塑料衍生碳材料用于超级电容器的研究现状

doi:10.16085/j.issn.1000-6613.2021-0597

化工进展 ›› 2022, Vol. 41 ›› Issue (2): 781-790.DOI: 10.16085/j.issn.1000-6613.2021-0597

塑料衍生碳材料用于超级电容器的研究现状

郭冠伦¹^,²(), 刘锐¹^,², 余洋洋¹^,², 汪云³()

^1. 武汉理工大学现代汽车零部件技术湖北省重点实验室，湖北武汉 430070
^2. 武汉理工大学汽车零部件技术湖北省协同创新中心，湖北武汉 430070
^3. 湖北文理学院汽车与交通工程学院，湖北襄阳 441053

收稿日期:2021-03-24 修回日期:2021-07-02 出版日期:2022-02-05 发布日期:2022-02-23
通讯作者: 汪云
作者简介:郭冠伦（1979—），男，副教授，硕士生导师，研究方向为动力电池性能衰减与安全及新型燃料燃烧与排放机理。E-mail：glguo@whut.edu.cn。
基金资助:
高等学校学科创新引智计划(B17034);湖北“机械与汽车”优势学科群开放基金(XKQ2021001)

Progress on carbon materials derived from waste plastic for supercapacitors

GUO Guanlun¹^,²(), LIU Rui¹^,², YU Yangyang¹^,², WANG Yun³()

^1. Hubei Key Laboratory of Advanced Technology for Automotive Components, Wuhan University of Technology, Wuhan 430070, Hubei, China
^2. Hubei Collaborative Innovation for Automotive Components Technology, Wuhan University of Technology, Wuhan 430070, Hubei, China
^3. School of Automotive and Traffic Engineering, Hubei University of Arts and Science, Xiangyang 441053, Hubei, China

Received:2021-03-24 Revised:2021-07-02 Online:2022-02-05 Published:2022-02-23
Contact: WANG Yun

摘要/Abstract

摘要：

塑料制品的过度使用，导致了严重的环境问题。将废旧塑料回收并转化为高附加值的碳材料并用于超级电容器等储能装置有着重要的意义，能够有效地降低环境污染并节约能源。本文首先对超级电容器的应用情况和塑料的使用以及回收处理现状进行了简单叙述，介绍了常见的废弃塑料处理方法、超级电容器的储能特点以及利用废弃塑料制备超级电容器碳材料的潜在价值；接着介绍了多孔碳电极材料的制备方法，对不同的制备方法的具体要求及其优缺点进行了简单分析；随后介绍了几种生活中常见的塑料，按照这些塑料的种类，分别对这些常见塑料回收用作超级电容器碳材料的研究现状进行了详细概述；最后对目前的研究现状进行总结，并对未来的研究方向进行展望。将废弃塑料回收并转化为超级电容器用活性碳材料，是一种新型的废弃塑料回收再利用的有效手段，能够有效地解决白色污染问题。

关键词: 废旧塑料, 超级电容器, 多孔碳, 电极材料

Abstract:

The overuse of plastic products has caused serious environmental problems. It is of great importance to recycle waste plastics and convert them into high value-added materials, which can reduce pollution and save energy effectively. In this review, firstly, the application of supercapacitors and the current state of plastic recycling were stated, and waste plastic treatment methods, the energy storage characteristics of supercapacitors and the potential value of using waste plastics to prepare carbon materials for supercapacitors were introduced. Then, the preparation methods of porous carbon electrode materials were presented, and the specific requirements of the methods and their advantages and disadvantages were briefly analyzed. Next, some kinds of common plastics were introduced according to the type of plastics, and the research status of these common plastics used as carbon materials for supercapacitor was summarized. Recycling and converting waste plastics into activated carbon materials for supercapacitors was a new type of waste plastic recycling and reuse mothed, which can solve the problem of white pollution effectively.

Key words: waste plastics, supercapacitor, porous carbon, electrode materials

中图分类号:

郭冠伦, 刘锐, 余洋洋, 汪云. 塑料衍生碳材料用于超级电容器的研究现状[J]. 化工进展, 2022, 41(2): 781-790.

GUO Guanlun, LIU Rui, YU Yangyang, WANG Yun. Progress on carbon materials derived from waste plastic for supercapacitors[J]. Chemical Industry and Engineering Progress, 2022, 41(2): 781-790.

图/表 6

参考文献 40

1	UTETIWABO W , YANG L , TUFAIL M K , et al . Electrode materials derived from plastic wastes and other industrial wastes for supercapacitors[J]. Chinese Chemical Letters, 2020, 31(6): 1474-1489.
2	姜文明 . 基于固废高分子材料制备多孔炭材料及其电化学性能研究[D]. 镇江: 江苏大学, 2015.
	JIANG Wenming . Study on the synthesis of porous carbon materials derived from polymer wastes and the electrochemical performance[D]. Zhenjiang: Jiangsu University, 2015.
3	闵嘉康 . 聚苯乙烯模板碳化反应在制备储能器件电极材料中的应用[D]. 北京: 中国科学院大学, 2018.
	MIN Jiakang . Application of template carbonization of polystyrene in energy storage devices[D]. Beijing: University of Chinese Academy of Sciences, 2018.
4	曹玉亭, 张锦赓 . 废旧塑料的再生利用[J]. 当代化工, 2011, 40(2): 190-192.
	CAO Yuting , ZHANG Jingeng . Recycling and reusing of waste plastic[J]. Contemporary Chemical Industry, 2011, 40(2): 190-192.
5	WANG G P , ZHANG L , ZHANG J J . A review of electrode materials for electrochemical supercapacitors[J]. Chemical Society Reviews, 2012, 41(2): 797-828.
6	SIMON P , GOGOTSI Y . Materials for electrochemical capacitors[J]. Nature Materials, 2008, 7(11): 845-854.
7	SHI H . Activated carbons and double layer capacitance[J]. Electrochimica Acta, 1996, 41(10): 1633-1639.
8	MA T Y , LIU L , YUAN Z Y . Direct synthesis of ordered mesoporous carbons[J]. Chemical Society Reviews, 2013, 42(9): 3977-4003.
9	MENG Y , GU D , ZHANG F Q , et al . Ordered mesoporous polymers and homologous carbon frameworks: amphiphilic surfactant templating and direct transformation[J]. Angewandte Chemie, 2005, 117(43): 7215-7221.
10	JAIN A , BALASUBRAMANIAN R , SRINIVASAN M P . Hydrothermal conversion of biomass waste to activated carbon with high porosity: a review[J]. Chemical Engineering Journal, 2016, 283: 789-805.
11	YOSHIDA S , HIRAGA K , TAKEHANA T , et al . A bacterium that degrades and assimilates poly(ethylene terephthalate)[J]. Science, 2016, 351(6278): 1196-1199.
12	ELESSAWY N A , NADY J EL , WAZEER W , et al . Development of high-performance supercapacitor based on a novel controllable green synthesis for 3D nitrogen doped graphene[J]. Scientific Reports, 2019, 9: 1129.
13	WEN Y L , KIERZEK K , MIN J K , et al . Porous carbon nanosheet with high surface area derived from waste poly(ethylene terephthalate) for supercapacitor applications[J]. Journal of Applied Polymer Science, 2020, 137(5): 48338.
14	AL-ENIZI A M , UBAIDULLAH M , AHMED J , et al . Synthesis of NiO _x @NPC composite for high-performance supercapacitor via waste PET plastic-derived Ni-MOF[J]. Composites Part B: Engineering, 2020, 183: 107655.
15	AL-ENIZI A M , AHMED J , UBAIDULLAH M , et al . Utilization of waste polyethylene terephthalate bottles to develop metal-organic frameworks for energy applications: a clean and feasible approach[J]. Journal of Cleaner Production, 2020, 248: 119251.
16	UBAIDULLAH M , AL-ENIZI A M , AHAMAD T , et al . Fabrication of highly porous N-doped mesoporous carbon using waste polyethylene terephthalate bottle-based MOF-5 for high performance supercapacitor[J]. Journal of Energy Storage, 2021, 33: 102125.
17	MIRJALILI A , DONG B , PENA P , et al . Upcycling of polyethylene terephthalate plastic waste to microporous carbon structure for energy storage[J]. Energy Storage, 2020, 2(6): e201.
18	MU X Y , LI Y H , LIU X G , et al . Controllable carbonization of plastic waste into three-dimensional porous carbon nanosheets by combined catalyst for high performance capacitor[J]. Nanomaterials, 2020, 10(6): 1097.
19	LIU X G , WEN Y L , CHEN X C , et al . Co-etching effect to convert waste polyethylene terephthalate into hierarchical porous carbon toward excellent capacitive energy storage[J]. Science of the Total Environment, 2020, 723: 138055.
20	SANGEETHA D N , SANTOSH M S , SELVAKUMAR M . Flower-like carbon doped MoS₂/activated carbon composite electrode for superior performance of supercapacitors and hydrogen evolution reactions[J]. Journal of Alloys and Compounds, 2020, 831: 154745.
21	ZHANG H , ZHOU X L , SHAO L M , et al . Upcycling of PET waste into methane-rich gas and hierarchical porous carbon for high-performance supercapacitor by autogenic pressure pyrolysis and activation[J]. The Science of the Total Environment, 2021, 772: 145309.
22	ZHU H . Preparation and electrochemical properties of porous carbon materials derived from waste plastic foam and their application for supercapacitors[J]. International Journal of Electrochemical Science, 2021: 210343.
23	LEE H M , KANG S J , KIM B J . Electrochemical behaviors LDPE-based activated carbon by steam activation[J]. Functional Nanostructures Proceedings, 2017: www.onecentralpress.com/.
24	ZHANG H , ZHOU X L , SHAO L M , et al . Hierarchical porous carbon spheres from low-density polyethylene for high-performance supercapacitors[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(4): 3801-3810.
25	LIAN Y M , NI M , HUANG Z H , et al . Polyethylene waste carbons with a mesoporous network towards highly efficient supercapacitors[J]. Chemical Engineering Journal, 2019, 366: 313-320.
26	LIAN Y M , UTETIWABO W , ZHOU Y D , et al . From upcycled waste polyethylene plastic to graphene/mesoporous carbon for high-voltage supercapacitors[J]. Journal of Colloid and Interface Science, 2019, 557: 55-64.
27	SUN L , WANG C L , ZHOU Y , et al . Activated nitrogen-doped carbons from polyvinyl chloride for high-performance electrochemical capacitors[J]. Journal of Solid State Electrochemistry, 2014, 18(1): 49-58.
28	CHANG Y N , PANG Y C , DANG Q D , et al . Converting polyvinyl chloride plastic wastes to carbonaceous materials via room-temperature dehalogenation for high-performance supercapacitor[J]. ACS Applied Energy Materials, 2018, 1(10): 5685-5693.
29	PANDEY S , KARAKOTI M , SURANA K , et al . Graphene nanosheets derived from plastic waste for the application of DSSCs and supercapacitors[J]. Scientific Reports, 2021, 11: 3916.
30	HU X , LIN Z D . Transforming waste polypropylene face masks into S-doped porous carbon as the cathode electrode for supercapacitors[J]. Ionics, 2021, 27(5): 2169-2179.
31	ZHANG Y X , SHEN Z M , YU Y F , et al . Porous carbon derived from waste polystyrene foam for supercapacitor[J]. Journal of Materials Science, 2018, 53(17): 12115-12122.
32	WANG G X , LIU L , ZHANG L L , et al . Porous carbon nanosheets prepared from plastic wastes for supercapacitors[J]. Journal of Electronic Materials, 2018, 47(10): 5816-5824.
33	MIN J K , ZHANG S , LI J X , et al . From polystyrene waste to porous carbon flake and potential application in supercapacitor[J]. Waste Management, 2019, 85: 333-340.
34	MA C D , LIU X G , MIN J K , et al . Sustainable recycling of waste polystyrene into hierarchical porous carbon nanosheets with potential applications in supercapacitors[J]. Nanotechnology, 2020, 31(3): 035402.
35	MA C D , MIN J K , GONG J , et al . Transforming polystyrene waste into 3D hierarchically porous carbon for high-performance supercapacitors[J]. Chemosphere, 2020, 253: 126755.
36	WEN Y L , WEN X , WENELSKA K , et al . Novel strategy for preparation of highly porous carbon sheets derived from polystyrene for supercapacitors[J]. Diamond and Related Materials, 2019, 95: 5-13.
37	URGUNDE A B , BAHUGUNA G , DHAMIJA A , et al . Ni ink-catalyzed conversion of a waste polystyrene-sugar composite to graphitic carbon for electric double-layer supercapacitors[J]. ACS Applied Electronic Materials, 2020, 2(10): 3178-3186.
38	CHEN X Y , CHENG L X , DENG X , et al . Generalized conversion of halogen-containing plastic waste into nanoporous carbon by a template carbonization method[J]. Industrial & Engineering Chemistry Research, 2014, 53(17): 6990-6997.
39	CHANG Y N , ZHANG G X , HAN B , et al . Polymer dehalogenation-enabled fast fabrication of N, S-codoped carbon materials for superior supercapacitor and deionization applications[J]. ACS Applied Materials & Interfaces, 2017, 9(35): 29753-29759.
40	SCHNEIDERMANN C , OTTO P , LEISTENSCHNEIDER D , et al . Upcycling of polyurethane waste by mechanochemistry: synthesis of N-doped porous carbon materials for supercapacitor applications[J]. Beilstein Journal of Nanotechnology, 2019, 10: 1618-1627.

合成的材料	塑料类型	测试系统	电解质	比电容/F·g^-1	扫描电压或电流密度	参考文献
Carbon-3∶1	PET	三电极	6mol/L KOH	402	1A/g	［2］
Carbon-2∶1∶2	PTFE	三电极	6mol/L KOH	237	1A/g	［2］
PTFE-1∶1-700	PTFE	三电极	6mol/L KOH	33.5	1A/g	［2］
PVC-1∶1-700	PVC	三电极	6mol/L KOH	31.7	1A/g	［2］
PVDF-1∶1-700	PVDF	三电极	6mol/L KOH	89.6	1A/g	［2］
PCF	PS	三电极	6mol/L KOH	126	1mV/s	［3］
PCF-mol/LnO₂	PS	三电极	6mol/L KOH	308	1mV/s	［3］
NG	PET	两电极	6mol/L KOH	405	1A/g	［12］
PCNS	PET	两电极	6mol/L KOH	169	—	［13］
NiO _x @NPC	PET	三电极	6mol/L KOH	581.3	5mV/s	［14］
ZnO@MC	PET	两电极	6mol/L KOH	97	5mV/s	［15］
Co₃O₄@MC	PET	两电极	6mol/L KOH	180	5mV/s	［15］
N-MC	PET	三电极	6mol/L KOH	295	0.5A/g	［16］
P750	PET	两电极	6mol/L KOH	32.6	2.5mA/cm²	［17］
PCS-MnO₂	PET	三电极	6mol/L KOH	210.5	0.5A/g	［18］
HPC	PET	三电极	6mol/L KOH	413±19	0.5A/g	［19］
PAC/MoS₂	PET	三电极	0.5mol/L Na₂SO₄	214	—	［20］
PAC/MoS₂//C	PET	三电极	0.5mol/L Na₂SO₄	288	—	［20］
AC-K	PET	三电极	6mol/L KOH	325	0.5A/g	［21］
PMC-700	PET	三电极	6mol/L KOH	296	1A/g	［22］
活性炭	LDPE	两电极	1mol/L TEABF₄/PC	20	—	［23］
HPC	LDPE	三电极	6mol/L KOH	355	0.2A/g	［24］
PE-HPC-900NH3	PE	三电极	6mol/L KOH	244	0.2A/g	［25］
ANC	PVC	三电极	6mol/L KOH	345	50mA/g	［27］
PW-C	PVC	三电极	6mol/L KOH	399	1A/g	［28］
GN	混合塑料	两电极	1mol/L H₃PO₄	398	0.005V/s	［29］
CMS-3	PP	三电极	6mol/L KOH	328.9	1A/g	［30］
3D网状多孔碳	PS	三电极	6mol/L KOH	208	1A/g	［31］
N-PCN	PS	三电极	6mol/L KOH	149	0.5A/g	［32］
PCF-MnO₂	PS	两电极	5mol/L LiCl	308	1mV/s	［33］
CNS	PS	三电极	6mol/L KOH	323	0.5A/g	［34］
U-3DHPC	PS	三电极	6mol/L KOH	284.1	0.5A/g	［35］
PCS-3	PS	两电极	1mol/L H₂SO₄	135	1mV/s	［36］
SPC8H	PS	三电极	3mol/L KOH	158	1A/g	［37］
PTFE-1∶3-700	PTFE	三电极	6mol/L KOH	313.7	0.5A/g	［38］
PVDF-1∶3-700	PVDF	三电极	6mol/L KOH	126.7	0.5A/g	［38］
PVC-1∶3-700	PVC	三电极	6mol/L KOH	41.9	0.5A/g	［38］
NS-DCM	PVDC	三电极	1mol/L H₂SO₄	427	1.0A/g	［39］
PUUPC-800-2	PU	三电极	1mol/L Li₂SO₄	99	0.1A/g	［40］

合成的材料	塑料类型	测试系统	电解质	比电容/F·g^-1	扫描电压或电流密度	参考文献
Carbon-3∶1	PET	三电极	6mol/L KOH	402	1A/g	［2］
Carbon-2∶1∶2	PTFE	三电极	6mol/L KOH	237	1A/g	［2］
PTFE-1∶1-700	PTFE	三电极	6mol/L KOH	33.5	1A/g	［2］
PVC-1∶1-700	PVC	三电极	6mol/L KOH	31.7	1A/g	［2］
PVDF-1∶1-700	PVDF	三电极	6mol/L KOH	89.6	1A/g	［2］
PCF	PS	三电极	6mol/L KOH	126	1mV/s	［3］
PCF-mol/LnO₂	PS	三电极	6mol/L KOH	308	1mV/s	［3］
NG	PET	两电极	6mol/L KOH	405	1A/g	［12］
PCNS	PET	两电极	6mol/L KOH	169	—	［13］
NiO _x @NPC	PET	三电极	6mol/L KOH	581.3	5mV/s	［14］
ZnO@MC	PET	两电极	6mol/L KOH	97	5mV/s	［15］
Co₃O₄@MC	PET	两电极	6mol/L KOH	180	5mV/s	［15］
N-MC	PET	三电极	6mol/L KOH	295	0.5A/g	［16］
P750	PET	两电极	6mol/L KOH	32.6	2.5mA/cm²	［17］
PCS-MnO₂	PET	三电极	6mol/L KOH	210.5	0.5A/g	［18］
HPC	PET	三电极	6mol/L KOH	413±19	0.5A/g	［19］
PAC/MoS₂	PET	三电极	0.5mol/L Na₂SO₄	214	—	［20］
PAC/MoS₂//C	PET	三电极	0.5mol/L Na₂SO₄	288	—	［20］
AC-K	PET	三电极	6mol/L KOH	325	0.5A/g	［21］
PMC-700	PET	三电极	6mol/L KOH	296	1A/g	［22］
活性炭	LDPE	两电极	1mol/L TEABF₄/PC	20	—	［23］
HPC	LDPE	三电极	6mol/L KOH	355	0.2A/g	［24］
PE-HPC-900NH3	PE	三电极	6mol/L KOH	244	0.2A/g	［25］
ANC	PVC	三电极	6mol/L KOH	345	50mA/g	［27］
PW-C	PVC	三电极	6mol/L KOH	399	1A/g	［28］
GN	混合塑料	两电极	1mol/L H₃PO₄	398	0.005V/s	［29］
CMS-3	PP	三电极	6mol/L KOH	328.9	1A/g	［30］
3D网状多孔碳	PS	三电极	6mol/L KOH	208	1A/g	［31］
N-PCN	PS	三电极	6mol/L KOH	149	0.5A/g	［32］
PCF-MnO₂	PS	两电极	5mol/L LiCl	308	1mV/s	［33］
CNS	PS	三电极	6mol/L KOH	323	0.5A/g	［34］
U-3DHPC	PS	三电极	6mol/L KOH	284.1	0.5A/g	［35］
PCS-3	PS	两电极	1mol/L H₂SO₄	135	1mV/s	［36］
SPC8H	PS	三电极	3mol/L KOH	158	1A/g	［37］
PTFE-1∶3-700	PTFE	三电极	6mol/L KOH	313.7	0.5A/g	［38］
PVDF-1∶3-700	PVDF	三电极	6mol/L KOH	126.7	0.5A/g	［38］
PVC-1∶3-700	PVC	三电极	6mol/L KOH	41.9	0.5A/g	［38］
NS-DCM	PVDC	三电极	1mol/L H₂SO₄	427	1.0A/g	［39］
PUUPC-800-2	PU	三电极	1mol/L Li₂SO₄	99	0.1A/g	［40］

[1]	张耀杰, 张传祥, 孙悦, 曾会会, 贾建波, 蒋振东. 煤基石墨烯量子点在超级电容器中的应用[J]. 化工进展, 2023, 42(8): 4340-4350.
[2]	王帅晴, 杨思文, 李娜, 孙占英, 安浩然. 元素掺杂生物质炭材料在电化学储能中的研究进展[J]. 化工进展, 2023, 42(8): 4296-4306.
[3]	朱薇, 齐鹏刚, 苏银海, 张书平, 熊源泉. 生物油分级多孔碳超级电容器电极材料的制备及性能[J]. 化工进展, 2023, 42(6): 3077-3086.
[4]	陈飞, 刘成宝, 陈丰, 钱君超, 邱永斌, 孟宪荣, 陈志刚. g-C₃N₄基超级电容器用电极材料的研究进展[J]. 化工进展, 2023, 42(5): 2566-2576.
[5]	王钰琢, 李刚. 硫、氮共掺杂三维石墨烯的全固态超级电容器[J]. 化工进展, 2023, 42(4): 1974-1982.
[6]	万茂华, 张小红, 安兴业, 龙垠荧, 刘利琴, 管敏, 程正柏, 曹海兵, 刘洪斌. MXene在生物质基储能纳米材料领域中的应用研究进展[J]. 化工进展, 2023, 42(4): 1944-1960.
[7]	刘静, 林琳, 张健, 赵峰. 生物质基炭材料孔径调控及电化学性能研究进展[J]. 化工进展, 2023, 42(4): 1907-1916.
[8]	蔡江涛, 候刘华, 兰雨金, 张晨陈, 刘国阳, 朱由余, 张建兰, 赵世永, 张亚婷. 沥青基多孔炭材料的制备及在超级电容器中的应用进展[J]. 化工进展, 2023, 42(4): 1895-1906.
[9]	杜保宁, 赵珊, 刘向卿, 张毅, 肖雅茹, 张少飞, 李田田, 孙金峰. 纳米多孔CuMn基氧化物电极的制备及性能[J]. 化工进展, 2023, 42(3): 1484-1492.
[10]	刘丹, 范云洁, 王慧敏, 严政, 李鹏飞, 李家成, 曹雪波. 基于废弃PET的高值化功能性多孔碳材料及其应用进展[J]. 化工进展, 2023, 42(2): 969-984.
[11]	卓祖优, 宋生南, 黄明堦, 杨旋, 卢贝丽, 陈燕丹. 草酸钾-尿素协同活化法制备超大比表面积面粉基多级孔炭及其电化学储能应用[J]. 化工进展, 2023, 42(2): 925-933.
[12]	田甜, 雷西萍, 于婷, 樊凯, 宋晓琪, 朱航. 碳材料在柔性超级电容器中的研究进展[J]. 化工进展, 2023, 42(2): 884-896.
[13]	王晓亮, 于振秋, 常雷明, 赵浩男, 宋晓琦, 高靖淞, 张一波, 黄传辉, 刘忆, 杨绍斌. 电沉积法制备氢氧化物/氧化物超级电容器电极的研究进展[J]. 化工进展, 2023, 42(10): 5272-5285.
[14]	龙垠荧, 杨健, 管敏, 杨怡洛, 程正柏, 曹海兵, 刘洪斌, 安兴业. 木质素基材料在混合型超级电容器电极材料中的研究进展[J]. 化工进展, 2022, 41(9): 4855-4865.
[15]	徐虎, 郭泓凯, 柴昌盛, 郝相忠, 杨子元, 徐卫军. 碳纤维类材料用于电芬顿体系电极的研究现状[J]. 化工进展, 2022, 41(7): 3707-3718.

塑料衍生碳材料用于超级电容器的研究现状

Progress on carbon materials derived from waste plastic for supercapacitors

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 40

相关文章 15

编辑推荐

Metrics

本文评价