基于尖晶石型CoFe2O4高级氧化降解水中有机污染物研究进展

doi:10.16085/j.issn.1000-6613.2023-1773

摘要/Abstract

摘要：

基于自由基反应的高级氧化技术（AOPs）作为一种简单、高效、清洁的有机污染物去除技术得到了广泛研究。尖晶石型钴铁氧体（CoFe₂O₄）具有催化性能好、金属浸出率低和回收再利用率高等特点，被广泛用作高级氧化过程中驱动自由基生成的催化剂。本文以尖晶石型CoFe₂O₄为研究对象，概述了CoFe₂O₄的结构与性质；归纳总结了包括形貌调控、元素掺杂、耦合复合材料在内的CoFe₂O₄改性方法；重点综述了CoFe₂O₄及其复合材料光催化氧化、非均相类芬顿氧化、过一硫酸盐氧化与臭氧催化氧化降解水中有机污染物的基本原理及研究进展；最后指出当前研究存在的问题，并对其后续研究方向进行展望。

关键词: 钴铁氧体, 高级氧化, 催化降解, 有机污染物, 机理, 水体

Abstract:

Advanced oxidation technologies (AOPs), which based on free radical reactions, have been widely investigated as a simple, efficient and clean technology for the removal of organic pollutants. Spinel-type cobalt ferrite (CoFe₂O₄) is widely used as a catalyst for driving radical generation in advanced oxidation processes due to its good catalytic performance, low metal leaching rate and high recycling rate. This review takes spinel-type CoFe₂O₄ as the research object. Herein, the structure and properties of CoFe₂O₄ are outlined. The modification methods of CoFe₂O₄, including morphology modification, elemental doping and coupling composite materials, are summarized. The basic principles and research progress of photocatalytic oxidation of CoFe₂O₄ and its composites, non-homogeneous Fenton-like oxidation, peroxydisulfate oxidation and ozone-catalyzed oxidation for the degradation of organic pollutants in water are highlighted. Finally, the problems of the current study are pointed out and the direction of its subsequent research is envisioned.

Key words: cobalt ferrite, advanced oxidation, catalytic degradation, organic pollutants, mechanism, water body

中图分类号:

O643

周添红, 王金怡, 苏旭, 曾虹霖, 翟天骄. 基于尖晶石型CoFe₂O₄高级氧化降解水中有机污染物研究进展[J]. 化工进展, 2024, 43(11): 6412-6427.

ZHOU Tianhong, WANG Jinyi, SU Xu, ZENG Honglin, ZHAI Tianjiao. Research progress on advanced oxidation degradation of organic pollutants in water based on spinel type CoFe₂O₄[J]. Chemical Industry and Engineering Progress, 2024, 43(11): 6412-6427.

图/表 11

参考文献 121

1	王庆宏, 姜晨旭, 王鑫, 等. 天然矿物催化氧化水中难降解有机污染物研究进展[J]. 化工进展, 2023, 42(1): 417-434.
	WANG Qinghong, JIANG Chenxu, WANG Xin, et al. An overview of natural mineral catalytic oxidation of refractory organic contaminants in wastewater[J]. Chemical Industry and Engineering Progress, 2023, 42(1): 417-434.
2	KRISHNAN Athira, SWARNALAL Anna, Divine DAS, et al. A review on transition metal oxides based photocatalysts for degradation of synthetic organic pollutants[J]. Journal of Environmental Sciences, 2024, 139: 389-417.
3	吴悦, 赖永忠, 陆国永, 等. 对水体中挥发性有机物分析的空白污染来源及解决措施的探讨[J]. 冶金分析, 2023, 43(2): 14-22.
	WU Yue, LAI Yongzhong, LU Guoyong, et al. Discussion on the sources and countermeasures of blank pollution in determination of volatile organic compounds in water samples[J]. Metallurgical Analysis, 2023, 43(2): 14-22.
4	ZEGHIOUD Hicham, FRYDA Lydia, DJELAL Hayet, et al. A comprehensive review of biochar in removal of organic pollutants from wastewater: Characterization, toxicity, activation/functionalization and influencing treatment factors[J]. Journal of Water Process Engineering, 2022, 47: 102801.
5	TANG Lei, MA Xiaoyan Y, WANG Yongkun K, et al. Removal of trace organic pollutants (pharmaceuticals and pesticides) and reduction of biological effects from secondary effluent by typical granular activated carbon[J]. Science of The Total Environment, 2020, 749: 141611.
6	MIAO Miao, LU Qingchen, WANG Xinqi, et al. Removal of micro-organic contaminants from wastewater: A critical review of treatment technology[J]. Next Materials, 2023, 1(2): 100016.
7	孙普, 李恩泽, 王淑军, 等. 聚硅酸钛强化混凝焦化废水预处理性能研究[J]. 应用化工, 2019, 48(2): 341-344.
	SUN Pu, LI Enze, WANG Shujun, et al. The investigation of the enhanced coagulation pretreatment performances on coking wastewater via poly titanium-silicate-chloride[J]. Applied Chemical Industry, 2019, 48(2): 341-344.
8	KUMARI Preeti, KUMAR Aditya. Advanced oxidation process: A remediation technique for organic and non-biodegradable pollutant[J]. Results in Surfaces and Interfaces, 2023, 11: 100122.
9	MA Dengsheng, YI Huan, LAI Cui, et al. Critical review of advanced oxidation processes in organic wastewater treatment[J]. Chemosphere, 2021, 275: 130104.
10	LIU Bingzhi, HUANG Baorong, WANG Zizeng, et al. Homogeneous/heterogeneous metal-catalyzed persulfate oxidation technology for organic pollutants elimination: A review[J]. Journal of Environmental Chemical Engineering, 2023, 11(3): 109586.
11	曹勇. 高级氧化技术处理抗生素污染的研究现状[J]. 安徽化工, 2023, 49(3): 28-32.
	CAO Yong. Research status of advanced oxidation technology in treating antibiotic pollution[J]. Anhui Chemical Industry, 2023, 49(3): 28-32.
12	LIU Yong, WANG Jianlong. Multivalent metal catalysts in Fenton/Fenton-like oxidation system: A critical review[J]. Chemical Engineering Journal, 2023, 466: 143147.
13	XING Mingyang, XU Wenjing, DONG Chencheng, et al. Metal sulfides as excellent co-catalysts for H₂O₂ decomposition in advanced oxidation processes[J]. Chem, 2018, 4(6): 1359-1372.
14	PATTNAIK Amruta, SAHU J N, POONIA Anil Kumar, et al. Current perspective of nano-engineered metal oxide based photocatalysts in advanced oxidation processes for degradation of organic pollutants in wastewater[J]. Chemical Engineering Research and Design, 2023, 190: 667-686.
15	WANG Shizong, WANG Jianlong. Decomposition of carbon-based catalysts in advanced oxidation processes: A neglected but noteworthy problem[J]. Chemical Engineering Journal, 2023, 456: 141086.
16	葛明, 胡征, 贺全宝. 基于尖晶石型铁氧体的高级氧化技术在有机废水处理中的应用[J]. 化学进展, 2021, 33(9): 1648-1664.
	GE Ming, HU Zheng, HE Quanbao. Application of spinel ferrite-based advanced oxidation processes in organic wastewater treatment[J]. Progress in Chemistry, 2021, 33(9): 1648-1664.
17	Annie VINOSHA P, MANIKANDAN A, Christy PREETHA A, et al. Review on recent advances of synthesis, magnetic properties, and water treatment applications of cobalt ferrite nanoparticles and nanocomposites[J]. Journal of Superconductivity and Novel Magnetism, 2021, 34(4): 995-1018.
18	DASGUPTA Subho, Bijoy DAS, LI Qiang, et al. Toward on-and-off magnetism: Reversible electrochemistry to control magnetic phase transitions in spinel ferrites[J]. Advanced Functional Materials, 2016, 26(41): 7507-7515.
19	ATIQ Shahid, MAJEED Maria, AHMAD Aqsa, et al. Synthesis and investigation of structural, morphological, magnetic, dielectric and impedance spectroscopic characteristics of Ni-Zn ferrite nanoparticles[J]. Ceramics International, 2017, 43(2): 2486-2494.
20	YAN Zhu, LUO Juhua. Effects of Ce Zn co-substitution on structure, magnetic and microwave absorption properties of nickel ferrite nanoparticles[J]. Journal of Alloys and Compounds, 2017, 695: 1185-1195.
21	BORHAN Adrian Iulian, Daniel GHERCĂ, IORDAN Alexandra Raluca, et al. Classification and types of ferrites[M]//Ferrite Nanostructured Magnetic Materials. Amsterdam: Elsevier, 2023: 17-34.
22	QIN Hong, HE Yangzhuo, XU Piao, et al. Spinel ferrites (MFe₂O₄): Synthesis, improvement and catalytic application in environment and energy field[J]. Advances in Colloid and Interface Science, 2021, 294: 102486.
23	HARRIS Vincent G, GEILER Anton, CHEN Yajie, et al. Recent advances in processing and applications of microwave ferrites[J]. Journal of Magnetism and Magnetic Materials, 2009, 321(14): 2035-2047.
24	HOUSHIAR Mahboubeh, ZEBHI Fatemeh, RAZI Zahra Jafari, et al. Synthesis of cobalt ferrite (CoFe₂O₄) nanoparticles using combustion, coprecipitation, and precipitation methods: A comparison study of size, structural, and magnetic properties[J]. Journal of Magnetism and Magnetic Materials, 2014, 371: 43-48.
25	JAVAID Shaghraf, AKHYAR FARRUKH Muhammad, MUNEER Iqra, et al. Influence of optical band gap and particle size on the catalytic properties of Sm/SnO₂-TiO₂ nanoparticles[J]. Superlattices and Microstructures, 2015, 82: 234-247.
26	Dina FATTAKHOVA-ROHLFING, ZALESKA Adriana, BEIN Thomas. Three-dimensional titanium dioxide nanomaterials[J]. Chemical Reviews, 2014, 114(19): 9487-9558.
27	AL-MAMUN M R, KADER S, ISLAM M S, et al. Photocatalytic activity improvement and application of UV-TiO₂ photocatalysis in textile wastewater treatment: A review[J]. Journal of Environmental Chemical Engineering, 2019, 7(5): 103248.
28	张竞哲, 苑高千, 解厚波, 等. 尖晶石型铁氧体处理废水中Cr(Ⅵ)研究现状与进展[J]. 环境化学, 2023, 42(6): 2048-2063.
	ZHANG Jingzhe, YUAN Gaoqian, XIE Houbo, et al. Current status and prospects of aqueous Cr(Ⅵ) removal by spinel ferrites[J]. Environmental Chemistry, 2023, 42(6): 2048-2063.
29	NEMIWAL Meena, ZHANG Tian C, KUMAR Dinesh. Recent progress in g-C₃N₄, TiO₂ and ZnO based photocatalysts for dye degradation: Strategies to improve photocatalytic activity[J]. Science of the Total Environment, 2021, 767: 144896.
30	SONU, DUTTA Vishal, SHARMA Sheetal, et al. Review on augmentation in photocatalytic activity of CoFe₂O₄ via heterojunction formation for photocatalysis of organic pollutants in water[J]. Journal of Saudi Chemical Society, 2019, 23(8): 1119-1136.
31	HOLINSWORTH B S, MAZUMDAR D, SIMS H, et al. Chemical tuning of the optical band gap in spinel ferrites: CoFe₂O₄ vs. NiFe₂O₄ [J]. Applied Physics Letters, 2013, 103(8): 082406.
32	AHMAD LONE Gulzar, IKRAM Mohd. Role of Ni doping in magnetic dilution of Fe sublattice and in tailoring optical properties of CoFe₂O₄ [J]. Journal of Alloys and Compounds, 2023, 934: 167891.
33	BASHA Beriham, IKRAM Mustabshira, ALROWAILI Z A, et al. Wet chemical route synthesis of Cr doped CoFe₂O₄@rGO nanocomposite for photodegradation of organic effluents present in drinking water[J]. Ceramics International, 2023, 49(18): 30049-30059.
34	REVATHI J, John ABEL M, ARCHANA V, et al. Synthesis and characterization of CoFe₂O₄ and Ni-doped CoFe₂O₄ nanoparticles by chemical co-precipitation technique for photo-degradation of organic dyestuffs under direct sunlight[J]. Physica B: Condensed Matter, 2020, 587: 412136.
35	SHI Weilong, LIU Yanan, SHI Yuxing, et al. Realization of photocatalytic hydrogen production by optimizing energy band structure and promoting charges separation over the S-doped CoFe₂O₄ microrods[J]. Materials Today Communications, 2023, 35: 105588.
36	FERDOSI E, BAHIRAEI H, GHANBARI D. Investigation the photocatalytic activity of CoFe₂O₄/ZnO and CoFe₂O₄/ZnO/Ag nanocomposites for purification of dye pollutants[J]. Separation and Purification Technology, 2018, 211: 35-39.
37	USHA P, HARI PRASAD K, RAMESH Somoju. Combustion-synthesized CoFe₂O₄ nanoparticles: Structure and electrical conductivity studies[J]. Materials Today: Proceedings, 2023, 92: 1246-1249.
38	GAO Wenkun, QIN Junfeng, WANG Kai, et al. Facile synthesis of Fe-doped Co₉S₈ nano-microspheres grown on nickel foam for efficient oxygen evolution reaction[J]. Applied Surface Science, 2018, 454: 46-53.
39	WANG Yanyong, LIU Dongdong, LIU Zhijuan, et al. Porous cobalt-iron nitride nanowires as excellent bifunctional electrocatalysts for overall water splitting[J]. Chemical Communications, 2016, 52(85): 12614-12617.
40	THAKUR Priyanka, THAKUR Prashant, KISHORE Kamal, et al. Structural, morphological, and magnetic properties of CoFe₂O₄ nano-ferrites synthesized via co-precipitation route[J]. Materials Today: Proceedings, DOI: 10.1016/j.matpr.2022.12.233 .
41	XI Guoxi, HENG Xiaoying, Changwei DUN, et al. The influence of MgO on the magnetic and magnetostrictive properties of CoFe₂O₄ nanoparticles synthesized using spent LIBs[J]. Physica B: Condensed Matter, 2020, 589: 412182.
42	OMELYANCHIK Alexander, SINGH Gurvinder, VOLOCHAEV Mikhail, et al. Tunable magnetic properties of Ni-doped CoFe₂O₄ nanoparticles prepared by the sol-gel citrate self-combustion method[J]. Journal of Magnetism and Magnetic Materials, 2019, 476: 387-391.
43	黄豹. 钴铁氧体纳米磁性材料的制备及磁性能研究[D]. 杭州: 中国计量学院, 2012.
	HUANG Bao. Preparation and magnetic properties of cobalt ferrite nano-magnetic materials[D]. Hangzhou: China University of Metrology, 2012.
44	KUMAR Manish, KUMAR Arvind, SINGH Abhishek, et al. Low temperature magnetic study and first principle calculation in ‘Mo’ doped CoFe₂O₄ for magnetic information storage applications[J]. Journal of Alloys and Compounds, 2022, 896: 163074.
45	WANG Xunliang, ZHANG Chen, ZHANG Yizhong, et al. Activation of peroxymonosulfate by an Enteromorpha prolifera derived biochar supported CoFe₂O₄ catalyst for highly efficient lomefloxacin hydrochloride degradation under a wide pH range[J]. Separation and Purification Technology, 2023, 316: 123846.
46	DEBNATH Bharati, SALUNKE Hemant G, BHATTACHARYYA Sayan. Spin disorder and particle size effects in cobalt ferrite nanoparticles with unidirectional anisotropy and permanent magnet-like characteristics[J]. The Journal of Physical Chemistry C, 2020, 124(47): 25992-26000.
47	LI Dichen, YUN Hongseok, DIROLL Benjamin T, et al. Synthesis and size-selective precipitation of monodisperse nonstoichiometric M _x Fe_3– _x O₄ (M=Mn, Co) nanocrystals and their DC and AC magnetic properties[J]. Chemistry of Materials, 2016, 28(2): 480-489.
48	KHAN Usman, NAIRAN Adeela, Shafaq NAZ, et al. Optical and temperature-dependent magnetic properties of Mn-doped CoFe₂O₄ nanostructures[J]. Materials Today Communications, 2023, 35: 106276.
49	LI Xinyuan, SUN Yong, ZONG Yan, et al. Size-effect induced cation redistribution on the magnetic properties of well-dispersed CoFe₂O₄ nanocrystals[J]. Journal of Alloys and Compounds, 2020, 841: 155710.
50	MAHHOUTI Z, MOUSSAOUI H EL, MAHFOUD T, et al. Chemical synthesis and magnetic properties of monodisperse cobalt ferrite nanoparticles[J]. Journal of Materials Science: Materials in Electronics, 2019, 30(16): 14913-14922.
51	CONG KHIEM Ta, DINH TUAN Duong, KWON Eilhann, et al. Degradation of dihydroxybenzophenone through monopersulfate activation over nanostructured cobalt ferrites with various morphologies: A comparative study[J]. Chemical Engineering Journal, 2022, 450: 137798.
52	MO Yuanmin, ZHANG Xiaoping. Insights into the mechanism of multiple Cu-doped CoFe₂O₄ nanocatalyst activated peroxymonosulfate for efficient degradation of Rhodamine B[J]. Journal of Environmental Sciences, 2024, 137: 382-394.
53	NGUYEN Loan T T, NGUYEN Hang T T, NGUYEN Lan T H, et al. Efficient and recyclable Nd³⁺-doped CoFe₂O₄ for boosted visible light-driven photocatalytic degradation of Rhodamine B dye[J]. RSC Advances, 2023, 13(16): 10650-10656.
54	GAO Y, ZHU W H, LIU J W, et al. Mesoporous sulfur-doped CoFe₂O₄ as a new Fenton catalyst for the highly efficient pollutants removal[J]. Applied Catalysis B: Environmental, 2021, 295: 120273.
55	LI Yongjie, HUANG Mingjie, Wen-Da OH, et al. Efficient activation of sulfite for reductive-oxidative degradation of chloramphenicol by carbon-supported cobalt ferrite catalysts[J]. Chinese Chemical Letters, 2023, 34(10): 108247.
56	URBAIN Félix, DU Ruifeng, TANG Pengyi, et al. Upscaling high activity oxygen evolution catalysts based on CoFe₂O₄ nanoparticles supported on nickel foam for power-to-gas electrochemical conversion with energy efficiencies above 80%[J]. Applied Catalysis B: Environmental, 2019, 259: 118055.
57	李英豪, 郑向前, 高晓亚, 等. CoFe₂O₄的制备及其活化过一硫酸盐降解磺胺甲𫫇唑[J]. 精细化工, 2022, 39(5): 1020-1027.
	LI Yinghao, ZHENG Xiangqian, GAO Xiaoya, et al. Preparation of CoFe₂O₄ and its peroxymonosulfate activation for degradation of sulfamethoxazole[J]. Fine Chemicals, 2022, 39(5): 1020-1027.
58	ZHANG Sai, WU Jia, LI Fangyun, et al. Enhanced photocatalytic performance of spinel ferrite (MFe₂O₄, M=Zn, Mn, Co, Fe, Ni) catalysts: The correlation between morphology-microstructure and photogenerated charge efficiency[J]. Journal of Environmental Chemical Engineering, 2022, 10(3): 107702.
59	TONG Yongchun, FENG Min, WEI Jihong, et al. One-step synthesis of CoFe₂O₄ nanomaterials by solvothermal method[J]. Bulletin of the Chemical Society of Japan, 2022, 95(7): 1086-1090.
60	GERBALDO María Verónica, MARCHETTI Sergio Gustavo, ELÍAS Verónica Rita, et al. Degradation of anti-inflammatory drug diclofenac using cobalt ferrite as photocatalyst[J]. Chemical Engineering Research and Design, 2021, 166: 237-247.
61	FOROUGHI Firoozeh, HASSANZADEH-TABRIZI S A, AMIGHIAN Jamshid. Microemulsion synthesis and magnetic properties of hydroxyapatite-encapsulated nano CoFe₂O₄ [J]. Journal of Magnetism and Magnetic Materials, 2015, 382: 182-187.
62	Esther NIMSHI R, Judith VIJAYA J, John KENNEDY L, et al. Effective microwave assisted synthesis of CoFe₂O₄@TiO₂@rGO ternary nanocomposites for the synergic sonophotocatalytic degradation of tetracycline and c antibiotics[J]. Ceramics International, 2023, 49(9): 13762-13773.
63	TATARCHUK Tetiana, DANYLIUK Nazarii, KOTSYUBYNSKY Volodymyr, et al. Eco-friendly synthesis of cobalt-zinc ferrites using quince extract for adsorption and catalytic applications: An approach towards environmental remediation[J]. Chemosphere, 2022, 294: 133565.
64	KAZEMI Mosstafa, GHOBADI Massoud, MIRZAIE Ali. Cobalt ferrite nanoparticles (CoFe₂O₄ MNPs) as catalyst and support: Magnetically recoverable nanocatalysts in organic synthesis[J]. Nanotechnology Reviews, 2018, 7(1): 43-68.
65	YANG Jinhui, WANG Donge, HAN Hongxian, et al. Roles of cocatalysts in photocatalysis and photoelectrocatalysis[J]. Accounts of Chemical Research, 2013, 46(8): 1900-1909.
66	马晓佳, 唐学静, 靳凤先, 等. 二氧化钛基材料光催化降解VOCs的研究进展[J]. 工程科学学报, 2023, 45(4): 590-601.
	MA Xiaojia, TANG Xuejing, JIN Fengxian, et al. Research advancements in the use of TiO₂-based materials for the photocatalytic degradation of volatile organic compounds[J]. Chinese Journal of Engineering, 2023, 45(4): 590-601.
67	李宁, 张伟, 李贵贤, 等. TiO₂光催化剂的研究进展[J]. 精细化工, 2021, 38(11): 2181-2188.
	LI Ning, ZHANG Wei, LI Guixian, et al. Research progress of TiO₂ photocatalysts[J]. Fine Chemicals, 2021, 38(11): 2181-2188.
68	SHYAMALDAS, BOUOUDINA M, MANOHARAN C. Dependence of structure/morphology on electrical/magnetic properties of hydrothermally synthesised cobalt ferrite nanoparticles[J]. Journal of Magnetism and Magnetic Materials, 2020, 493: 165703.
69	Patricia GARCIA-MUÑOZ, FRESNO Fernando, DE LA PEÑA O’SHEA Víctor A, et al. Ferrite materials for photoassisted environmental and solar fuels applications[J]. Topics in Current Chemistry, 2020, 378(1): 6.
70	ZENG Y, GUO N, SONG Y J, et al. Fabrication of Z-scheme magnetic MoS₂/CoFe₂O₄ nanocomposites with highly efficient photocatalytic activity[J]. Journal of Colloid and Interface Science, 2018, 514: 664-674.
71	ABDUL KADER Huda D, MOHAMMED Israa SH, AMMAR Saad H. Synthesis of recyclable core/shell CoFe₂O₄@CoWO₄ photocatalysts for efficient visible-light photocatalytic degradation of environmental pollutants[J]. Environmental Nanotechnology, Monitoring & Management, 2022, 17: 100664.
72	SYED Asad, AHMED Bilal, ELGORBAN Abdallah M, et al. Designing spinel CoFe₂O₄ loaded sheet-like Bi₂O₃ nano-heterostructure for synergetic white-light photocatalysis with recombination delay and antibacterial applications[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 629: 127449.
73	HUANG Shangpan, WEI Zhiqiang, DING Meijie, et al. Photo-electrochemical and photocatalytic properties of hierarchical flower-like BiOI/CoFe₂O₄ nanocomposites synthesized by co-precipitation method[J]. Optical Materials, 2021, 111: 110643.
74	SHI Weilong, FU Yongming, SUN Haoran, et al. Construction of 0D/3D CoFe₂O₄/MIL-101(Fe) complement each other S-scheme heterojunction for effectively boosted photocatalytic degradation of tetracycline[J]. Inorganic Chemistry Communications, 2022, 146: 110140.
75	SONG Jiahe, ZHANG Jingjing, ZADA Amir, et al. CoFe₂O₄/NiFe₂O₄ S-scheme composite for photocatalytic decomposition of antibiotic contaminants[J]. Ceramics International, 2023, 49(8): 12327-12333.
76	GEBRESLASSIE Gebrehiwot, GEBREZGIABHER Mamo, LIN Bin, et al. Direct Z-scheme CoFe₂O₄-loaded g-C₃N₄ photocatalyst with high degradation efficiency of methylene blue under visible-light irradiation[J]. Inorganics, 2023, 11(3): 119.
77	WANG Xinruo, CHEN Yan. ZnIn₂S₄/CoFe₂O₄ P-N junction-decorated biochar as magnetic recyclable nanocomposite for efficient photocatalytic degradation of ciprofloxacin under simulated sunlight[J]. Separation and Purification Technology, 2022, 303: 122156.
78	ZHU Pengfei, LUO Dan, DUAN Ming, et al. Based on a dual Z-scheme heterojunction and magnetically separable CoFe₂O₄/g-C₃N₄/Bi₄Ti₃O₁₂ flower-like composite for efficient visible-light photocatalytic degradation of organic pollutants[J]. Journal of Alloys and Compounds, 2022, 911: 164907.
79	周添红, 翟天骄, 王金怡, 等. 外场辅助光催化机理及降解有机污染物研究进展[J]. 精细化工, 2023, 40(6): 1202-1213.
	ZHOU Tianhong, ZHAI Tianjiao, WANG Jinyi, et al. Field-assisted photocatalysis mechanism and degradation of organic pollutants: A review[J]. Fine Chemicals, 2023, 40(6): 1202-1213.
80	AL-MUSAWI Tariq J, MCKAY Gordon, RAJIV Periakaruppan, et al. Efficient sonophotocatalytic degradation of acid blue 113 dye using a hybrid nanocomposite of CoFe₂O₄ nanoparticles loaded on multi-walled carbon nanotubes[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2022, 424: 113617.
81	MUSHTAQ Fajer, CHEN Xiangzhong, TORLAKCIK Harun, et al. Enhanced catalytic degradation of organic pollutants by multi-stimuli activated multiferroic nanoarchitectures[J]. Nano Research, 2020, 13(8): 2183-2191.
82	SHOKRI Aref, FARD Mahdi Sanavi. A critical review in Fenton-like approach for the removal of pollutants in the aqueous environment[J]. Environmental Challenges, 2022, 7: 100534.
83	VILARDI Giorgio, OCHANDO-PULIDO Javier Miguel, STOLLER Marco, et al. Fenton oxidation and chromium recovery from tannery wastewater by means of iron-based coated biomass as heterogeneous catalyst in fixed-bed columns[J]. Chemical Engineering Journal, 2018, 351: 1-11.
84	JAIN Bhawana, SINGH Ajaya Kumar, KIM Hyunook, et al. Treatment of organic pollutants by homogeneous and heterogeneous Fenton reaction processes[J]. Environmental Chemistry Letters, 2018, 16(3): 947-967.
85	HONG Peidong, LI Yulian, HE Junyong, et al. Rapid degradation of aqueous doxycycline by surface CoFe₂O₄/H₂O₂ system: Behaviors, mechanisms, pathways and DFT calculation[J]. Applied Surface Science, 2020, 526: 146557.
86	PIGNATELLO Joseph J, OLIVEROS Esther, MACKAY Allison. Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry[J]. Critical Reviews in Environmental Science and Technology, 2006, 36(1): 1-84.
87	贺框, 黄凯华, 胡小英, 等. 用尖晶石CoFe₂O₄磁性颗粒非均相芬顿氧化废水中的柠檬酸镍[J]. 电镀与涂饰, 2022, 41(21): 1552-1557.
	HE Kuang, HUANG Kaihua, HU Xiaoying, et al. Heterogeneous Fenton oxidation of nickel citrate in wastewater by using magnetic spinel CoFe₂O₄ particles[J]. Electroplating & Finishing, 2022, 41(21): 1552-1557.
88	WANG Zhiwei, YOU Junhua, LI Jingjing, et al. Review on cobalt ferrite as photo-Fenton catalysts for degradation of organic wastewater[J]. Catalysis Science & Technology, 2023, 13(2): 274-296.
89	MAZARJI Mahmoud, ESMAILI Hassan, BIDHENDI Gholamreza Nabi, et al. Green synthesis of reduced graphene oxide-CoFe₂O₄ nanocomposite as a highly efficient visible-light-driven catalyst in photocatalysis and photo Fenton-like reaction[J]. Materials Science and Engineering: B, 2021, 270: 115223.
90	BAGHERZADEH Seyed Behnam, KAZEMEINI Mohammad, MAHMOODI Niyaz Mohammad. Preparation of novel and highly active magnetic ternary structures (metal-organic framework/cobalt ferrite/graphene oxide) for effective visible-light-driven photocatalytic and photo-Fenton-like degradation of organic contaminants[J]. Journal of Colloid and Interface Science, 2021, 602: 73-94.
91	GUO Meiting, LU Mingjie, ZHAO Heng, et al. Efficient electro-Fenton catalysis by self-supported CFP@CoFe₂O₄ electrode[J]. Journal of Hazardous Materials, 2022, 423: 127033.
92	蔡鹏程. 钴镍双金属催化剂活化过氧单硫酸盐降解诺氟沙星的协同机制研究[D]. 青岛: 青岛大学, 2022.
	CAI Pengcheng. Study on synergistic mechanism of norfloxacin degradation by activated peroxymonosulfate with Co-Ni bimetallic catalyst[D]. Qingdao: Qingdao University, 2022.
93	LEE Juhyeok, SINGH Bhupendra Kumar, HAFEEZ Muhammad Aamir, et al. Comparative study of PMS oxidation with Fenton oxidation as an advanced oxidation process for Co-EDTA de complexation[J]. Chemosphere, 2022, 300: 134494.
94	时旭. 钴基双金属催化剂活化过一硫酸盐处理典型染料废水及其机制研究[D]. 合肥: 中国科学技术大学, 2022.
	SHI Xu. Treatment of typical dye wastewater by activating persulfate with cobalt-based bimetallic catalyst and its mechanism[D]. Hefei: University of Science and Technology of China, 2022.
95	ZHAO Wenjia, SHEN Qiwen, Tingting NAN, et al. Cobalt-based catalysts for heterogeneous peroxymonosulfate (PMS) activation in degradation of organic contaminants: Recent advances and perspectives[J]. Journal of Alloys and Compounds, 2023, 958: 170370.
96	ZHU Shijun, XU Yongpeng, ZHU Zhigao, et al. Activation of peroxymonosulfate by magnetic Co-Fe/SiO₂ layered catalyst derived from iron sludge for ciprofloxacin degradation[J]. Chemical Engineering Journal, 2020, 384: 123298.
97	LIU Lili, MI Haosheng, ZHANG Meng, et al. Efficient moxifloxacin degradation by CoFe₂O₄ magnetic nanoparticles activated peroxymonosulfate: Kinetics, pathways and mechanisms[J]. Chemical Engineering Journal, 2021, 407: 127201.
98	LI Jun, XU Mengjuan, YAO Gang, et al. Enhancement of the degradation of atrazine through CoFe₂O₄ activated peroxymonosulfate (PMS) process: Kinetic, degradation intermediates, and toxicity evaluation[J]. Chemical Engineering Journal, 2018, 348: 1012-1024.
99	GAN Lu, ZHONG Qiang, GENG Aobo, et al. Cellulose derived carbon nanofiber: A promising biochar support to enhance the catalytic performance of CoFe₂O₄ in activating peroxymonosulfate for recycled dimethyl phthalate degradation[J]. Science of the Total Environment, 2019, 694: 133705.
100	LIANG Yu, LI Lihua, YANG Chunmeng, et al. Bimetallic zeolitic imidazolate framework-derived nitrogen-doped porous carbon-coated CoFe₂O₄ core-shell composite with high catalytic performance for peroxymonosulfate activation in Rhodamine B degradation[J]. Journal of Alloys and Compounds, 2022, 907: 164504.
101	WU Junxue, CAGNETTA Giovanni, WANG Bin, et al. Efficient degradation of carbamazepine by organo-montmorillonite supported nCoFe₂O₄-activated peroxymonosulfate process[J]. Chemical Engineering Journal, 2019, 368: 824-836.
102	ZHI Zejian, WU Di, MENG Fanyue, et al. Facile synthesis of CoFe₂O₄@BC activated peroxymonosulfate for p-nitrochlorobenzene degradation: Matrix effect and toxicity evaluation[J]. Science of the Total Environment, 2022, 828: 154275.
103	WANG Qiongfang, SHAO Yisheng, GAO Naiyun, et al. Activation of peroxymonosulfate by Al₂O₃-based CoFe₂O₄ for the degradation of sulfachloropyridazine sodium: Kinetics and mechanism[J]. Separation and Purification Technology, 2017, 189: 176-185.
104	YANG Zhiquan, LI Ying, ZHANG Xinyi, et al. Sludge activated carbon-based CoFe₂O₄-SAC nanocomposites used as heterogeneous catalysts for degrading antibiotic norfloxacin through activating peroxymonosulfate[J]. Chemical Engineering Journal, 2020, 384: 123319.
105	PENG Xiaoming, YANG Zhanhong, HU Fengping, et al. Mechanistic investigation of rapid catalytic degradation of tetracycline using CoFe₂O₄@MoS₂ by activation of peroxymonosulfate[J]. Separation and Purification Technology, 2022, 287: 120525.
106	ZHANG Ke, SUN Dedong, MA Chun, et al. Activation of peroxymonosulfate by CoFe₂O₄ loaded on metal-organic framework for the degradation of organic dye[J]. Chemosphere, 2020, 241: 125021.
107	LI Xinran, LIU Zhehua, ZHU Yongjuan, et al. Facile synthesis and synergistic mechanism of CoFe₂O₄@three-dimensional graphene aerogels towards peroxymonosulfate activation for highly efficient degradation of recalcitrant organic pollutants[J]. Science of the Total Environment, 2020, 749: 141466.
108	HNAMTE Malsawmdawngkima, PULIKKAL Ajmal Koya. Clay-polymer nanocomposites for water and wastewater treatment: A comprehensivereview[J]. Chemosphere, 2022, 307: 135869.
109	HUANG Na, WANG Tong, WU Yingxuan, et al. Preparation of magnetically recyclable hierarchical porous sludge-pine needle derived biochar loaded CoFe₂O₄ nanoparticles for rapid degradation of tetracycline by activated PMS[J]. Materials Today Communications, 2023, 35: 106313.
110	TAN Ye, LI Chunquan, SUN Zhiming, et al. Natural diatomite mediated spherically monodispersed CoFe₂O₄ nanoparticles for efficient catalytic oxidation of bisphenol A through activating peroxymonosulfate[J]. Chemical Engineering Journal, 2020, 388: 124386.
111	WANG Fuxue, ZHANG Ziyue, WANG Chongchen. Selective oxidation of aqueous organic pollutants over MOFs-based catalysts: A mini review[J]. Chemical Engineering Journal, 2023, 459: 141538.
112	YANG Shengjiong, QIU Xiaojie, JIN Pengkang, et al. MOF-templated synthesis of CoFe₂O₄ nanocrystals and its coupling with peroxymonosulfate for degradation of bisphenol A[J]. Chemical Engineering Journal, 2018, 353: 329-339.
113	HASSANI Aydin, EGHBALI Paria, MAHDIPOUR Fayyaz, et al. Insights into the synergistic role of photocatalytic activation of peroxymonosulfate by UVA-LED irradiation over CoFe₂O₄-rGO nanocomposite towards effective bisphenol A degradation: Performance, mineralization, and activation mechanism[J]. Chemical Engineering Journal, 2023, 453: 139556.
114	DEHVARI Mahboobeh, BABAEI Ali Akbar, ESMAEILI Shirin. Amplification of oxidative elimination of atrazine by ultrasound/ultraviolet-assisted sono/photocatalyst using a spinel cobalt ferrite-anchored MWCNT as peroxymonosulfate activator[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2023, 437: 114452.
115	ISSAKA Eliasu, AMU-DARKO Jesse Nii-Okai, YAKUBU Salome, et al. Advanced catalytic ozonation for degradation of pharmaceutical pollutants-A review[J]. Chemosphere, 2022, 289: 133208.
116	孔涛, 任诺, 陈春茂, 等. 多金属氧化物催化臭氧氧化有机污染物的研究进展[J]. 工业水处理, 2021, 41(7): 1-18.
	KONG Tao, REN Nuo, CHEN Chunmao, et al. Research progress of catalytic ozonation of organic contaminants by poly-metallic oxides[J]. Industrial Water Treatment, 2021, 41(7): 1-18.
117	DE OLIVEIRA Jivago Schumacher, SILVEIRA SALLA Julia DA, KUHN Raquel Cristine, et al. Catalytic ozonation of melanoidin in aqueous solution over CoFe₂O₄ catalyst[J]. Materials Research, 2018, 22(1): e20180405.
118	CAI C, DUAN X D, XIE J, et al. Efficient degradation of clofibric acid by heterogeneous catalytic ozonation using CoFe₂O₄ catalyst in water[J]. Journal of Hazardous Materials, 2021, 410: 124604.
119	ZHANG Fengzhen, WEI Chaohai, WU Kaiyi, et al. Mechanistic evaluation of ferrite AFe₂O₄ (A=Co, Ni, Cu, and Zn) catalytic performance in oxalic acid ozonation[J]. Applied Catalysis A: General, 2017, 547: 60-68.
120	徐俐, 刘东方, 安晓静, 等. CoFe₂O₄@MS活化过一硫酸盐处理6-硝氧体废水的研究[J]. 水处理技术, 2022, 48(8): 48-53.
	XU Li, LIU Dongfang, AN Xiaojing, et al. Treatment of 6-nitrogen wastewater by CoFe₂O₄@MS activated peroxymonosulfate[J]. Technology of Water Treatment, 2022, 48(8): 48-53.
121	HU Zheng, GE Ming, GUO Changsheng. Efficient removal of levofloxacin from different water matrices via simultaneous adsorption and photocatalysis using a magnetic Ag₃PO₄/rGO/CoFe₂O₄ catalyst[J]. Chemosphere, 2021, 268: 128834.

催化剂	制备方法	异质结类型	光源	污染物	降解效率	稳定性	参考文献
MoS₂/CoFe₂O₄	水热法	Z型	氙灯光源（300W，λ>420nm）	罗丹明B （20mg/L）	93.8% （90min）	7次循环（>82.1%）	[70]
MoS₂/CoFe₂O₄	水热法	Z型	氙灯光源（300W，λ>420nm）	刚果红（30mg/L）	94.43% （50min）	7次循环（>83.5%）	[70]
CoFe₂O₄@CoWO₄	共沉淀法	Ⅱ型	可见光（10W LED灯）	亚甲基蓝（20mg/L）	96.3% （120min）	6次循环（87.6%）	[71]
CoFe₂O₄-Bi₂O₃	共沉淀法	Ⅰ型	卤素灯（9500lm）	亚甲基蓝（10mg/L）	80.0% （200min）	6次循环（约80.0%）	[72]
BiOI/CoFe₂O₄	共沉淀法	Z型	模拟太阳光光源	罗丹明B （5mg/L）	91.3% （90min）	3次循环（80.2%）	[73]
CoFe₂O₄/MIL-101(Fe)	溶剂热法	S型	氙灯光源（300W，λ>420nm）	四环素（10mg/L）	90.0% （120min）	4次循环（约75.0%）	[74]
CoFe₂O₄/NiFe₂O₄	水热法	S型	模拟太阳光光源	盐酸四环素（10mg/L）	76.1% （60min）	—	[75]
CoFe₂O₄/g-C₃N₄	水热法	Z型	可见光（10W LED灯）	亚甲基蓝（10mg/L）	98.86% （140min）	5次循环（约82.5%）	[76]
ZnIn₂S₄/CoFe₂O₄/BC	溶剂热法	p-n型	氙灯光源（150W）	环丙沙星（20mg/L）	96.9% （120min）	6次循环（约96.9%）	[77]
CoFe₂O₄/g-C₃N₄/Bi₄Ti₃O₁₂	超声辅助热处理法	双Z型	可见光（45W节能灯）	孔雀石绿（10mg/L）	98.05% （120min）	3次循环（约98.05%）	[78]

催化剂	制备方法	异质结类型	光源	污染物	降解效率	稳定性	参考文献
MoS₂/CoFe₂O₄	水热法	Z型	氙灯光源（300W，λ>420nm）	罗丹明B （20mg/L）	93.8% （90min）	7次循环（>82.1%）	[70]
MoS₂/CoFe₂O₄	水热法	Z型	氙灯光源（300W，λ>420nm）	刚果红（30mg/L）	94.43% （50min）	7次循环（>83.5%）	[70]
CoFe₂O₄@CoWO₄	共沉淀法	Ⅱ型	可见光（10W LED灯）	亚甲基蓝（20mg/L）	96.3% （120min）	6次循环（87.6%）	[71]
CoFe₂O₄-Bi₂O₃	共沉淀法	Ⅰ型	卤素灯（9500lm）	亚甲基蓝（10mg/L）	80.0% （200min）	6次循环（约80.0%）	[72]
BiOI/CoFe₂O₄	共沉淀法	Z型	模拟太阳光光源	罗丹明B （5mg/L）	91.3% （90min）	3次循环（80.2%）	[73]
CoFe₂O₄/MIL-101(Fe)	溶剂热法	S型	氙灯光源（300W，λ>420nm）	四环素（10mg/L）	90.0% （120min）	4次循环（约75.0%）	[74]
CoFe₂O₄/NiFe₂O₄	水热法	S型	模拟太阳光光源	盐酸四环素（10mg/L）	76.1% （60min）	—	[75]
CoFe₂O₄/g-C₃N₄	水热法	Z型	可见光（10W LED灯）	亚甲基蓝（10mg/L）	98.86% （140min）	5次循环（约82.5%）	[76]
ZnIn₂S₄/CoFe₂O₄/BC	溶剂热法	p-n型	氙灯光源（150W）	环丙沙星（20mg/L）	96.9% （120min）	6次循环（约96.9%）	[77]
CoFe₂O₄/g-C₃N₄/Bi₄Ti₃O₁₂	超声辅助热处理法	双Z型	可见光（45W节能灯）	孔雀石绿（10mg/L）	98.05% （120min）	3次循环（约98.05%）	[78]

催化剂	制备方法	污染物	催化剂用量	PMS用量	降解效率	稳定性	参考文献
CoFe₂O₄@NPC	水热碳化法	罗丹明B （100mg/L）	0.06g/L	0.3g/L	99.05% （20min）	5次循环（约83.2%）	[100]
CoFe₂O₄/OMt	改性水热法	卡马西平（5mg/L）	0.4g/L	0.5mmol/L	93% （60min）	3次循环（73.0%）	[101]
CoFe₂O₄@BC	溶胶-凝胶法	对硝基氯苯（10mg/L）	0.1g/L	1mmol/L	89% （240min）	5次循环（87.8%）	[102]
CoFe₂O₄/Al₂O₃	溶胶-凝胶法	磺胺氯吡啶（5mg/L）	1.0mmol/L	0.5mmol/L	97.8% （15min）	4次循环（97.6%）	[103]
CoFe₂O₄-SAC	水热法	诺氟沙星（10mg/L）	0.1g/L	0.15g/L	>92% （60min）	5次循环（>90.0%）	[104]
CoFe₂O₄@MoS₂	一锅水热法	四环素（10mg/L）	0.2g/L	0.5mmol/L	94.45% （30min）	5次循环（约90.0%）	[105]
CoFe₂O₄/ZIF-8	溶剂热法	亚甲基蓝（20mg/L）	0.04g/L	0.3g/L	97.9% （60min）	4次循环（80.4%）	[106]
CoFe₂O₄@3DG	水热法	苯并三唑（100mg/L）	0.2g/L	16mmol/L	100% （150min）	7次循环（90.4%）	[107]

催化剂	制备方法	污染物	催化剂用量	PMS用量	降解效率	稳定性	参考文献
CoFe₂O₄@NPC	水热碳化法	罗丹明B （100mg/L）	0.06g/L	0.3g/L	99.05% （20min）	5次循环（约83.2%）	[100]
CoFe₂O₄/OMt	改性水热法	卡马西平（5mg/L）	0.4g/L	0.5mmol/L	93% （60min）	3次循环（73.0%）	[101]
CoFe₂O₄@BC	溶胶-凝胶法	对硝基氯苯（10mg/L）	0.1g/L	1mmol/L	89% （240min）	5次循环（87.8%）	[102]
CoFe₂O₄/Al₂O₃	溶胶-凝胶法	磺胺氯吡啶（5mg/L）	1.0mmol/L	0.5mmol/L	97.8% （15min）	4次循环（97.6%）	[103]
CoFe₂O₄-SAC	水热法	诺氟沙星（10mg/L）	0.1g/L	0.15g/L	>92% （60min）	5次循环（>90.0%）	[104]
CoFe₂O₄@MoS₂	一锅水热法	四环素（10mg/L）	0.2g/L	0.5mmol/L	94.45% （30min）	5次循环（约90.0%）	[105]
CoFe₂O₄/ZIF-8	溶剂热法	亚甲基蓝（20mg/L）	0.04g/L	0.3g/L	97.9% （60min）	4次循环（80.4%）	[106]
CoFe₂O₄@3DG	水热法	苯并三唑（100mg/L）	0.2g/L	16mmol/L	100% （150min）	7次循环（90.4%）	[107]

[1]	林梅洁, 米烁东, 包成. 金属-掺杂氧化铈体系H₂/CO电化学反应机理研究进展[J]. 化工进展, 2024, 43(S1): 209-224.
[2]	李帅哲, 聂懿宸, PHIDSAVARD Keomeesay, 顾雯, 张伟, 刘娜, 徐高翔, 刘莹, 李兴勇, 陈玉保. 非贵金属催化生物质加氢脱氧制备烃基生物燃料的研究进展[J]. 化工进展, 2024, 43(S1): 225-242.
[3]	石磊, 王倩, 赵晓胜, 刘宏臣, 车远军, 段玉, 李庆. 油页岩灰基分子筛的制备及对亚甲基蓝的吸附[J]. 化工进展, 2024, 43(S1): 650-661.
[4]	张政, 刘琳, 李子晨, 王梦琦, 黄春燕, 葛圆圆. 载铜地质聚合物微球的制备及其催化降解双酚S的性能[J]. 化工进展, 2024, 43(9): 5290-5301.
[5]	吴宇琦, 李江涛, 丁建智, 宋秀兰, 苏冰琴. 焙烧镁铝水滑石脱除厌氧消化沼气中CO₂的效果及机制[J]. 化工进展, 2024, 43(9): 5250-5261.
[6]	李镇武, 蒲迪, 熊亚春, 吴定莹, 金诚, 郭拥军. 驱油用纳米材料在提高采收率方面研究进展[J]. 化工进展, 2024, 43(9): 5035-5048.
[7]	焦文磊, 刘震, 陈俊先, 张天钰, 姬忠礼. 叶片式分离元件结构及性能影响因素研究进展[J]. 化工进展, 2024, 43(8): 4187-4202.
[8]	张茜, 李皓芯, 张天阳, 李子富, 孙文俊, 敖秀玮. 基于紫外线的高级氧化或高级还原技术降解水中全氟或多氟烷基化合物[J]. 化工进展, 2024, 43(8): 4587-4600.
[9]	刘玉灿, 高中鲁, 徐心怡, 纪现国, 张岩, 孙洪伟, 王港. 钙改性水葫芦基生物炭吸附水中敌草隆的效能与机理[J]. 化工进展, 2024, 43(8): 4630-4641.
[10]	曹景沛, 姚乃瑜, 庞新博, 赵小燕, 赵静平, 蔡士杰, 徐敏, 冯晓博, 伊凤娇. 煤热解研究进展及其发展历程[J]. 化工进展, 2024, 43(7): 3620-3636.
[11]	胡锐, 李先如, 朴玮玲, 冯盼, 罗磊, 罗刚, 卫皇曌, 刘振刚, 张士成. 有机废物水热转化设备与技术研究进展[J]. 化工进展, 2024, 43(7): 3672-3691.
[12]	龚德成, 沈倩, 朱贤青, 黄云, 夏奡, 张敬苗, 朱恂, 廖强. 微藻超临界水气化制取富氢合成气的研究进展[J]. 化工进展, 2024, 43(7): 3709-3728.
[13]	林翔, 焦芬, 魏茜, 张政权. 菱锌矿硫化浮选机理及影响因素研究进展[J]. 化工进展, 2024, 43(7): 4015-4031.
[14]	何弈雪, 秦先超, 马伟芳. 过硫酸盐高级氧化原位修复地下水中卤代烃污染研究进展[J]. 化工进展, 2024, 43(7): 4072-4088.
[15]	孟卫波, 邢宝林, 程松, 冯来宏, 施凤, 曾会会, 雷思乐, 王雪, 赵赛丹, 曾祥旺. 废塑料催化热解制备碳纳米管及其生长机理[J]. 化工进展, 2024, 43(6): 3468-3478.

基于尖晶石型CoFe₂O₄高级氧化降解水中有机污染物研究进展

Research progress on advanced oxidation degradation of organic pollutants in water based on spinel type CoFe₂O₄

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 11

参考文献 121

相关文章 15

编辑推荐

Metrics

本文评价