化工进展 ›› 2017, Vol. 36 ›› Issue (11): 4124-4131.DOI: 10.16085/j.issn.1000-6613.2017-0416

• 材料科学与技术 • 上一篇    下一篇

石墨烯-酞菁复合材料制备及应用研究进展

牛素冉1,2, 王永杰1,2, 朱丽君2, 周玉路1, 项玉芝1, 夏道宏2   

  1. 1. 中国石油大学(华东)理学院, 山东 青岛 266580;
    2. 中国石油大学(华东)重质油国家重点实验室, 山东 青岛 266580
  • 收稿日期:2017-03-15 修回日期:2017-07-21 出版日期:2017-11-05 发布日期:2017-11-05
  • 通讯作者: 项玉芝,教授;夏道宏,教授。
  • 作者简介:牛素冉(1985-),女,硕士研究生。E-mail:niusuran_zsy@163.com。

Research progress in the preparation and application of graphene-phthalocyanine composite

NIU Suran1,2, WANG Yongjie1,2, ZHU Lijun2, ZHOU Yulu1, XIANG Yuzhi1, XIA Daohong2   

  1. 1. College of Science, China University of Petroleum(East China), Qingdao 266580, Shandong, China;
    2. State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, Shandong, China
  • Received:2017-03-15 Revised:2017-07-21 Online:2017-11-05 Published:2017-11-05

摘要: 石墨烯和酞菁结合形成的新型多功能复合材料既兼备了石墨烯与酞菁的优良特性,又有效克服了两者的缺点,并且它们之间有一定的协同作用,表现出卓越的性能,具有广阔的应用前景,是一种有极大发展潜力的复合材料。本文介绍了石墨烯-酞菁复合材料的两种链接方式,并详细阐述了石墨烯通过不同链接方式与单核酞菁、双核酞菁等形成复合材料的制备方法以及这种复合材料在作为电极材料、制备传感器、降解有机污染物、催化氧化、光解水制氢等方面的应用研究进展。这种复合材料在电催化、光催化等方面的研究是今后应用研究的主要发展方向。

关键词: 复合材料, 链接类型, 制备, 电化学, 催化作用

Abstract: The new multifunctional composite that combined graphene and phthalocyanine not only possesses the excellent characteristics of both graphene and phthalocyanine,but also can effectively overcome their respective shortcomings. So,this composite has excellent performance and broad application prospects. In this paper,we introduce the two link types of graphene-phthalocyanine composite and the preparation methods of graphene with mononuclear phthalocyanine or binuclear phthalocyanine by different link types. The advances in the applications of this composite are also introduced,such as electrode material,fabrication of sensor,degradation of organic pollutants,catalytic oxidation and photocatalytic water splitting. The application of the composite in electrocatalysis and photocatalysis is the major development direction in the future.

Key words: composites, link type, preparation, electrochemistry, catalysis

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