特殊形貌g-C3N4基光催化材料的研究进展

doi:10.16085/j.issn.1000-6613.2018-1160

化工进展 ›› 2019, Vol. 38 ›› Issue (01): 495-504.DOI: 10.16085/j.issn.1000-6613.2018-1160

特殊形貌g-C₃N₄基光催化材料的研究进展

杨冬^1,²(),周致远¹,丁菲^3,⁴,赵旭阳¹,陈瑶^3,⁴,姜忠义^3,⁴()

1. 天津大学化工学院系统生物工程教育部重点实验室，天津 300354
2. 天津大学环境科学与工程学院，天津 300354
3. 天津大学化工学院绿色化学化工教育部重点实验室，天津 300354
4. 天津化学化工协同创新中心，天津 300072

收稿日期:2018-06-03 修回日期:2018-08-24 出版日期:2019-01-05 发布日期:2019-01-05
通讯作者: 姜忠义
作者简介:杨冬（1973—），男，副教授，硕士生导师，研究方向为光催化。E-mail：<email>dongyang@tju.edu.cn</email>。|姜忠义，教授，博士生导师，研究方向为光催化。E-mail：<email>zhyjiang@tju.edu.cn</email>。
基金资助:
国家自然科学基金创新研究群体项目(21621004);国家自然科学基金创新研究群体项目（21621004）。

Research advances of g-C₃N₄-based photocatalytic materials with special morphologies

Dong YANG^1,²(),Zhiyuan ZHOU¹,Fei DING^3,⁴,Xuyang ZHAO¹,Yao CHEN^3,⁴,Zhongyi JIANG^3,⁴()

1. Key Laboratory of Systems Bioengineering of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300354, China
2. School of Environmental Science and Engineering, Tianjin University, Tianjin 300354, China
3. Key Laboratory for Green Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300354, China
4. Collaborative Innovation Center of Chemical Science and Engineering Tianjin, Tianjin 300072, China

Received:2018-06-03 Revised:2018-08-24 Online:2019-01-05 Published:2019-01-05
Contact: Zhongyi JIANG

摘要/Abstract

摘要：

特殊形貌石墨相氮化碳（g-C₃N₄）基材料具有多级结构、可调变的短程电子传递路径等特点，能较好地解决传统g-C₃N₄基材料存在的比表面积小、可见光利用效率低以及光生载流子易复合等问题，因而具有广阔的发展前景和应用潜力。本文对管/棒/阵列、多孔微球、凝胶和仿生形貌等特殊形貌g-C₃N₄基光催化材料的研究进展进行了系统评述，并对该类材料的形貌与催化功能之间的构效关系进行了分析和总结。指出目前该类材料的研究尚处于起步阶段，还存在着形貌数量种类偏少、合成方法较少、构效关系认识不够深入等问题。因此，该领域未来应该在拓展形貌种类、调控能带位置、光生载流子转移机理和分子模拟等方面进行深入研究，为高性能光催化剂的研制提供更好的思路。

关键词: 石墨相氮化碳, 催化剂, 太阳能, 聚合物

Abstract:

The g-C₃N₄-based materials with special morphologies have the characteristics of hierarchical structure and adjustable short-range electron transfer pathway etc., and thus could well overcome the problems of traditional g-C₃N₄-based materials such as small specific surface area, low visible-light utilization efficiency, and high recombination rate of photo-generated carriers. Consequently, they demonstrate broad development prospect and great application potential in the photocatalysis field. This review highlights the recent advances of g-C₃N₄-based materials with special morphologies, such as tube/rod/array, porous microsphere, gel and biomimetic morphology, and discusses the structure-function relationship between their morphologies and the photocatalytic performance. At present, the research for this kind of materials is in their infancy and they still exhibit a few problems, such as limited morphology types, few synthetic methods and insufficient understanding of the structure-function relationship. Therefore, the investigation should be focused on the expansion of the morphology type, regulation of the energy band position, the transfer mechanism of photo-generated carriers and the molecular modeling in the future, so as to afford better ideas for the exploration of high-performance photocatalytic materials.

Key words: graphitic carbon nitride, catalyst, solar energy, polymers

中图分类号:

O643

杨冬, 周致远, 丁菲, 赵旭阳, 陈瑶, 姜忠义. 特殊形貌g-C₃N₄基光催化材料的研究进展[J]. 化工进展, 2019, 38(01): 495-504.

Dong YANG, Zhiyuan ZHOU, Fei DING, Xuyang ZHAO, Yao CHEN, Zhongyi JIANG. Research advances of g-C₃N₄-based photocatalytic materials with special morphologies[J]. Chemical Industry and Engineering Progress, 2019, 38(01): 495-504.

图/表 10

参考文献 65

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催化剂种类	制备方法	形貌	应用领域	光催化活性	参考文献
g-C₃N₄	热聚合	体相	产氢	12μmol·h^-1	Wang等^[7]
g-C₃N₄	模板法	手性纳米棒	产氢	74 μmol·h^-1	Zheng等^[34]
g-C₃N₄	自组装	氮缺陷纳米管	产氢	118.5μmol·h^-1	Mo等^[37]
g-C₃N₄	水热合成	自掺杂六棱形微管	产氢	1575μmol·h^-1·g^-1	Tong等^[39]
g-C₃N₄/InVO₄	无模板法	纳米棒/空心球	降解抗生素	体相g-C₃N₄降解速率的2.5倍	You等^[40]
g-C₃N₄	微波加热	金字塔阵列	降解罗丹明B	脱色率99.5%（2h）	Yu等^[42]
g-C₃N₄	模板法	多孔微球	产氢	157μmol·h^-1	Zhao等^[45]
g-C₃N₄	模板法	多壳层微囊	产氢	630μmol·h·^-1·g^-1	Tong等^[48]
g-C₃N₄	水热合成	凝胶	性能研究	氧化还原能力增强	Zeng等^[55]
g-C₃N₄/GO	水热合成	凝胶	降解甲基橙	去除率92%（4h）	Tong等^[56]
g-C₃N₄ /GO	超声化学	凝胶	去除NO	NO去除率为64.9%和60.7%	Li等^[59]
g-C₃N₄	无模板法	磷掺杂纳米花	产氢	104μmol·h^-1	Zhu等^[60]
g-C₃N₄/C	超分子组装	微米花	性能研究	高析氧反应活性	Tong等^[61]
g-C₃N₄	热结晶	树状结构	产氢	178μmol·h^-1	Song等^[65]

催化剂种类	制备方法	形貌	应用领域	光催化活性	参考文献
g-C₃N₄	热聚合	体相	产氢	12μmol·h^-1	Wang等^[7]
g-C₃N₄	模板法	手性纳米棒	产氢	74 μmol·h^-1	Zheng等^[34]
g-C₃N₄	自组装	氮缺陷纳米管	产氢	118.5μmol·h^-1	Mo等^[37]
g-C₃N₄	水热合成	自掺杂六棱形微管	产氢	1575μmol·h^-1·g^-1	Tong等^[39]
g-C₃N₄/InVO₄	无模板法	纳米棒/空心球	降解抗生素	体相g-C₃N₄降解速率的2.5倍	You等^[40]
g-C₃N₄	微波加热	金字塔阵列	降解罗丹明B	脱色率99.5%（2h）	Yu等^[42]
g-C₃N₄	模板法	多孔微球	产氢	157μmol·h^-1	Zhao等^[45]
g-C₃N₄	模板法	多壳层微囊	产氢	630μmol·h·^-1·g^-1	Tong等^[48]
g-C₃N₄	水热合成	凝胶	性能研究	氧化还原能力增强	Zeng等^[55]
g-C₃N₄/GO	水热合成	凝胶	降解甲基橙	去除率92%（4h）	Tong等^[56]
g-C₃N₄ /GO	超声化学	凝胶	去除NO	NO去除率为64.9%和60.7%	Li等^[59]
g-C₃N₄	无模板法	磷掺杂纳米花	产氢	104μmol·h^-1	Zhu等^[60]
g-C₃N₄/C	超分子组装	微米花	性能研究	高析氧反应活性	Tong等^[61]
g-C₃N₄	热结晶	树状结构	产氢	178μmol·h^-1	Song等^[65]

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特殊形貌g-C₃N₄基光催化材料的研究进展

Research advances of g-C₃N₄-based photocatalytic materials with special morphologies

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