生物质微波催化热解制备高值产品的研究进展

doi:10.16085/j.issn.1000-6613.2021-0303

化工进展 ›› 2022, Vol. 41 ›› Issue (1): 133-145.DOI: 10.16085/j.issn.1000-6613.2021-0303

生物质微波催化热解制备高值产品的研究进展

李攀¹^,²^,³(), 师晓鹏¹^,²^,³, 宋建德²^,³, 方书起¹^,²^,³, 白净¹^,²^,³, 常春¹^,²^,³()

^1.郑州大学机械与动力工程学院，河南郑州 450001
^2.河南省生物基化学品绿色制造重点实验室，河南濮阳 457000
^3.生物质炼制技术与装备河南省工程实验室，河南郑州 450001

收稿日期:2021-02-05 修回日期:2021-03-12 出版日期:2022-01-05 发布日期:2022-01-24
通讯作者: 常春
作者简介:李攀（1987—），男，副教授，研究方向为生物质资源化利用。E-mail：lipanhust@163.com。
基金资助:
国家自然科学基金(52006200);煤燃烧国家重点实验室开放课题(FSKLCCA2108);河南科技智库调研课题(HNKJZK-2021-22C);南阳市协同创新重大专项（郑州大学南阳研究院）(NRIZU2020CIP0006)

Research progress of biomass microwave catalytic pyrolysis for preparation of high value-added products

LI Pan¹^,²^,³(), SHI Xiaopeng¹^,²^,³, SONG Jiande²^,³, FANG Shuqi¹^,²^,³, BAI Jing¹^,²^,³, CHANG Chun¹^,²^,³()

^1.School of Mechanical and Power Engineering, Zhengzhou University, Zhengzhou 450001, Henan, China
^2.Henan Key Laboratory of Green Manufacturing of Biobased Chemicals, Puyang 457000, Henan, China
^3.Henan Province Engineering Laboratory for Biorefinery Technology and Equipment, Zhengzhou 450001, Henan, China

Received:2021-02-05 Revised:2021-03-12 Online:2022-01-05 Published:2022-01-24
Contact: CHANG Chun

摘要/Abstract

摘要：

生物质微波热解具有反应速率快、能量利用率高等优点，但存在产物选择性不高、品质较低等问题，结合催化剂使用，具有制备高值产品的应用潜力。本文对生物质微波催化热解的研究进展进行了综述，介绍了微波催化热解的机理、反应体系、热解产物等对制备高附加值产品的影响。简述了微波催化热解的机理，从原料、微波吸收剂、催化剂三个方面对微波催化热解体系进行讨论，介绍了不同种类原料对产物产率的差异、不同催化剂对于产物选择性的区别。分析了不同提高产物产率和选择性的方法，指出优化和改善催化剂特性使其具备复合功能、开发大型微波反应器、产物定向富集和转化是目前仍需解决的问题。为生产富烃生物油、高性能生物炭等产品，进而推广到工业应用提供参考。

关键词: 生物质, 微波热解, 微波吸收剂, 催化剂, 热解产物

Abstract:

Microwave pyrolysis of biomass has the advantages of fast reaction rate and high energy utilization, but there are problems such as low product selectivity and low quality. Combined with the use of catalysts, it has the application potential for preparing high-value products. In this paper, the research progress of microwave catalyzed pyrolysis of biomass is reviewed, and the mechanism of microwave catalyzed pyrolysis, the reaction system, and the effects of pyrolysis products on the preparation of high value-added products are introduced. The mechanism of microwave catalytic pyrolysis is briefly described. The microwave catalytic pyrolysis system is discussed from three aspects of raw materials, microwave absorbers and catalysts. The difference in product yields of different types of raw materials and the difference in product selectivity of different catalysts are introduced. Different methods for improving product yield and selectivity are analyzed, and it is pointed out that optimizing and improving catalyst characteristics to make it have compound function, developing large-scale microwave reactor, product directional enrichment and conversion are still problems that need to be solved. It provides a reference for the production of hydrocarbon-rich bio-oil, high-performance bio-char and other products, and then promote to industrial applications.

Key words: biomass, microwave pyrolysis, microwave absorbent, catalyst, pyrolysis product

中图分类号:

李攀, 师晓鹏, 宋建德, 方书起, 白净, 常春. 生物质微波催化热解制备高值产品的研究进展[J]. 化工进展, 2022, 41(1): 133-145.

LI Pan, SHI Xiaopeng, SONG Jiande, FANG Shuqi, BAI Jing, CHANG Chun. Research progress of biomass microwave catalytic pyrolysis for preparation of high value-added products[J]. Chemical Industry and Engineering Progress, 2022, 41(1): 133-145.

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生物质微波催化热解制备高值产品的研究进展

Research progress of biomass microwave catalytic pyrolysis for preparation of high value-added products

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