催化反应技术在滨海电厂的CO2资源化利用和海洋防污领域的应用

doi:10.16085/j.issn.1000-6613.2021-0395

化工进展 ›› 2021, Vol. 40 ›› Issue (9): 5145-5155.DOI: 10.16085/j.issn.1000-6613.2021-0395

催化反应技术在滨海电厂的CO₂资源化利用和海洋防污领域的应用

刘安仓¹(), 陈川², 陈建忠¹, 陈裕忠¹, 朱晨亮¹, 江永¹, 鲁福身², 王双喜², 钟子宜³, 宋一兵²()

^1.华能（广东）能源开发有限公司，广东广州 510627
^2.汕头大学化学系，广东汕头 515063
^3.广东以色列理工学院，广东汕头 515063

收稿日期:2021-03-01 修回日期:2021-06-07 出版日期:2021-09-05 发布日期:2021-09-13
通讯作者: 宋一兵
作者简介:刘安仓（1968—），男，硕士，高级工程师，研究方向为大型发电企业的清洁生产。E-mail：hngd111@126.com。
基金资助:
中国华能集团科技计划(HNKJ19-G011);李嘉诚基金会跨学科研究项目(2020LKSFG09A);广东省教育厅资助项目(2018KTSCX063)

Application of catalytic reaction for CO₂ resource utilization and marine antifouling in coastal power plants

LIU Ancang¹(), CHEN Chuan², CHEN Jianzhong¹, CHEN Yuzhong¹, ZHU Chenliang¹, JIANG Yong¹, LU Fushen², WANG Shuangxi², ZHONG Ziyi³, SONG Yibing²()

^1.Huaneng (Guangdong) Energy Development Co. , Ltd. , Guangzhou 510627, Guangdong, China
^2.Department of Chemistry, Shantou University, Shantou 515063, Guangdong, China
^3.Guangdong Technion-Israel Institute of Technology, Shantou 515063, Guangdong, China

Received:2021-03-01 Revised:2021-06-07 Online:2021-09-05 Published:2021-09-13
Contact: SONG Yibing

摘要/Abstract

摘要：

二氧化碳（CO₂）减排和海洋生物污损防治是滨海火电厂亟待解决的重大课题。近年来，CO₂固体吸附材料及新能源催化反应技术的快速发展，推动了碳捕集与利用技术（CCU）的实用化进程。在燃煤火电厂原有的基础上增加碳捕集与利用技术，将其改造成碳捕集与CO₂资源化电厂，有望从根本上实现CO₂减排的目标，是火电企业未来发展的方向。另外，洁净能源驱动的催化反应技术也已延伸至海洋生物污损防治领域，并取得了积极的成效。本文综述了固体CO₂吸附材料研发的新进展，重点介绍了金属有机框架（MOF）材料结构改性和功能化修饰对提高CO₂选择性吸附性能等方面的研究成果，并基于滨海火电厂的生产实况和能源资源优势，分析、总结了热催化、光/电催化反应技术在CO₂资源化利用及生物污损防治等方面的研究现状和存在的问题，提出并论证了利用光触媒涂层阻断或抑制海洋生物黏附与生长的污损防护策略及其在具体场景中应用的可行性。最后从环保和实用化的角度对滨海电厂在CO₂减排和生物污损防治技术方面的发展趋势进行了展望。

关键词: 二氧化碳资源化利用, 海洋防污, 催化, 新能源技术

Abstract:

Carbon dioxide (CO₂) emission reduction and marine antifouling are the two major issues to be solved in coast-area thermal power plants. In recent years, the rapid development of CO₂ solid sorption materials and new-energy-related catalytic reaction technologies has promoted the practical application of CO₂ capture and utilization (CCU) technology. Applying CCU technology to the coal-fired power plants could transform them into CO₂-captured and CO₂-resourced power plants to achieve CO₂ emission reduction, which sets a good future development tendency for thermal power enterprises. Besides, the catalytic reaction technology driven by clean-energy development has been extended to the field of marine antifouling and achieved substantial progress in recent years. In this paper, the new progress in the research and development of solid CO₂ sorption materials is reviewed, particularly emphasizing the structural and functional modification of MOF materials for improving the selective CO₂ sorption performance. Based on the operation situation and rich energy resource of the coastal thermal power plants, we have analyzed and summarized the achievements of thermal catalysis and photoelectron-catalysis in CO₂ resource utilization and marine antifouling. Furthermore, an antifouling strategy using photocatalytic coatings to prevent and/or inhibit the adhesion and growth of marine organisms is proposed, and the feasibility of its application in some specific fields is demonstrated. Finally, we prospect the development trend of CO₂ emission reduction and antifouling technology in coastal power plants.

Key words: carbon dioxide (CO₂) resource utilization, marine antifouling, catalysis, renewable energy technology

中图分类号:

X701

刘安仓, 陈川, 陈建忠, 陈裕忠, 朱晨亮, 江永, 鲁福身, 王双喜, 钟子宜, 宋一兵. 催化反应技术在滨海电厂的CO₂资源化利用和海洋防污领域的应用[J]. 化工进展, 2021, 40(9): 5145-5155.

LIU Ancang, CHEN Chuan, CHEN Jianzhong, CHEN Yuzhong, ZHU Chenliang, JIANG Yong, LU Fushen, WANG Shuangxi, ZHONG Ziyi, SONG Yibing. Application of catalytic reaction for CO₂ resource utilization and marine antifouling in coastal power plants[J]. Chemical Industry and Engineering Progress, 2021, 40(9): 5145-5155.

图/表 5

图1 MUF-16 材料的合成与结构[24]

图2 mbpy-[IrⅢ]-UiO和mbpyOH-[IrⅢ]-UiO催化剂的制备及结构表征[41]

图3 胺功能化TiO2光电催化CO2还原[49]

图4 铋系及氧化亚铜半导体材料的微观形貌和部分材料的抗菌性能

图5 光/电催化杀菌体系及催化灭活E.coli性能[68]

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催化反应技术在滨海电厂的CO₂资源化利用和海洋防污领域的应用

Application of catalytic reaction for CO₂ resource utilization and marine antifouling in coastal power plants

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