化工进展 ›› 2022, Vol. 41 ›› Issue (12): 6419-6429.DOI: 10.16085/j.issn.1000-6613.2022-0284

• 材料科学与技术 • 上一篇    下一篇

高温煤焦油沥青黏结剂碳化固结作用在炭质型材中的应用与研究进展

杨永斌(), 董寅瑞, 钟强(), 李骞, 王林, 姜涛   

  1. 中南大学资源加工与生物工程学院,湖南 长沙 410083
  • 收稿日期:2022-02-24 修回日期:2022-05-15 出版日期:2022-12-20 发布日期:2022-12-29
  • 通讯作者: 钟强
  • 作者简介:杨永斌(1969—),男,教授,博士生导师,主要从事钢铁冶金与资源综合利用研究。E-mail:ybyangcsu@126.com
  • 基金资助:
    国家重点研发计划(2020YFC1909805);湖南省重点研发计划(2022NK2057);湖南省自然科学基金(2021JJ40776)

Application and research progress of carbonization consolidation of high temperature coal tar pitch binder in formed carbon material

YANG Yongbin(), DONG Yinrui, ZHONG Qiang(), LI Qian, WANG Lin, JIANG Tao   

  1. School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, Hunan, China
  • Received:2022-02-24 Revised:2022-05-15 Online:2022-12-20 Published:2022-12-29
  • Contact: ZHONG Qiang

摘要:

高温煤焦油沥青(high temperature coal tar pitch,HTCTP)具有优良的润湿性和黏结性,可用作黏结剂。HTCTP黏结剂能与炭质颗粒物料产生良好的固结作用,因此在不同类型炭质型材的制备中获得广泛的应用与研究,HTCTP高温过程的黏结性能及碳化固结作用效果决定了炭质型材的机械强度和理化性能。本文综述了HTCTP作黏结剂制备炭质型材的一般工艺过程和相关研究进展,梳理了不同应用领域对HTCTP碳化固结作用的共性机制和个性特点,总结了HTCTP的性能影响因素及碳化固结作用机理。通过分析HTCTP不同组分在碳化固结过程中的作用及转化过程,揭示HTCTP碳化固结作用与炭质型材机械强度的关联机制及影响碳化固结强度的关键因素,提出强化HTCTP碳化固结作用的措施,提升HTCTP黏结剂在炭质型材制备中的应用效果。

关键词: 高温煤焦油沥青, 黏结剂, 颗粒物料, 炭质型材, 制备, 碳化固结

Abstract:

High temperature coal tar pitch (HTCTP) has excellent wettability and cohesiveness, and can be used as binder. HTCTP binder can produce good consolidation with carbonaceous granular materials, so it has been widely used and studied in the preparation of different types of formed carbon material. The mechanical strength and physicochemical properties of formed carbon material are determined by the bonding performance and carbonization consolidation effect of HTCTP in high temperature process. In this paper, the general technological process and relative research progress of carbonization materials prepared with HTCTP as binder are reviewed, and the common mechanism and individual characteristics of carbonization consolidation of HTCTP in different application fields are combed. The factors affecting the performance of HTCTP and the mechanism of carbonation consolidation are also summarized. By analyzing the role and transformation process of different components of coal pitch in carbonization consolidation process, the related mechanism between the carbonization consolidation of HTCTP and the mechanical strength of formed carbon material and the key factors influencing the carbonization consolidation strength are revealed. The measures to strengthen the carbonization consolidation of HTCTP were proposed to enhance the application effect of carbonization consolidation in the preparation of formed carbon material.

Key words: high temperature coal tar pitch, binder, granular materials, formed carbon material, preparation, carbonation consolidation

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