新型MgCl2/SiO2复合载体丙烯聚合催化剂的研究

化工进展

新型MgCl2/SiO2复合载体丙烯聚合催化剂的研究

祖小京，林舸，陈伟，姜涛

中国科学院广州地球化学研究所；中国石油化工股份有限公司北京化工研究院；大庆石油学院化学化工学院

出版日期:2006-12-25 发布日期:2006-12-25

Novel MgCl2/SiO2 complex support catalyst for propylene polymerization

ZU Xiaojing，LIN Ge，CHEN Wei，JIANG Tao

Guangzhou Institute of Geochemistry，Chinese Academy of Science；
Beijing Research Institute of Chemical Industry，SINOPEC；Department of Chemical Engineering，Daqing Petroleum Institute

Online:2006-12-25 Published:2006-12-25

摘要/Abstract

摘要：

采用喷雾干燥法制备了MgCl₂/SiO₂球形复合载体，经载钛处理后得到丙烯聚合催化剂。利用SEM、XRD、XPS、EDX等分析了催化剂的形态和物性，并进行了丙烯本体聚合研究。结果表明：负载TiCl₄后制备出的球形丙烯聚合催化剂中，Ti/Mg活性组分均匀负载于SiO₂堆成的微球中，催化剂保持了良好的颗粒形态。该催化剂用于丙烯聚合，具有催化活性高、立体定向性好、氢调敏感性好等特点。

Abstract: The MgCl₂/SiO₂ complex support was prepared by spray drying using alcoholic suspension containing MgCl₂ and SiO₂. The complex support reacted with TiCl₄ and di-n-butyl phthalate to prepare the catalyst for propylene polymerization. The catalyst was characterized with SEM，XRD，XPS and EDX. The analysis results showed that SiO₂ functioned as an inert support and there was no chemical reaction between silica and magnesium or titanium. The performance of the catalyst for polymerization of propylene was investigated. The results showed that the catalyst had high activity，high stereo-specificity and sensitive hydrogen response.

祖小京，林舸，陈伟，姜涛. 新型MgCl2/SiO2复合载体丙烯聚合催化剂的研究 [J]. 化工进展.

ZU Xiaojing，LIN Ge，CHEN Wei，JIANG Tao. Novel MgCl2/SiO2 complex support catalyst for propylene polymerization[J]. Chemical Industry and Engineering Progree.