二氧化碳水合物稳定储存的影响因素研究进展

doi:10.16085/j.issn.1000-6613.2021-1275

化工进展 ›› 2021, Vol. 40 ›› Issue (S2): 364-372.DOI: 10.16085/j.issn.1000-6613.2021-1275

二氧化碳水合物稳定储存的影响因素研究进展

王英梅¹^,²^,³^,⁴(), 张兆慧¹^,²^,³, 牛爱丽¹^,²^,³, 刘生浩¹^,²^,³, 焦雯泽¹^,²^,³, 张鹏⁴

^1.兰州理工大学能源与动力工程学院，甘肃兰州 730050
^2.甘肃省生物质能与太阳能互补供能系统重点实验室，甘肃兰州 730050
^3.兰州理工大学西部能源与环境研究中心，甘肃兰州 730050
^4.中国科学院西北生态环境资源研究院冻土工程国家重点实验室，甘肃兰州 730050

收稿日期:2021-06-17 修回日期:2021-06-28 出版日期:2021-11-12 发布日期:2021-11-12
通讯作者: 王英梅
作者简介:王英梅（1987—），女，博士，副教授，硕士研究生导师，主要从事多年冻土区天然气水合物方面的研究工作。E-mail: wymch@lab.ac。
基金资助:
国家自然科学基金(41661103);中国科学院冻土工程国家重点实验室开放基金(SKLFSE201406);国家重点研发计划(2017YFC0307303)

Research progress on influencing factors of stable storage of carbon dioxide hydrate

WANG Yingmei¹^,²^,³^,⁴(), ZHANG Zhaohui¹^,²^,³, NIU Aili¹^,²^,³, LIU Shenghao¹^,²^,³, JIAO Wenze¹^,²^,³, ZHANG Peng⁴

^1.School of Energy and Power Engineering, Lanzhou University of Technology, Lanzhou 730050, Gansu, China
^2.Key Lab of Complementary Energy System of Biomass and Solar Energy Gansu Province, Lanzhou 730050, Gansu, China
^3.Western China Energy & Environment Research Center, Lanzhou University of Technology, Lanzhou 730050, Gansu, China
^4.Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730050, Gansu, China

Received:2021-06-17 Revised:2021-06-28 Online:2021-11-12 Published:2021-11-12
Contact: WANG Yingmei

摘要/Abstract

摘要：

CO₂置换开采天然气水合物以及水合物法气体储运技术是当前科学家们研究的热点，而水合物的稳定性对其长时间储存和长距离运输至关重要。因此必须提高二氧化碳水合物储存能力和寻求水合物高效稳定的储存条件，然而科学家们发现一些促进剂可以使水合物在温和的条件下长时间存储。本文从“自保护”效应的3种机制、温度、压力以及粒径、促进剂和水合物形态这些因素分析了其对二氧化碳水合物稳定性的影响，证明气体水合物普遍在260~270K和0.1~0.4MPa的条件下稳定性较好，并且同种促进剂在冰点上下对水合物稳定性的影响不同，最后指出了水合物稳定性方面今后的研究方向。

关键词: 二氧化碳水合物, 可控分解, 稳定储存, 促进剂

Abstract:

Gas hydrate extraction by CO₂ replacement and gas storage and transportation by gas hydrate method are the focus of research by scientists at present, and the stability of gas hydrate is very important for its long-term storage and long-distance transportation. Therefore, it is necessary to improve the storage capacity of carbon dioxide hydrate and to seek the high efficient and stable storage conditions of hydrate. However, scientists have found that some accelerators can make hydrate stored for a long time under mild conditions. This paper analyzes the influence of the“self-protection”effect on the stability of carbon dioxide hydrate from the three mechanisms, temperature, pressure, particle size, accelerator and hydrate form, and proves that gas hydrate generally has good stability under the conditions of 260~270K and 0.1~0.4MPa. In addition, the same accelerators have different effects on the stability of hydrate above and below freezing point. Finally, the research direction of hydrate stability in the future is pointed out.

Key words: carbon dioxide hydrate, controlled decomposition, stable storage, accelerator

中图分类号:

O643.1

王英梅, 张兆慧, 牛爱丽, 刘生浩, 焦雯泽, 张鹏. 二氧化碳水合物稳定储存的影响因素研究进展[J]. 化工进展, 2021, 40(S2): 364-372.

WANG Yingmei, ZHANG Zhaohui, NIU Aili, LIU Shenghao, JIAO Wenze, ZHANG Peng. Research progress on influencing factors of stable storage of carbon dioxide hydrate[J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 364-372.

图/表 2

参考文献 80

1	宋琦. 多元复杂体系水合物生成的实验及热动力学模型研究[D]. 常州: 常州大学,2010.
	SONG Qi. Experimental study and thermodynamic model of hydrate formation in multi-complex system[D]. Changzhou: Changzhou University,2010.
2	李旭光. 天然气水合物生成影响因素及稳定性研究[D]. 北京:中国石油大学,2008.
	LI Xuguang. Study on the influencing factors and stability of natural gas hydrate generation[D]. Beijing：China University of Petroleum, 2008.
3	王林军, 张学民, 张东, 等. 水合物法储存温室气体二氧化碳的可行性分析[J]. 中国沼气,2011,29(6):28-32.
	WANG Linjun, ZAHNG Xuemin, ZHANG Dong, et al. Feasibility analysis of greenhouse gas carbon dioxide storage by hydrate method [J]. China Biogas, 2011, 29(6): 28-32.
4	孙玉景, 周立发, 李越. CO₂海洋封存的发展现状[J]. 地质科技情报,2018,37(4):212-218.
	SUN Yujing, ZHOU Lifa, LI Yue. Current situation of CO₂ sequestration in ocean[J]. Geological Science and Technology Information, 2018, 37(4):212-218.
5	王菲菲. 二氧化碳置换甲烷水合物微观实验研究[D]. 武汉: 中国地质大学,2015.
	WNAG Feifei. Microscopic experimental study on carbon dioxide replacement of methane hydrate[D]. Wuhan: China University of Geosciences, 2015.
6	刘锋. 南海北部陆坡天然气水合物分解引起的海底滑坡与环境风险评价[D]. 青岛: 中国科学院研究生院（海洋研究所）, 2010.
	LIU Feng. Geochemical characteristics and environmental risk assessment of natural gas hydrate decomposition in the Northern Slope of South China Sea[D]. Qingdao: Graduate University of Chinese Academy of Sciences (Institute of Oceanology),2010.
7	郭彪, 侯吉瑞, 于春磊, 等. CO₂在多孔介质中扩散系数的测定[J]. 石油化工高等学校学报,2009, 22(4):38-40.
	GUO Biao, HOU Jirui, YU Chunlei, et al. Determination of diffusion coefficient of CO₂ in porous media[J]. Journal of Petrochemical Universities, 2009, 22(4): 38-40.
8	ZHONG D L, HE S Y, SUN D J, et al. Comparison of methane hydrate formation in stirred reactor and porous media in the presence of SDS[J]. Energy Procedia, 2014, 61(3): 1573-1576.
9	PENG X M, HU Y F, YANG L Y, et al. Decomposition kinetics for formation of CO₂ hydrates in natural silica sands[J]. Chinese Journal of Chemical Engineering, 2010, 18(1): 61-65.
10	陶向磊. 基于天然气水合物奇异自保护效应研究发展及其应用[J]. 化工管理, 2014(27): 22-22.
	TAO Xianglei. Research development and application based on the singular self-protection effect of natural gas hydrate[J]. Chemical Enterprise Management, 2014(27): 22-22.
11	张军. 二氧化碳水合物结构及其稳定性的分子动力学研究[D]. 湘潭: 湘潭大学, 2016.
	ZHANG Jun. Molecular dynamics study on the structure and stability of carbon dioxide hydrate[D]. Xiangtan: Xiangtan University, 2016.
12	孙长宇, 马昌峰, 陈光进, 等. 二氧化碳水合物分解动力学研究[J]. 石油大学学报(自然科学版), 2001, 25(3): 8-10.
	SUN Changyu, MA Changfeng, CHEN Guangjin, et al. Study on decomposition kinetics of carbon dioxide hydrate[J]. Journal of the University of Petroleum, China, 2001, 25(3): 8-10.
13	田龙, 樊栓狮, 郝文峰. 甲烷水合物常压分解[J]. 武汉理工大学学报, 2006, 28(7): 23-26.
	TIAN Long, FAN Shuanshi, HAO Wenfeng. Methane hydrate is decomposed by constant pressure[J]. Journal of Wuhan University of Technology, 2006, 28(7):23-26.
14	PATEL N C, TEJA A S. A new cubic equation of state for fluids and fluid mixtures[J]. Chemical Engineering Science, 1982, 37(3): 463-473.
15	陈雪萍, 张鹏, 吴青柏. “自保护”态CO₂水合物分解动力及影响因素[J].天然气地球科学, 2020, 31(2): 184-193.
	CHEN Xueping, ZHANG Peng, WU Qingbai. Decomposition dynamics and influencing factors of "self-protecting" CO₂ hydrate[J]. Natural Gas Geoscience,2020, 31(2): 184-193.
16	展静, 吴青柏, 杨玉忠. 冰点以下甲烷水合物分解实验对天然气储运的影响[J]. 天然气地球科学, 2012, 23(2): 348-352.
	ZHAN Jing, WU Qingbai, YANG Yuzhong. Effect of methane hydrate decomposition experiment below freezing point on natural gas storage and transportation[J]. Natural Gas Geoscience, 2012, 23(2): 348-352.
17	TAKEYA S, SHIMADA W, KAMATA Y, et al. In situ X-ray diffraction measurements of the self-preservation effect of CH₄hydrate[J]. The Journal of Physical Chemistry A, 2001, 105(42): 9756-9759.
18	MISYURA S Y, DONSKOY I G. Dissociation of natural and artificial gas hydrate[J]. Chemical Engineering Science, 2016, 148(8): 65-77.
19	REHDER G, ECKL R, ELFGEN M, et al. Methane hydrate pellet transport using the self-preservation effect: a techno-economic analysis[J]. Energies, 2012, 5(7): 2499-2523.
20	展静, 吴青柏, 蒋观利. 冰颗粒粒径对冰点以下甲烷水合物自保护效应的影响[J]. 天然气地球科学, 2008, 19(4): 577-580.
	ZHAN Jing, WU Qingbai, JIANG Guanli. Effect of ice particle size on self-protection of methane hydrate below freezing point[J]. Natural Gas Geoscience,2008, 19(4): 577-580.
21	STERN L A, CIRCONE S, KIRBY S H, et al. Anomalous preservation of pure methane hydrate at 1atm[J]. The Journal of Physical Chemistry B, 2001, 105(9): 1756-1762.
22	STERN L A, CIRCONE S, KIRBY S H, et al. Temperature, pressure, and compositional effects on anomalous or “self”preservation of gas hydrates[J]. Canadian Journal of Physics, 2003, 81(1): 271-283.
23	DUO S, YUSUKE, et al. Preservation of carbon dioxide clathrate hydrate at temperatures below the water freezing point under atmospheric pressure[J]. Industrial & Engineering Chemistry Research,2011, 50(24): 13854-13858.
24	TAKEYA K, TAKAHASHI R, KAWASE K. Terahertz time domain spectroscopy on methane hydrate[C]//2016 41st International Conference on Infrared, Millimeter, and Terahertz waves (IRMMW-THz). IEEE, 2016.
25	雷旭. CO₂水合物生成和分解过程的核磁共振研究[D]. 大连: 大连理工大学, 2019.
	LEI Xu. NMR study on the formation and decomposition of CO₂ hydrate [D]. Dalian: Dalian University of Technology, 2019.
26	UCHIDA T, YAMAZAKI K, GOHARA K. Generation of micro- and nano-bubbles in water by dissociation of gas hydrates[J]. Korean Journal of Chemical Engineering, 2016, 33(5): 1749-1755.
27	YAGASAKI T, MATSUMOTO M, ANDOH Y, et al. Effect of bubble formation on the dissociation of methane hydrate in water: a molecular dynamics study[J]. The Journal of Physical Chemistry B, 2014, 118(7):1900-1906.
28	苏凯. 多元体系水合物降压分解实验研究[D]. 长春: 吉林大学,2017.
	SU Kai. Experimental study on decompression of hydrate in multi-component system[D]. Changchun: Jilin University, 2017.
29	王英梅, 吴青柏, 张鹏, 等. 冰点以下甲烷水合物等压分解实验研究[J].天然气地球科学, 2009, 20(2): 244-248.
	WANG Yingmei, WU Qingbai, ZHANG Peng, et al. Experimental study on isobaric decomposition of methane hydrate below freezing point[J]. Natural Gas Geoscience, 2009, 20(2): 244-248.
30	林微, 陈光进, 吴志恺, 等. 甲烷水合物热稳定性的研究[J].天然气工业,2005,25(2): 169-171, 221.
	LIN Wei, CHEN Guangjin, WU Zhikai, et al. Study on thermal stability of methane hydrate[J]. Natural Gas Industry,2005, 25(2): 169-171, 221.
31	GIAVARINI C, MACCIONI F, POLITI M, et al. CO₂ Hydrate: formation and dissociation compared to methane hydrate[J]. Energy & Fuels, 2007, 21(6): 3284-3291.
32	GUDMUNDSSON J S, PARLAKTUNA M, LEVIK O I, et al. Laboratory for continuous production of natural gas hydrates[J]. Annals of the New York Academy of Sciences, 2000, 912(1): 851-858.
33	温永刚, 陈秋雄, 陈运文, 等. 冰点以下甲烷水合物密闭分解特性实验研究[J]. 低温工程, 2013(6): 10-14.
	WEN Yonggang, CHEN Qiuxiong, CHEN Yunwen, et al. Experimental study on closed decomposition characteristics of methane hydrate below freezing point[J]. Cryogenic Engineering, 2013(6): 10-14.
34	LIN W, CHEN G J, SUN C Y, et al. Effect of surfactant on the formation and dissociation kinetic behavior of methane hydrate[J]. Chemical Engineering Science, 2004, 59(21): 4449-4455.
35	LIN W, CHEN W D, CHEN G J, et al. The dependence of the dissociation rate of methane SDS hydrate below ice point on its manners of forming and processing[J]. Chinese Journal of Chemical Engineering, 2009, 17(1): 128-135.
36	QIANG W, ZHANG B. Effect of surfactant on the induction time of gas hydrate formation[J]. Journal of China University of Mining & Technology, 2007, 18(1): 18-21.
37	ZHOU S D, WANG S L, ZAHNG G Z. Effect of different surfactants on gas hydrate formation[J]. Advanced Materials Research, 2013, 645(15):146-149.
38	赵光华. CO₂-N₂-TBAB-H₂体系水合物生成实验和模型研究[J]. 石油化工高等学校学报, 2016, 29(6): 11-17.
	ZAHO Guanghua. Experimental study on hydrate formation in CO₂-N₂-TBAB-H₂ system [J]. Journal of Petrochemical Universities, 2016,29(6): 11-17.
39	何京玲, 诸林. SD和THF对水合物法捕集模拟烟气中CO₂的影响[J]. 石油与天然气化工, 2019, 48(2): 63-69.
	HE Jingling, ZHU Lin. Effect of SDS and THF on CO₂ in simulated flue gas trapping by hydrate process [J]. Chemical Engineering of Oil and Gas, 2019, 48(2): 63-69.
40	王素莹. 天然产物促进甲烷水合物形成动力学研究[D]. 广州: 华南理工大学, 2019.
	WANG Suying. Study on the kinetics of methane hydrate formation by natural products[D]. Guangzhou: South China University of Technology,2019.
41	杜建伟, 梁德青, 戴兴学，等. Span80促进甲烷水合物生成动力学研究[J]. 工程热物理学报, 2011, 32(2): 197-200.
	DU Jianwei, LIANG Deqing, DAI Xingxue, et al. Span80 promotes the kinetics of methane hydrate generation[J]. Journal of Engineering Thermophysics, 2011, 32(2): 197-200.
42	李建敏, 王树立, 饶永超, 等. 离子液体强化二氧化碳水合物生成实验研究[J]. 现代化工, 2014, 34(12):124-127.
	LI Jianmin, WANG Shuli, RAO Yongchao, et al. Experimental study on the formation of carbon dioxide hydrate enhanced by ionic liquid[J]. Modern Chemical Industry, 2014, 34(12): 124-127.
43	张琳, 徐小军, 周诗岽, 等. 1-甲基咪唑离子液体促进CO₂水合物生成实验探究[J]. 天然气化工(C1化学与化工), 2013, 38(5): 1-4, 46.
	ZAHNG Lin, XU Xiaojun, ZHOU Shidong, et al. Experimental study on the formation of CO₂ hydrate by 1-methylimidazole ionic liquid[J]. Natural Gas Chemical Industry, 2013, 38(5): 1-4, 46.
44	于永涛, 徐恒, 王树立, 等. 几类新型添加剂对气体水合物生成促进的研究[J]. 天然气化工(C1化学与化工), 2011, 36(6): 15-20.
	YU Yongtao, XU Heng, WANG Shuli, et al. Study on the promotion of gas hydrate by several new additives[J]. Natural Gas Chemical Industry, 2011, 36(6): 15-20.
45	LI Z, YAN S, ZHOU Y. Enhancement of the methane storage on activated carbon by preadsorbed water[J]. Aiche Journal, 2002, 48(10):2412-2416.
46	LI Z, MING L, YAN S, et al. Effect of moisture in microporous activated carbon on the adsorption of methane[J]. Carbon, 2001, 39(5):773-776.
47	WANG W X, ZENG P Y, Methane storage in tea clathrates[J].Chemical communications, 2014, 50(10): 1244-1246.
48	SUN Q, CHEN B, LI Y, et al. Promotion effects of mung starch on methane hydrate formation equilibria/rate and gas storage capacity[J]. Fluid Phase Equilibria, 2018, 475(4): 95-99.
49	李凌乾. 撞击流反应器内二氧化碳水合物生成动力学研究[D]. 郑州: 郑州大学, 2018.
	LI Lingqian. Research on the kinetics of carbon dioxide hydrate formation in impingement flow reactor[D]. Zhengzhou: Zhengzhou University, 2018.
50	刘妮, 由龙涛, 余宏毅. 含盐体系二氧化碳水合物的生成与分解特性[J]. 中国电机工程学报, 2014, 34(2): 295-299.
	LIU Ni, YOU Longtao, HONG Yuyi. Formation and decomposition characteristics of carbon dioxide hydrate in saline system[J]. Proceedings of the CSEE, 2014, 34(2): 295-299.
51	ZANG X Y, DU J W, LIANG D P, et al. Influence of A-type zeolite on methane hydrate formation[J]. Chinese Journal of Chemical Engineering, 2009, 17(5): 854-859.
52	KANG S P, LEE J W. Formation characteristics of synthesized natural gas hydrates in meso and macroporous silica gels[J]. The Journal of Pphysical Chemistry, 2010, 114(20): 6973-6978.
53	周诗岽, 余益松, 张锦, 等. 纳米流体强化气体水合物生成研究进展[J]. 现代化工, 2014, 34(4): 51-56.
	ZHOU Shidong, YU Yisong, ZHANG Jin, et al. Research progress in enhancing gas hydrate generation by nanofluids[J]. Modern Chemical Industry, 2014, 34(4): 51-56.
54	陈玉龙. 氨基酸促进甲烷水合物形成的机理研究[D]. 广州: 华南理工大学, 2016.
	CHEN Yulong. Study on the mechanism of amino acids promoting the formation of methane hydrate[D]. Guangzhou: South China University of Technology, 2016.
55	VELUSWAMY H P, KUMAR A, KUMAR R, et al. An innovative approach to enhance methane hydrate formation kinetics with leucine for energy storage application[J]. Applied Energy, 2017, 188(7): 356-360.
56	FAKHARIAN H, GAN J H, FAR A N, et al. Potato starch as methane hydrate promoter[J]. Fuel, 2012, 94(16): 356-360.
57	李金平, 马涛, 王建森, 等. 表面活性剂对水合物生长过程的定量影响[J]. 工程热物理学报, 2010, 31(5): 793-796.
	LI Jinping, MA Tao, WANG Jiansen, et al. Quantitative effect of surfactant on hydrate growth process[J]. Journal of Engineering Thermophysics, 2010, 31(5): 793-796.
58	章春笋, 樊栓狮, 郭彦坤, 等. 不同类型表面活性剂对天然气水合物形成过程的影响[J]. 天然气工业, 2003(1): 91-95.
	ZHANG Chunsun, FAN Shuanshi, GUO Yankun, et al. Effects of different types of surfactants on the formation of natural gas hydrates [J]. Natural Gas Industry, 2003(1): 91-95.
59	JIANG L L, LI A R, XU J F, et al. Effects of SDS and SDBS on CO₂ hydrate formation, induction time, storage capacity and stability at 274.15K and 5.0MPa[J]. Chemistry Select, 2016, 1(19): 6111-6114.
60	ZHANG G, ROGERS R E. Ultra-stability of gas hydrates at 1atm and 268.2K[J]. Chemical Engineering Science, 2008, 63(8): 2066-2074.
61	CHENG C X, WANG F, ZHANG J, et al. Cyclic formation stability of 1,1,1,2-tetrafluoroethane hydrate in different SDS solution systems and dissociation characteristics using thermal stimulation combined with depressurization[J]. ACS Omega, 2019, 4(7): 11397-11407.
62	ZENG Y, CHEN J, YU X, et al. Suppression of methane hydrate dissociation from SDS-dry solution hydrate formation system by a covering liquid method[J]. Fuel, 2020, 277(12): 118222.
63	GAN J H, MANTEGHIAN M, ZADEH K S, et al. Effect of different surfactants on methane hydrate formation rate, stability and storage capacity[J]. Fuel, 2007, 86(3): 434-441.
64	KO G, SEO Y. Formation and dissociation behaviors of SF₆ hydrates in the presence of a surfactant and an antifoaming agent for hydrate-based greenhouse gas (SF₆) separation[J]. Chemical Engineering Journal,2020, 400(3): 38-52.
65	MOHAMMADI A. Kinetic study of carbon dioxide hydrate formation in presence of silver nanoparticles and SDS[J]. Chemical Engineering Journal, 2014, 237(21): 387-395.
66	YU Y S, XU C G, LI X S. Evaluation of CO₂hydrate formation from mixture of graphite nanoparticle and sodium dodecyl benzene sulfonate[J]. Journal of Industrial and Engineering Chemistry, 2018, 59(8): 64-69.
67	LIRIO C, PESSOA F, ULLER A. Storage capacity of carbon dioxide hydrates in the presence of sodium dodecyl sulfate (SDS) and tetrahydrofuran (THF)[J]. Chemical Engineering Science,2013, 96(12):118-123.
68	LIN W, DELAHAYE A, FOURNAISON L. Phase equilibrium and dissociation enthalpy for semi-clathrate hydrate of CO₂+TBAB[J]. Fluid Phase Equilibria, 2008, 264(1): 220-227.
69	WU Q, WANG Y, JING Z. Effect of rapidly depressurizing and rising temperature on methane hydrate dissociation[J]. Journal of Natural Gas Chemistry, 2012, 21(1): 91-97.
70	SUN C Y, CHEN G J. Methane hydrate dissociation above 0℃ and below 0℃[J]. Fluid Phase Equilibria, 2006, 242(2): 123-128.
71	LI K H, CHEN B B, SONG Y C, et al. Molecular dynamics simulation of the effects of different thermodynamic parameters on methane hydrate dissociation: an analysis of temperature, pressure and gas concentrations[J]. Fluid Phase Equilibria, 2020, 516(25): 83-87.
72	TAKEYA S. Particle size effect of CH₄ hydrate for self-preservation[J]. Chemical Engineering Science, 2004, 60(9): 1383-1387.
73	彭效明, 胡玉峰, 杨兰英, 等.天然石英砂中CO₂水合物的分解动力学[J]. 中国化学工程学报, 2010, 18(1): 61-65.
	PENG Xiaoming, HU Yufeng, YANG Lanying, et al. Decomposition kinetics of CO₂hydrate in natural quartz sand[J]. Chinese Journal of Chemical Engineering, 2010, 18(1): 61-65.
74	陈强, 业渝光, 孟庆国, 等. 甲烷水合物分解过程模拟实验研究[J]. 现代地质, 2008,16(3): 475-479.
	CHEN Qiang, YE Yuguang, MENG Qingguo, et al. Simulation experiment on decomposition process of methane hydrate[J]. Geoscience,2008, 16(3): 475-479.
75	VELUSWAMY H P. Rapid methane hydrate formation to develop a cost effective large scale energy storage system[J]. Chemical Engineering Journal, 2016, 290(23): 161-173.
76	薛倩, 王晓霖, 李遵照, 等. 水合物利用技术应用进展[J]. 化工进展, 2021, 40(2): 722-735.
	XUE Qian, WANG Xiaolin, LI Zunzhao, et al. Research progresses in hydrate based technologies and processes[J]. Chemical Industry and Engineering Progress, 2021, 40(2): 722-735.
77	MIMACHI H, TAKAHASHI M, TAKEYA S, et al. Effect of long-term storage and thermal history on the gas content of natural gas hydrate pellets under ambient pressure[J]. Energy & Fuels, 2015, 29(8): 4827-4834.
78	MISYURA S Y, DONSKOY I G. Ways to improve the efficiency of carbon dioxide utilization and gas hydrate storage at low temperatures[J]. Journal of CO₂Utilization, 2019, 34(13): 313-324.
79	KIDA M, WATANABE M, JIN Y, et al. Pressurization effects on methane hydrate dissociation[J]. Japanese Journal of Applied Physics, 2014, 53(1): 83-90.
80	KIDA M, JIN Y, NARITA H, et al. Effective control of gas hydrate dissociation above the melting point of ice[J]. Physical Chemistry Chemical Physics, 2011, 13(41): 18481-18484.

[1]	岳子瀚, 龙臻, 周雪冰, 臧小亚, 梁德青. sⅡ型水合物储氢研究进展[J]. 化工进展, 2023, 42(10): 5121-5134.
[2]	王英梅, 张兆慧, 刘生浩, 焦雯泽, 王立瑾, 滕亚栋, 刘杰. 促进剂体系中二氧化碳水合物常压分解[J]. 化工进展, 2022, 41(S1): 141-149.
[3]	毛港涛, 李治平, 王凯, 丁垚. 全可视化反应釜内二氧化碳水合物的生成分解特征[J]. 化工进展, 2022, 41(10): 5363-5372.
[4]	王英梅, 牛爱丽, 张兆慧, 展静, 张学民. 二氧化碳水合物快速生成方法研究进展[J]. 化工进展, 2021, 40(S2): 117-125.
[5]	刘曾奇, 刘智琪, 王逸伟, 刘爱贤, 孙强, 杨兰英, 郭绪强. 水合物形态学研究进展[J]. 化工进展, 2021, 40(S1): 88-100.
[6]	石君君, 原晓华, 谢吴成, 陈海军. 新型干法中温脱硝剂的设计制备及脱硝机理[J]. 化工进展, 2020, 39(9): 3835-3841.
[7]	何骋远,周诗岽,张文文,张青宗,吕晓方,王树立,赵书华. 间歇流下二氧化碳水合物生成形态与堵塞机理[J]. 化工进展, 2020, 39(3): 842-850.
[8]	谷霞, 王若飞, 邵怀启, 姜涛. AlCl₃/促进剂协同催化1-癸烯齐聚制备聚α-烯烃合成油[J]. 化工进展, 2020, 39(11): 4497-4502.
[9]	乔泽敏1，黄志峰1，李瑜2，汤汉良3，罗辉3. 聚丙烯用附着力促进剂研究进展[J]. 化工进展, 2012, 31(09): 2006-2010.
[10]	徐纯刚1，2，李小森1，陈朝阳1. 水合物法分离二氧化碳的研究现状 [J]. 化工进展, 2011, 30(4): 701-.
[11]	梁生荣1，2，樊君1，张君涛2，丁丽芹2. 润滑油清净剂金属化工艺研究进展 [J]. 化工进展, 2010, 29(8): 1451-.
[12]	戈军1，2，郭龙德1，郭智慧1，石斌1，张建芳1. 溶剂与溶胀促进剂对神华煤溶胀行为的影响 [J]. 化工进展, 2010, 29(10): 1885-.
[13]	齐国杰，董勇，崔琳，马春元. 超细颗粒物增湿团聚技术研究进展 [J]. 化工进展, 2009, 28(5): 745-.
[14]	卫云路，郑成，宁正祥. 表面活性剂作为发酵促进剂的国内外研究进展 [J]. 化工进展, 2008, 27(7): 983-.

二氧化碳水合物稳定储存的影响因素研究进展

Research progress on influencing factors of stable storage of carbon dioxide hydrate

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 2

参考文献 80

相关文章 14

编辑推荐

Metrics

本文评价