化工进展 ›› 2022, Vol. 41 ›› Issue (5): 2555-2565.doi: 10.16085/j.issn.1000-6613.2021-1011
梁华根1(), 齐正伟2, 贾林辉1, 盖泽嘉2, 荆胜羽2, 尹诗斌3(
)
收稿日期:
2021-05-12
修回日期:
2021-06-17
出版日期:
2022-05-05
发布日期:
2022-05-24
通讯作者:
尹诗斌
E-mail:lianghg@cumt.edu.cn;yinshibin@gxu.edu.cn
作者简介:
梁华根(1985—),男,副研究员,研究方向为电催化与能源材料。E-mail:基金资助:
LIANG Huagen1(), QI Zhengwei2, JIA Linhui1, GAI Zejia2, JING Shengyu2, YIN Shibin3(
)
Received:
2021-05-12
Revised:
2021-06-17
Online:
2022-05-05
Published:
2022-05-24
Contact:
YIN Shibin
E-mail:lianghg@cumt.edu.cn;yinshibin@gxu.edu.cn
摘要:
正极是锂-氧气(Li-O2)电池的电化学反应场所,其直接决定了电池性能。本研究采用泡桐木为原材料,在NaCl/CoCl2混合熔融盐介质中,以三聚氰胺和硫脲为氮源和硫源,一步热解炭化制备出Co、N、S共掺杂的三维自支撑多孔炭材料(wd-NSC),并直接用作Li-O2电池正极。利用X射线衍射、扫描电镜、透射电镜、氮气吸脱附、拉曼光谱、X射线光电子能谱等对所获三维自支撑多孔炭材料的形貌、晶体结构与化学成分进行了表征。研究结果表明,Co、N、S共掺杂的三维自支撑多孔炭材料表现出高比容量(在0.05mA/cm2的电流密度下,放电比容量可达12.83mA·h/cm2)和出色的循环稳定性(在电流密度为0.1mA/cm2和限定容量为0.5mA·h/cm2下,循环寿命可达125次),优异的电池性能可归因于三维分级多孔结构及Co、N、S共掺杂的协同作用。
中图分类号:
梁华根, 齐正伟, 贾林辉, 盖泽嘉, 荆胜羽, 尹诗斌. 锂-氧气电池用泡桐木衍生三维自支撑Co、N、S共掺杂多孔炭[J]. 化工进展, 2022, 41(5): 2555-2565.
LIANG Huagen, QI Zhengwei, JIA Linhui, GAI Zejia, JING Shengyu, YIN Shibin. Three dimensional self-supporting Co, N, S co-doped porous carbon derived from paulownia wood for Li-O2 batteries[J]. Chemical Industry and Engineering Progress, 2022, 41(5): 2555-2565.
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