聚苯胺的合成及机理研究进展

doi:10.16085/j.issn.1000-6613.2016.s1.032

摘要/Abstract

摘要： 聚苯胺是研究较多的共轭聚合物,其合成工艺简单,在电学材料、非线性光学材料、光伏及光电材料等方面都得到很多应用,但合成工艺不断更新,对机理的认识也不断深入。本文回顾了2013-2015年来对聚苯胺合成及机理的最新研究结果,尤其是以二苯胺为基础的聚偶氮苯是以前关于聚苯胺的综述文章未提及的。以二苯胺为基础的聚偶氮苯经掺杂后,显示良好的导电性能,未来在电学材料、光电材料、光伏材料及非线性光学材料等将得到越来越广泛的应用。聚偶氮苯的重氮耦合机理相比聚苯胺的氧化聚合来说,反应机理明确,选择性更强,工艺简单,值得去做进一步研究。

关键词: 聚苯胺, 合成, 聚合, 电化学

Abstract: Polyaniline is the famous conjugated polymer that used widely in rechargeable batteries shielding of electromagnetic interference, microwave and radar absorbing materials, non-linear optical and light-emitting devices, fuel and solar cells.The method of synthesis is devoloping and the mechanism of synthesis is devoloping also.The paper reviews the new research result about the synthesis and mechanism from 2013 to 2015, especially the azo benzene polymer that use dianiline as raw material.The polymer show good conductive capacity after dosing, will be used wildly in rechargeable batteries shielding of electromagnetic interference, microwave and radar absorbing materials, non-linear optical and light-emitting devices, fuel and solar cells.The synthesis mechanism is clear, simple synthesis process, is worth to study further.

Key words: polyaniline, synthesis, polymerization, electrochemistry

中图分类号:

O625.52

胡洪超, 舒绪刚, 崔英德. 聚苯胺的合成及机理研究进展[J]. 化工进展, 2016, 35(S1): 195-201.

HU Hongchao, SHU Xugang, CUI Yingde. Progress in synthesis and mechanism of polyaniline[J]. Chemical Industry and Engineering Progree, 2016, 35(S1): 195-201.

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