化工进展 ›› 2019, Vol. 38 ›› Issue (01): 394-403.DOI: 10.16085/j.issn.1000-6613.2018-1250
收稿日期:
2018-06-16
修回日期:
2018-07-02
出版日期:
2019-01-05
发布日期:
2019-01-05
通讯作者:
范益群
作者简介:
陈献富(1989—),男,博士,讲师,研究方向为膜分离。E-mail:<email>chenxianfu@njtech.edu.cn</email>。|范益群,教授,博士生导师,研究方向为膜分离。E-mail:<email>yiqunfan@njtech.edu.cn</email>。
基金资助:
Xianfu CHEN(),Hua JI,Yiqun FAN()
Received:
2018-06-16
Revised:
2018-07-02
Online:
2019-01-05
Published:
2019-01-05
Contact:
Yiqun FAN
摘要:
功能性低聚糖具有抗肿瘤、抗放射、抗凝血、消炎和调节免疫力等医疗保健作用,广泛应用于食品科学和生物医药等领域。纳滤作为一种高效的膜分离技术,在功能性低聚糖的分离与纯化中的应用得到越来越多的关注。本文分析了纳滤膜对功能性低聚糖的分离机理,综述了纳滤膜在功能性多糖分离纯化中的应用进展,讨论了纳滤分离过程的影响因素,主要包括功能性多糖料液的性质、膜过程的操作参数以及膜材料本身的性质等。其中,料液的性质主要体现在组成、浓度、黏度等方面;操作参数主要体现在压力、温度、膜面流速和pH等方面;而膜材料的性质主要体现在微结构和表面性质两个方面。最后,进一步指出纳滤膜技术用于功能性多糖分离纯化时在设备成本、膜材料及膜污染等方面存在的问题,并对未来纳滤膜技术在低成本专用膜材料及系统开发和膜污染控制方面的研究进行了展望。
中图分类号:
陈献富, 季华, 范益群. 纳滤膜在功能性低聚糖分离纯化中的应用研究进展[J]. 化工进展, 2019, 38(01): 394-403.
Xianfu CHEN, Hua JI, Yiqun FAN. Application of nano-filtration membranes in the separation and purification of functional oligosaccharides[J]. Chemical Industry and Engineering Progress, 2019, 38(01): 394-403.
1 | 王成福 . 现代膜分离技术及其在功能糖生产中的应用[J]. 中国食品添加剂, 2013(s1): 117-122. |
WANG Chengfu . Membrane separation technology and its application in the production of functional sugar[J]. China Food Additives, 2013(s1): 117-122. | |
2 | 程安玮, 金征宇, 王家启 . 功能性多糖免疫调节机理的研究进展[J]. 食品科技, 2006(12): 4-8. |
CHENG Anwei , JIN Zhengyu , WANG Jiaqi . Research development on the immumodulatory mechanism of polysaccharides[J]. Food Science and Technology, 2006(12): 4-8. | |
3 | TANG Y J , ZHONG J J . Fed-batch fermentation of Ganoderma lucidum for hyperproduction of polysaccharide and ganoderic acid[J]. Enzyme and Microbial Technology, 2002, 31(1/2): 20-28. |
4 | Iris FORNEFETT , Christoph BUTTERSACK . Exo-enzyme like degradation of a polysaccharide by an inorganic solid acid catalyst[J]. Carbohydrate Polymers, 2018, 187: 126-132. |
5 | ZOROV I N , SINITSYN A P , KONDRAT'EVA E G . Effectiveness of enzyme preparations of fodder in the degradation of nonstarch polysaccharides from grain substrates[J]. Applied Biochemistry and Microbiology, 2006, 42(6): 620-624. |
6 | 米运宏, 邓梁华, 黄扩宇 . 高纯度低聚果糖制备研究进展[J]. 广西轻工业, 2007, 99(2): 25-26. |
MI Yunhong , DENG Lianghua , HUANG Kuoyu . Research progress on the preparation of high-purity fructooligosaccharides[J]. Guangxi Journal of Light Industry, 2007, 99(2): 25-26. | |
7 | 马镝, 吴元华, 赵秀香 . 壳寡糖的制备、分离分析方法及在农业上的应用[J]. 现代农药, 2007, 6(2): 1-5. |
Di MA , WU Yuanhua , ZHAO Xiuxiang . Preparation and purification and analysis of chito-oligosaccharide and its application in agriculture[J]. Modern Agrochemicals, 2007, 6(2): 1-5. | |
8 | LI Jing , CHASE H A . Applications of membrane techniques for purification of natural products[J]. Biotechnol Lett., 2010, 32: 601-608. |
9 | Oguz AKIN , Feral TEMELLI , Sefa KOESEOGLU . Membrane applications in functional foods and nutraceuticals[J]. Critical Reviews in Food Science and Nutrition, 2012, 52(4): 347-371. |
10 | 王晓琳 . 纳滤膜分离机理及其应用研究进展[J]. 化学通报, 2001(2): 86-90. |
WANG Xiaolin . Progress in the separation mechanism and applications of nanofiltration membranes[J]. Chemistry, 2001(2): 86-90. | |
11 | 王晓琳, 涂丛慧, 方彦彦, 等 . 纳滤膜孔结构、荷电性质、分离机理及动电性质研究进展[J]. 膜科学与技术, 2011, 31(3): 127-134. |
WANG Xiaolin , TU Conghui , FANG Yanyan , et al . The researches on the pore structure, charge property, seperation mechanism and electrokinetic phenomena of nanofiltration membranes[J]. Membrane Science and Technology, 2011, 31(3): 127-134. | |
12 | 王晓琳, 张澄洪, 赵杰 . 纳滤膜的分离机理及其在食品和医药行业中的应用[J]. 膜科学与技术, 2000, 20(1): 29-36. |
WANG Xiaolin , ZHANG Chenghong , ZHAO Jie . Separation mechanism of nanofiltration membranes and its applications in food and pharmaceutical industries[J]. Membrane Science and Technology, 2000, 20(1): 29-36. | |
13 | WANG X L , TSURU T , NAKAO S , et al . The electrostatic and steric-hindrance model for the transport of charged solutes through nanofiltration membranes[J]. Journal of Membrane Science, 1997, 135(1): 19-32. |
14 | WANG X L , TSURU T , TOGOH M , et al . Evaluation of pore structure and electrical properties of nanofiltration membranes[J]. Journal of Chemical Engineering of Japan, 1995, 28(2): 186-192. |
15 | 方彦彦, 涂丛慧, 王晓琳 . 静电位阻模型在纳滤膜跨膜电位解析中的应用[J]. 高等学校化学学报, 2010, 31(4): 782-789. |
FANG Yanyan , TU Conghui , WANG Xiaolin . Application of the electrostatic and steric-hindrance model to analysis of transmembrane potential across nanofiltration membranes[J]. Chemical Journal of Chinese Universities, 2010, 31(4): 782-789. | |
16 | SCHULTZ S G , SOLOMON A K . Determination of the effective hydrodynamic radii of small molecules by viscometry[J]. The Journal of General Physiology, 1961, 44: 1189-1199. |
17 | RIBEIRO Ana C F , Ornella ORTONA , SIMOES Susana M N , et al . Binary mutual diffusion coefficients of aqueous solutions of sucrose, lactose, glucose, and fructose in the temperature range from (298.15 to 328.15)K[J]. Journal of Chemical and Engineering Data, 2006, 51(5): 1836-1840. |
18 | PUHLFÜRß P , VOIGT A , WEBER R , et al . Microporous TiO2 membranes with a cut off <500Da[J]. Journal of Membrane Science, 2000, 174: 123-133. |
19 | 马嫄, 阚建全, 陈宗道 . 纳滤技术及其在功能性低聚糖分离纯化中的应用[J]. 广州食品工业科技, 2002, 18(3): 64-66. |
Yuan MA , KAN Jianquan , CHEN Zongdao . Nanofiltration technology and its application in separation and purification of functional oligosaccharide[J]. Guangzhou Food Science and Technology, 2002, 18(3): 64-66. | |
20 | Fakhreddin SALEHI . Current and future applications for nanofiltration technology in the food processing[J]. Food and Bioproducts Processing, 2014, 92(C2): 161-177. |
21 | DAUFIN G , ESCUDIER J P , CARRERE H , et al . Recent and emerging applications of membrane processes in the food and dairy industry[J]. Food and Bioproducts Processing, 2001, 79(C2): 89-102. |
22 | SANGEETHA P T , RAMESH M N , PRAPULLA S G . Recent trends in the microbial production, analysis and application of Fructooligosaccharides[J]. Trends in Food Science & Technology, 2005, 16(10): 442-457. |
23 | MACHADO M T C , TREVISAN S , PIMENTEL-SOUZA J D R , et al . Clarification and concentration of oligosaccharides from artichoke extract by a sequential process with microfiltration and nanofiltration membranes[J]. Journal of Food Engineering, 2016, 180: 120-128. |
24 | LEDUR ALLES Maria Julia, TESSARO Isabel Cristina, ZAPATA NORENA Caciano Pelayo . Concentration and purification of yacon (smallanthus sonchifolius) root fructooligosaccharides using membrane technology[J]. Food Technology and Biotechnology, 2015, 53(2): 190-200. |
25 | 孙蔚榕, 韩亮, 鲍元兴 . 低聚糖的纳滤分离技术[J]. 无锡轻工大学学报, 2002, 21(6): 574-578, 596. |
SUN Weirong , HAN Liang , BAO Yuanxing . The nanofiltration technique for isolation of oligosacchride[J]. Journal of Wuxi University of Light Industry, 2002, 21(6): 574-578, 596. | |
26 | 冯文亮, 王静, 贾晓江 . 纳滤技术生产高纯度低聚果糖的研究[J]. 乳业科学与技术, 2003, 104(3): 102-105. |
FENG Wenliang , WANG Jing , JIA Xiaojiang . Study on the high-purity fructooligosaccharide by the nanofiltration[J]. Dairy Science and Technology, 2003, 104(3): 102-105. | |
27 | 李炜怡, 李继定, 陈翠仙, 等 . 纳滤提纯蔗果低聚糖实验研究和渗滤模型[J]. 膜科学与技术, 2004, 24(5): 6-10. |
LI Weiyi , LI Jiding , CHEN Cuixian , et al . Experimental study on nanofiltration for purifying fructo-oligosaccharide and diafiltration model[J]. Membrane Science and Technology, 2004, 24(5): 6-10. | |
28 | Andres CORDOVA , Carolina ASTUDILLO , Cecilia GUERRERO , et al . Assessment of the fouling mechanisms of an ultrafiltration membrane bioreactor during synthesis of galacto-oligosaccharides: effect of the operational variables[J]. Desalination, 2016, 393: 79-89. |
29 | SARNEY D B , HALE C , FRANKEL G , et al . A novel approach to the recovery of biologically active oligosaccharides from milk using a combination of enzymatic treatment and nanofiltration[J]. Biotechnology and Bioengineering, 2000, 69(4): 461-467. |
30 | GOULAS A K , KAPASAKALIDIS P G , SINCLAIR H R , et al . Purification of oligosaccharides by nanofiltration[J]. Journal of Membrane Science, 2002, 209(1): 321-335. |
31 | BOTELHO-CUNHA V A , MATEUS M , PETRUS J C C , et al . Tailoring the enzymatic synthesis and nanofiltration fractionation of galacto-oligosaccharides[J]. Biochemical Engineering Journal, 2010, 50(1-2): 29-36. |
32 | PRUKSASRI S , NGUYEN T H , HALTRICH D , et al . Fractionation of a galacto-oligosaccharides solution at low and high temperature using nanofiltration[J]. Separation and Purification Technology, 2015, 151: 124-130. |
33 | Cristian-Teodor BURUIANA , Belen GOMEZ , Camelia VIZIREANU , et al . Manufacture and evaluation of xylooligosaccharides from corn stover as emerging prebiotic candidates for human health[J]. LWT-Food Science and Technology, 2017, 77: 449-459. |
34 | Vikash KUMAR , SATYANARAYANA T . Generation of xylooligosaccharides from microwave irradiated agroresidues using recombinant thermo-alkali-stable endoxylanase of the polyextremophilic bacterium bacillus halodurans expressed in Pichia pastoris[J]. Bioresource Technology, 2015, 179: 382-389. |
35 | Manuel PINELO , Gunnar JONSSON , MEYER Anne S . Membrane technology for purification of enzymatically produced oligosaccharides: molecular and operational features affecting performance[J]. Separation and Purification Technology, 2009, 70(1): 1-11. |
36 | 杨刚, 王焕章, 邢卫红, 等 . 木糖溶液的纳滤浓缩[J]. 膜科学与技术, 2000, 20(5): 21-26. |
YANG Gang , WANG Huanzhang , XING Weihong , et al . Concentration of xylose solution through nanofiltration[J]. Membrane Science and Technology, 2000, 20(5): 21-26. | |
37 | 赵鹤飞, 杨瑞金, 赵伟, 等 . 秸秆低聚木糖溶液纳滤分离特性和渗滤工艺[J]. 农业工程学报, 2009, 25(4): 253-259. |
ZHAO Hefei , YANG Ruijin , ZHAO Wei , et al . Separation performance of xylo-oligosaccharides from wheat straw using nanofiltration membrance and technology for diafiltration[J]. Tansactions of the CSAE, 2009, 25(4): 253-259. | |
38 | ZHAO H F , HUA X , YANG R J , et al . Diafiltration process on xylo-oligosaccharides syrup using nanofiltration and its modelling[J]. International Journal of Food Science and Technology, 2012, 47(1): 32-39. |
39 | HUA X A , ZHAO H F , YANG R J , et al . Coupled model of extended Nernst-Planck equation and film theory in nanofiltration for xylo-oligosaccharide syrup[J]. Journal of Food Engineering, 2010, 100(2): 302-309. |
40 | Suwimol CHOCKCHAISAWASDEE , Naiyatat POOSARAN . Production of isomaltooligosaccharides from banana flour[J]. Journal of the Science of Food and Agriculture, 2013, 93(1): 180-186. |
41 | 鲍元兴, 孙蔚榕, 杨维亚 . 低聚异麦芽糖的纳滤分离技术和色谱分离技术[J]. 无锡轻工大学学报, 2001, 20(4): 351-355. |
BAO Yuanxing , SUN Weirong , YANG Weiya . The advanced separation technology of isomaltooligosacchride[J]. Journal of Wuxi University of Light Industry, 2001, 20(4): 351-355. | |
42 | GOULAS A K , GRANDISON A S , RASTALL R A . Fractionation of oligosaccharides by nanofiltration[J]. Journal of the Science of Food and Agriculture, 2003, 83(7): 675-680. |
43 | 黄秀娟, 钟振声 . 纳滤法去除低聚异麦芽糖中的单糖[J]. 中国调味品, 2012, 37(1): 92-96. |
HUANG Xiujuan , ZHONG Zhensheng . Monosaccharide removal from isomaltooligosaccharides by nanofiltration[J]. China Condiment, 2012, 37(1): 92-96. | |
44 | 崔强, 王一, 李秋红, 等 . 纳滤法在色谱残液中单糖去除工艺中的应用研究[J]. 食品工业, 2016, 37(8): 139-141. |
CUI Qiang , WANG Yi , LI Qiuhong , et al . Study on removing of glucose from chromatographic raffinate by nanofiltration process[J]. Science and Technology of Food Industry, 2016, 37(8): 139-141. | |
45 | 王鲁霞, 吴延立, 马文平 . 壳寡糖的制备方法及其在食品中的应用现状[J]. 安徽农业科学, 2014, 42(32): 11485-11487. |
WANG Luxia , WU Yanli , Wenping MA . The preparation method and application status of chitooligosaccharide in food[J]. Journal of Anhui Agricultural Sciences, 2014, 42(32): 11485-11487. | |
46 | 乔莹, 白雪芳, 杜昱光 . 壳寡糖医药保健功能的研究进展[J]. 中国生化药物杂志, 2008, 29(3): 210-213. |
QIAO Ying , BAI Xuefang , DU Yuguang . Research advances of chitosan oligosaccharides on keeping healthy[J]. Chinese Journal of Biochemical Pharmaceutics, 2008, 29(3): 210-213. | |
47 | 韩永萍, 林强, 何绪文 . 纳滤对糖溶液中一价盐离子的脱出研究[J]. 食品科技, 2008(4): 95-99. |
HAN Yongping , LIN Qiang , HE Xuwen . Research on nanofiltration removing univalent ion from sugar solution[J]. Food Science and Technology, 2008(4): 95-99. | |
48 | 韩永萍, 林强, 何绪文 . 纳滤对壳寡糖制备液的纯化性能研究[J]. 膜科学与技术, 2009, 29(6): 105-109. |
HAN Yongping , LIN Qiang , HE Xuwen . Research on desalination and purification characteristics of chitobiose solution with nanofiltration membrane[J]. Membrane Science and Technology, 2009, 29(6): 105-109. | |
49 | IWASAKI K , MATSUBARA Y . Purification of pectate oligosaccharides showing root-growth-promoting activity in lettuce using ultrafiltration and nanofiltration membranes[J]. Journal of Bioscience and Bioengineering, 2000, 89(5): 495-497. |
50 | LIU Jianhua , LI Hu , WU Jinhong , et al . Determination of phosphoryl-oligosaccharides obtained from canna edulis Ker starch[J]. Starch-Starke, 2017, 69(1/2): 1-6. |
51 | LI Zhaokui , WANG Kai , ZHANG Yushan . Eco-friendly separation and purification of soybean oligosaccharides via nanofiltration technology[J]. Separation Science and Technology, 2018, 53(5): 777-785. |
52 | 董艳, 高瑞昶, 潘勤, 等 . 超滤和纳滤分离技术提取纯化地黄低聚糖的研究[J]. 中草药, 2008, 39(3): 359-363. |
DONG Yan , GAO Ruichang , PAN Qin , et al . Ultrafiltrat ion and nanofiltrat ion membrane separation technology in extracting and purifying oligosaccharides of Rehmannia glutinosa[J]. Chinese Traditional and Herbal Drugs, 2008, 39(3): 359-363. | |
53 | 韩少卿, 赵芹, 彭奇均 . 膜分离技术提取海藻糖的工艺[J]. 食品与生物技术学报, 2005, 24(2): 93-96. |
HAN Shaoqing , ZHAO Qin , PENG Qijun . Trehalose extraction by the technology of membrane separation[J]. Journal of Food and Science and Biotechnology, 2005, 24(2): 93-96. | |
54 | 韩少卿, 慈龙剑, 陈贵锐, 等 . 膜法酵母提取海藻糖应用初探[J]. 中国调味品, 2004, 307(9): 21-25. |
HAN Shaoqing , Longjian CI , CHEN Guirui , et al . Development of extracting trehalose from baker's yeast by membrane process[J]. China Condiment, 2004, 307(9): 21-25. | |
55 | VELLENGA E , TRAGARDH G . Nanofiltration of combined salt and sugar solutions: coupling between retentions[J]. Desalination, 1998, 120(3): 211-220. |
56 | Rodolfo VEGAS , Andres MOURE , Herminia DOMINGUEZ , et al . Evaluation of ultra- and nanofiltration for refining soluble products from rice husk xylan[J]. Bioresource Technology, 2008, 99(13): 5341-5351. |
57 | 张云, 齐婷, 石姝, 等 . 陶瓷超滤膜在右旋糖酐分离中的应用[J]. 膜科学与技术, 2018, 38(2): 86-91, 97. |
ZHANG Yun , QI Ting , SHI Shu , et al . Application of ceramic ultrafiltration membranes for dextran separation[J]. Membrane Science and Technology, 2018, 38(2): 86-91, 97. | |
58 | 冯咏梅, 常秀莲, 王文华, 等 . 膜技术分离纯化低聚半乳糖[J]. 精细化工, 2009, 26(9): 873-877. |
FENG Yongmei , CHANG Xiulian , WANG Wenhua , et al . Purification of galacto-oligosaccharides by membrane technology[J]. Fine Chemicals, 2009, 26(9): 873-877. | |
59 | TSURU T , IZUMI S , YOSHIOKA T , et al . Temperature effect on transport performance by inorganic nanofiltration membranes[J]. AIChE Journal, 2000, 46(3): 565-574. |
60 | GONZÁLEZ-MUÑOZ M J , DOMÍNGUEZ H , PARAJÓ J C . Depolymerization of xylan-derived products in an enzymatic membrane reactor[J]. Journal of Membrane Science, 2008, 320(1): 224-231. |
61 | LUO Jianquan , GUO Shiwei , WU Yuanyuan , et al . Separation of sucrose and reducing sugar in cane molasses by nanofiltration[J]. Food and Bioprocess Technology, 2018, 11(5): 913-925. |
62 | SHI J F , ZHANG W Y , SU Y L , et al . Composite polyelectrolyte multilayer membranes for oligosaccharides nanofiltration separation[J]. Carbohydrate Polymers, 2013, 94(1): 106-113. |
63 | I Elizabeth ORTIZ-CERDA , Johanne BONNIN , Stephane BOSTYN , et al . Experimental and CFD modeling study of inulin-type fructan purification from a model solution by diafiltration on a pilot-scale unit[J]. Separation Science and Technology, 2014, 49(8): 1125-1134. |
64 | COHEN J L , BARILE D , LIU Y , et al . Role of pH in the recovery of bovine milk oligosaccharides from colostrum whey permeate by nanofiltration[J]. International Dairy Journal, 2017, 66: 68-75. |
65 | 芦鑫, 宋国辉, 张丽霞, 等 . 膜分离应用于花生根中白藜芦醇初级纯化[J]. 食品工业科技, 2016, 37(18): 282-286. |
LU Xin , SONG Guohui , ZHANG Lixia , et al . Application of membrane separation on preliminary purification of resveratrol from extract of peanut root[J]. Science and Technology of Food Industry, 2016, 37(18): 282-286. | |
66 | Mou PAUL , JONS Steven D . Chemistry and fabrication of polymeric nanofiltration membranes: a review[J]. Polymer, 2016, 103: 417-456. |
67 | JI Yanli , QIAN Weijie , YU Yawei , et al . Recent developments in nanofiltration membranes based on nanomaterials[J]. Chinese Journal of Chemical Engineering, 2017, 25(11): 1639-1652. |
68 | 范益群, 漆虹 . 陶瓷纳滤膜制备与应用研究进展[J]. 化工进展, 2016, 35(6): 1786-1793. |
FAN Yiqun , QI Hong . Research progress of ceramic nanofiltration membranes[J]. Chemical Industry and Engineering Progress, 2016, 35(6): 1786-1793. | |
69 | 范益群, 漆虹, 徐南平 . 多孔陶瓷膜制备技术研究进展[J]. 化工学报, 2013, 64(1): 107-115. |
FAN Yiqun , QI Hong , XU Nanping . Recent advances in research on preparation techniques of porous ceramic membranes[J]. CIESC Journal, 2013, 64(1): 107-115. | |
70 | CHEN Xianfu , ZHANG Yun , TANG Jianxiong , et al . Novel pore size tuning method for the fabrication of ceramic multi-channel nanofiltration membrane[J]. Journal of Membrane Science, 2018, 552: 77-85. |
71 | YUAN Q P , ZHANG H , QIAN Z M , et al . Pilot-plant production of xylo-oligosaccharides from corncob by steaming, enzymatic hydrolysis and nanofiltration[J]. Journal of Chemical Technology and Biotechnology, 2004, 79(10): 1073-1079. |
72 | LI W Y , LI J D , CHEN T Q , et al . Study on nanofiltration for purifying fructo-oligosaccharides Ⅱ. Extended pore model[J]. Journal of Membrane Science, 2005, 258(1/2): 8-15. |
73 | LI W Y , LI J D , CHEN T Q , et al . Study on nanofiltration for purifying fructo-oligosaccharides I. Operation modes[J]. Journal of Membrane Science, 2004, 245(1/2): 123-129. |
74 | Rodolfo VEGAS , Susana LUQUE , ALVAREZ Jose Ramon, et al . Membrane-assisted processing of xylooligosaccharide-containing liquors[J]. Journal of Agricultural and Food Chemistry, 2006, 54(15): 5430-5436. |
75 | CHEN Xianfu , ZHANG Wei , LIN Yuqing , et al . Preparation of high-flux γ-alumina nanofiltration membranes by using a modified sol-gel method[J]. Microporous and Mesoporous Materials, 2015, 214: 195-203. |
76 | CAI Yuanyuan , CHEN Xianfu , WANG Yi , et al . Fabrication of palladium-titania nanofiltration membranes via a colloidal sol-gel process[J]. Microporous and Mesoporous Materials, 2015, 201: 202-209. |
77 | CAI Yuanyuan , WANG Yi , CHEN Xianfu , et al . Modified colloidal sol–gel process for fabrication of titania nanofiltration membranes with organic additives[J]. Journal of Membrane Science, 2015, 476: 432-441. |
78 | Xiaowei DA , WEN Juanjuan , LU Yawei , et al . An aqueous sol-gel process for the fabrication of high-flux YSZ nanofiltration membranes as applied to the nanofiltration of dye wastewater[J]. Separation and Purification Technology, 2015, 152: 37-45. |
79 | Xiaowei DA , CHEN Xianfu , SUN Baohong , et al . Preparation of zirconia nanofiltration membranes through an aqueous sol–gel process modified by glycerol for the treatment of wastewater with high salinity[J]. Journal of Membrane Science, 2016, 504: 29-39. |
80 | ZHU Guizhi , JIANG Qian , QI Hong , et al . Effect of sol size on nanofiltration performance of a sol-gel derived microporous zirconia membrane[J]. Chinese Journal of Chemical Engineering, 2015, 23(1): 31-41. |
81 | LU Yawei , CHEN Ting , CHEN Xianfu , et al . Fabrication of TiO2-doped ZrO2 nanofiltration membranes by using a modified colloidal sol-gel process and its application in simulative radioactive effluent[J]. Journal of Membrane Science, 2016, 514: 476-486. |
82 | GUO Honglin , ZHAO Shuaifei , WU Xiaoxian , et al . Fabrication and characterization of TiO2/ZrO2 ceramic membranes for nanofiltration[J]. Microporous and Mesoporous Materials, 2018, 260: 125-131. |
[1] | 张祚群, 高扬, 白超杰, 薛立新. 二次界面聚合同步反扩散原位生长ZIF-8纳米粒子制备聚酰胺混合基质反渗透(RO)膜[J]. 化工进展, 2023, 42(S1): 364-373. |
[2] | 徐杰, 夏隆博, 罗平, 邹栋, 仲兆祥. 面向膜蒸馏过程的全疏膜制备及其应用进展[J]. 化工进展, 2023, 42(8): 3943-3955. |
[3] | 李雪佳, 李鹏, 李志霞, 晋墩尚, 郭强, 宋旭锋, 宋芃, 彭跃莲. 亲水和疏水改性膜的抗结垢和润湿能力的对比[J]. 化工进展, 2023, 42(8): 4458-4464. |
[4] | 潘宜昌, 周荣飞, 邢卫红. 高效分离同碳数烃的先进微孔膜:现状与挑战[J]. 化工进展, 2023, 42(8): 3926-3942. |
[5] | 王报英, 王皝莹, 闫军营, 汪耀明, 徐铜文. 聚合物包覆膜在金属分离回收中的研究进展[J]. 化工进展, 2023, 42(8): 3990-4004. |
[6] | 陆诗建, 刘苗苗, 杨菲, 张俊杰, 陈思铭, 刘玲, 康国俊, 李清方. 改良型CO2湿壁塔内气液两相流动规律及传质特性[J]. 化工进展, 2023, 42(7): 3457-3467. |
[7] | 冯江涵, 宋钫. 阴离子交换膜电解池的研究进展[J]. 化工进展, 2023, 42(7): 3501-3509. |
[8] | 陈香李, 李倩倩, 张甜, 李彪, 李康康. 自愈合油水分离膜的研究进展[J]. 化工进展, 2023, 42(7): 3600-3610. |
[9] | 任重远, 何金龙, 袁清. 分子筛膜晶间缺陷控制与修复技术研究进展[J]. 化工进展, 2023, 42(5): 2454-2463. |
[10] | 王林, 辛梅华, 李明春, 陈琦, 毛扬帆. 季铵化/磺化壳聚糖的制备及其抗生物被膜活性[J]. 化工进展, 2023, 42(5): 2577-2585. |
[11] | 孙鲁芹, 卢会霞, 王建友. 电渗析/超滤内在耦合过程分离蛋清中溶菌酶[J]. 化工进展, 2023, 42(5): 2262-2271. |
[12] | 于捷, 张文龙. 锂离子电池隔膜的发展现状与进展[J]. 化工进展, 2023, 42(4): 1760-1768. |
[13] | 赵珍珍, 郑喜, 王雪琪, 王涛, 冯英楠, 任永胜, 赵之平. 聚酰胺复合膜微孔支撑基底的研究进展[J]. 化工进展, 2023, 42(4): 1917-1933. |
[14] | 叶海星, 陈宇昊, 陈仪, 孙海翔, 牛青山. 镁锂分离复合纳滤膜研究进展[J]. 化工进展, 2023, 42(4): 1934-1943. |
[15] | 常晓青, 彭东来, 李东洋, 张延武, 王景, 张亚涛. MOFs基丙烯/丙烷高效分离混合基质膜研究进展[J]. 化工进展, 2023, 42(4): 1961-1973. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||
京ICP备12046843号-2;京公网安备 11010102001994号 版权所有 © 《化工进展》编辑部 地址:北京市东城区青年湖南街13号 邮编:100011 电子信箱:hgjz@cip.com.cn 本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn |