热裂解烃制炭黑的机理及工程化技术发展历程

doi:10.16085/j.issn.1000-6613.2023-2295

摘要/Abstract

摘要：

简介人类制造和利用炭黑（CB）的历史和炭黑特性，对烃热解过程中碳原子组成六碳环并历经一维（1D）、二维（2D）和三维（3D）增长形成准石墨微晶（GMC）和最终形成CB粒子的系列参数进行了模拟计算，总结有关CB准石墨微晶结构增长机理、粒子结构及其与粒子硬度和导电性等性能间的关系等方面基础研究的最新成果。基于CB中碳原子结构研究成果和基本理化性能，建议了CB的分子式。结合检测数据解读CB拥有高达30GPa硬度、补强橡胶的活性和独特导电性的结构原因。本文还从键能变化角度计算了用于制造CB的几种典型烃热裂解生成CB的化学反应热，解释CB生产时煤系原料油比石油系原料油收率高10%的原因，重点介绍现代热裂解烃制造CB的工程化技术在原料、反应器、耐火材料、装置大型化、资源综合利用技术与装备等方面取得突破并促成我国成为炭黑制造第一大国的发展历程。对炭黑行业节能环保的最新要求进行了归纳，展望了行业未来，并对其技术进步重点方向和研究内容提出建议。

关键词: 烃类化合物, 热解, 炭黑, 粒子, 聚集, 显微结构

Abstract:

Introduction to the history of human manufacturing and utilization of carbon black (CB) as well as the characteristics of CB, this paper simulated and calculated a series of parameters related to the formation of quasi graphite microcrystals (GMCs) and the final formation of CB particles during the process of hydrocarbon pyrolysis, where carbon atoms formed a six carbon ring and undergo one-dimensional (1D), two-dimensional (2D) and three-dimensional (3D) growth. The latest achievements for the growth mechanism of quasi graphite microcrystals in CB and basic research on particle structure as well as its relationship with properties such as particle hardness and conductivity were introduced. Based on the research results of carbon atomic structure and basic physicochemical properties in CB, the molecular formula of CB was proposed. The structural reasons why CB had a hardness of up to 30GPa, the activity of reinforcing rubber and unique conductivity were interpreted based on testing data. This article also calculated the chemical reaction heat of several typical hydrocarbons used to produce CB through thermal cracking from the perspective of bond energy changes. It explained the reason why the yield of coal-based feedstock oil was 10% higher than that of petroleum based-feedstock oil during CB production. The article focused on introducing the engineering technology of modern hydrocarbons pyrolysis to produce CB in terms of raw materials, reactors, refractory materials, large-scale equipment, comprehensive resource utilization technology with equipment achieved and the development process of China becoming the largest country in CB manufacturing. This article summarized the latest requirements for energy conservation and environmental protection in the CB industry, looked forward to the future of the industry, and put forward suggestions for the key directions and research content of its technological progress.

Key words: hydrocarbons, pyrolysis, carbon black, particle, aggregation, microscopic structure

中图分类号:

TQ-9

王定友, 陈建, 范汝新, 李大舜. 热裂解烃制炭黑的机理及工程化技术发展历程[J]. 化工进展, 2024, 43(7): 3551-3566.

WANG Dingyou, CHEN Jian, FAN Ruxin, LI Dashun. Mechanism and engineering technology development of hydrocarbons pyrolysis to produce carbon black[J]. Chemical Industry and Engineering Progress, 2024, 43(7): 3551-3566.

图/表 20

图1 炭黑技术发展脉络

图2 炭黑的准石墨微晶结构模型

图3 CB聚集体典型结构

图4 CB粒子表面硬度测试

表1 CB粒子表面硬度与粒径

项目	炭黑品种
项目	N115	N330	N550	N660
表面硬度/GPa
1	23.74	53.98	33.96	26.23
2	18.65	27.54	16.16	52.1
3	13.84	14.98	45.15	19.73
4	32.77	16.29	42.44	51.87
5	37.98	39.74	11.39	61.42
6	15.42	34.48	54.4	44.15
7	45.56	15.99	45.99	42.16
8	13.61	41.34	19.48	40.62
均值	25.2	30.5	33.6	42.3
粒径/nm	10~19	26~30	40~48	49~60

图5 石墨中碳原子及结构的增长

表2 C(6+4n)中活性点占比r1ec值

n	r_1ec
1	0.80
2	0.71
3	0.67
4	0.64
5	0.62
6	0.60
7	0.59
8	0.58
9	0.57
10	0.57

表3 C(6+4n)(t+1)中活性点占比r2ec值

n	L_n /nm	r_2ec/%	n	L_n /nm	r_2ec/%
1	0.50	66.9	11	3.0	14.6
2	0.74	49.3	12	3.2	13.6
3	1.0	39.0	13	3.5	12.6
4	1.2	32.3	14	3.7	11.8
5	1.5	27.5	15	4.0	11.1
6	1.7	24.0	16	4.2	10.5
7	2.0	21.3	17	4.5	9.9
8	2.2	19.1	18	4.7	9.4
9	2.5	17.3	19	5.0	9.0
10	2.7	15.9	20	5.2	8.6

图6 C(6+4n)(p+1)的3D增长

表4 GMC的典型参数

n	p	t	L_n /nm	N_3c/个	V₃/nm³	N_3cu/个·nm^-3
1	0	1	0.50	22	0.117	187
2	1	2	0.74	64	0.368	174
3	2	3	0.99	141	0.868	162
4	2	4	1.24	262	1.71	153
5	3	4	1.49	438	2.98	147
6	3	5	1.73	679	4.78	142
7	4	6	1.98	996	7.18	139
8	5	7	2.23	1398	10.3	136
9	5	7	2.48	1896	14.2	133
10	6	8	2.72	2500	19.0	132
11	6	9	2.97	3221	24.8	130
12	7	10	3.22	4068	31.6	129
13	7	10	3.47	5052	39.7	127
14	8	11	3.72	6183	48.9	126
15	9	12	3.96	7471	59.5	126
16	9	13	4.21	8927	71.5	125
17	10	13	4.46	10561	85.1	124
18	10	14	4.71	12383	100	124
19	11	15	4.95	14403	117	123
20	11	16	5.20	16632	136	122

表5 单个CB粒子包含GMC数量（Rb=20nm）

n	N_GMC	n	N_GMC
1	35802	11	169
2	11383	12	133
3	4826	13	106
4	2450	14	86
5	1406	15	70
6	876	16	59
7	583	17	49
8	407	18	42
9	295	19	36
10	220	20	31

图7 CB粒子粒径Rb与体积Vb变化关系

图8 GMC的活性面与惰性面

表6 粒径为Rb的CB粒子中活性点占比rRbec值

R_b/nm	$r R b e c$ /%
5	52.0
10	25.2
20	12.4
30	8.2
40	6.1
50	4.9
60	4.1
70	3.5
80	3.1
90	2.7
100	2.4

表6 粒径为Rb的CB粒子中活性点占比rRbec值

R_b/nm	$r R b e c$ /%
5	52.0
10	25.2
20	12.4
30	8.2
40	6.1
50	4.9
60	4.1
70	3.5
80	3.1
90	2.7
100	2.4

表7 炭黑原料的C含量与原子H/C

项目	沥青	蒽	萘	乙炔	煤焦油	乙烯焦油	催化裂化油浆	乙烯	乙烷	甲烷
C/%	83~87	94.38	93.75	92.31	91.86	91.6	—	85.7	80.0	75
H/C	1.41	0.71	0.80	1.00	0.71	0.88	1.22	2.00	3.00	4.00

表8 C与H的化学键能

化学键	键能/kJ·mol^-1
C—C	332
C $̿$ C	611
C≡≡ C	837
C—H	414
H—H	436

表8 C与H的化学键能

化学键	键能/kJ·mol^-1
C—C	332
C $̿$ C	611
C≡≡ C	837
C—H	414
H—H	436

图9 C10结构

图10 C14结构

表9 典型烃热裂制CB的反应热

序号	烃品种	化学反应式	键能/kJ			反应热（以C计）/kJ·mol^-1
序号	烃品种	化学反应式	反应物	产物	E_△	反应热（以C计）/kJ·mol^-1
1	甲烷	6CH₄→C₆+12H₂	9936	9057	-879	-146.5
2	乙烷	3C₂H₆→C₆+9H₂	8448	7749	-699	-116.5
3	乙烯	3C₂H₄→C₆+6H₂	6801	6441	-360	-60.0
4	萘	C₁₀H₈→C₁₀+4H₂	9687	9447	-240	-24.0
5	蒽油	C₁₄H₁₀→C₁₄+5H₂	13065	12765	-300	-21.4
6	乙炔	3C₂H₂→C₆+3H₂	4995	5133	138	23.0

表10 不同烃原料特点比较

序号	烃种类	能耗	CB产品
序号	烃种类	能耗	产量占比	性能特点	主要用途
1	天然气	高	1%	粒径80~170nm，结构简单，品种单一	填充橡胶并赋予其高伸长率和低硬度，高纯碳源
2	乙炔	低	1%	粒径35~45nm，品种较单一，吸液量大，电阻率较低	在电池、橡塑制品中广泛使用，作工作液保持剂和导电、抗静电、导热、吸波等材料用
3	矿物油	中	98%	粒径10~300nm，品种丰富	橡胶制品（轮胎及管、板、带等）补强、填充、导电剂，高分子材料（塑料、树脂、纤维）等增强与改性剂（抗紫外线老化）、油漆油墨造纸着色剂、特种陶瓷造孔剂等
4	废旧轮胎	较低	5%	—	橡胶制品（轮胎及管、板、带等）补强、填充剂等

参考文献 52

1	李炳炎. 炭黑生产与应用手册[M]. 北京: 化学工业出版社, 2000.
	LI Bingyan. Handbook of carbon black production and application[M], Beijing: Chemical Industry Press, 2000.
2	吴立峰, 丁丽萍. 炭黑应用手册[M]. 北京: 化学工业出版社. 2008.
	WU Lifeng, DING Liping. Carbon Black Application Manual[M]. Beijing: Chemical Industry Press, 2008.
3	丁利虎, 孙鲁光, 陈新中. 炭黑技术产业发展现状研究[J]. 清洗世界, 2021, 37(9): 60-61.
	DING Lihu, SUN Luguang, CHEN Xinzhong. Research on the development status of carbon black technology industry [J]. Clean World, 2021, 37(9): 60-61.
4	熊佳, 黄英, 李鹏, 等. 新型炭黑的发展及其在轮胎工业中的应用[J]. 合成橡胶工业, 2004, 27(6): 388-390.
	XIONG Jia, HUANG Ying, LI Peng, et al. Development of new carbon black and its application in tire industry[J]. Synthetic Rubber Industry, 2004, 27(6): 388-390
5	FAN Y R, FOWLER G D, ZHAO M. The past, present and future of carbon black as a rubber reinforcing filler—A review[J]. Journal of cleaner production, 2020, 247: 119115.
6	道奈, 沃埃特, 王梦蛟. 炭黑[M]. 北京: 化学工业出版社. 1982.
	DONNET J B, VOET A, WANG Mengjiao. Carbon black[M]. Beijing: Chemical Industry Press, 1982.
7	DONNET J B. Structure and reactivity of carbons: from carbon black to carbon composites[J]. Carbon, 1982, 20(4): 267-282.
8	王梦蛟, 张平, Mahmud Khaled, 等. 轮胎用新补强材料的发展[J]. 轮胎工业, 2004, 24(8): 482-488.
	WANG Mengjiao, ZHANG Ping, MAHMUD Khaled, et al. Development of new reinforcement materials for tires[J]. Tire Industry, 2004, 24(8): 482-488.
9	王梦蛟. 填料-弹性体相互作用对填充硫化胶滞后损失、湿摩擦性能和磨耗性能的影响（续一）[J]. 轮胎工业, 2007(11): 648-656.
	WANG Mengjiao. Effects of filler elastomer interaction on hysteresis loss, wet friction performance, and wear performance of filled vulcanized rubber[J]. Tire Industry, 2007(11): 648-656.
10	王梦蛟, 王正, 贾维杰, 等. 橡胶/白炭黑连续液相混炼胶在轮胎中的应用[J]. 橡胶工业, 2023, 70(9): 655-666.
	WANG Mengjiao, WANG Zheng, JIA Weijie, et al. Application of silica-filled masterbatches produced with continuous liquid phase mixing in tires[J]. China Rubber Industry, 2023, 70(9): 655-666.
11	陈建, 金永中. 炭黑结构与活性研究[M]. 北京: 科学出版社, 2018.
	CHEN Jian, JIN Yongzhong. Study on structure and activity of carbon black[M]. Beijing: Science Press, 2018.
12	王定友, 陈建. 炭黑分散体的聚集体间距研究[J], 炭黑工业, 2019(1): 28-29.
	WANG Dingyou, CHEN Jian. Study on aggregation distance of carbon black dispersions[J]. Carbon Black Industry, 2019(1): 28-29.
13	CHEN Jian, HU Maoyuan, QING Long, et al. Study on boundary layer and surface hardness of carbon black in natural rubber using atomic force microscopy[J]. Polymers, 2022, 14(21): 4642.
14	CHEN Jian, HU Maoyuan, LI Yuming, et al. Significant influence of bound rubber thickness on the rubber reinforcement effect[J]. Polymers, 2023, 15(9): 2051.
15	王道宏, 徐亦飞, 张继炎. 炭黑的物化性质及表征[J]. 化学工业与工程, 2002, 19(1): 76-82.
	WANG Daohong, XU Yifei, ZHANG Jiyan. The physicochemical properties and characterization of carbon black[J]. Chemical Industry and Engineering, 2002, 19(1): 76-82.
16	庄清平. 炭黑粒子的表面形貌及其聚集体的纳米力学属性[J]. 橡胶工业, 2006, 53(4): 216-222.
	ZHUANG Qingping. Surface morphology of carbon black particle and nanomechanics of its aggregate[J]. China Rubber Industry, 2006, 53(4): 216-222.
17	KOHJIYA Shinzo, KATOH Atushi, SUDA Toshiya, et al. Visualisation of carbon black networks in rubbery matrix by skeletonisation of 3D-TEM image[J]. Polymer, 2006, 47(10): 3298-3301.
18	ABOUDI I EL, MDARHRI A, BROSSEAU C, et al. Investigating carbon-black-filled polymer composites’ brittleness[J]. Polymer Bulletin, 2020, 77(9): 4959-4969.
19	Marek PÖSCHL, Martin VAŠINA, Petr ZÁDRAPA, et al. Study of carbon black types in SBR rubber: Mechanical and vibration damping properties[J]. Materials, 2020, 13(10): 2394.
20	KUNTI Nitya Narayan, SENGUPTA Ranjan. Reduction of filler-filler interaction and hysteresis loss of carbon black filled rubber compound by using modified carbon Black[J]. Progress in Rubber, Plastics and Recycling Technology, 2023, 39(2): 156-168.
21	WEBER Marcel, MAYER Julian K, KWADE Arno. The carbon black dispersion index DI_CB: A novel approach describing the dispersion progress of carbon black containing battery slurries[J]. Energy Technology, 2023, 11(5): 2201299.
22	VICENTINI Fernando Campanhã, ALMEIDA SILVA Tiago, Orlando FATIBELLO-FILHO. Carbon black electrodes applied in electroanalysis[J]. Current Opinion in Electrochemistry, 2024, 43: 101415.
23	ABDALLAH KHALAF Eyad Sayed. A comparative study for the main properties of silica and carbon black Filled bagasse-styrene butadiene rubber composites[J]. Polymers and Polymer Composites, 2023, 31: 096739112311710.
24	COSTA CORNELLÀ Aleix, HARDMAN David, COSTI Leone, et al. Variable sensitivity multimaterial robotic e-skin combining electronic and ionic conductivity using electrical impedance tomography[J]. Scientific Reports, 2023, 13(1): 20004.
25	JIANG Xu, ZHANG Longlong, WANG Fengyin, et al. Investigation of carbon black production from coal tar via chemical looping pyrolysis[J]. Energy & Fuels, 2016, 30(4): 3535-3540.
26	TOTH Pal, Therese VIKSTRÖM, MOLINDER Roger, et al. Structure of carbon black continuously produced from biomass pyrolysis oil[J]. Green Chemistry, 2018, 20(17): 3981-3992.
27	NORRIS C J, López CERDÁN A, HAAR P TER. Understanding recovered carbon black[J]. Rubber Chemistry and Technology, 2023, 96(2): 196-213.
28	SUGATRI Rana Ida, WIRASADEWA Yudo Chandrasa, SAPUTRO Kurniawan Eko, et al. Recycled carbon black from waste of tire industry: Thermal study[J]. Microsystem Technologies, 2018, 24(1): 749-755.
29	于兴智, 石灵, 张学军, 等. 微波能在废轮胎裂解回收中的工程化应用[J]. 真空电子技术, 2013(6): 83-85.
	YU Xingzhi, SHI Ling, ZHANG Xuejun, et al. The engineering applications of microwave energy pyrolysis in recovery waste tires[J]. Vacuum Electronics, 2013(6): 83-85.
30	乔慧君, 陈亚薇, 刘英俊, 等. 废轮胎裂解炭黑的酸洗改性及其在丁苯橡胶中的应用[J]. 合成橡胶工业, 2016, 39(5): 418-422.
	QIAO Huijun, CHEN Yawei, LIU Yingjun, et al. Pickling modification of pyrolytic carbon black made from waste tire and its application in butadiene-styrene rubber[J]. China Synthetic Rubber Industry, 2016, 39(5): 418-422.
31	OKOYE Chiemeka Onyeka, JONES Isabelle, ZHU Mingming, et al. Manufacturing of carbon black from spent tyre pyrolysis oil—A literature review[J]. Journal of Cleaner Production, 2021, 279: 123336.
32	FAULKNER B P, WEINECKE M. Carbon black production from waste tires[J]. Mining, Metallurgy & Exploration, 2001, 18(4): 215-220.
33	SONG Pan, WAN Chaoying, XIE Yanling, et al. Vegetable derived-oil facilitating carbon black migration from waste tire rubbers and its reinforcement effect[J]. Waste Management, 2018, 78: 238-248.
34	XU Junqing, YU Jiaxue, HE Wenzhi, et al. Wet compounding with pyrolytic carbon black from waste tyre for manufacture of new tyre—A mini review[J]. Waste Management & Research, 2021, 39(12): 1440-1450.
35	TANG L, HUANG H. Thermal plasma pyrolysis of used tires for carbon black recovery[J]. Journal of Materials Science, 2005, 40(14): 3817-3819.
36	KIANI Aida, Rosaria ACOCELLA M, GRANATA Veronica, et al. Green oxidation of carbon black by dry ball milling[J]. ACS Sustainable Chemistry & Engineering, 2022, 10(48): 16019-16026.
37	LASHKAR Vishnu Teja, MINHAS Gurminder, FISHER Geoffrey, et al. Production of greener styrene-butadiene rubber (SBR) composites through partial substitution of carbon black with bi-modal cellulose fibers[J]. Cellulose, 2023, 30(15): 9485-9499.
38	KHAN Aamer, AWAIS Muhammad, MOHSIN Muhammad. Recycling textile waste into innovative carbon black and applications to smart textiles: A sustainable approach[J]. Biomass Conversion and Biorefinery, 2023: 1-16.
39	Drupitha MP, MISRA Manjusri, MOHANTY Amar Kumar. Recent advances on value-added biocarbon preparation by the pyrolysis of renewable and waste biomass, their structure and properties: A move toward an ecofriendly alternative to carbon black[J]. Environmental Science: Advances, 2023, 2(10): 1282-1301.
40	LEE So-Hyeon, KIM Jun-Hyun, PARK Hyun-Ho. Upcycling green carbon black as a reinforcing agent for styrene-butadiene rubber materials[J]. RSC Advances, 2022, 12(47): 30480-30486.
41	黄敬彬. 炭黑生产技术进步五十年[J]. 炭黑工业, 2000(6): 19-29.
	HUANG Jingbin. Fifty years of technological progress in carbon black production[J]. Carbon Black Industry, 2000(6): 19-29.
42	潘宇涵, 徐俊, 赵光杰, 等. 废轮胎梯级热解中试装置开发与产物特性分析[J]. 化工进展, 2023, 42(3): 1240-1247.
	PAN Yuhan, XU Jun, ZHAO Guangjie, et al. Development of pilot-plant for the step pyrolysis of waste tires and analysis of product characteristics[J]. Chemical Industry and Engineering Progress, 2023, 42(3): 1240-1247.
43	范妆新. 中国新工艺炭黑技术的发展[J]. 橡胶工业, 2000, 47(4): 237-242.
	FAN Jianxin. Development of new process carbon black technology in China[J]. Rubber Industry, 2000, 47(4): 237-242.
44	袁景彬, 李岗领, 刘江红. 双切线软质炭黑反应炉内运动状态研究[J]. 广州化工, 2022, 50(23): 163-164.
	YUAN Jingbin, LI Gangling, LIU Jianghong. Study on moving state of double tangent soft carbon black reactor[J]. Guangzhou Chemical Industry, 2022, 50(23): 163-164.
45	张周明, 吴爱军, 王赣华. 高温炭黑反应炉炉衬选材分析[J]. 耐火材料, 1999, 33(5): 286-288, 291.
	ZHANG Zhouming, WU Aijun, WANG Ganhua. Optimization of materials lined on high temperature carbon black reactor[J]. Refractories, 1999, 33(5): 286-288, 291.
46	张海达. 富氧空气技术用于炭黑生产的展望[J]. 炭黑工业, 1994(2): 1-8.
	ZHANG Haida. The prospect of using enriched oxygen air technology for carbon black production in the carbon black industry[J]. 1994(2): 1-8.
47	苏吉春, 高献庭, 毕志虎. 950℃高温空气预热器在炭黑生产中的应用小结[J]. 炭黑工业, 2010(1): 6-7.
	SU Jichun, GAO Xianting, BI Zhihu, et al. Summary of the application of 950℃ high temperature air preheater in carbon black production[J]. Carbon Black Industry, 2010(1): 6-7.
48	黄锡甫, 朱社教, 郑忠东, 等. 年产3万吨炭黑尾气的综合治理与利用[J], 炭黑工业, 2010(2): 1-5.
	HUANG Xifu, ZHU Shejiao, ZHENG Zhongdong, et al. Comprehensive treatment and utilization of carbon black tail gas with an annual production of 30000 tons[J]. Carbon Black Industry, 2010(2): 1-5.
49	张慧明, 牛平波, 林小妍. 炭黑工业烟气余热的回收及利用[J]. 节能, 1996, 15(2): 31-35.
	ZHANG Huiming, NIU Pingbo, LIN Xiaoyan. Recovery and utilization of flue gas waste heat from carbon black industry[J]. Energy Conservation, 1996, 15(2): 31-35.
50	曲波, 魏振文. 炭黑烟气余热的回收利用[J]. 天津化工, 2003, 17(4): 37-38.
	QU Bo, WEI Zhenwen. Recovery and utilization of waste heat from carbon black flue gas[J]. Tianjin Chemical Industry, 2003, 17(4): 37-38.
51	李炳炎. 中国炭黑工业的节能和碳减排[J]. 炭黑工业, 2013(1): 1-6.
	LI Bingyan. Energy conservation and carbon reduction in China's carbon black industry[J]. Carbon Black Industry, 2013(1): 1-6.
52	排污许可证申请与核发技术规范专用化学产品制造工业: [S].
	Application and issuance of pollutant discharge permits, Technical specifications for specialized chemical product manufacturing industry: [S].

[1]	吴琪, 白柏杨, 尹永杰, 马晓迅. 鄂尔多斯褐煤显微组分结构与其热解特性间的关系[J]. 化工进展, 2024, 43(5): 2370-2385.
[2]	黄淄博, 周文静, 魏进家. 基于ReaxFF MD模拟的低阶煤热解产物演化规律及反应机理[J]. 化工进展, 2024, 43(5): 2409-2419.
[3]	刘显哲, 胡振中, 胡大为, 李显, 贺世泽, 赵纯亮, 夏慈良, 吴波, 张小勇, 罗光前, 姚洪. 低阶煤热溶萃取物的配煤炼焦性能[J]. 化工进展, 2024, 43(5): 2420-2427.
[4]	焦锟鹏, 赵子涛, 犹成裔, 莫文龙, 郭凤娇, 杨晓勤, 张书培, 郭佳, 魏贤勇, 樊星, AKRAM Naeem. 五彩湾次烟煤醇解可溶物的组成特征与不溶物的快速热解产物分布[J]. 化工进展, 2024, 43(5): 2449-2462.
[5]	李凯, 魏鹤琳, 左夏华, 杨卫民, 阎华, 安瑛. 水基炭黑-胶原蛋白纳米流体制备及稳定性实验[J]. 化工进展, 2024, 43(4): 1944-1952.
[6]	齐亚兵, 吴子波, 杨清翠. Pickering乳液制备及稳定性研究进展[J]. 化工进展, 2024, 43(4): 2017-2030.
[7]	李开瑞, 高照华, 刘甜甜, 李静, 魏海生. 还原温度调变Rh/FePO₄催化剂喹啉选择加氢性能[J]. 化工进展, 2024, 43(3): 1342-1349.
[8]	刘斌, 王勇军, 吕汪洋, 陈文兴. 高稳定性钛系聚酯催化剂TiOC@SiO₂的制备及应用[J]. 化工进展, 2024, 43(3): 1395-1402.
[9]	杨嘉琪, 巨晓洁, 谢锐, 汪伟, 刘壮, 潘大伟, 褚良银. 光热响应型控释微球的可控制备及其性能[J]. 化工进展, 2024, 43(3): 1474-1483.
[10]	张鑫, 汤吉昀, 陈娟, 宋占龙, 董勇, 姚洪. 高温烟气热解废轮胎过程中痕量金属Cu、Pb的迁移特性分析[J]. 化工进展, 2024, 43(3): 1606-1613.
[11]	王粤, 孙凯, 刘艳, 陈龙, 朱效宇, 许传龙. 基于全局位置迭代PCSS算法的光场PTV气泡跟踪测速方法[J]. 化工进展, 2024, 43(2): 844-854.
[12]	张瑞凯, 张会书, 郑龙云, 曾爱武. CO₂吸收过程中气相分压对Rayleigh对流传质特性的影响[J]. 化工进展, 2024, 43(2): 913-924.
[13]	陈国徽, 王君雷, 李世龙, 李金宇, 徐运飞, 罗俊潇, 王昆. 火焰喷雾热解制备锂离子电池三元正极材料研究进展[J]. 化工进展, 2024, 43(2): 971-983.
[14]	任鹏锟, 仲兆平, 杨宇轩, 张杉, 杜浩然, 李骞. 改性海泡石对污泥热解过程中重金属的控制[J]. 化工进展, 2024, 43(1): 541-550.
[15]	张祚群, 高扬, 白超杰, 薛立新. 二次界面聚合同步反扩散原位生长ZIF-8纳米粒子制备聚酰胺混合基质反渗透（RO）膜[J]. 化工进展, 2023, 42(S1): 364-373.