反式-1-氯-3,3,3-三氟丙烯的制备研究进展

doi:10.16085/j.issn.1000-6613.2017-0367

摘要/Abstract

摘要： 反式-1-氯-3，3，3-三氟丙烯[HCFO-1233zd（E）]的臭氧消耗潜值（ODP）为0.00024，温室效应潜值（GWP）为7.0，环保性能优良，已被国际社会认定为第四代氟代烃发泡剂，应用前景广阔。本文对现有HCFO-1233zd（E）制备方法进行综述，通过比较各合成路线优缺点，提出以HCC-240fa及其衍生物为原料的合成路线最具工业化前景。同时，对制备工艺中涉及的HCFO-1233zd（E）与HF和副产物共沸分离问题进行了分析总结。最后指出高效的氟化催化剂和绿色的分离工艺是未来HCFO-1233zd（E）工业化开发的研究重点。

关键词: 反式-1-氯-3, 3, 3-三氟丙烯, 发泡剂, 合成, 分离

Abstract: Trans-1-chloro-3,3,3-trifluoropropene[HCFO-1233zd(E)] has virtually zero ozone depletion potential(ODP,0.00024)and very low global warming potential(GWP,7),and therefore it has been proposed as the fourth-generation blowing agent to replace 1,1-dichloro-1-fluoroethane(HCFC-141b)and 1,1,1,3,3-pentafluoropropane(HFC-245fa),due to its very low impact for environment. Synthetic methods of HCFO-1233zd(E) were summarized according to the starting materials. Compared with other routes,the process using HCC-240fa and its derivatives as starting material features good yield and excellent selectivity,and thus has an industrialization prospect. Moreover,the azeotropic separation of HCFO-1233zd(E) with HF and by-product in the preparation process was analyzed and summarized. Developing efficient fluorination catalyst and environmentally friendly purification technology is fundamentally important for industrial synthesis of HCFO-1233zd(E).

Key words: trans-1-chloro-3,3,3-trifluoropropene[HCFO-1233zd(E)], blowing agent, synthesis, separation

中图分类号:

TQ222.4

曾纪珺, 韩升, 唐晓博, 赵波, 郝志军, 张伟, 吕剑. 反式-1-氯-3,3,3-三氟丙烯的制备研究进展[J]. 化工进展, 2017, 36(11): 4132-4141.

ZENG Jijun, HAN Sheng, TANG Xiaobo, ZHAO Bo, HAO Zhijun, ZHANG Wei, LÜ Jian. Progress of preparation of trans-1-chloro-3,3,3-trifluoropropene[J]. Chemical Industry and Engineering Progress, 2017, 36(11): 4132-4141.

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