化工进展 ›› 2020, Vol. 39 ›› Issue (6): 2345-2353.DOI: 10.16085/j.issn.1000-6613.2019-1448

• 化工过程与装备 • 上一篇    下一篇

来瓦希尔骨架材料MIL-53(Al)填充PEBA膜渗透汽化分离水中苯胺

韩光鲁1,2(), 陈哲1, 张永辉1(), 蔡立芳1   

  1. 1.郑州轻工业大学材料与化学工程学院,河南 郑州 450001
    2.河南省化工分离过程强化工程技术研究中心,河南 郑州 450001
  • 出版日期:2020-06-05 发布日期:2020-06-16
  • 通讯作者: 张永辉
  • 作者简介:韩光鲁(1985—),男,博士,讲师,硕士生导师,研究方向为功能膜材料的制备和应用。E-mail:2014115@zzuli.edu.cn
  • 基金资助:
    国家自然科学基金(21606211);中原千人科技创新领军人才项目(194200510013);河南省科技计划基础与前沿技术研究计划(152300410127);郑州轻工业大学博士科研基金(2014BSJJ056)

Lavoisier framework MIL-53(Al) incorporated PEBA membranes for pervaporation separation of aniline from water

Guanglu HAN1,2(), Zhe CHEN1, Yonghui ZHANG1(), Lifang CAI1   

  1. 1.School of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, Henan, China
    2.Henan Engineering Research Center of Chemical Engineering Separation Process Intensification, Zhengzhou 450001, Henan, China
  • Online:2020-06-05 Published:2020-06-16
  • Contact: Yonghui ZHANG

摘要:

将来瓦希尔骨架材料MIL-53(Al)引入到聚醚共聚酰胺(PEBA-2533)高分子相中制备了不同填充量的PEBA/MIL-53(Al)杂化膜并用于渗透汽化分离水中微量苯胺。X-射线衍射结果证实MIL-53(Al)被成功合成。扫描电镜和激光粒度分析结果表明所制备MIL-53(Al)颗粒粒径在纳米尺度范围内。采用扫描电镜、红外光谱、X-射线衍射、差示扫描量热和水接触角对杂化膜进行了表征,并考察了杂化膜的溶胀行为和分离性能。结果表明,所得杂化膜的热稳定性较好。当MIL-53(Al)质量分数小于20%时,MIL-53(Al)在高分子相中分散均匀,继续增大填充量出现团聚现象。杂化膜的结晶度随MIL-53(Al)填充量的增加而降低。MIL-53(Al)的引入增强了杂化膜的疏水性和溶胀度。在料液温度为60℃、膜下游压力400Pa、料液苯胺质量分数为3.6%时,MIL-53(Al)质量分数为20%的杂化膜(M-20)综合分离性能最优,渗透通量达到2.15kg/(m2·h),分离因子为264。12天的稳定性测试结果表明所得杂化膜分离性能无显著变化,能够满足渗透汽化应用要求。

关键词: 膜, 分离, 渗透汽化, 杂化, 制备, 苯胺

Abstract:

Lavoisier framework MIL-53(Al) was incorporated into the polyether block amide (PEBA-2533) to prepare PEBA/MIL-53(Al) hybrid membranes with different loadings and to be used for pervaporation separation of aniline from water. X-ray diffraction results confirmed that MIL-53(Al) was successfully synthesized. The results of scanning electron microscopy and laser particle size analysis showed that the particle size of MIL-53(Al) was in the nano-scale range. The hybrid membranes were characterized by scanning electron microscopy, infrared spectroscopy, X-ray diffraction, differential scanning calorimetry and water contact angle. The swelling behavior and separation performance of the hybrid membranes were also investigated. The results indicated that the hybrid membranes demonstrated good thermal stability. When the mass fraction of MIL-53(Al) was less than 20%, MIL-53(Al) was evenly dispersed in the polymer phase, and agglomeration occured when the loading amount continued to increase. The crystallinity of hybrid membranes decreased with the increase of MIL-53(Al) loading. The introduction of MIL-53(Al) enhanced the hydrophobicity and swelling of the hybrid membranes. When the feed temperature was 60 ℃, the downstream pressure was 400 Pa and the mass fraction of aniline was 3.6%, the hybrid membrane (M-20) with MIL-53(Al) mass fraction of 20% exhibited the best comprehensive separation performance. The permeation flux reached to 2.15 kg/(m2·h) and the separation factor was high as 264. The long-term test results for 12 days showed that the separation performance of the hybrid membranes had no significant change and can meet the requirements of pervaporation application.

Key words: membranes, separation, pervaporation, hybrid, preparation, aniline

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