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Table of Content
25 December 2006, Volume 25 Issue 12
    进展与述评

    Development of ultrasonic dewatering and reusage of refinery scum

    YE Guoxiang,LU Xiaoping,SHU Changhao,HAN Pingfang,ZHU Yongjun
    2006, 25(12):  1381. 
    Abstract ( 1901 )  
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    This paper presents the scum dewatering technologies and ultrasonic demulsificationand reviews the benefit of ultrasonic demulsification. A new way is introduced to recover the scum as for reuse. At a proper condition of ultrasound can reduce more than 20 flocculant; ultrasonic dewatering technology can enhance scum treatmentreduce dewatering timeand the moisture content of scum after 5min ultrasonic treatment is the same as that after 72 hours settling; and the final dewatering rate can be increased by 67. Finallya new way for scum reuse is proposed to use the dewatered scum in delayed coking.
    Research progress of waterborne chlorinated polypropylene and its application
    DONG Xueru,SUN Peiqin,LIU Dazhuang,SUN Shaohui
    2006, 25(12):  1386. 
    Abstract ( 1697 )  
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    The recent development of waterborne chlorinated polypropylene was reviewed. The characteristics of mechanical methodphase inversion method and chemical modification method (including emulsion graft polymerizationsuspension polymerization and solution graft polymerization) were discussedand both advantages and disadvantages of various methods were also pointed out. The application of waterborne CPP in coating systems as primer and additive were introduced. The prospect of waterborne CPP coatings was also presented.
    Recent development of oxidative dehydrogenating agent–N2O
    ZHENG Wen,CHENG Dangguo,CHEN Fengqiu,ZHAN Xiaoli
    2006, 25(12):  1391. 
    Abstract ( 1579 )  
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    The recent advances in using of N2O as oxidative dehydrogenating agent were reviewed. The new investigation of N2O used in oxidative dehydrogenation of n-butane,propane and benzene was summarized. The discussion was focused on the oxidative dehydrogenation of ethylbenzene to styrene in the presence of N2O and the role of N2O in the oxidative dehydrogenation reactions. Finally,research trend of renovating catalysts,developing new catalyst materials and studying the mechanism of oxidative dehydrogenation of ethylbenzene to styrene in the presence of N2O was discussed.
    Oxide modified electrodes and its application to organic wastewater treatment by electrochemical method
    ZHANG Yi,LIU Lei,ZHANG Rongqing,Qu Yunlong,ZHANG Yanli
    2006, 25(12):  1395. 
    Abstract ( 1577 )  
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    In this paperthe preparation methods of oxide modified electrodes were discussedsuch as sputteringspray pyrolysisthermal decompositionsol-gelelectro-depositionetc. The application of oxides modified electrodes to organic wastewater treatment was introducedthe difficulties of this method were analyzed in practical applicationand the great potential of oxides modified electrodes in organic wastewater treatment was proposed.

    Technology and advances of supercritical fluid chelating extraction of radioactive metals

    BIE Peng,BAI Yu,YANG Haijian
    2006, 25(12):  1400. 
    Abstract ( 1631 )  
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    The supercritical carbon dioxide (SC-CO2) extraction of radioactive metals such as lanthanides and actinides was reviewed and its latest development was introduced. The possibility of utilizing supercritical fluid extraction (SFE) technique for the treatment of mixed wastes and spent nuclear fuels was discussed.
    Research progress in microcapsule with self-repair composite
    QIAO Jichao,HU Xiaoling,GUAN Ping
    2006, 25(12):  1405. 
    Abstract ( 1765 )  
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    The self-repair mechanism of self-repair compositesfor microcapsule was introduced and the methods of manufacturing microcapsules were reviewed. The research achievements of self-repair composites for microcapsule were discussed. The research trends were also proposed.
    Development of preparation and application of cross-linked hyaluronan
    YANG Hao,XIONG Wenshuo,YING Guoqing,YI Yu,WANG Hong
    2006, 25(12):  1410. 
    Abstract ( 1554 )  
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    Hyaluronan (HA) has wonderful biocompatibility and biodegradability,but needs cross- linking modification to improve its mechanical properties for its use as a biomaterial. This review concentrates on the recent advances of cross-linking reagent for producing HA derivatives,and introduces the application and development of common cross-linking reagent and new type cross-linking reagent,so as to provide more advice for the development of HA reagent.
    研究开发
    Synthesis of NaY molecular sieve
    CAI LianguoXU YongquanCHEN JianfengSHAO Lei
    2006, 25(12):  1415. 
    Abstract ( 1545 )  
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    A novel method for the preparation of NaY molecular sieve by using a Si-Al gel with special composition as the directing agent was presented. The as-synthesized NaY molecular sieve was characterized with SEM, XRD and BET. The NaY molecular sieve had a particle size of approximately 2μm, n(SiO2)/n(Al2O3) of 3.28, crystallinity of 90% and specific surface area of 703 m2/g. Except the crystallization process, the synthesis of the NaY molecular sieve was conducted at room temperature under mild and controllable reaction conditions.
    Synthesis of 3,4-dimethylnitrobenzene by regioselective nitration with SO42-/ZrO2 supported on MCM-48 catalyst
    XI Limin,YU Hongyan
    2006, 25(12):  1419. 
    Abstract ( 1921 )  
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    The solid superacid SO42-/ZrO2 supported on mesoporous MCM-48 was prepared by the liquid-phase precipitation,and the process for the formation of superacid on the catalyst surface and mechanism of regioselective nitration by catalysis were presented. The regioselective nitration of o-xylene with nitric acid was selected as a probe reaction to test the catalytic performance. The structure of the solid superacid was characterized with acid base titration,TEM,N2 adsorption/desorption and Hammett indicator. The results showed that the mesoporous structure of MCM-48 was maintained in the catalyst system,and there were Brønsted acid and Lewis acid sites on catalyst surface with a high BET surface area of 208 m2/g and better solid acidity (H0<-13.75). The optimum conditions were as follows:calcination temperature of catalyst was 500 ℃,the reaction was carried out at 60 ℃ for 3 h with n(nitric acid)/n(o-xylene) 2.5 and m(o-xylene)/m(catalyst) 25 to get the yield of 91.8%,the content of product up to 82.1%.
    Production of β-glucanase by cultivation of immobilized recombinant
    E. coli cells in a packed bed reactor
    CHEN Wenmou,LU Yinghua,LI Qingbiao,CHENG Zhijing,HE Ning
    2006, 25(12):  1423. 
    Abstract ( 1949 )  
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    β-glucanase produced by immobilized Escherichia coli JM 109-pLF3 in a packed bed bioreactor was studied. In batch fermentation,the highest enzyme activity of 100.3 U/mL was achieved at a recycling rate of 44.49 mL/min and an aeration rate of 0.6 mL/min after 48 h cultivation. In repeated batch operation,the enzyme activity up to 100 U/mL was obtained in 5 cycles,showing high stability of the immobilized cells. In continuous fermentation,the production of β-glucanase by immobilized cells was kept more or less constant. When the dilution rate was 0.05 h-1,the enzyme activity in the fermentation broth was 39.1 U/mL.
    Hydrothermal preparation and characters of magnetic ions doped titanate nanotubes
    WANG Meili,SONG Gongbao,LI Jian,MIAO Landong,ZHANG Baoshu
    2006, 25(12):  1428. 
    Abstract ( 1578 )  
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    Taking pure anatase TiO2 as the precursor, doped magnetic ions doped with titanate nanotubes were synthesized by the hydrothermal method. In this process the nanotubes were prepared at the same time with the doping of magnetic ions. The products were characterized with X-ray diffraction (XRD), Transmission Electron Microscope (TEM), Thermal Analysis (TG-DTA) and BET surface area. The results showed that the structure of the nanotube was that of titanate different from anatase phase. The nanotubes had very large surface area and pore volume. The doping of magnetic ions did not make an obvious effect on the morphology and structures of titanate nanotubes. Treatment at a high temperature would bring big changes to the structures of titanate nanotubes. When the calcination temperature was higher than 450℃, the tubulous structure of titanate nanotubes was destroyed and transformed into anatase phase.
    Preparation and characterization of water-soluble chitosan nanoparticles as BSA delivery system
    WANG Chun,YANG Liansheng,FU Xiong
    2006, 25(12):  1431. 
    Abstract ( 1719 )  
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    In order to avoid the low solubility of high molecular weight chitosan in aqueous media and the disadvantages induced by acetic acid that is used usually as a solubilizerwater-soluble chitosan (WSC) was investigated. WSC nanoparticles (WSC NP) with various ratios of WSC/ tripolyphsphoric acid cross-linking agent were prepared based on ionic gelationand were used to load bovine serum albumin (BSA) for release in vitro. Blank and BSA-loaded WSC nanoparticles were examined with diameter 35190 nmzeta potential 3542 mV and spherical shape. FTIR and XRD confirmed tripolyphsphoric groups of tripolyphsphoric acid linked with amino groups of WSC in the nanoparticles. WSC NP loading studies showed that altering concentration of BSA from 0.05 to 1 mg/mL enhanced loading capacity of BSA but decreased loading efficiency simultaneously. Release studies in vitro suggested that WSC had the properties of controlled-release proteins delivery. These results indicate that WSC nanoparticles are promising carriers system for protein delivery.
    Adsorption performance of ion-exchange fiber for UDMH
    CHEN Lili,ZENG Qingxuan,CHEN Tao
    2006, 25(12):  1436. 
    Abstract ( 1681 )  
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    The adsorptiondesorption performance of strong acidic ion-exchange fiber (IEF) for unsymmetrical dimethyl hydrazine (UDMH) was investigated. Static adsorption showed that the adsorption effect was related to reaction temperature. Dynamic adsorption and desorption showed that the adsorption effect was also related to the loading density of IEF in the ion-exchange columnthe concentration and flow velocity of UDMH solution. UDMH can be desorbed rapidly with sodium chloride solutionand the concentration multiple reached 28.3.
    Novel MgCl2/SiO2 complex support catalyst for propylene polymerization
    ZU Xiaojing,LIN Ge,CHEN Wei,JIANG Tao
    2006, 25(12):  1439. 
    Abstract ( 2061 )  
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    The MgCl2/SiO2 complex support was prepared by spray drying using alcoholic suspension containing MgCl2 and SiO2. The complex support reacted with TiCl4 and di-n-butyl phthalate to prepare the catalyst for propylene polymerization. The catalyst was characterized with SEMXRDXPS and EDX. The analysis results showed that SiO2 functioned as an inert support and there was no chemical reaction between silica and magnesium or titanium. The performance of the catalyst for polymerization of propylene was investigated. The results showed that the catalyst had high activityhigh stereo-specificity and sensitive hydrogen response.
    Development of pyromellitic dianhyride with Ce-Mo-Ti-V as catalyst
    DING Zhiping,YANG Xiaodong, ZHU Zhiqing
    2006, 25(12):  1443. 
    Abstract ( 1478 )  
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    A catalyst for obtaining pyromellitic dianhyride by catalytic gaseous phase oxidation from durene are developmented. The catalyst contains Ce-Mo-Ti-V as essential active constituent. The types of carriers, active constituent as well as the influence on the processing result, some processing conditions such as the temperature, the speed of air and the concentration of the reactors, have been studied through experiments. By using the catalyst, at 455, space veiocity 6 000 h1 and durene concentration in air 20g/m3,the weight yield of pyromellitic dianhyride is 99.7%.
    应用技术
    Tentative study on clean production of artemisinin by combined ultrasonic
    extraction-membrane filtration-supercritical fluid extraction
    XU Zhaohui,TONG Jinrong ,WAN Duanji
    2006, 25(12):  1447. 
    Abstract ( 1992 )  
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    In this paper,ultrasonic extraction,membrane separation technology and supercritical–CO2-fluid extraction (SFE-CO2) was combined,and used for the production of artemisinin. Different reagents and methods of extraction and the selection of membrane were discussed to determine an optimal operation condition. The extraction rate and the content of crude artemisinin reached 0.48% and 92% respectively.
    Sewage treatment in Cainan oil field
    ZHOU Zhiling;LI Cunfu;LU Jungang,WANG Xueliang,YAO Yunsheng
    2006, 25(12):  1451. 
    Abstract ( 2111 )  
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    Water flooding and process scheme in Cainan oil field, Zhunggar basin,Xinjiang were introduced. Based on the quality of produced water and the technical standards of re-injected water, the bacteria, oil content, suspension, sulfide, corrosion rate of produced water were investigated. The treatment reagents were tested and screened in the laboratory and the reagents of Sanda Company PAC, JM-300, the reagents of Keli company KL-0308, KL-0305 were used in field application. After treatment the produced water quality met the standards for re-injection.
    过程系统工程专栏
    Intelligent control technique for ethylene plant
    WANG Zhenlei,DU Wenli,QIAN Feng
    2006, 25(12):  1454. 
    Abstract ( 1585 )  
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    Intelligent techniques,such as artificial neural network,fuzzy inference logic and expert system,are used in several applications. These techniques are based on human intelligence and way of thinking. They do not need much system information. New ideas and methods are presented for resolving the key problems of complex control system. The intelligent techniques were used in ethylene plant. The intelligent system structure and application were demonstrated in thermal cracker,and the application results in the process were shown. The successful application illustrates that the intelligent techniques are very attractive in process control.
    Application of advanced process control and optimization for ethylene glycol distillation system
    HU Chun,QIAN Feng
    2006, 25(12):  1457. 
    Abstract ( 1990 )  
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    Based on process mechanism analysis, this paper presents an application of advanced process control strategy to resolve the practical issues of ethylene glycol distillation system. The inferential control, decouple control, and expert control technologies are applied and integrated with distributed control system seamlessly. And operation conditions are optimized based on exact industrial process models for ethylene glycol distillation system. As a result of these work, control stability is improved obviously, energy consumption decreases effectively, and operation period is prolonged.
    Emergy analysis and comparison of methanol synthesis processes using different feedstocks
    CAO Kai,FENG Xiao
    2006, 25(12):  1461. 
    Abstract ( 1818 )  
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    Methanol is a kind of important chemical raw material that has extensive uses. The processes of synthesizing methanol by using different feedstockssuch as natural gascoal-water slurrycoke-oven gasyellow phosphorus tail gas and acetylene off-gas were analyzed and compared by means of the emergy accounting methodology. The results showed that the process of synthesizing methanol from coke-water slurry was better than other processes because it had a low value of environmental loading ratiomiddle value of emergy yield ratiohigh value of emergy investment ratiomiddle value of emergy index of sustainability and low value of transformity of methanol. To meet the increasing demand for methanolChinawhich is short of natural gas and petroleumshould make good use of the plentiful coal to actively develop the process of synthesizing methanol from coke-water slurry.
    CO2 emission reduction through energy integration
    WANG Gang,FENG Xiao
    2006, 25(12):  1467. 
    Abstract ( 1688 )  
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    The CO2 emissions are mostly from energy utilization. Energy integration not only improves energy utilization efficiencybut also reduces CO2 emission. This paper introduces a calculation method for the reduction capacity of CO2 emission through saving energy. In this papera case study based on a project of energy integration on a purified terephthalic acid (PTA) plant is presented. The results of the case study indicate that energy integration has significant effect on CO2 emission reduction.
    Analysis of technologies for water system integration
    BAI Jie,FENG Xiao
    2006, 25(12):  1471. 
    Abstract ( 1488 )  
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    Water system integrationwhich treats the water utilization processes in an enterprise as an organic whole to consider how to allocate water in a water systemshows remarkable effectiveness in saving water. In this paperthree technologies for water system integration in recent yearsincluding pinch technologymathematical programming and the integration with internal water mainsare analyzed. The advantages and disadvantages of each method are demonstrated and an example is used to compare these methods. Finally the future development of the methods for water system integration is discussed.
    Improved WCA method to determine water pinch point and wastewater minimization for batch processes
    YANG Xia,LI Yugang,WANG Lingmei,ZHENG Shiqing
    2006, 25(12):  1477. 
    Abstract ( 1544 )  
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    Water Cascade Analysis (WCA) technology was used to synthesize the water use network for batch processes,which could determine the water pinch point location and the minimum utilities target of the batch process:minimum fresh water use and wastewater discharge. Based on pinch analysis,WCA used water cascade table (WCT) to avoid the tedious drawing work of graphical methods and the solving difficulty of mathematical methods,and it could handle water-using processes with and without mass-transfer,so it was applicable to a wide range of water-using operations. The batch processes referred to in this work could be defined as the processes which operated discontinuously and every one of water-using operations had its own start and stop. So,batch processes were divided into several intervals according to the starts and stops of water-using operations. The method firstly ignored time constraints to define the global pinch and utilities target of the batch process,then identified every local water pinch location and the minimum utilities of intervals for the batch process without and with storages respectively. Water-using bottleneck of the batch process was defined by comparison of the global and local pinch,then the storage location was determined to minimize the utilities targets for the batch process. An example was used to illustrate the method,and the results showed that WCA is an effective and efficient method for the synthesis of the water use network for batch processes.
    Steady-state simulation of liquid-phase catalytic oxidation of toluene
    ZHANG Yukun,LI Chufu,REN Shiming,HE Xiaorong,CHEN Bingzhen
    2006, 25(12):  1481. 
    Abstract ( 1592 )  
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    Preparation of benzoic acid by liquid-phase catalytic oxidation of toluene is the pivotal step in the production of caprolactam in SNIA technology of Italy. According to the kinetic model and material balance for 4 key componentsa novel method for simulating this reactive system was proposed. The influence of operation conditions on benzoic acid concentration was studied. The kinetic model included the effects of benzaldehydebenzyl alcohol on the reaction. A new group of kinetic parameters were obtained through multiple nonlinear regressions with industrial data. Hooke-Jeeves algorithm was used to solve the problem. The simulation result showed that the error for benzoic acid mass ratio was within 5%. For the actual industrial processin a reaction temperature range from 164.8 ℃ to 167.2 ℃ and a toluene feed in mass flux range from 79.7 t/h to 104.1 t/hbenzoic acid concentration would increase if the temperature rose or the toluene feed in mass flux decreased.
    Fault analysis using process signed directed graph model
    SHI Yu,QIU Tong,CHEN Bingzhen
    2006, 25(12):  1484. 
    Abstract ( 1830 )  
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    The process signed directed graph (SDG) model represents the cause and effect linkages to connect the fault origin to the observed symptoms of the fault. Fault analysis using the process SDG-based model is based on directed graph qualitative reasoning strategy. In this paperthe elementary conception and improved arithmetic of SDG-based fault analysis are introduced. Finallya case study of a chlorine release accident occurred in a vinyl chloride plant is given.
    PCA-based early fault diagnosis of solid waste incinerator
    HUANG Jianchao,ZHAO Jinsong,SUN Wei,DING Yankun
    2006, 25(12):  1489. 
    Abstract ( 2090 )  
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    Because of uncertainty factors in the burning process of solid waste,it is impossible to execute fault diagnosis by using first principle models. Principal Component Analysis (PCA) was introduced in this paper for incipient fault diagnosis of a waste solid incinerator (WSI). Based on historical data,a PCA model was built to represent its normal states. Fault detection was then realized based on two statistical variables T2 and SPE. Residual Subspace Contribution Factor graphs were then utilized to assist the fault diagnosis. The research result indicated that PCA was an effective approach to incipient fault detection and diagnosis of WSIs.
    Application of response surface methodology to treatment of landfill leachate processing using Fenton’s oxidation
    FU Jianfeng,WU Qiuli
    2006, 25(12):  1493. 
    Abstract ( 1524 )  
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    In this paper,the effects of operating conditions on the Fenton’s oxidation process of landfill leathate were investigated by using statistical methods. Response surface methodology (RSM) was used to investigate the effect of FeSO4•7H2O concentration,H2O2/FeSO4•7H2O and pH on COD removal. The high and low levels of pH values,K2S2O8 concentration and bias potential were 0.01 to 0.02 mol/L,1 to 5mg/L and 2 to 6 respectively. Using the software of Design-Expert 5,a response surface quadratic model in terms of actual factors was obtained based on the experimental data. The optimum FeSO4•7H2O concentration,H2O2/FeSO4•7H2O and pH were found to be 0.013mol/L,4.60,and 4.45 respectively and the highest COD removal efficiency (69.85%) could be achieved.
    Application of OPC technology in DCS system
    HE Yanghuan
    2006, 25(12):  1496. 
    Abstract ( 1633 )  
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    This paper is about the application of OPC technology in data-collecting system. According to the DCS system in Changling Branch, Sinopec, the application of OLE (object linking and Embedding) for Process Control (OPC) communication technology is mainly described here.
    Improving liquid flow on distillation tray with CFD
    LIU DexinLI XingangXU Shimin
    2006, 25(12):  1499. 
    Abstract ( 1943 )  
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    Computational Fluid Dynamics (CFD) was used to improve liquid flow on distillation trayand the factors affecting liquid flow were analyzedsuch as liquid flow intensity and the ratio of weir to diameter. Based on these resultstwo methods were studied and simulation results showed that the placement of suitable inlet weir with unequal height or guide plates could reduce retrograde flow effectively to achieve uniform liquid flow on the whole tray.
    Optimal scheduling of multi-product batch chemical process with consideration of energy consumption
    ZHU Zhenxing,WEI Hongyuan,YANG Hua
    2006, 25(12):  1504. 
    Abstract ( 1843 )  
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    A mixed integer non-linear programming (MINLP) model solving a multi-objective optimization problem that minimized make span and impact of energy consumption was proposed for multi-product batch chemical process scheduling. In this model,the energy consumption factor and decision factor for various products were defined for trade-off between make span and energy consumption. An improved simulated annealing (SA) algorithm was used for solving the problem,and several cases for an example problem were studied. The proposed model could be used to show how the energy consumption consideration affects the scheduling of a multi-product batch process.
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