Chemical Industry and Engineering Progress ›› 2025, Vol. 44 ›› Issue (10): 5911-5925.DOI: 10.16085/j.issn.1000-6613.2024-1326
• Resources and environmental engineering • Previous Articles
Progress in remediation of organic contaminated soil by microwave combined advanced oxidation processes
ZHAO Xiwang1,2(
), GAO Li1(), LIANG Zhenming1, LIU Xitao2()
- 1.North China Power Engineering Co. , Ltd. of China Power Engineering Consulting Group, Beijing 100011, China
2.School of Environmental, Beijing Normal University, Beijing 100875, China
-
Received:2024-08-14Revised:2024-10-11Online:2025-11-10Published:2025-10-25 -
Contact:GAO Li, LIU Xitao
微波协同高级氧化技术修复有机污染土壤的研究进展
赵锡望1,2(), 高丽1(), 梁振明1, 刘希涛2()
- 1.中国电力工程顾问集团华北电力设计院有限公司，北京 100011
2.北京师范大学环境学院，北京 100875
-
通讯作者:高丽,刘希涛 -
作者简介:赵锡望（2000—），男，博士研究生，研究方向为土壤污染控制。E-mail：zhaoxw@mail.bnu.edu.cn。 -
基金资助:中国电力工程顾问集团项目(DG2-G02-2023)
CLC Number:
Cite this article
ZHAO Xiwang, GAO Li, LIANG Zhenming, LIU Xitao. Progress in remediation of organic contaminated soil by microwave combined advanced oxidation processes[J]. Chemical Industry and Engineering Progress, 2025, 44(10): 5911-5925.
赵锡望, 高丽, 梁振明, 刘希涛. 微波协同高级氧化技术修复有机污染土壤的研究进展[J]. 化工进展, 2025, 44(10): 5911-5925.
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| 污染物 | 微波反应体系 | 最优反应条件 | 土壤性质 | 降解效果/% | 参考文献 |
|---|---|---|---|---|---|
| 微波协同氧化剂体系 | |||||
| 邻苯二甲酸二丁酯（21.7mg/kg） | MW/过碳酸钠 | Power=480W，[SPC]=0.196g/10g土，T=80℃，t=40min，W/S=4/1① | pH=8.36，SOM=1.11% | 85.14 | [ |
毒死蜱 （100mg/kg） | MW/PS | Power=480W，[PS]=28.57mmol/kg，T=80℃（PDS）/60℃（PMS），t=45min，W/S=1 | pH=7.65，SOM=1.96%，sand=80.27%，silt=12.39%，clay=7.34%③ | >90.00 | [ |
乙基对硫磷 （60mg/kg） | MW/PDS | [PDS]=23.8g/kg，T=100℃，t=60min，W/S=1/10 | pH=7.78 | 75.30 | [ |
| 萘 | MW/PDS | [PDS]=1.0mol/L，T=80℃，t=60min， | pH=6.45，Moi=4.37%，SOM=3.45%，sand=19.37%，silt=71.35%，clay=9.28%④ | 96.50 | [ |
阿特拉津 （50mg/kg） | MW/PDS | Power=400W，[PDS]=24mmol/L，T=80℃，t=60min，W/S=1 | — | 97.90 | [ |
| 对硫磷（50mg/kg） | MW/PDS | Power<900W，[PDS]=2mol/L，T=80℃，t=90min，W/S=1/4 | pH=6.8，sand=35.4%，silt=58.8%，clay=5.8% | 90.03 | [ |
| 菲（1000mg/kg） | MW/PDS | Power=480W，[PDS]=50g/L，T=80℃，t=5min，W/S=5 | pH=7.65，SOM≈2.4%，sand=46%，silt=10%，clay=44% | 约96.00 | [ |
2,4-二氯酚 （500mg/kg） | MW/O3 | Power=750W（C）②，[O3]≈3g/h，T≈110℃，t=10min | pH=7.41，SOM=0.71%，sand=29%，silt=14%，clay=57% | 90.50 | [ |
| 蒽（50mg/kg） | MW/O3 | Power=750W(C)，[O3]≈3g/h，T≈110℃，t=10min | pH=7.41，SOM=0.71%，sand=29%，silt=14%，clay=57% | 99.60 | [ |
| 微波协同催化剂-氧化剂体系 | |||||
芘 （50mg/kg） | MW/PDS/β-MnO2 | Power<900W，[PDS]=1.5mol/L，[β-MnO2]=0.10g/5g soil，T=80℃，t=25min，W/S=1/4 | pH=6.8，sand=35.4%，silt=58.8%，clay=5.9% | 81.30 | [ |
芘 （50mg/kg） | MW/PDS/Fe3O4 | [PDS]=1.5mol/L，[Fe3O4]=8g/kg，T=60℃，t=45min，W/S=1/5.6 | pH=6.8，SOM=1.34%，sand=57.1%，silt=34.7%，clay=8.2% | 91.70 | [ |
| 乙基对硫磷（60mg/kg） | MW/PDS/生物炭（Biochar） | [PDS]=23.8g/kg，[Biochar]=30g/kg，T=100℃，t=80min，W/S=1/10 | pH=7.78 | 约95.00 | [ |
毒死蜱 （100mg/kg） | MW/PMS/暖贴固废（HPW） | Power=480W，[PMS]=28.57mmol/kg，[HPW]=10g/kg，T=60℃，t=45min，W/S=1 | pH=7.65，SOM=1.96%，sand=80.27%，silt=12.39%，clay=7.34% | >90.00 | [ |
十溴二苯醚 （20mg/kg） | MW/PDS/Fe@SiC | Power=240W（C），[PDS]=0.5mol/L，[Fe@SiC]=50g/kg，T<95℃，t=20min，W/S=3 | 模拟污染硅藻土 | 90.30 | [ |
| 六氯苯（约167mg/kg） | MW/PDS/Al2O3负载石墨棒 | Power=1100W（C），[PDS]=15g/L，石墨棒尺寸3cm×5cm，t=3min，W/S=2/3 | — | 约89.00 | [ |
| 微波协同高级氧化的其他体系 | |||||
2,4-二氯酚 （500mg/kg） | MW/SiC/nZVI/EDTA | Power=540W，[SiC/nZVI]=2.5g/L，[EDTA]=1.2mmol/L，T=95℃，t=30min，W/S=20 | 模拟污染高岭土 | 约100.00 | [ |
对氯硝基苯 （50mg/kg） | MW/PDS/厌氧 | [PDS]=1.0mol/L，T=60℃，t=60min，W/S=1/5.6 | pH=6.8，SOM=1.34%，sand=57.1%，silt=34.7%，clay=8.2% | 84.30 | [ |
| 污染物 | 微波反应体系 | 最优反应条件 | 土壤性质 | 降解效果/% | 参考文献 |
|---|---|---|---|---|---|
| 微波协同氧化剂体系 | |||||
| 邻苯二甲酸二丁酯（21.7mg/kg） | MW/过碳酸钠 | Power=480W，[SPC]=0.196g/10g土，T=80℃，t=40min，W/S=4/1① | pH=8.36，SOM=1.11% | 85.14 | [ |
毒死蜱 （100mg/kg） | MW/PS | Power=480W，[PS]=28.57mmol/kg，T=80℃（PDS）/60℃（PMS），t=45min，W/S=1 | pH=7.65，SOM=1.96%，sand=80.27%，silt=12.39%，clay=7.34%③ | >90.00 | [ |
乙基对硫磷 （60mg/kg） | MW/PDS | [PDS]=23.8g/kg，T=100℃，t=60min，W/S=1/10 | pH=7.78 | 75.30 | [ |
| 萘 | MW/PDS | [PDS]=1.0mol/L，T=80℃，t=60min， | pH=6.45，Moi=4.37%，SOM=3.45%，sand=19.37%，silt=71.35%，clay=9.28%④ | 96.50 | [ |
阿特拉津 （50mg/kg） | MW/PDS | Power=400W，[PDS]=24mmol/L，T=80℃，t=60min，W/S=1 | — | 97.90 | [ |
| 对硫磷（50mg/kg） | MW/PDS | Power<900W，[PDS]=2mol/L，T=80℃，t=90min，W/S=1/4 | pH=6.8，sand=35.4%，silt=58.8%，clay=5.8% | 90.03 | [ |
| 菲（1000mg/kg） | MW/PDS | Power=480W，[PDS]=50g/L，T=80℃，t=5min，W/S=5 | pH=7.65，SOM≈2.4%，sand=46%，silt=10%，clay=44% | 约96.00 | [ |
2,4-二氯酚 （500mg/kg） | MW/O3 | Power=750W（C）②，[O3]≈3g/h，T≈110℃，t=10min | pH=7.41，SOM=0.71%，sand=29%，silt=14%，clay=57% | 90.50 | [ |
| 蒽（50mg/kg） | MW/O3 | Power=750W(C)，[O3]≈3g/h，T≈110℃，t=10min | pH=7.41，SOM=0.71%，sand=29%，silt=14%，clay=57% | 99.60 | [ |
| 微波协同催化剂-氧化剂体系 | |||||
芘 （50mg/kg） | MW/PDS/β-MnO2 | Power<900W，[PDS]=1.5mol/L，[β-MnO2]=0.10g/5g soil，T=80℃，t=25min，W/S=1/4 | pH=6.8，sand=35.4%，silt=58.8%，clay=5.9% | 81.30 | [ |
芘 （50mg/kg） | MW/PDS/Fe3O4 | [PDS]=1.5mol/L，[Fe3O4]=8g/kg，T=60℃，t=45min，W/S=1/5.6 | pH=6.8，SOM=1.34%，sand=57.1%，silt=34.7%，clay=8.2% | 91.70 | [ |
| 乙基对硫磷（60mg/kg） | MW/PDS/生物炭（Biochar） | [PDS]=23.8g/kg，[Biochar]=30g/kg，T=100℃，t=80min，W/S=1/10 | pH=7.78 | 约95.00 | [ |
毒死蜱 （100mg/kg） | MW/PMS/暖贴固废（HPW） | Power=480W，[PMS]=28.57mmol/kg，[HPW]=10g/kg，T=60℃，t=45min，W/S=1 | pH=7.65，SOM=1.96%，sand=80.27%，silt=12.39%，clay=7.34% | >90.00 | [ |
十溴二苯醚 （20mg/kg） | MW/PDS/Fe@SiC | Power=240W（C），[PDS]=0.5mol/L，[Fe@SiC]=50g/kg，T<95℃，t=20min，W/S=3 | 模拟污染硅藻土 | 90.30 | [ |
| 六氯苯（约167mg/kg） | MW/PDS/Al2O3负载石墨棒 | Power=1100W（C），[PDS]=15g/L，石墨棒尺寸3cm×5cm，t=3min，W/S=2/3 | — | 约89.00 | [ |
| 微波协同高级氧化的其他体系 | |||||
2,4-二氯酚 （500mg/kg） | MW/SiC/nZVI/EDTA | Power=540W，[SiC/nZVI]=2.5g/L，[EDTA]=1.2mmol/L，T=95℃，t=30min，W/S=20 | 模拟污染高岭土 | 约100.00 | [ |
对氯硝基苯 （50mg/kg） | MW/PDS/厌氧 | [PDS]=1.0mol/L，T=60℃，t=60min，W/S=1/5.6 | pH=6.8，SOM=1.34%，sand=57.1%，silt=34.7%，clay=8.2% | 84.30 | [ |
| 微波反应体系 | 主要活性物种 | 氧化电位 | 活性物种寿命 | 其他可能活性物种 | 参考文献 |
|---|---|---|---|---|---|
| MW/PDS | SO4·- | 2.5~3.1V（vs. NHE） | 30~40μs | OH·，O2·-，1O2 | [ |
| MW/PMS | 1O2 | 0.81~2.2V（vs. NHE） | 3.5μs | SO4·-，OH· | [ |
| MW/O3 | O3 | 2.07V（vs. NHE） | 20min | OH· | [ |
| MW/SPC或UHP | CO3·-（SPC），OH· | 1.57~1.78（vs. NHE)（CO3·-） 1.8~2.7V（vs. NHE)（OH·） | 1μs（OH·） — | O2·- | [ |
| 微波反应体系 | 主要活性物种 | 氧化电位 | 活性物种寿命 | 其他可能活性物种 | 参考文献 |
|---|---|---|---|---|---|
| MW/PDS | SO4·- | 2.5~3.1V（vs. NHE） | 30~40μs | OH·，O2·-，1O2 | [ |
| MW/PMS | 1O2 | 0.81~2.2V（vs. NHE） | 3.5μs | SO4·-，OH· | [ |
| MW/O3 | O3 | 2.07V（vs. NHE） | 20min | OH· | [ |
| MW/SPC或UHP | CO3·-（SPC），OH· | 1.57~1.78（vs. NHE)（CO3·-） 1.8~2.7V（vs. NHE)（OH·） | 1μs（OH·） — | O2·- | [ |
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