化工进展 ›› 2023, Vol. 42 ›› Issue (10): 5363-5372.DOI: 10.16085/j.issn.1000-6613.2022-2124

• 材料科学与技术 • 上一篇    下一篇

响应面优化温敏水凝胶汲取剂的制备及性能

仉洁1,2,3(), 王旭东1,2,3(), 杨逸飞1,2,3, 任玥1,2,3, 陈立成1,2,3   

  1. 1.西安建筑科技大学环境与市政工程学院,陕西 西安 710055
    2.陕西省膜分离重点实验室,陕西 西安 710055
    3.陕西省膜分离技术研究院,陕西 西安 710055
  • 收稿日期:2022-11-16 修回日期:2023-02-08 出版日期:2023-10-15 发布日期:2023-11-11
  • 通讯作者: 王旭东
  • 作者简介:仉洁(1998-),女,硕士研究生,研究方向为膜分离理论与技术。E-mail:zhangjieya@xauat.edu.cn
  • 基金资助:
    国家重点研发计划(2022YFC2904303);陕西省教育厅科研计划(22JC041)

Response surface optimization of preparation and performance of thermo-responsive hydrogels as draw agent

ZHANG Jie1,2,3(), WANG Xudong1,2,3(), YANG Yifei1,2,3, REN Yue1,2,3, CHEN Licheng1,2,3   

  1. 1.School of Environmental and Municipal Engineering, Xi’an University of Architecture and Technology, Xi’an 710055, Shaanxi, China
    2.Shaanxi Key Laboratory of Membrane Separation Technology, Xi’an 710055, Shaanxi, China
    3.Research Institute of Membrane Separation Technology of Shaanxi Province, Xi’an 710055, Shaanxi, China
  • Received:2022-11-16 Revised:2023-02-08 Online:2023-10-15 Published:2023-11-11
  • Contact: WANG Xudong

摘要:

随温度变化可逆吸水脱水的热响应水凝胶作为正渗透(FO)汲取剂,在降低回收能耗、减少泄漏方面有巨大的潜力,然而较低的溶胀速率限制了其在FO工艺中的发展,而加入亲水性离子基团可提高水凝胶的吸水膨胀压力,从而产生更高的水通量。通过自由基聚合法制备了简易回收且无反向溶质扩散的聚(N-异丙基丙烯酰胺/丙烯酸钠-蒙脱土)[P(NIPAM/SA-MMT)]水凝胶,采用傅里叶变换红外光谱(FTIR)、X射线衍射仪(XRD)、扫描电子显微镜(SEM)表征水凝胶的化学结构和内部形貌,使用响应面法优化3个因素(交联剂、丙烯酸钠、蒙脱土)的添加量。由于亲水性羧酸根和羟基含量的增加,P(NIPAM/SA-MMT)水凝胶的平衡溶胀率及热刺激下的脱水量相较于聚N-异丙基丙烯酰胺(PNIPAM)水凝胶大幅提高;以去离子水为原料液,0.5h内的初始水通量达0.87L/(m2·h),且随着原料液浓度的升高,水通量逐渐降低;过水12h后,将其置于60℃温度刺激下脱水60min,水回收率达98.1%。结果表明,制备的水凝胶表现出良好的水通量及水回收性能。

关键词: 温敏水凝胶, 聚合, 优化, 汲取剂, 再生

Abstract:

Thermal-responsive hydrogel can absorb water and dehydrate reversibly with temperature change. As a draw agent in forward osmosis (FO), it has great potential in reducing recovery energy consumption and leakage. However, the low swelling rate limits its development in the FO process. The addition of hydrophilic ionic groups can increase the swelling pressure of hydrogels, resulting in higher water flux. Poly(N-isopropylacrylamide/sodium acrylate-montmorillonite) [P(NIPAM/SA-MMT)] hydrogel with simple recovery and no reverse solute diffusion was fabricated by free-radical polymerization. The chemical structure and internal morphology of hydrogels were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). Response surface methodology was used to optimize the addition of cross-linker, sodium acrylate and montmorillonite. Due to the increase of hydrophilic carboxylate and hydroxyl groups, the equilibrium swelling ratio and dehydration under thermal stimulation of P(NIPAM/SA-MMT) hydrogels were significantly higher than those of poly(N-isopropylacrylamide) (PNIPAM) hydrogels. With P(NIPAM/SA-MMT) hydrogel as draw agent and deionized water as the feed solution, the initial water flux in 0.5h was 0.87L/(m2·h) and the water flux decreased gradually with increasing feed solution concentration. After soaking in deionized water for 12h, the hydrogel was dehydrated at 60℃ for 60 minutes, and the water recovery rate reached 98.1%. The results showed that the prepared hydrogels had good water flux and water recovery performance.

Key words: thermo-responsive hydrogel, polymerization, optimization, draw agent, regeneration

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