MOFs及其衍生物在非均相Fenton催化中应用的研究进展

doi:10.16085/j.issn.1000-6613.2022-0064

摘要/Abstract

摘要：

非均相Fenton氧化技术作为高级氧化工艺（AOP）的一种，能够有效解决传统Fenton技术适用pH范围窄、易产生铁污泥、催化剂难回收等问题，但其反应活性受催化剂材料限制。本文介绍了近几年金属有机骨架（MOFs）及其衍生物在非均相Fenton技术中的应用成果，分析了MOFs及其衍生物比表面积大、活性位点丰富、易于结构调控等优点在改善非均相Fenton技术活性位点不足、Fe²⁺/Fe³⁺循环效率低、传质效率差等问题时所发挥的作用，综述了对MOFs进行改性设计以获得高活性催化剂的研究进展，总结了当前应用MOFs作为催化剂材料仍存在的缺陷。未来MOFs催化剂的研究应集中在高活性改性设计及商业化应用这两方面。

关键词: 金属有机骨架, 非均相Fenton反应, 催化剂, 设计, 氧化

Abstract:

As an advanced oxidation process (AOP), heterogeneous Fenton oxidation can effectively solve the problems of traditional Fenton technology, such as narrow applicable pH range, easy to produce iron sludge, and difficult to recover catalyst, but its reaction activity is limited by the catalyst material. This paper introduces the application of MOFs and its derivatives in heterogeneous Fenton technology in recent years. The advantages of MOFs and their derivatives, such as large specific surface area, abundant active sites, and easy structural control, which could improve the bottlenecks of the heterogeneous Fenton technology, such as insufficient active sites, low Fe²⁺/Fe³⁺ cycle efficiency, and poor mass transfer efficiency, were analyzed. This work summarizes the research progress on modifying MOFs to obtain high activity catalysts, and points out the shortcomings of the current application of MOFs as catalyst materials. In the future, MOFs catalyst researches should focus on modification design for high activity and their commercial application.

Key words: metal organic frameworks, heterogeneous Fenton reaction, catalyst, design, oxidation

中图分类号:

X132

李航, 杨鸿辉, 石博方, 延卫. MOFs及其衍生物在非均相Fenton催化中应用的研究进展[J]. 化工进展, 2022, 41(11): 5811-5819.

LI Hang, YANG Honghui, SHI Bofang, YAN Wei. Research progress on the application of MOFs and their derivatives in heterogeneous Fenton catalysis[J]. Chemical Industry and Engineering Progress, 2022, 41(11): 5811-5819.

图/表 7

图1 通过双位MIL-101（Fe，Co）类Fenton降解增强CIP机理示意图[38]

图2 MOF衍生磁性多孔Fe3O4/C八面体制备过程示意图[63]

图3 卵壳Pd@Fe3O4@MOFs降解TCP的可能机理[64]

图4 在MIL-101/H2O2 /可见光系统中去除TC-HCl的模拟反应机理示意图[65]

图5 Fe3O4@GO@MIL-100(Fe)催化降解2，4-二氯酚的机理[70]

图6 基于吸附和非均相Fenton氧化协同的NH2-MIL-88B去除培氟沙星的机理[74]

图7 在MOFs材料中掺杂三聚氰胺机理说明[75]

参考文献 80

1	HAN Dongmei, CURRELL Matthew J, CAO Guoliang. Deep challenges for China’s war on water pollution[J]. Environmental Pollution, 2016, 218: 1222-1233.
2	ZENG Guangming, CHEN Ming, ZENG Zhuotong. Shale gas: surface water also at risk[J]. Nature, 2013, 499(7457): 154.
3	SCHWARZENBACH René P, EGLI Thomas, HOFSTETTER Thomas B, et al. Global water pollution and human health[J]. Annual Review of Environment and Resources, 2010, 35(1): 109-136.
4	陶洋, 张璨, 孙永军. 非均相类Fenton技术研究进展[J]. 山东化工, 2020, 49(9): 66-68.
	TAO Yang, ZHANG Can, SUN Yongjun. Optimization of heterogeneous Fenton-like processes[J]. Shandong Chemical Industry, 2020, 49(9): 66-68.
5	SPONGBERG Alison L, WITTER Jason D, ACUNA J, et al. Reconnaissance of selected PPCP compounds in Costa Rican surface waters[J]. Water Research, 2011, 45(20): 6709-6717.
6	CHENG Min, ZENG Guangming, HUANG Danlian, et al. Combined biological removal of methylene blue from aqueous solutions using rice straw and Phanerochaete chrysosporium [J]. Applied Microbiology and Biotechnology, 2015, 99(12): 5247-5256.
7	MARTINEZ-HUITLE Carlos A, RODRIGO Manuel A, SIRES Ignasi, et al. Single and coupled electrochemical processes and reactors for the abatement of organic water pollutants: a critical review[J]. Chemical Reviews, 2015, 115(24): 13362-13407.
8	BAO Lianjun, MARUYA Keith A, SNYDER Shane A, et al. China’s water pollution by persistent organic pollutants[J]. Environmental Pollution, 2012, 163: 100-108.
9	VELLINGIRI Kowsalya, PHILIP Ligy, KIM Ki Hyun. Metal-organic frameworks as media for the catalytic degradation of chemical warfare agents[J]. Coordination Chemistry Reviews, 2017, 353: 159-179.
10	CHENG Min, ZENG Guangming, HUANG Danlian, et al. High adsorption of methylene blue by salicylic acid-methanol modified steel converter slag and evaluation of its mechanism[J]. Journal of Colloid and Interface Science, 2018, 515: 232-239.
11	POJANA Giulio, GOMIERO Alessio, JONKERS Niels, et al. Natural and synthetic endocrine disrupting compounds (EDCs) in water, sediment and biota of a coastal lagoon[J]. Environment International, 2007, 33(7): 929-936.
12	ZHOU Chengyun, LAI Cui, XU Piao, et al. In situ grown AgI/Bi₁₂O₁₇Cl₂ heterojunction photocatalysts for visible light degradation of sulfamethazine: efficiency, pathway, and mechanism[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(3): 4174-4184.
13	HU Chanjuan, HUANG Danlian, ZENG Guangming, et al. The combination of Fenton process and Phanerochaete chrysosporium for the removal of bisphenol A in river sediments: mechanism related to extracellular enzyme, organic acid and iron[J]. Chemical Engineering Journal, 2018, 338: 432-439.
14	JU Yongming, YU Yunjiang, WANG Xiaoyan, et al. Environmental application of millimetre-scale sponge iron (s-Fe⁰) particles (Ⅳ): new insights into visible light photo-Fenton-like process with optimum dosage of H₂O₂ and RhB photosensitizers[J]. Journal of Hazardous Materials, 2017, 323: 611-620.
15	KHAN Javed Ali, HE Xuexiang, KHAN Hasan M, et al. Oxidative degradation of atrazine in aqueous solution by UV/H₂O₂/Fe²⁺, UV/S₂O₈ ^2-/Fe²⁺ and UV/HSO₅ ^-/Fe²⁺ processes: a comparative study[J]. Chemical Engineering Journal, 2013, 218: 376-383.
16	GENG Nannan, CHEN Wei, XU Hang, et al. Insights into the novel application of Fe-MOFs in ultrasound-assisted heterogeneous Fenton system: efficiency, kinetics and mechanism[J]. Ultrasonics Sonochemistry, 2021, 72: 105411.
17	MAROUDAS Antonis, PANDIS Pavlos K, CHATZOPOULOU Anastasia, et al. Synergetic decolorization of azo dyes using ultrasounds, photocatalysis and photo-Fenton reaction[J]. Ultrasonics Sonochemistry, 2021, 71: 105367.
18	张森, 郑莹, 韩仕强, 等. 低频超声驱动BaTiO₃压电-芬顿体系降解水中卡马西平[J]. 净水技术, 2020, 39(7): 130-138.
	ZHANG Sen, ZHENG Ying, HAN Shiqiang, et al. Degradation of carbamazepine in water by piezo-Fenton process based on BaTiO₃ driven with low frequency ultrasound[J]. Water Purification Technology, 2020, 39(7): 130-138.
19	REN Gengbo, ZHOU Minghua, LIU Mengmeng, et al. A novel vertical-flow electro-Fenton reactor for organic wastewater treatment[J]. Chemical Engineering Journal, 2016, 298: 55-67.
20	DAVARNEJAD Reza, AZIZI Jamal. Alcoholic wastewater treatment using electro-Fenton technique modified by Fe₂O₃ nanoparticles[J]. Journal of Environmental Chemical Engineering, 2016, 4(2): 2342-2349.
21	LE Thi Xuan Huong, BECHELANY Mikhael, LACOUR Stella, et al. High removal efficiency of dye pollutants by electron-Fenton process using a graphene based cathode[J]. Carbon, 2015, 94: 1003-1011.
22	GULKAYA Ipek, SURUCU Gulerman A, DILEK Filiz B. Importance of H₂O₂/Fe²⁺ ratio in Fenton’s treatment of a carpet dyeing wastewater[J]. Journal of Hazardous Materials, 2006, 136(3): 763-769.
23	KLAMERTH N, MALATO S, AGÜERA A, et al. Photo-Fenton and modified photo-Fenton at neutral pH for the treatment of emerging contaminants in wastewater treatment plant effluents: a comparison[J]. Water Research, 2013, 47(2): 833-840.
24	MIRZAEI Amir, CHEN Zhi, HAGHIGHAT Fariborz, et al. Removal of pharmaceuticals from water by homo/heterogonous Fenton-type processes—A review[J]. Chemosphere, 2017, 174: 665-688.
25	ZHANG Xinyue, DING Yaobin, TANG Heqing, et al. Degradation of bisphenol A by hydrogen peroxide activated with CuFeO₂ microparticles as a heterogeneous Fenton-like catalyst: efficiency, stability and mechanism[J]. Chemical Engineering Journal, 2014, 236: 251-262.
26	MUNOZ Macarena, DE PEDRO Zahara M, CASAS Jose A, et al. Preparation of magnetite-based catalysts and their application in heterogeneous Fenton oxidation—A review[J]. Applied Catalysis B: Environmental, 2015, 176/177: 249-265.
27	LU Sen, LIU Libing, DEMISSIE Hailu, et al. Design and application of metal-organic frameworks and derivatives as heterogeneous Fenton-like catalysts for organic wastewater treatment: a review[J]. Environment International, 2021, 146: 106273.
28	ZHENG Haoquan, ZHANG Yuning, LIU Leifeng, et al. One-pot synthesis of metal-organic frameworks with encapsulated target molecules and their applications for controlled drug delivery[J]. Journal of the American Chemical Society, 2016, 138(3): 962-968.
29	YUAN Shuai, SUN Xing, PANG Jiandong, et al. PCN-250 under pressure: sequential phase transformation and the implications for MOF densification[J]. Joule, 2017, 1(4): 806-815.
30	LIU Yang, LIU Gongping, ZHANG Chen, et al. Enhanced CO₂/CH₄ separation performance of a mixed matrix membrane based on tailored MOF-polymer formulations[J]. Advanced Science, 2018, 5(9): 1800982.
31	HOU Chunchao, XU Qiang. Metal-organic frameworks for energy[J]. Advanced Energy Materials, 2019, 9(23): 1801307.
32	DU Miao, LI Chengpeng, LIU Chunsen, et al. Design and construction of coordination polymers with mixed-ligand synthetic strategy[J]. Coordination Chemistry Reviews, 2013, 257(7/8): 1282-1305.
33	YIN Zheng, WAN Shuang, YANG Jian, et al. Recent advances in post-synthetic modification of metal-organic frameworks: new types and tandem reactions[J]. Coordination Chemistry Reviews, 2019, 378: 500-512.
34	YAGHI O M, LI Hailian. Hydrothermal synthesis of a metal-organic framework containing large rectangular channels[J]. Journal of the American Chemical Society, 1995, 117(41): 10401-10402.
35	CORMA A, GARCÍA H, XAMENA F X Llabrés I. Engineering metal organic frameworks for heterogeneous catalysis[J]. Chemical Reviews, 2010, 110(8): 4606-4655.
36	HAQUE Enamul, Jong Won JUN, JHUNG Sung Hwa. Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235)[J]. Journal of Hazardous Materials, 2011, 185(1): 507-511.
37	LI Yuanyuan, JIANG Jun, FANG Yu, et al. TiO₂ nanoparticles anchored onto the metal-organic framework NH₂-MIL-88B(Fe) as an adsorptive photocatalyst with enhanced Fenton-like degradation of organic pollutants under visible light irradiation[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(12): 16186-16197.
38	MEEK Scott T, GREATHOUSE Jeffery A, ALLENDORF Mark D. Metal-organic frameworks: a rapidly growing class of versatile nanoporous materials[J]. Advanced Materials, 2011, 23(2): 249-267.
39	ZHOU Yinxi, SONG Jinliang, LIANG Shuguang, et al. Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification[J]. Journal of Molecular Catalysis A: Chemical, 2009, 308(1/2): 68-72.
40	MURRAY Leslie J, DINCA Mircea, LONG Jeffrey R. Hydrogen storage in metal-organic frameworks[J]. Chemical Society Reviews, 2009, 38(5): 1294-1314.
41	DHAKSHINAMOORTHY Amarajothi, ASIRI Abdullah M, GARCIA Hermenegildo. Catalysis by metal-organic frameworks in water[J]. Chemical Communications, 2014, 50(85): 12800-12814.
42	LIANG He, LIU Ruiping, HU Chengzhi, et al. Synergistic effect of dual sites on bimetal-organic frameworks for highly efficient peroxide activation[J]. Journal of Hazardous Materials, 2021, 406: 124692.
43	GAO Cong, CHEN Shuo, QUAN Xie, et al. Enhanced Fenton-like catalysis by iron-based metal organic frameworks for degradation of organic pollutants[J]. Journal of Catalysis, 2017, 356: 125-132.
44	MA Mingyan, NOEI Heshmat, MIENERT Bernd, et al. Iron metal-organic frameworks MIL-88B and NH₂-MIL-88B for the loading and delivery of the gasotransmitter carbon monoxide[J]. Chemistry (Weinheim an Der Bergstrasse, Germany), 2013, 19(21): 6785-6790.
45	HORCAJADA Patricia, SALLES Fabrice, WUTTKE Stefan, et al. How linker’s modification controls swelling properties of highly flexible iron(Ⅲ) dicarboxylates MIL-88[J]. Journal of the American Chemical Society, 2011, 133(44): 17839-17847.
46	VERMOORTELE Frederik, AMELOOT Rob, ALAERTS Luc, et al. Tuning the catalytic performance of metal-organic frameworks in fine chemistry by active site engineering[J]. Journal of Materials Chemistry, 2012, 22(20): 10313-10321.
47	LI Yue, LIU Huan, LI Wenjuan, et al. A nanoscale Fe(Ⅱ) metal-organic framework with a bipyridinedicarboxylate ligand as a high performance heterogeneous Fenton catalyst[J]. RSC Advances, 2016, 6(8): 6756-6760.
48	LI Xuning, WANG Zhaohui, ZHANG Bo, et al. Fe _x Co_3- _x O₄ nanocages derived from nanoscale metal-organic frameworks for removal of bisphenol A by activation of peroxymonosulfate[J]. Applied Catalysis B: Environmental, 2016, 181: 788-799.
49	WANG Chongchen, LI Jianrong, Xiuliang LYU, et al. Photocatalytic organic pollutants degradation in metal-organic frameworks[J]. Energy & Environmental Science, 2014, 7(9): 2831-2867.
50	DHAKSHINAMOORTHY Amarajothi, ASIRI Abdullah M, GARCIA Hermenegildo. Metal organic frameworks as versatile hosts of Au nanoparticles in heterogeneous catalysis[J]. ACS Catalysis, 2017, 7(4): 2896-2919.
51	DHAKSHINAMOORTHY Amarajothi, ASIRI Abdullah M, Hermenegildo GARCÍA. Metal-organic framework (MOF) compounds: photocatalysts for redox reactions and solar fuel production[J]. Angewandte Chemie International Edition, 2016, 55(18): 5414-5445.
52	WANG Jinliang, WANG Cheng, LIN Wenbin. Metal-organic frameworks for light harvesting and photocatalysis[J]. ACS Catalysis, 2012, 2(12): 2630-2640.
53	WANG Dengke, HUANG Renkun, LIU Wenjun, et al. Fe-based MOFs for photocatalytic CO₂ reduction: role of coordination unsaturated sites and dual excitation pathways[J]. ACS Catalysis, 2014, 4(12): 4254-4260.
54	WANG Qibao, JING Ziyan, HU Xiangming, et al. Synthesis, structure, and heterogeneous Fenton reaction of new Cu(Ⅱ)-based discrete Cu₂L _x coordination complexes[J]. CrystEngComm, 2021, 23(1): 216-220.
55	HANG Jing, YI Xiaohong, WANG Chongchen, et al. Heterogeneous photo-Fenton degradation toward sulfonamide matrix over magnetic Fe₃S₄derived from MIL-100(Fe)[J]. Journal of Hazardous Materials, 2022, 424: 127415.
56	DREYER Daniel R, PARK Sungjin, BIELAWSKI Christopher W, et al. The chemistry of graphene oxide[J]. Chemical Society Reviews, 2010, 39(1): 228-240.
57	PETIT Camille, BANDOSZ Teresa J. MOF-graphite oxide composites: combining the uniqueness of graphene layers and metal-organic frameworks[J]. Advanced Materials, 2009, 21(46): 4753-4757.
58	ZHANG Yang, LI Gang, LU Hong, et al. Synthesis, characterization and photocatalytic properties of MIL-53(Fe)-graphene hybrid materials[J]. RSC Advances, 2014, 4(15): 7594-7600.
59	JAHAN Maryam, BAO Qiaoliang, YANG Jiaxiang, et al. Structure-directing role of graphene in the synthesis of metal-organic framework nanowire[J]. Journal of the American Chemical Society, 2010, 132(41): 14487-14495.
60	ROSTAMNIA Sadegh, ALAMGHOLILOO Hassan, LIU Xiao. Pd-grafted open metal site copper-benzene-1, 4-dicarboxylate metal organic frameworks (Cu-BDC MOF’s) as promising interfacial catalysts for sustainable Suzuki coupling[J]. Journal of Colloid and Interface Science, 2016, 469: 310-317.
61	LU Xuefeng, GU Linfei, WANG Jiawei, et al. Bimetal-organic framework derived CoFe₂O₄/C porous hybrid nanorod arrays as high-performance electrocatalysts for oxygen evolution reaction[J]. Advanced Materials, 2017, 29(3): 1604437.
62	PAN Yue, JIANG Songshan, XIONG Wei, et al. Supported CuO catalysts on metal-organic framework (Cu-UiO-66) for efficient catalytic wet peroxide oxidation of 4-chlorophenol in wastewater[J]. Microporous and Mesoporous Materials, 2020, 291: 109703.
63	LI Wenhui, WU Xiaofeng, LI Shuangde, et al. Magnetic porous Fe₃O₄/carbon octahedra derived from iron-based metal-organic framework as heterogeneous Fenton-like catalyst[J]. Applied Surface Science, 2018, 436: 252-262.
64	NIU Hongyun, ZHENG Yang, WANG Saihua, et al. Continuous generation of hydroxyl radicals for highly efficient elimination of chlorophenols and phenols catalyzed by heterogeneous Fenton-like catalysts yolk/shell Pd@Fe₃O₄@metal organic frameworks[J]. Journal of Hazardous Materials, 2018, 346: 174-183.
65	WU Qiangshun, YANG Hanpei, KANG Li, et al. Fe-based metal-organic frameworks as Fenton-like catalysts for highly efficient degradation of tetracycline hydrochloride over a wide pH range: acceleration of Fe(Ⅱ)/Fe(Ⅲ) cycle under visible light irradiation[J]. Applied Catalysis B: Environmental, 2020, 263: 118282.
66	PENG Jianbiao, XUE Jie, LI Jianhua, et al. Catalytic effect of low concentration carboxylated multi-walled carbon nanotubes on the oxidation of disinfectants with Cl-substituted structure by a Fenton-like system[J]. Chemical Engineering Journal, 2017, 321: 325-334.
67	YANG Zhichao, YU Anqing, SHAN Chao, et al. Enhanced Fe(Ⅲ)-mediated Fenton oxidation of atrazine in the presence of functionalized multi-walled carbon nanotubes[J]. Water Research, 2018, 137: 37-46.
68	ZHANG Hang, CHEN Shuo, ZHANG Haiguang, et al. Carbon nanotubes-incorporated MIL-88B-Fe as highly efficient Fenton-like catalyst for degradation of organic pollutants[J]. Frontiers of Environmental Science & Engineering, 2019, 13(2): 1-11.
69	GAO Cong, SU Yan, QUAN Xie, et al. Electronic modulation of iron-bearing heterogeneous catalysts to accelerate Fe(Ⅲ)/Fe(Ⅱ) redox cycle for highly efficient Fenton-like catalysis[J]. Applied Catalysis B: Environmental, 2020, 276: 119016.
70	GONG Qingjiao, LIU Yun, DANG Zhi. Core-shell structured Fe₃O₄@GO@MIL-100(Fe) magnetic nanoparticles as heterogeneous photo-Fenton catalyst for 2,4-dichlorophenol degradation under visible light[J]. Journal of Hazardous Materials, 2019, 371: 677-686.
71	TANG Juntao, WANG Jianlong. MOF-derived three-dimensional flower-like FeCu@C composite as an efficient Fenton-like catalyst for sulfamethazine degradation[J]. Chemical Engineering Journal, 2019, 375: 122007.
72	ZHANG Yuwei, LIU Fei, YANG Zhichao, et al. Weakly hydrophobic nanoconfinement by graphene aerogels greatly enhances the reactivity and ambient stability of reactivity of MIL-101-Fe in Fenton-like reaction[J]. Nano Research, 2021, 14(7): 2383-2389.
73	LI Baojun, CAO Huaqiang. ZnO@graphene composite with enhanced performance for the removal of dye from water[J]. Journal of Materials Chemistry, 2011, 21(10): 3346-3349.
74	MA Huijing, YU Bing, WANG Qingping, et al. Enhanced removal of pefloxacin from aqueous solution by adsorption and Fenton-like oxidation using NH₂-MIL-88B[J]. Journal of Colloid and Interface Science, 2021, 583: 279-287.
75	YIN Na, WANG Ke, XIA Yi’an, et al. Novel melamine modified metal-organic frameworks for remarkably high removal of heavy metal Pb (Ⅱ)[J]. Desalination, 2018, 430: 120-127.
76	JIANG Yuanyuan, NI Pengjuan, CHEN Chuanxia, et al. Selective electrochemical H₂O₂ production through two-electron oxygen electrochemistry[J]. Advanced Energy Materials, 2018, 8(31): 1801909.
77	ZHANG Danyu, LIU Tongcai, YIN Kai, et al. Selective H₂O₂ production on N-doped porous carbon from direct carbonization of metal organic frameworks for electro-Fenton mineralization of antibiotics[J]. Chemical Engineering Journal, 2020, 383: 123184.
78	TANG Juntao, WANG Jianlong. Fe-based metal organic framework/graphene oxide composite as an efficient catalyst for Fenton-like degradation of methyl orange[J]. RSC Advances, 2017, 7(80): 50829-50837.
79	WU Yan, LUO Hanjin, WANG Hou. Synthesis of iron(Ⅲ)-based metal-organic framework/graphene oxide composites with increased photocatalytic performance for dye degradation[J]. RSC Advances, 2014, 4(76): 40435-40438.
80	ANGAMUTHU M, SATISHKUMAR G, LANDAU M V. Precisely controlled encapsulation of Fe₃O₄ nanoparticles in mesoporous carbon nanodisk using iron based MOF precursor for effective dye removal[J]. Microporous and Mesoporous Materials, 2017, 251: 58-68.

[1]	杨寒月, 孔令真, 陈家庆, 孙欢, 宋家恺, 王思诚, 孔标. 微气泡型下向流管式气液接触器脱碳性能[J]. 化工进展, 2023, 42(S1): 197-204.
[2]	徐晨阳, 都健, 张磊. 基于图神经网络的化学反应优劣评价[J]. 化工进展, 2023, 42(S1): 205-212.
[3]	杨建平. 降低HPPO装置反应系统原料消耗的PSE[J]. 化工进展, 2023, 42(S1): 21-32.
[4]	王福安. 300kt/a环氧丙烷工艺反应器降耗减排分析[J]. 化工进展, 2023, 42(S1): 213-218.
[5]	王胜岩, 邓帅, 赵睿恺. 变电吸附二氧化碳捕集技术研究进展[J]. 化工进展, 2023, 42(S1): 233-245.
[6]	陈匡胤, 李蕊兰, 童杨, 沈建华. 质子交换膜燃料电池气体扩散层结构与设计研究进展[J]. 化工进展, 2023, 42(S1): 246-259.
[7]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[8]	时永兴, 林刚, 孙晓航, 蒋韦庚, 乔大伟, 颜彬航. 二氧化碳加氢制甲醇过程中铜基催化剂活性位点研究进展[J]. 化工进展, 2023, 42(S1): 287-298.
[9]	谢璐垚, 陈崧哲, 王来军, 张平. 用于SO₂去极化电解制氢的铂基催化剂[J]. 化工进展, 2023, 42(S1): 299-309.
[10]	杨霞珍, 彭伊凡, 刘化章, 霍超. 熔铁催化剂活性相的调控及其费托反应性能[J]. 化工进展, 2023, 42(S1): 310-318.
[11]	郑谦, 官修帅, 靳山彪, 张长明, 张小超. 铈锆固溶体Ce_0.25Zr_0.75O₂光热协同催化CO₂与甲醇合成DMC[J]. 化工进展, 2023, 42(S1): 319-327.
[12]	戴欢涛, 曹苓玉, 游新秀, 徐浩亮, 汪涛, 项玮, 张学杨. 木质素浸渍柚子皮生物炭吸附CO₂特性[J]. 化工进展, 2023, 42(S1): 356-363.
[13]	高雨飞, 鲁金凤. 非均相催化臭氧氧化作用机理研究进展[J]. 化工进展, 2023, 42(S1): 430-438.
[14]	王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497.
[15]	顾永正, 张永生. HBr改性飞灰对Hg⁰的动态吸附及动力学模型[J]. 化工进展, 2023, 42(S1): 498-509.