FCC工艺中提升增产丙烯助剂性能研究进展

doi:10.16085/j.issn.1000-6613.2021-0175

摘要/Abstract

摘要：

流化催化裂化（FCC）是炼厂最重要的二次加工工艺，也是石油化工应用中丙烯的第二大来源。随着丙烯需求消费的不断增长，在FCC催化剂中添加增产丙烯助剂是一种灵活、高效提高丙烯收率的途径，其助剂主要由活性组分ZSM-5分子筛和基质组成。本文主要从活性组分ZSM-5分子筛和基质两方面分别介绍目前阶段增产丙烯助剂的研究现状，通过对ZSM-5分子筛的改性来提升活性组分的性能，重点综述了调变分子筛的酸度、改善孔结构及粒度和提高水热稳定性；分析了基质孔结构和酸性的梯度分布对助剂在FCC工艺中提高原料的转化、减少生焦和增产丙烯的重要作用。最后指出在合成分子筛过程中引入改性元素，减少元素流失，提高改性元素的利用率，同时在助剂基质方面的研究仍有不足，开发低成本、大孔径和适宜酸度的高性能基质也是增产丙烯助剂未来的研究方向。

关键词: 流化催化裂化（FCC）, 助剂, ZSM-5分子筛, 基质, 增产丙烯

Abstract:

Fluid catalytic cracking (FCC) is the most important secondary processing process in refineries, and also the second largest source of propylene in petrochemical applications. Adding propylene production-increasing additives, mainly composed of active component ZSM-5 zeolite and matrix, to FCC catalyst is a flexible and efficient method to increase propylene yield. In this paper, the research status of additives for increasing propylene production is introduced from two aspects of active component ZSM-5 zeolite and matrix. The modification of ZSM-5 zeolite is used to improve the performance of active component, which is by adjusting the acidity, improving pore structure and particle size, and improving hydrothermal stability of zeolite. The important effects of structure and acid gradient distribution of matrix in improving feedstock conversion, reducing coke formation and increasing propylene production in FCC process is analyzed. Finally, it is pointed out that introducing modification elements in the synthesis of zeolite can reduce the loss of elements, improve the utilization rate of modified elements. At the same time, there are still some deficiencies in the research of additive matrix. The development of high-performance matrix with low cost, large pore size and suitable acidity is also the future research direction of additives for increasing propylene production.

Key words: fluid catalytic cracking (FCC), additives, ZSM-5 zeolite, matrix, increasing propylene production

中图分类号:

TE624.9

吕鹏刚, 刘涛, 叶行, 黄校亮, 段宏昌, 谭争国. FCC工艺中提升增产丙烯助剂性能研究进展[J]. 化工进展, 2022, 41(1): 210-220.

LYU Penggang, LIU Tao, YE Hang, HUANG Xiaoliang, DUAN Hongchang, TAN Zhengguo. Advances in improving the performance of additives for increasing propylene production in FCC process[J]. Chemical Industry and Engineering Progress, 2022, 41(1): 210-220.

图/表 2

参考文献 86

43	JERMY B R, SIDDIQUI M A B, AITANI A M, et al. Utilization of ZSM-5/MCM-41 composite as FCC catalyst additive for enhancing propylene yield from VGO cracking[J]. Journal of Porous Materials, 2012, 19(4): 499-509.
44	KONNO H, OKAMURA T, NAKASAKA Y, et al. Effects of crystal size and Si/Al ratio of MFI-type zeolite catalyst on n-hexane cracking for light olefin synthesis[J]. Journal of the Japan Petroleum Institute, 2012, 55(4): 267-274.
45	MOCHIZUKI H, YOKOI T, IMAI H, et al. Facile control of crystallite size of ZSM-5 catalyst for cracking of hexane[J]. Microporous & Mesoporous Materials, 2011, 145(1/2/3): 165-171.
46	LYU J, HUA Z L, GE T G, et al. Phosphorus modified hierarchically structured ZSM-5 zeolites for enhanced hydrothermal stability and intensified propylene production from 1-butene cracking[J]. Microporous & Mesoporous Materials, 2017, 247: 31-37.
47	TAKAHASHI A, XIA W, NAKAMURA I, et al. Effects of added phosphorus on conversion of ethanol to propylene over ZSM-5 catalysts[J]. Applied Catalysis A: General, 2012, 423/424: 162-167.
48	ZHUANG J Q, MA D, YANG G, et al. Solid-state MAS NMR studies on the hydrothermal stability of the zeolite catalysts for residual oil selective catalytic cracking[J]. Journal of Catalysis, 2004, 228(1): 234-242.
49	XUE N H, OLINDO R, LERCHER J A. Impact of forming and modification with phosphoric acid on the acid sites of HZSM-5[J]. Journal of Physical Chemistry C, 2010, 114(37): 15763-15770.
50	VÉDRINE J C, AUROUX A, DEJAIFVE P, et al. Catalytic and physical properties of phosphorus-modified ZSM-5 zeolite[J]. Journal of Catalysis, 1982, 73(1): 147-160.
1	MOHAMMED F A, BASHEER A A, MOHAMMED H A, et al. ZSM-5 zeolite based additive in FCC process: a review on modifications for improving propylene production[J]. Catalysis Surveys from Asia, 2020, 24(1): 1-10.
2	王梦瑶, 周嘉文, 任天华, 等. 催化裂化多产丙烯[J]. 化工进展, 2015, 34(6): 1619-1625.
	WAMG Mengyao, ZHOU Jiawen, REN Tianhua, et al. Catalytic craking processes for maximizing propylene production[J]. Chemical Industry and Engineering Progress, 2015, 34(6): 1619-1625.
3	陈永利, 陈浩, 郭振宇. 丙烯产业发展现状及趋势分析[J]. 炼油技术与工程, 2019, 49(12): 1-5.
51	SONG Z X, LIU W, CHEN C, et al. Production of propylene from ethanol over ZSM-5 co-modified with zirconium and phosphorus[J]. Reaction Kinetics Mechanisms & Catalysis, 2013, 109(1): 221-231.
52	SONG Z X, TAKAHASHI A, NAKAMURA I, et al. Phosphorus-modified ZSM-5 for conversion of ethanol to propylene[J]. Applied Catalysis A: General, 2010, 384(1/2): 201-205.
53	BIJ H E V D, WECKHUYSEN B M. Phosphorus promotion and poisoning in zeolite-based materials: synthesis, characterisation and catalysis[J]. Chemical Society Reviews, 2015, 44(20): 7406-7428.
3	CHEN Yongli, CHEN Hao, GUO Zhenyu. Present situation and trend analysis of propylene industry[J]. Petroleum Refinery Engineering, 2019, 49(12): 1-5.
4	张忠东, 柳召永, 高雄厚, 等. 催化裂化装置平衡剂复配丙烯助剂的制备与性能[J]. 石化技术与应用, 2020, 38(5): 304-308.
	ZHANG Zhongdong, LIU Zhaoyong, GAO Xionghou, et al. Preparation and properties of propylene additive for equilibrium catalyst blending in FCC unit[J]. Petrochemical Technology & Application, 2020, 38(5): 304-308.
5	武俊平. 催化裂化增产丙烯助剂LTB-1的工业应用[J]. 石油炼制与化工, 2007(5): 10-13.
	WU Junping. Commercial application of LTB-1 FCC additive for enhancing propylene yield[J]. Petroleum Processing and Petrochemicals, 2007(5): 10-13.
6	王巍慈. HOA-03增产丙烯助剂的工业应用[J]. 石化技术与应用, 2007(3): 244-246，249.
	WANG Weici. Industrial application of HOA-03 type additive for producing more propylene[J]. Petrochemical Technology & Application, 2007(3): 244-246, 249.
7	何立柱, 郑云锋, 杨玉峰, 等. 多产丙烯高辛烷值助剂LHP-A的工业应用[J]. 石化技术与应用, 2020, 38(4): 255-258.
	HE Lizhu, ZHENG Yunfeng, YANG Yufeng, et al. Industrial application of propylene maximizing and high octane number additive LHP-A[J]. Petrochemical Technology & Application, 2020, 38(4): 255-258.
8	曾光乐, 陈蓓艳, 王中军, 等. 多产丙烯和异丁烯催化裂化助剂FLOS-Ⅲ的工业应用[J]. 石油炼制与化工, 2015, 46(3): 24-28.
	ZENG Guangle, CHEN Beiyan, WANG Zhongjun, et al. Application of catalytic cracking additive FLOS-Ⅲ for more propylene and isobutene[J]. Petroleum Processing and Petrochemicals, 2015, 46(3): 24-28.
9	王巍慈, 郑平. LTB-1型增产丙烯助剂在催化裂化装置上的应用[J]. 石化技术与应用, 2008(2): 163-165.
	WANG Weici, ZHENG Ping. Application of assistant LTB-1 for enhancing yield of propylene in FCCU[J]. Petrochemical Technology & Application, 2008(2): 163-165.
10	石功军. LOSA-1多产丙烯助剂的工业应用[J]. 石油炼制与化工, 2007(8): 10-14.
	SHI Gongjun. Industrial application of LOSA-1 FCC additive for enhancing propylene yield[J]. Petroleum Processing and Petrochemicals, 2007(8): 10-14.
11	吴志伟, 杨发新, 王庆明. ZCAT-HP丙烯增产助剂在重油催化裂化装置的工业应用[J]. 炼油技术与工程, 2004(11): 31-34.
	WU Zhiwei, YANG Faxin, WANG Qingmin. Commercial application of assistant ZCAT-HP for increasing propylene production in RFCC unit[J]. Petroleum Refinery Engineering, 2004(11): 31-34.
12	VELTHOEN M E Z, ALESSANDRA L P, TEUNE I E, et al. Matrix effects in a fluid catalytic cracking catalyst particle: Influence on structure, acidity, and accessibility[J]. Chemistry: A European Journal, 2020, 26(52): 11995-12009.
13	HUSSAIN A I, AITANI A M, KUBU M, et al. Catalytic cracking of Arabian light VGO over novel zeolites as FCC catalyst additives for maximizing propylene yield[J]. Fuel, 2016, 167: 226-239.
14	LAPPAS A A, TRIANTAFILLIDIS C S, TSAGRASOULI Z A, et al. Development of new ZSM-5 catalyst-additives in the fluid catalytic cracking process for the maximization of gaseous alkenes yield[J]. Studies in Surface Science & Catalysis, 2002, 142: 807-814.
15	CORMA A, CORRESA E, MATHIEU Y, et al. Crude oil to chemicals: light olefins from crude oil[J]. Catalysis Science & Technology, 2017, 7(1):12-46.
16	WANG B, HAN C Y, ZHANG Q, et al. Studies on the preliminary cracking of heavy oils: the effect of matrix acidity and a proposal of a new reaction route[J]. Energy and Fuels, 2015, 29(9): 5701-5713.
17	朱小顺, 张烈清, 林毅辉, 等. 新型FCC汽油辛烷值助剂开发[C]//湖南省石油学会产学研结合论坛. 湖南省石油学会, 2014: 43-47.
	ZHU Xiaoshun, ZHANG Lieqing, LIN Yihui, et al. Development of new FCC gasoline octane additives[C]//Hunan Petroleum Society Production-University-Research Combination Forum. Hunan Petroleum Society, 2014: 43-47.
18	曹庚振, 王林, 张艳惠, 等. 氮气物理吸附法和压汞法表征FCC催化剂孔径分布研究[J]. 炼油与化工, 2015, 26(1): 9-12.
	CAO Gengzhen, WANG Lin, ZHANG Yanhui, et al. Research on nitrogen physical adsorption method and mercury intrusion method used for characterization of FCC catalyst pore size distribution[J]. Refining and Chemical Industry, 2015, 26(1): 9-12.
19	RANA M S, SAMANO V, ANCHEYTA J, et al. A review of recent advances on process technologies for upgrading of heavy oils and residua[J]. Fuel, 2007, 86 (9), 1216-1231.
20	王斌, 张强, 韩东敏, 等. 催化剂基质Lewis及Brönsted酸性位强度对催化裂化小分子烯烃收率的影响[J]. 石油学报(石油加工), 2016, 32(4): 666-673.
	WANG Bin, ZHANG Qiang, HAN Dongmin, et al. Effects of acid strength of matrix in catalyst on the yield of small olefins during the catalytic cracking process[J]. Acta Petrolei Sinica(Petroleum Processing Section), 2016, 32(4): 666-673.
21	GHRIB Y, FRINI-SRASRA, SRASRA E, et al. Synthesis of cocrystallized USY/ZSM-5 zeolites from kaolin and its use as fluid catalytic cracking catalysts[J]. Catalysis Science & Technology, 2018, 8: 716-725.
22	WAN J L, WEI Y X, LIU Z M, et al. A ZSM-5-based catalyst for efficient production of light olefins and aromatics from fluidized-bed naphtha catalytic cracking[J]. Catalysis Letters, 2008, 124(1/2): 150-156.
23	SIDDIQUI M A B, AITANI A M, SAEED M R, et al. Enhancing the production of light olefins by catalytic cracking of FCC naphtha over mesoporous ZSM-5 catalyst[J]. Topics in Catalysis, 2010, 53(19/20): 1387-1393.
24	LIN L F, ZHAO S F, ZHANG D W, et al. Acid strength controlled reaction pathways for the catalytic cracking of 1-pentene to propene over ZSM-5[J]. ACS Catalysis, 2015, 5(7): 4048-4059.
25	AWAYSSA O, AI-YASSIR N, AITANI A, et al. Modified HZSM-5 as FCC additive for enhancing light olefins yield from catalytic cracking of VGO[J]. Applied Catalysis A: General, 2014, 477: 172-183.
26	YOSHIMURA Y, KIJIMA N, HAYAKAWA T, et al. Catalytic cracking of naphtha to light olefins[J]. Catalysis Surveys from Japan, 2001, 4(2): 157-167.
27	WANG X N, ZHAO Z, XU C M, et al. Effects of light rare earth on acidity and catalytic performance of HZSM-5 zeolite for catalytic cracking of butane to light olefins[J]. Journal of Rare Earths, 2007, 25(3): 321-328.
28	王鹏, 代振宇, 田辉平, 等. La、Ce改性对ZSM-5分子筛上烯烃裂解制丙烯反应的影响及其作用机理[J]. 石油炼制与化工, 2013, 44(5): 1-5.
	WANG Peng, DAI Zhenyu, TIAN Huiping, et al. Effect and mechanism of La or Ce modified ZSM-5 zeolite on olefin cracking for propylene[J]. Petroleum Processing and Petrochemicals, 2013, 44(5): 1-5.
29	RANE N, KERSBULCK M, SANTEN R A V, et al. Cracking of n-heptane over Brönsted acid sites and Lewis acid Ga sites in ZSM-5 zeolite[J]. Microporous & Mesoporous Materials, 2008, 110(2/3): 279-291.
30	LI X F, SHEN B J, XU C M. Interaction of titanium and iron oxide with ZSM-5 to tune the catalytic cracking of hydrocarbons[J]. Applied Catalysis A: General, 2010, 375(2): 222-229.
31	JUNG J S, PARK J W, SEO G. Catalytic cracking of n-octane over alkali-treated MFI zeolites[J]. Applied Catalysis A: General, 2005, 288(1/2): 149-157.
32	WAKUI K, SATOH K, SAWADA G, et al. Cracking of n-butane over alkaline earth-containing HZSM-5 Catalysts[J]. Catalysis Letters, 2002, 84(3): 259-264.
33	MEHLA S, KUKADE S, KUMAR P, et al. Fine tuning H-transfer and β‍-scission reactions in VGO FCC using metal promoted dual functional ZSM-5[J]. Fuel, 2019, 242: 487-495.
34	OGURA M, SHINOMIYA S Y, TATENO J, et al. Alkali-treatment technique—New method for modification of structural and acid-catalytic properties of ZSM-5 zeolites[J]. Applied Catalysis A: General, 2001, 219(1/2): 33-43.
35	徐天宇, 崔君君, 孙浩伟, 等. HZSM-5/Y复合分子筛的制备、表征及催化裂化性能研究[J]. 中国油脂, 2020, 45(1): 76-81.
	XU Tianyu, CUI Junjun, SUN Haowei, et al. Preparation characterization and catalytic cracking properties of HZSM-5/Y composite molecular sieve[J]. China Oils and Fats, 2020, 45(1): 76-81.
36	SCHNEIDER D, MEHLHORN D, ZEIGERMANN P, et al. Transport properties of hierarchical micro-mesoporous materials[J]. Chemical Society Reviews, 2016, 47(12): 3439-3467.
37	KONNO H, OHNAKA R, NISHIMURA J I, et al. Kinetics of the catalytic cracking of naphtha over ZSM-5 zeolite: effect of reduced crystal size on the reaction of naphthenes[J]. Catalysis Science & Technology, 2014, 4(12): 4265-4273.
38	KIM J C, RYOO R, OPANASENKO M V, et al. Mesoporous MFI zeolite nanosponge as a high-performance catalyst in the pechmann condensation reaction[J]. ACS Catalysis, 2015, 5(4): 2596-2604.
39	VOGT E T C, WECKHUYSEN B M. Fluid catalytic cracking: recent developments on the grand old lady of zeolite catalysis[J]. Chemical Society Reviews, 2015, 44(20): 7342-7370.
40	LI K H, VALLA J, GARCIA-MARTINEZ J. Realizing the commercial potential of hierarchical zeolites: new opportunities in catalytic cracking[J]. ChemCatChem, 2014, 6(1): 46-66.
41	SIDDIQUI M A B, AITANI A M, SAEED M R, et al. Enhancing propylene production from catalytic cracking of Arabian Light VGO over novel zeolites as FCC catalyst additives[J]. Fuel, 2011, 90(2): 459-466.
42	DONG X L, SHAIKH S, VITTENET J R, et al. Fine tuning the diffusion length in hierarchical ZSM-5 to maximize the yield of propylene in catalytic cracking of hydrocarbons[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(11): 15832-15840.
54	XUE N H, CHEN X K, NIE L, et al. Understanding the enhancement of catalytic performance for olefin cracking: hydrothermally stable acids in P/HZSM-5[J]. Journal of Catalysis, 2007, 248(1): 20-28.
55	BLASCO T, CORMA A, MARTÍNEZ-TRIGUERO J. Hydrothermal stabilization of ZSM-5 catalytic-cracking additives by phosphorus addition[J]. Journal of Catalysis, 2006, 237(2): 267-277.
56	ZHAO G L, TENG J W, XIE Z K, et al. Effect of phosphorus on HZSM-5 catalyst for C₄-olefin cracking reactions to produce propylene[J]. Journal of Catalysis, 2007, 248(1): 29-37.
57	VINEK H, RUMPLMAYR G, LERCHER J A. Catalytic properties of postsynthesis phosphorus-modified H-ZSM5 zeolites[J]. Journal of Catalysis, 1989, 115(2): 291-300.
58	KAEDING W W, BUTTER S A. Production of chemicals from methanol. Ⅰ. Low molecular weight olefins[J]. Journal of Catalysis, 1980, 61(1): 155-164.
59	YANG G, ZHUANG J Q, WANG Y, et al. Enhancement on the hydrothermal stability of ZSM-5 zeolites by the cooperation effect of exchanged lanthanum and phosphoric species[J]. Journal of Molecular Structure, 2005, 737(2/3): 271-276.
60	KOLLMER F, HAUSMANN H, HÖLDERICH W F. (NH₄)₂SiF₆-modified ZSM-5 as catalysts for direct hydroxylation of benzene with N₂O[J]. Journal of Catalysis, 2004, 227(2): 398-407.
61	SÁNCHEZ N A, SANIGER J M, D’ESPINOSE DE LA CAILLERIE J B, et al. Dealumination and surface fluorination of H-ZSM-5 by molecular fluorine[J]. Microporous & Mesoporous Materials, 2001, 50(1): 41-52.
62	QIN Z, LAKISS L, GILSON J P, et al. Chemical equilibrium controlled etching of MFI-type zeolite and its influence on zeolite structure, acidity, and catalytic activity[J]. Chemistry of Materials, 2013, 25(14): 2759-2766.
63	JI Y J, YANG H H, YAN W. Catalytic cracking of n-hexane to light alkene over ZSM-5 zeolite: influence of hierarchical porosity and acid property[J]. Molecular Catalysis, 2018, 448: 91-99.
64	赵国良, 滕加伟, 谢在库, 等. 氟硅酸铵改性的HZSM-5催化剂的表征及其碳四烯烃裂解催化性能[J]. 催化学报, 2005, 26(12): 1083-1087.
	ZHAO Guoliang, TENG Jiawei, XIE Zaiku, et al. Characterization and catalytic performance of (NH₄)₂SiF₆-modified HZSM-5 catalyst for C₄ olefin cracking[J]. Chinese Journal of Catalysis, 2005, 26(12): 1083-1087.
65	GAO Z, TANG Y. Influence of Si/Al ratio on the properties of faujasites enriched in silicon[J]. Zeolites, 1988, 8(3): 232-237.
66	杜艳泽, 秦波, 王会刚, 等. 多级孔分子筛在重油加氢裂化催化剂的应用进展[J]. 化工进展, 2021, 40(4): 1859-1868.
	DU Yanze, QIN Bo, WANG Huigang, et al. Development of hierarchical zeolites in hydrocracking catalysts of heavy oil[J]. Chemical Industry and Engineering Progress, 2021, 40(4): 1859-1868.
67	WANG B, LI N, ZHANG Q, et al. Studies on the preliminary cracking: the reasons why matrix catalytic function is indispensable for the catalytic cracking of feed with large molecular size[J]. Journal of Energy Chemistry, 2016, 25(4): 641-653.
68	秦素亚, 高伟, 张瑛, 等. 大孔径FCC催化剂基质的研究进展[J]. 石油化工, 2008, 37: 561-563.
	QING Suya, GAO Wei, ZHANG Ying, et al. Research progress of large pore size FCC catalyst matrix[J]. Petrochemical Technology, 2008, 37: 561-563.
69	ISHIHARA A, WAKAMATSU T, NASU H, et al. Preparation of amorphous silica-aluminausing polyethylene glycol and its role for matrix in catalytic cracking of n-dodecane[J]. Applied Catalysis A: General, 2014, 478 (20): 58-65.
70	刘从华, 邓友全, 高雄厚, 等. 酸改性高岭土基质FCC催化剂的反应性能[J]. 工业催化, 2003, 11(4): 49-52.
	LIU Conghua, DENG Youquan, GAO Xionghou, et al. Catalytic performance of FCC catalyst with acid-modified kaolin as matrix[J]. Industrial Catalysis, 2003, 11(4): 49-52.
71	王宁生, 闫伟建, 孙书红. 高岭土改性及其在FCC催化剂中的应用[J]. 工业催化, 2007, 15(4): 14-16.
	WANG Ningsheng, YAN Weijian, SUN Shuhong. Modification of kaolin and its application in FCC catalyst[J]. Industrial Catalysis, 2007, 15(4): 14-16.
72	王韵金, 卓润生, 王洪飞, 等. 富介孔-大孔的FCC催化剂基质制备工艺研究[J]. 广州化工, 2018, 46(19): 44-47.
	WANG Yunjin, ZHUO Runsheng, WANG Hongfei, et al. Preparation of macroporous-macroporous matrix for FCC catalyst[J]. Guangzhou Chemical Industry, 2018, 46(19): 44-47.
73	CHEN W Z, HAN D M, SUN X H, et al. Studies on the preliminary cracking of heavy oils: contributions of various factors[J]. Fuel, 2013, 106: 498-504.
74	OTTERSTEDT J E, ZHU Y M, STERTE. Catalytic cracking of heavy oil over catalysts containing different types of zeolite Y in active and inactive matrices[J]. Applied Catalysis A: General, 1988, 38 (1): 143-155.
75	XU S J, ZHANG Q, FENG Z X, et al. A high-surface-area silicoaluminophosphate material rich in Brönsted acid sites as a matrix in catalytic cracking[J]. Journal of Natural Gas Chemistry, 2012, 21 (6): 685-693.
76	FENG R, LIU S T, BAI P, et al. Preparation and characterization of γ-Al₂O₃ with rich Brönsted acid sites and its application in the fluid catalytic cracking process[J]. The Journal of Chemical Physics, 2014, 118 (12): 6226-6234.
77	HOLLAND B T, SUBRAMANI V, GANGWAL S K. Utilizing colloidal silica and aluminum-doped colloidal silica as a binder in FCC catalysts: effects on porosity, acidity, and microactivity[J]. Industrial & Engineering Chemistry Research, 2007, 46 (13): 4486-4496
78	LIU H, ZHOU Y M, ZHANG Y W, et al. Influence of binder on the catalytic performance of PtSnNa/ZSM-5 catalyst for propane dehydrogenation[J]. Industrial & Engineering Chemistry Research, 2008, 47(21): 8142-8147.
79	刘全新, 袁颖, 杨恒吉, 等. 黏结剂对FCC汽油加氢改质催化剂性能的影响研究[J]. 当代化工, 2018, 47(2): 272-274.
	LIU Quanxin, YUAN Ying, YANG Hengji. et al. Effect of binder on catalytic performance of FCC gasoline hydro-upgrading catalyst[J]. Contemporary Chemical Industry, 2018, 47(2): 272-274.
80	ZHANG Y W, ZHOU Y M, QIU A D, et al. Effect of alumina binder on catalytic performance of PtSnNa/ZSM-5 catalyst for propane dehydrogenation[J]. Industrial & Engineering Chemistry Research, 2006, 45(7): 2213-2219.
81	TARIGHI S, JUIBARI N M, BINAEIZADEH M. Different binders in FCC catalyst preparation: impact on catalytic performance in VGO cracking[J]. Research on Chemical Intermediates, 2019, 45(4): 1737-1752.
82	LUCAS A D, SÁNCHEZ P, FÚNEZ A, et al. Influence of clay binder on the liquid phase hydroisomerization of n-octane over palladium-containing zeolite catalysts[J]. Journal of Molecular Catalysis A: Chemical, 2006, 259(1/2): 259-266.
83	WHITING G T, CHOWDHURY A D, OORD R, et al. The curious case of zeolite-clay/binder interactions and their consequences for catalyst preparation[J]. Faraday Discussions, 2016, 188: 369-386.
84	李侃, 王栋, 翟佳宁, 等. 黏结剂对催化裂化催化剂物化性质的影响[J]. 应用化工, 2014, 43(3): 485-487.
	LI Kan, WANG Dong, ZHAI Jianing, et al. The effect of binder on the properties of FCC catalyst[J]. Applied Chemical Industry, 2014, 43(3): 485-487.
85	PETROVIC R, MILONJIC S, JOKANOVIC V, et al. Influence of synthesis parameters on the structure of boehmite sol particles[J]. Powder Technology, 2003, 133(1/2/3):185-189.
86	ZHENG Y S, SONG J Q, XU X Y, et al. Peptization mechanism of boehmite and its effect on the preparation of a fluid catalytic cracking catalyst[J]. Sci-Tech Information Development & Economy, 2007, 53(24): 10029-10034.

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