太阳能电絮凝技术在水处理中的研究进展

doi:10.16085/j.issn.1000-6613.2021-1230

摘要/Abstract

摘要：

太阳能电絮凝技术（SPEC）是一种水处理新技术，其结合了太阳能光伏发电可再生、可持续的特点和电絮凝处理废水无需添加化学药剂、产泥量少、设备易操作、占地小的优势，为太阳能丰富的地区带来了更加高效、环保和节能的水处理方法。本文阐明了电絮凝的原理，并分析了阳极材料、电极连接方式、电流密度、初始pH、电导率和极板间距对废水中污染物去除效率的影响。随后，重点综述了国内外学者对SPEC技术处理染料废水、含磷废水、含油废水、偏远地区分散式废水和SPEC与其他技术耦合处理废水的研究进展。最后，点明了SPEC技术当前存在的不足及挑战，并对未来的研究方向提出了展望。

关键词: 电絮凝, 再生能源, 废水, 电化学

Abstract:

Solar powered electrocoagulation technology is a new water treatment technology, which combines the renewable and sustainable characteristics of solar photovoltaic power generation and the advantages of electrocoagulation in wastewater treatment. Such as no need to add chemicals, less sludge production, easy operation of equipment and small land occupation. SPEC brings a more efficient, environmentally friendly and energy-saving water treatment method for areas rich in solar energy. The principle of electrocoagulation is expounded, and analyze the effects of anode material, electrode arrangement, current density, pH, initial conductivity and plate spacing on pollutant removal efficiency. Then the research progress of domestic and foreign scholars on the treatment of dye wastewater, phosphorus-containing wastewater, oily wastewater,diecentralized wastewater in remote areas and SPEC coupled with other technologies for wastewater treatment are emphatically discussed. In the end, the shortages and challenges of solar powered electrocoagulation technology are pointed out, and put forward prospect of the future research direction.

Key words: electrocoagulation, renewable energy, waste water, electrochemistry

中图分类号:

X703

王一茹, 宋小三, 王三反, 范文江. 太阳能电絮凝技术在水处理中的研究进展[J]. 化工进展, 2021, 40(S2): 373-379.

WANG Yiru, SONG Xiaosan, WANG Sanfan, FAN Wenjiang. Research progress of solar powered electrocoagulation technology in water treatment[J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 373-379.

图/表 2

参考文献 36

1	张俊, 杨敬一, 徐心茹. 电絮凝技术处理油田含油污水的研究 [J]. 现代化工, 2013, 33(1): 52-56.
	ZHANG Jun, YANG Jingyi, XU Xinru. Study on the treatment of oily wastewater by electrocoagulation technology[J]. Modern Chemical Industry, 2013, 33(1): 52-56.
2	KHANDEGAR V, SAROHA A K. Electrocoagulation for the treatment of textile industry effluent—A review[J]. Journal of Environmental Management, 2013, 128: 949-963.
3	SHAFAEI A, REZAIE M, NIKAZAR M. Evaluation of Mn²⁺ and Co²⁺ removal by electrocoagulation: a case study[J]. Chemical Engineering and Processing: Process Intensification, 2011, 50(11-12): 1115-1121.
4	GILPAVAS E, DOBROSZ-GOMEZ I, GOMEZ-GARCIA M A. The removal of the trivalent chromium from the leather tannery wastewater: the optimisation of the electro-coagulation process parameters[J]. Water Science and Technology, 2011, 63(3): 385-394.
5	高艳娇, 黄继国, 沈照理, 等. 电絮凝工艺处理垃圾填埋场渗滤液 [J]. 水处理技术, 2006(1): 48-50.
	GAO Yanjiao, HUANG Jiguo, SHEN Zhaoli, et al. Treatment of landfill leachate by electrocoagulation process[J]. Technology of Water Treatment, 2006(1): 48-50.
6	戴常超, 陈大宏, 刘峻峰, 等. 强化电絮凝技术的基础，现状和未来展望 [J]. 工业水处理, 2021(1): 11-22.
	DAI Changchao, CHEN Dahong, LIU Junfeng, et al. Foundation, present situation and future prospect of enhanced electrocoagulation technology[J]. Industrial Water Treatment, 2021(1): 11-22.
7	RICHARDS B S, SCHÄFER A I. Design considerations for a solar-powered desalination system for remote communities in Australia [J]. Desalination, 2002, 144(1): 193-199.
8	ŞEN Z. Solar energy in progress and future research trends[J]. Progress in Energy and Combustion Science, 2004, 30(4): 367-416.
9	TIANZE L, HENGWEI L, CHUAN J, et al. Application and design of solar photovoltaic system[J]. Journal of Physics: Conference Series, 2011, 276(1):116-145.
10	李柯, 何凡能. 中国陆地太阳能资源开发潜力区域分析[J]. 地理科学进展, 2010, 29(9): 1049-1054.
	KE Li, HE Fanneng. Regional analysis of the development potential of terrestrial solar energy resources in China[J]. Progress in Geography, 2010, 29(9): 1049-1054.
11	ZHANG Y, SIVAKUMAR M, YANG S, et al. Application of solar energy in water treatment processes: a review[J]. Desalination, 2018, 428(1): 116-145.
12	赵星. 光伏发电系统在水处理行业中的应用探讨[J]. 城市建设理论研究(电子版), 2016, 22(1): 101-103.
	ZHAO Xing. Application of photovoltaic power generation system in water treatment industry[J]. Urban Construction Theory Research, 2016, 22(1): 101-103.
13	DANESHVAR N, SORKHABI H A, KASIRI M B. Decolorization of dye solution containing Acid Red 14 by electrocoagulation with a comparative investigation of different electrode connections[J]. Journal of Hazardous Materials, 2004, 112(1/2): 55-62.
14	符文祥. 电子凝絮技术在火力发电厂煤水回用处理中的应用[J]. 自动化应用, 2020(8): 96-98.
	FU Wenxiang. Application of electronic flocculation technology in coal water reuse treatment of thermal power plant[J]. Automation Application, 2020(8): 96-98.
15	周杰, 宋小三, 王三反. 水处理电絮凝技术的研究进展与挑战[J]. 化工进展, 2020, 39(S2): 329-335.
	ZHOU Jie, SONG Xiaosan, WANG Sanfan. Research progress and challenge of electrocoagulation technology in water treatment[J]. Chemical Industry and Engineering Progress, 2020, 39(S2): 329-335.
16	李燕莉. 电凝聚对微污染水中污染物的去除研究[D]. 武汉: 武汉科技大学, 2004.
	LI Yanli. Study on the removal of pollutants in micro-polluted water by electrocoagulation[D]. Wuhan: Wuhan University of Science and Technology, 2004.
17	CALVO L S, LECLERC J P, TANGUY G, et al. An electrocoagulation unit for the purification of soluble oil wastes of high COD[J]. Environmental Progress, 2003, 22(1): 57-65.
18	N.P JOHNSON, AMIRTHARAJAH, et al. Ferric chloride and alum as single and dual coagulants[J]. Journal- American Water Works Association, 1983, 75(5): 232-239.
19	林辉. 脉冲电絮凝处理餐饮废水的研究[D]. 武汉:武汉大学, 2004.
	LIN Hui. Study on the treatment of restaurant wastewater by pulse electrocoagulation[D]. Wuhan: Wuhan University, 2004.
20	DEMIRCI Y, PEKEL L C, ALPBAZ M. Investigation of different electrode connections in electrocoagulation of textile wastewater treatment)[J]. International Journal of Electrochemical Science, 2015, 10(3): 2685-2693.
21	MOLLAH M Y A, MORKOVSKY P, GOMES J A G, et al. Fundamentals, present and future perspectives of electrocoagulation[J]. Journal of Hazardous Materials, 2004, 114(1): 199-210.
22	李勇东, 吴迪, 郑文笑, 等. PbO₂/Fe双阳极耦合促进焦化废水除碳脱氮[J]. 环境化学, 2020, 39(6): 1650-1659.
	LI Yongdong, WU Di, ZHENG Wenxiao, et al. PbO₂/Fe double anode coupling promotes carbon and nitrogen removal from coking wastewater[J]. Environmental Chemistry, 2020, 39(6): 1650-1659.
23	CHEN X, CHEN G, YUE P L. Separation of pollutants from restaurant wastewater by electrocoagulation[J]. Separation and Purification Technology, 2000, 19(1): 65-76.
24	BAYRAMOGLU M, KOBYA M, CAN O T, et al. Operating cost analysis of electrocoagulation of textile dye wastewater[J]. Separation and Purification Technology, 2004, 37(2): 117-125.
25	秦彬, 谷晋川, 殷萍, 等. 染料废水处理技术研究进展 [J]. 化工环保, 2021, 41(1): 9-18.
	QIN Bin, GU Jinchuan, YIN Ping, et al. Research progress of dye wastewater treatment technology[J]. Environmental Protection of Chemical Industry, 2021, 41(1): 9-18.
26	VALERO D, ORTIZ J, EXPOSITO E, et al. Electrocoagulation of a synthetic textile effluent powered by photovoltaic energy without batteries: direct connection behaviour[J]. Solar Energy Materials and Solar Cells, 2008, 92(3): 291-297.
27	PIRKARAMI A, OLYA M E, TABIBIAN S. Treatment of colored and real industrial effluents through electrocoagulation using solar energy[J]. Journal of Environmental Science and Health, Part A, 2013, 48(10): 1243-1252.
28	ZHANG S, ZHANG J, WANG W, et al. Removal of phosphate from landscape water using an electrocoagulation process powered directly by photovoltaic solar modules[J]. Solar Energy Materials and Solar Cells, 2013, 117(1):73-80.
29	李俊聪, 黄尚雄, 吴东亮, 等. 电絮凝法去除新农村微污染水体中磷的研究[J]. 广东化工, 2012, 39(11): 147-148.
	LI Juncong, HUANG Shangxiong, WU Dongliang, et al. Study on phosphorus removal from micro-polluted water in new countryside by electrocoagulation[J]. Guangdong Chemical Industry, 2012, 39(11): 147-148.
30	刘杨. 含油污水电絮凝法除油机理及强化除油性能实验研究[D]. 青岛: 中国石油大学(华东), 2017.
	LIU Yang. Experimental study on oil removal mechanism and enhanced oil removal performance of oil-contaminated hydropower flocculation method[D]. Qingdao: China University of Petroleum (East China), 2017.
31	王宇航, 黄秋阳, 卫治安, 等. 关于太阳能耦合电絮凝处理沿海油库含油污水的研究[J]. 中国水运(下半月), 2017, 17(8): 173-174.
	WANG Yuhang, HUANG Qiuyang, WEI Zhian, et al. Study on the treatment of oily wastewater from coastal oil depots by solar coupled electrocoagulation[J]. China Water Transport, 2017, 17(8): 173-174.
32	ST-ONGE J, CARABIN A, DIA O, et al. Development of a solar electrocoagulation technology for decentralised water treatment[J]. Proceedings of the Institution of Civil Engineers-Water Management, 2020, 173(1): 46-52.
33	NAWARKAR C J, SALKAR V D. Solar powered electrocoagulation system for municipal wastewater treatment[J]. Fuel, 2019, 237(1): 222-226.
34	SHARMA G, CHOI J, SHON H K, et al. Solar-powered electrocoagulation system for water and wastewater treatment[J]. Desalination and Water Treatment, 2011, 32(1-3): 381-388.
35	HUSSIN F, AROUA M K, SZLACHTA M. Combined solar electrocoagulation and adsorption processes for Pb(Ⅱ) removal from aqueous solution[J]. Chemical Engineering and Processing-Process Intensification, 2019, 143(1): 111-166
36	GARCÍA-GARCÍA A, MARTÍNEZ-MIRANDA V, MARTÍNEZ-CIENFUEGOS I G, et al. Industrial wastewater treatment by electrocoagulation-electrooxidation processes powered by solar cells[J]. Fuel, 2015, 149(1): 46-54.

[1]	张明焱, 刘燕, 张雪婷, 刘亚科, 李从举, 张秀玲. 非贵金属双功能催化剂在锌空气电池研究进展[J]. 化工进展, 2023, 42(S1): 276-286.
[2]	胡喜, 王明珊, 李恩智, 黄思鸣, 陈俊臣, 郭秉淑, 于博, 马志远, 李星. 二硫化钨复合材料制备与储钠性能研究进展[J]. 化工进展, 2023, 42(S1): 344-355.
[3]	张杰, 白忠波, 冯宝鑫, 彭肖林, 任伟伟, 张菁丽, 刘二勇. PEG及其复合添加剂对电解铜箔后处理的影响[J]. 化工进展, 2023, 42(S1): 374-381.
[4]	许春树, 姚庆达, 梁永贤, 周华龙. 共价有机框架材料功能化策略及其对Hg(Ⅱ)和Cr(Ⅵ)的吸附性能研究进展[J]. 化工进展, 2023, 42(S1): 461-478.
[5]	赵景超, 谭明. 表面活性剂对电渗析减量化工业含盐废水的影响[J]. 化工进展, 2023, 42(S1): 529-535.
[6]	雷伟, 姜维佳, 王玉高, 和明豪, 申峻. N、S共掺杂煤基碳量子点的电化学氧化法制备及用于Fe³⁺检测[J]. 化工进展, 2023, 42(9): 4799-4807.
[7]	王晨, 白浩良, 康雪. 大功率UV-LED散热与纳米TiO₂光催化酸性红26耦合系统性能[J]. 化工进展, 2023, 42(9): 4905-4916.
[8]	王琦, 寇丽红, 王冠宇, 王吉坤, 刘敏, 李兰廷, 王昊. 焦化废水生物出水中可溶解性有机物的分子识别[J]. 化工进展, 2023, 42(9): 4984-4993.
[9]	史天茜, 石永辉, 武新颖, 张益豪, 秦哲, 赵春霞, 路达. Fe²⁺对厌氧氨氧化EGSB反应器运行性能的影响[J]. 化工进展, 2023, 42(9): 5003-5010.
[10]	王耀刚, 韩子姗, 高嘉辰, 王新宇, 李思琪, 杨全红, 翁哲. 铜基催化剂电还原二氧化碳选择性的调控策略[J]. 化工进展, 2023, 42(8): 4043-4057.
[11]	刘毅, 房强, 钟达忠, 赵强, 李晋平. Ag/Cu耦合催化剂的Cu晶面调控用于电催化二氧化碳还原[J]. 化工进展, 2023, 42(8): 4136-4142.
[12]	张亚娟, 徐惠, 胡贝, 史星伟. 化学镀法制备NiCoP/rGO/NF高效电解水析氢催化剂[J]. 化工进展, 2023, 42(8): 4275-4282.
[13]	王帅晴, 杨思文, 李娜, 孙占英, 安浩然. 元素掺杂生物质炭材料在电化学储能中的研究进展[J]. 化工进展, 2023, 42(8): 4296-4306.
[14]	郑梦启, 王成业, 汪炎, 王伟, 袁守军, 胡真虎, 何春华, 王杰, 梅红. 菌藻共生技术在工业废水零排放中的应用与展望[J]. 化工进展, 2023, 42(8): 4424-4431.
[15]	李海东, 杨远坤, 郭姝姝, 汪本金, 岳婷婷, 傅开彬, 王哲, 何守琴, 姚俊, 谌书. 炭化与焙烧温度对植物基铁碳微电解材料去除As(Ⅲ)性能的影响[J]. 化工进展, 2023, 42(7): 3652-3663.