption capacity and redox removal ability, good smoothness and stability of interlayer nano-confined channels, and nice antifouling properties are introduced firstly. After that, the latest research progress of MoS₂ nanosheets in nanoporous membranes, laminated membranes and mixed matrix membranes are reviewed. Finally, the critical issues in the future development of the MoS₂ nanosheets based NF/RO membranes are summarized, mainly including the preparation of large-scale nanosheets and uniform sub-nanopores, the construction of ultra-thin and perfect MoS₂ separation layer, the exploration of molecular and ion transport behaviors and potential separation mechanisms in the nano-confined channels, and the modification strategies to enhance their interfacial compatibility in polymer matrix, which are of great significance for the development of the next-generation high-performance NF/RO membranes.

Key words: membranes, nanofiltration, reverse osmosis, molybdenum disulfide

中图分类号:

TQ028

赵东升. 二硫化钼纳米片基水处理纳滤/反渗透膜研究进展[J]. 化工进展, 2021, 40(10): 5590-5599.

ZHAO Dongsheng. Research progress in molybdenum disulfide nanosheet-based NF/RO membranes for water treatment[J]. Chemical Industry and Engineering Progress, 2021, 40(10): 5590-5599.

图/表 3

参考文献 65

1	WERBER J R, OSUJI C O, ELIMELECH M. Materials for next-generation desalination and water purification membranes[J]. Nature Reviews Materials, 2016, 1(5): 16018.
2	SHANNON M A, BOHN P W, ELIMELECH M, et al. Science and technology for water purification in the coming decades[J]. Nature, 2008, 452(7185): 301-310.
3	PENDERGAST M M, HOEK E M V. A review of water treatment membrane nanotechnologies[J]. Energy & Environmental Science, 2011, 4(6): 1946-1971.
4	NAIR R R, WU H A, JAYARAM P N, et al. Unimpeded permeation of water through helium-leak-tight graphene-based membranes[J]. Science, 2012, 335(6067): 442-444.
5	HAN Y, XU Z, GAO C. Ultrathin graphene nanofiltration membrane for water purification[J]. Advanced Functional Materials, 2013, 23(29): 3693-3700.
6	ANAND A, UNNIKRISHNAN B, MAO J Y, et al. Graphene-based nanofiltration membranes for improving salt rejection, water flux and antifouling—A review[J]. Desalination, 2018, 429: 119-133.
7	YUAN Y, GAO X, WEI Y, et al. Enhanced desalination performance of carboxyl functionalized graphene oxide nanofiltration membranes[J]. Desalination, 2017, 405: 29-39.
8	ZHENG S, TU Q, URBAN J J, et al. Swelling of graphene oxide membranes in aqueous solution: characterization of interlayer spacing and insight into water transport mechanisms[J]. ACS Nano, 2017, 11(6): 6440-6450.
9	ZHANG C J, PINILLA S, MCEVOY N, et al. Oxidation stability of colloidal two-dimensional titanium carbides (MXenes)[J]. Chemistry of Materials, 2017, 29(11): 4848-4856.
10	MALESKI K, MOCHALIN V N, GOGOTSI Y. Dispersions of two-dimensional titanium carbide MXene in organic solvents[J]. Chemistry of Materials, 2017, 29(4): 1632-1640.
11	WANG Y, LI L, WEI Y, et al. Water transport with ultralow friction through partially exfoliated g-C₃N₄ nanosheet membranes with self-supporting spacers[J]. Angewandte Chemie International Edition, 2017, 56(31): 8974-8980.
12	ZHOU J, QIN Z, LU Y, et al. MoS₂/polyelectrolytes hybrid nanofiltration (NF) membranes with enhanced permselectivity[J]. Journal of the Taiwan Institute of Chemical Engineers, 2018, 84: 196-202.
13	LI W, YANG Y, WEBER J K, et al. Tunable, strain-controlled nanoporous MoS₂ filter for water desalination[J]. ACS Nano, 2016, 10(2): 1829-1835.
14	WANG Z, MI B. Environmental applications of 2D molybdenum disulfide (MoS₂) nanosheets[J]. Environmental Science & Technology, 2017, 51(15): 8229-8244.
15	SUN L, HUANG H, PENG X. Laminar MoS₂ membranes for molecule separation[J]. Chemical Communications, 2013, 49(91): 10718-10720.
16	WANG Z, TU Q, ZHENG S, et al. Understanding the aqueous stability and filtration capability of MoS₂ membranes[J]. Nano Letters, 2017, 17(12): 7289-7298.
17	DENG M, KWAC K, LI M, et al. Stability, molecular sieving, and ion diffusion selectivity of a lamellar membrane from two-dimensional molybdenum disulfide[J]. Nano Letters, 2017, 17(4): 2342-2348.
18	AI K, RUAN C, SHEN M, et al. MoS₂ nanosheets with widened interlayer spacing for high-efficiency removal of mercury in aquatic systems[J]. Advanced Functional Materials, 2016, 26(30): 5542-5549.
19	RADISAVLJEVIC B, RADENOVIC A, BRIVIO J, et al. Single-layer MoS₂ transistors[J]. Nature Nanotechnology, 2011, 6(3): 147-150.
20	COLEMAN J N, LOTYA M, O'NEILL A, et al. Two-dimensional nanosheets produced by liquid exfoliation of layered materials[J]. Science, 2011, 331(6017): 568-571.
21	EDA G, YAMAGUCHI H, VOIRY D, et al. Photoluminescence from chemically exfoliated MoS₂[J]. Nano Letters, 2011, 11(12): 5111-5116.
22	FAN X, XU P, ZHOU D, et al. Fast and efficient preparation of exfoliated 2H MoS₂ nanosheets by sonication-assisted lithium intercalation and infrared laser-induced 1T to 2H phase reversion[J]. Nano Letters, 2015, 15(9): 5956-5960.
23	TAN C, LUO Z, CHATURVEDI A, et al. Preparation of high-percentage 1T-phase transition metal dichalcogenide nanodots for electrochemical hydrogen evolution[J]. Advanced Materials, 2018, 30(9): 1705509.
24	CHHOWALLA M, SHIN H S, EDA G, et al. The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets[J]. Nature Chemistry, 2013, 5(4): 263-275.
25	CHOU S S, DE M, KIM J, et al. Ligand conjugation of chemically exfoliated MoS₂[J]. Journal of the American Chemical Society, 2013, 135(12): 4584-4587.
26	VOIRY D, GOSWAMI A, KAPPERA R, et al. Covalent functionalization of monolayered transition metal dichalcogenides by phase engineering[J]. Nature Chemistry, 2015, 7(1): 45-49.
27	HIRUNPINYOPAS W, PRESTAT E, WORRALL S D, et al. Desalination and nanofiltration through functionalized laminar MoS₂ membranes[J]. ACS Nano, 2017, 11(11): 11082-11090.
28	RIES L, PETIT E, MICHEL T, et al. Enhanced sieving from exfoliated MoS₂ membranes via covalent functionalization[J]. Nature Materials, 2019, 18(10): 1112-1117.
29	HU W, CUI X, XIANG L, et al. Tannic acid modified MoS₂ nanosheet membranes with superior water flux and ion/dye rejection[J]. Journal of Colloid and Interface Science, 2020, 560: 177-185.
30	MA M Q, ZHANG C, ZHU C Y, et al. Nanocomposite membranes embedded with functionalized MoS₂ nanosheets for enhanced interfacial compatibility and nanofiltration performance[J]. Journal of Membrane Science, 2019, 591: 117316.
31	ZHANG H, GONG X Y, LI W X, et al. Thin-film nanocomposite membranes containing tannic acid-Fe³⁺ modified MoS₂ nanosheets with enhanced nanofiltration performance[J]. Journal of Membrane Science, 2020, 616: 118605.
32	LIANG X, WANG P, WANG J, et al. Zwitterionic functionalized MoS₂ nanosheets for a novel composite membrane with effective salt/dye separation performance[J]. Journal of Membrane Science, 2019, 573: 270-279.
33	SMITH R J, KING P J, LOTYA M, et al. Large-scale exfoliation of inorganic layered compounds in aqueous surfactant solutions[J]. Advanced Materials, 2011, 23(34): 3944-3948.
34	LIU Q, LI X, HE Q, et al. Gram-scale aqueous synthesis of stable few-layered 1T-MoS₂: applications for visible-light-driven photocatalytic hydrogen evolution[J]. Small, 2015, 11(41): 5556-5564.
35	JIA F, ZHANG X, SONG S. AFM study on the adsorption of Hg²⁺ on natural molybdenum disulfide in aqueous solutions[J]. Physical Chemistry Chemical Physics, 2017, 19(5): 3837-3844.
36	WANG Z, SIM A, URBAN J J, et al. Removal and recovery of heavy metal ions by two-dimensional MoS₂ nanosheets: performance and mechanisms[J]. Environmental Science & Technology, 2018, 52(17): 9741-9748.
37	WANG J, ZHANG W, YUE X, et al. One-pot synthesis of multifunctional magnetic ferrite-MoS₂-carbon dot nanohybrid adsorbent for efficient Pb(Ⅱ) removal[J]. Journal of Materials Chemistry A, 2016, 4(10): 3893-3900.
38	WANG J, WANG P, WANG H, et al. Preparation of molybdenum disulfide coated Mg/Al layered double hydroxide composites for efficient removal of chromium(Ⅵ)[J]. ACS Sustainable Chemistry & Engineering, 2017, 5(8): 7165-7174.
39	AGHAGOLI M J, SHEMIRANI F. Hybrid nanosheets composed of molybdenum disulfide and reduced graphene oxide for enhanced solid phase extraction of Pb(Ⅱ) and Ni(Ⅱ)[J]. Microchimica Acta, 2017, 184(1): 237-244.
40	AGHAGOLI M J, HOSSEIN BEYKI M, SHEMIRANI F. Application of dahlia-like molybdenum disulfide nanosheets for solid phase extraction of Co(Ⅱ) in vegetable and water samples[J]. Food Chemistry, 2017, 223: 8-15.
41	HEISING J, KANATZIDIS M G. Exfoliated and restacked MoS₂ and WS₂: ionic or neutral species? Encapsulation and ordering of hard electropositive cations[J]. Journal of the American Chemical Society, 1999, 121(50): 11720-11732.
42	ALAM I, GUINEY L M, HERSAM M C, et al. Pressure-driven water transport behavior and antifouling performance of two-dimensional nanomaterial laminated membranes[J]. Journal of Membrane Science, 2020, 599: 117812.
43	RAN J, ZHANG P, CHU C, et al. Ultrathin lamellar MoS₂ membranes for organic solvent nanofiltration[J]. Journal of Membrane Science, 2020, 602: 117963.
44	JIANG J W, QI Z N, PARK H S, et al. Elastic bending modulus of single-layer molybdenum disulfide (MoS₂): finite thickness effect[J]. Nanotechnology, 2013, 24(43): 435705.
45	LU Q, ARROYO M, HUANG R. Elastic bending modulus of monolayer graphene[J]. Journal of Physics D: Applied Physics, 2009, 42(10): 102002.
46	ALAM I, GUINEY L M, HERSAM M C, et al. Antifouling properties of two-dimensional molybdenum disulfide and graphene oxide[J]. Environmental Science: Nano, 2018, 5(7): 1628-1639.
47	FENG J, GRAF M, LIU K, et al. Single-layer MoS₂ nanopores as nanopower generators[J]. Nature, 2016, 536(7615): 197-200.
48	INOUE A, KOMORI T, SHUDO K I. Atomic-scale structures and electronic states of defects on Ar⁺-ion irradiated MoS₂[J]. Journal of Electron Spectroscopy and Related Phenomena, 2013, 189: 11-18.
49	FENG J, LIU K, GRAF M, et al. Electrochemical reaction in single layer MoS₂: nanopores opened atom by atom[J]. Nano Letters, 2015, 15(5): 3431-3438.
50	ZHOU W, ZOU X, NAJMAEI S, et al. Intrinsic structural defects in monolayer molybdenum disulfide[J]. Nano Letters, 2013, 13(6): 2615-2622.
51	SAPKOTA B, LIANG W, VAHIDMOHAMMADI A, et al. High permeability sub-nanometre sieve composite MoS₂ membranes[J]. Nature Communications, 2020, 11(1): 2747.
52	LI H, KO T J, LEE M, et al. Experimental realization of few layer two-dimensional MoS₂ membranes of near atomic thickness for high efficiency water desalination[J]. Nano Letters, 2019, 19(8): 5194-5204.
53	KOU J, YAO J, WU L, et al. Nanoporous two-dimensional MoS₂ membranes for fast saline solution purification[J]. Physical Chemistry Chemical Physics, 2016, 18(32): 22210-22216.
54	HEIRANIAN M, FARIMANI A B, ALURU N R. Water desalination with a single-layer MoS₂ nanopore[J]. Nature Communications, 2015, 6: 8616.
55	ANG E Y M, NG T Y, YEO J, et al. Investigations on different two-dimensional materials as slit membranes for enhanced desalination[J]. Journal of Membrane Science, 2020, 598: 117653.
56	MAO S, WANG W, JIA F, et al. Laminar MoS₂ membrane for high-efficient rejection of methyl orange from aqueous solution[J]. Chemical Physics, 2020, 530: 110609.
57	LI Z K, WEI Y, GAO X, et al. Antibiotics separation with MXene membranes based on regularly stacked high-aspect-ratio nanosheets[J]. Angewandte Chemie International Edition, 2020, 59(24): 9751-9756.
58	GAO J, ZHANG M, WANG J, et al. Bioinspired modification of layer-stacked molybdenum disulfide (MoS₂) membranes for enhanced nanofiltration performance[J]. ACS Omega, 2019, 4(2): 4012-4022.
59	SUN L, YING Y, HUANG H, et al. Ultrafast molecule separation through layered WS₂ nanosheet membranes[J]. ACS Nano, 2014, 8(6): 6304-6311.
60	SU Y, LIU D, YANG G, et al. Transition metal dichalcogenide (TMD) membranes with ultrasmall nanosheets for ultrafast molecule separation[J]. ACS Applied Materials & Interfaces, 2020, 12(40): 45453-45459.
61	LU X, GABINET U R, RITT C L, et al. Relating selectivity and separation performance of lamellar two-dimensional molybdenum disulfide (MoS₂) membranes to nanosheet stacking behavior[J]. Environmental Science & Technology, 2020, 54(15): 9640-9651.
62	YANG S, ZHANG K. Few-layers MoS₂ nanosheets modified thin film composite nanofiltration membranes with improved separation performance[J]. Journal of Membrane Science, 2020, 595: 117526.
63	LI Y, YANG S, ZHANG K, et al. Thin film nanocomposite reverse osmosis membrane modified by two dimensional laminar MoS₂ with improved desalination performance and fouling-resistant characteristics[J]. Desalination, 2019, 454: 48-58.
64	ZHANG H, TAYMAZOV D, LI M P, et al. Construction of MoS₂ composite membranes on ceramic hollow fibers for efficient water desalination[J]. Journal of Membrane Science, 2019, 592: 117369.
65	YANG S, JIANG Q, ZHANG K. Few-layers 2D O–MoS₂ TFN nanofiltration membranes for future desalination[J]. Journal of Membrane Science, 2020, 604: 118052.

[1]	张祚群, 高扬, 白超杰, 薛立新. 二次界面聚合同步反扩散原位生长ZIF-8纳米粒子制备聚酰胺混合基质反渗透（RO）膜[J]. 化工进展, 2023, 42(S1): 364-373.
[2]	潘宜昌, 周荣飞, 邢卫红. 高效分离同碳数烃的先进微孔膜：现状与挑战[J]. 化工进展, 2023, 42(8): 3926-3942.
[3]	王报英, 王皝莹, 闫军营, 汪耀明, 徐铜文. 聚合物包覆膜在金属分离回收中的研究进展[J]. 化工进展, 2023, 42(8): 3990-4004.
[4]	李雪佳, 李鹏, 李志霞, 晋墩尚, 郭强, 宋旭锋, 宋芃, 彭跃莲. 亲水和疏水改性膜的抗结垢和润湿能力的对比[J]. 化工进展, 2023, 42(8): 4458-4464.
[5]	徐杰, 夏隆博, 罗平, 邹栋, 仲兆祥. 面向膜蒸馏过程的全疏膜制备及其应用进展[J]. 化工进展, 2023, 42(8): 3943-3955.
[6]	陆诗建, 刘苗苗, 杨菲, 张俊杰, 陈思铭, 刘玲, 康国俊, 李清方. 改良型CO₂湿壁塔内气液两相流动规律及传质特性[J]. 化工进展, 2023, 42(7): 3457-3467.
[7]	冯江涵, 宋钫. 阴离子交换膜电解池的研究进展[J]. 化工进展, 2023, 42(7): 3501-3509.
[8]	陈香李, 李倩倩, 张甜, 李彪, 李康康. 自愈合油水分离膜的研究进展[J]. 化工进展, 2023, 42(7): 3600-3610.
[9]	任重远, 何金龙, 袁清. 分子筛膜晶间缺陷控制与修复技术研究进展[J]. 化工进展, 2023, 42(5): 2454-2463.
[10]	王林, 辛梅华, 李明春, 陈琦, 毛扬帆. 季铵化/磺化壳聚糖的制备及其抗生物被膜活性[J]. 化工进展, 2023, 42(5): 2577-2585.
[11]	于捷, 张文龙. 锂离子电池隔膜的发展现状与进展[J]. 化工进展, 2023, 42(4): 1760-1768.
[12]	赵珍珍, 郑喜, 王雪琪, 王涛, 冯英楠, 任永胜, 赵之平. 聚酰胺复合膜微孔支撑基底的研究进展[J]. 化工进展, 2023, 42(4): 1917-1933.
[13]	叶海星, 陈宇昊, 陈仪, 孙海翔, 牛青山. 镁锂分离复合纳滤膜研究进展[J]. 化工进展, 2023, 42(4): 1934-1943.
[14]	常晓青, 彭东来, 李东洋, 张延武, 王景, 张亚涛. MOFs基丙烯/丙烷高效分离混合基质膜研究进展[J]. 化工进展, 2023, 42(4): 1961-1973.
[15]	王林, 辛梅华, 李明春, 张涛, 毛扬帆. 烷基季铵化壳聚糖的制备及其抗生物被膜的活性[J]. 化工进展, 2023, 42(4): 1995-2002.