氨气检测仪研究现状

doi:10.16085/j.issn.1000-6613.2017-1383

摘要/Abstract

摘要： 氨气检测仪是一种能够对氨气进行快速检测的产品，克服了传统检测手段复杂、繁琐、准确性差的缺点。当前市场上的氨气检测仪种类繁多，但各类产品性能参差不齐。本文探讨了当前氨气检测仪的研究现状，对其中应用较广的红外氨气检测仪、半导体氨气检测仪和电化学氨气检测仪进行了概述，着重介绍了其工作原理和结构特点，并重点对各类检测仪的核心部件，即传感器的种类和性能影响因素进行了阐述；最后对3种检测仪在环保、生产、养殖以及医疗等多个领域的应用现状进行了分析展望，随着人们对环境安全性要求的提高以及政府相关政策法规的推行，氨气检测仪会得到更普遍的应用，相应地，为了适应更多领域的需求，氨气检测仪也必将会朝着更加微型化、精准化、便携化方向发展。

关键词: 污染, 电解, 电化学, 半导体, 红外

Abstract: The ammonia gas detector is a kind of product that can detect ammonia quickly.It overcomes the shortcomings of traditional detection methods,such as complicated,cumbersome and inaccurate.There are various kinds of ammonia detector in the current market,but the performance of various products is uneven.In this paper the research status of ammonia gas detector was discussed,the application of the infrared ammonia detector,semiconductor detector and electrochemistry detetor were summarized,besides the working principle and structural characteristics were introduced,the part of sensor,which was considered as the most important component of the whole detector,was introduced particularly.Finally,the application of the detectors in environmental protection,production,breeding,medical and other fields were introduced.According to this article,ammonia gas detector will get more general application,along with the people on the improvement of environmental security requirements and the implementation of the relevant government policies and regulations,accordingly,in order to meet the requirement of more fields,ammonia gas detector will develop towards the direction of more miniaturized,more precised and more portable.

Key words: pollution, electrolysis, electrochemistry, semiconductor, infrared

中图分类号:

TP212

朱宝余, 孙成勋, 王兰, 陈涛, 刘屹. 氨气检测仪研究现状[J]. 化工进展, 2017, 36(S1): 27-33.

ZHU Baoyu, SUN Chengxun, WANG Lan, CHEN Tao, LIU Yi. Research status of ammonia gas detector[J]. Chemical Industry and Engineering Progress, 2017, 36(S1): 27-33.

参考文献

[1] 郑建旭,官永川,冉慧丽,等.氨气传感器的应用和研究进展[J].化工新型材料,2010,38(2):6-8. ZHENG J X,GUAN Y C,RAN H L,et al.Application and research progress of ammonia sensor[J].New Chemical Materials,2010,38(2):6-8.
[2] 姚善卓,张玲玲,李友杰,等.氨气来源及氨气传感器应用[J].广州化工,2011,39(2):44-46. YAO S Z,ZHANG L L,LI Y J,et al.The source of ammonia and application of ammonia aensors[J].GuangZhou Chemical Industry,2011,39(2):44-46.
[3] KUGIMIYA A,TAKAMITSU E.Spectrophotometric detection of histidine and lysine using combined enzym atic reactions[J].Materials Science and Engineering C,2013,33(8):4867-4870.
[4] 张佳薇,王云龙,薛瑞,等.大气环境中先进与实用NH₃测量技术进展[J].传感器与微系统,2013,32(12):10-14. ZHANG J W,WANG Y L,XUE R,et al.Progress of advanced and practical NH₃ measurement technology in atmosphere environment[J].Transducer and Microsystem Technologies,2013,32(12):10-14.
[5] 张潜,王立人,杨祥龙,等.养殖场氨气检测方法研究现状[J].农业环境科学学报,2007,26(B03):309-312. ZHANG Q,WANG L R,YANG X L,et al.Monitoring procedures of ammonia released from livestock farm[J].Journal of Agro-Environment Science,2007,26(B03):309-312
[6] 陈东,刘文清,张玉钧,等.开放光程TDLAS系统对北京城区NH₃浓度的连续检测[J].光学技术,2007,33(2):311-314. CHEN D,LIU W Q,ZHANG Y J,et al.Successive measurement of atmospheric ammonia in urban area of Beijing using open-path TDLAS system[J].Optical Technique,2007,33(2):311-314.
[7] DUBAS S T,VIMOLVAN P.Green synthesis of silver nanoparticles for ammonia sensing[J].Talanta,2008,76(1):29-33.
[8] 陆婉珍,袁洪福,徐广通.现代近红外光谱分析技术[M].北京:中国石化出版社,2000:35-39. LU W Z,YUAN H F,Xu G T,et al.Near infrared spectrometry[M].Beijing:China Petrochemical Press,2000:35-39.
[9] WANG C Q,CHEN D R,JIAO X L.Flower-like In₂O₃ nanostructures derived from novel precursor:synthesis,characterization,and formation mechanism[J].The Journal of Physical Chemistry C,2009,113(18):7714-7718.
[10] ZHANG H J,WU R F,CHEN Z W,et al.Self-assembly fabrication of 3D flower-like ZnO hierarchical nanostructures and their gas sensing properties[J].Crystengcomm,2012,14(5):1775-1782.
[11] SONG F,SU H L,CHEN J J,et al.3D Hierarchical porous SnO₂ derived from self-assembled biological systems for superior gas sensing application[J].Journal of Materials Chemistry,2012,22(3):1121-1126.
[12] 张强,管自生.电阻式半导体气体传感器[J].仪表技术与传感器,2006,(7):6-10. ZHANG Q,GUAN Z S.Gas sensors of electric resistance semiconductors[J].Instrument Technique and Sensor,2006,(7):6-10.
[13] 徐建波,华凯峰,王玉江,等.电流型氨气传感器的研究[J].郑州轻工业学院学报(自然科学版),2004,19(4):39-41. XU J B,HUA K F,WANG Y J,et al.Study of amperometric ammonia sensor[J].Journal of Zhengzhou Institute of Light Industy(Nature Science),2004,19(4):39-41.
[14] 曹晔,张光友,丛继信.控制电位电解型气体传感器在液体推进剂检测中的应用[J].导弹与航天运载技术,2006,281(1):49-53. CAO Y,ZHANG G Y,CONG J X.Application of electrochemical gas sensor on detection of liquid rocket propellant[J].Missile and Space Vehcile,2006,281(1):49-53.
[15] 户桂涛,范云场,董兴,等.电化学传感器在食品分析中的应用进展[J].材料导报,2015,29(10):40-44. HU G T,FAN Y C,DONG X,et al.Progress in application of electrochemical sensors in food analysis[J].Materials Review,2015,29(10):40-44.
[16] 王玮琪.高精度红外多气体传感器吸收池的研究与设计[D].长春:吉林大学,2014. WANG W Q.Research and design of high precision infrared absorption multi-gas sensor[D].Changchun:Jilin University,2014.
[17] 赵笑宇.便携式氨气检测仪的研制[D].长春:吉林大学,2005. Zhao X Y.Development of portable ammonia-air tester[D].Changchun:Jilin University,2005.
[18] 王昌明.传感与测试技术[M].北京:北京航空航天大学出版社,2005:40-50. WANG C M.Sensor and testing technology[M].Beijing:Beihang University Press,2005,40-50.
[19] 杨卫国.微量溶解氧传感器结构研究[J].热能动力工程,2015,30(2):277-281. YANG W G.Study of the structure of a trace dissolved oxygen sensor[J].Journal of Engineering for Thermal Energy and Power,2015,30(2):277-281.
[20] 刘彬,刘咏松,金庆辉.溶解氧传感器微电极的制作及测试[D].杭州:浙江理工大学,2012. LIU B,LIU Y S,JIN Q H.The fabrication and detection of microelectrode for dissolved oxygen sensor[D].Hangzhou:Zhejiang Sci-Tech University,2012.
[21] 尚景玉,唐玉宏.溶解氧传感器研究进展[J].微纳电子技术,2014,51(3):168-175. SHANG J Y,TANG Y H.Research progress of the dissolved oxygen sensor[J].Micronanoelectronic Technology,2014,51(3):168-175.
[22] 张建华,吴建寨,韩书庆,等.农业传感器技术研究进展与性能分析[J].农业展望,2017(1):38-42. ZHANG J H,WU J Z,HAN S Q,et al.Research progress and performance analysis of agricultural sensor technology[J].Agricultural Outlook,2017(1):38-42.
[23] 王化正,电化学传感器[J].计测技术,1990(2):26-29,36. WANG H Z,Electrochemical sensor[J].Metrology & Measurement Technology,1990(2):26-29,36.
[24] BUZZEO M C,HARDACRE C,COMPTON R G.Use of room temperature ionic liquids in gas sensor design[J].Analytic Chemistry,2004,76:4583-4588.
[25] BUZZEO M C,HARDACRE C,COMPTON R G.Extended electrochemical windows made accessible by room temperature ionic liquid/organic solvent electrolyte systems[J].Chemphys-chem,2006,7(1):176-180.
[26] 陈冲,李林儒,陆天虹.电流型电化学气体传感器电解液的研究进展[J].应用化学,2012,29(3):245-250. CHEN C,LI L R,LU T H.Development of electrolytes in current-type electrochemical gas sensor[J].Chinese Journal of Applied Chemistry,2012,29(3):245-250.
[27] 刘建国,安振涛,张倩.新型电化学传感器的研究进展[J].传感器与微系统,2013,32(7):1-7. LIU J G,AN Z T,ZHANG Q.Research progress on novel electrochemical sensor[J].Transducer and Microsystem Technologies,2013,32(7):1-7.
[28] 中国国家计量技术规范.JJF.1059.1-2012,测量不确定度评定与表示[S]. National Verification Regulations and Calibration Speci-fications of Measuring Instruments of People's Republic of China.JJF.1059.1-2012,Evaluation and expression of uncertainty in measurement[S].
[29] 中国国家计量检定规程.JJG1105-2015,氨气检测仪[S]. National Metrological Verification Regulation of People's Republic of China.JJG1105-2015,Ammonia gas detectors[S].
[30] GB9666-1999,公共场所国家卫生标准[S]. GB9666-1999,National Hygienic standard for public places[S].
[31] BHUVANESHWARI S,GOPALAKRISHNAN N.Hydro-thermally synthesized copper oxide(CuO)superstructures for ammonia sensing[J].Journal of Colloid and Interface Science,2016,480(6):76-84.
[32] 邓丽芬,袁若浩.一种新的氨气检测报警仪[J].上海计量测试,2016(2):13-15. DENG L F,YUAN R H.A new ammonia alarm detector[J].Shanghai Measurement and Testing,2016(2):13-15.
[33] GB/T18883-2002,室内空气质量标准[S]. GB/T18883-2002,Indoor air quality standard[S].
[34] 梁学玉,朱茜,李博.浅谈氨气分析仪量值溯源的发展现状[J].计量与测试技术,2016,43(7):26-27. LIANG X Y,ZHU Q,LI B.Talking about the development of traceability ammonia analyzer[J].Metrology & Measurement Technique,2016,43(7):26-27.
[35] 张嘉琪,胡馨升,陈培飞.纳米TiO₂敏感膜修饰的QCM气体传感器检测氨气的研究[J].仪表技术与传感,2015,(2):5-7. ZHANG J Q,HU X S,CHEN P F.Research for detection of ammonia gas through QCM gas sensor modified by nanometer TiO₂[J].Instrument Technique and Sensor,2015,(2):5-7.
[36] 孟丽辉,李聪,卢庆萍,等.不同氨气浓度对肉鸡福利的影响[J].畜牧兽医学报,2016,47(8):1574-1580. MENG L H,LI C,LU Q P,et al.The influence of different ammonia concentration of poultry welfare[J].Journal of Animal Husbandry and Veterinary,2016,47(8):1574-1580.
[37] 董学良.规模猪场形成的环境污染及治理措施[J].中国畜牧兽医文摘,2015,31(11):86. DONG X L.The environmental pollution and control measures of scale pig farms[J].China Animal Husbandry and Veterinary Abstract,2015,31(11):86.
[38] 何诚,梁礼成.肉鸡腹水症发病机理研究[J].中国农业大学学报,2000,5(3):111-116. HE C,LIANG L C.Broiler ascites syndrome pathogenesis research[J].Journal of China Agricultural University,2000,5(3):111-116.
[39] 李聪,卢庆萍,唐湘方,等.不同浓度氨气对肉鸡生长性能及呼吸道黏膜屏障的影响[J].中国农业科学,2014,47(22):4516-4523. LI C,LU Q P,TANG X F,et al.The influence of different concentrations of ammonia on broiler growth performance and the respiratory tract mucous membrane barrier[J].China's Agricultural Science,2014,47(22):4516-4523.
[40] RUMBURG B,NEGER M,MOUNT G H,et al.Liquid and atmospheric ammonia concentrations from a dairy lagoon during an aeration experiment[J].Atmospheric Environment,2004,38(1):1523-1533.
[41] WANG Y M,MENG Q P,GUO Y M,et al.Effect of atmospheric ammonia on growth performance and immunological response of broiler chickens[J].Journal of Animal and Veterinary Advances,2010,9(22):2802-2806.
[42] 朱柏正,姜海涛.浅析养殖业生产中氨气的危害[J].养殖与饲料,2010,39(6):4. ZHU B Z,Jiang H T.Analyses of the harm of ammonia in the breeding production[J].Animals Breeding and Feed,2010,39(6):4.
[43] SUJA D B,SUE E,RENUKA B,et al.Breath ammonia testing for diagnosis of hepatic encephalopathy[J].Digestive Diseases and Science,2005,50(10):1780-1784.