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Table of Content
05 July 2011, Volume 30 Issue 7
    特约评述
    Research and application of ultrasound-enhanced membrane filtration
    CUI Peng,WANG Fenglai,XIONG Wei,CHEN Yazhong
    2011, 30(7):  1391. 
    Abstract ( 1749 )  
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    Ultrasound technique has been proved to be an effective approach to enhancing the flux in membrane process because of its characteristics of mechanical vibration,acoustic streaming and acoustic cavitation,which may be capable of removing portions of the fouled layer from the membrane surface,and preventing the deposition of particles that lead to membrane fouling. Based on the analysis of primary enhancing mechanism and current research on ultrasound enhanced membrane separation process,the integrated systems of ultrasound with membrane module,membrane materials,structure and stability in the ultrasonic field,and a combined utilization of ultrasonic field associated with other technology were reviewed. At the same time,ultrasound enhanced membrane separation in the system containing particle suspension,bio-food industry,and water treatment were also summarized.

    化工过程与装备
    Advance in research on residence time distribution in mixers
    JIN Dan,FU Hailing,WU Jianhua,SUN Dan
    2011, 30(7):  1399. 
    Abstract ( 2379 )  
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    It is important to study the residence time distribution in mixers for a better understanding of flow and mixing. The statistical parameters for describing the RTD are introduced and the different experimental methods for RTD are presented according to the measurement principles and different modes for tracer inputting. The developments of model simulation in chemical reaction engineering method for RTD and flow field simulations for RTD are described. Comparison analysis is made for the choice of different models in flow field simulation. Finally,the applications of statistical methods in RTD are discussed. Future research and development of RTD methods are discussed.

    Research progress of molecular simulation of diffusion in zeolites
    LIU Lifeng,ZHAO Liang,CHEN Yu,GAO Jinsen
    2011, 30(7):  1406. 
    Abstract ( 2575 )  
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    The diffusion in zeolites by using molecular simulation methods has become a new technology in recent years. Molecular simulation technique has contributed to greatly accelerated research on catalysis in a cost-effective manner. Typical methods of molecular simulation are reviewed. Molecular simulation of diffusion in zeolites are introduced in detail,including diffusion coefficients,inffluence factors of diffusion coefficients,application of diffusion interaction energy and transition state theory. In addition,the trend and challenges of molecular simulation technique in heterogeneous catalysis are also discussed.

    Progress of water network integration with multiple contaminants
    LIU Zhihua,HE Haina,LIU Zhiyong?
    2011, 30(7):  1416. 
    Abstract ( 2322 )  
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    This paper describes water network integration with multiple contaminants in recent years,and discusses the current water network design methods for multiple contaminants:water pinch and graphical methods,mathematical programming,internal water mains technology and design methods based on experience. The methods involve the direct reuse of waste water,regeneration reuse and recycling reuse. The characteristics of various methods and future development are presented.

    Research on distillation of heat-sensitive epoxycyclohexane
    XIE Yanxin,CAO Yunbing,XU Yanping,JIANG Denggao
    2011, 30(7):  1421. 
    Abstract ( 2156 )  
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    From the oil phase reaction liquor of H2O2 oxidation of cyclohexene,epoxycyclohexane was separated and purified by atmospheric distillation,and the optimum conditions were determined. Under the optimum conditions the purity of epoxycyclohexane obtained was 99.59% and the single pass yield of product was 85.87 %. Epoxycyclohexane in the high boiling point bottom residue was recovered by vacuum distillation,and the total yield of epoxycyclohexane could be over 90%.

    Purification of cholesterol from lanolin by column chromatography
    HU Wenna,SU Baogen,SU Yun,YANG Yiwen,REN Qilong
    2011, 30(7):  1426. 
    Abstract ( 2319 )  
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    Cholesterol was purified from lanolin by column chromatography. The separation process was optimized based on the resolution between cholesterol and lanosterol,which was one of the impurities. The regeneration of adsorbent was also studied. The optimum purification condition was as follows:adsorbent was silica gel,mixture solvent of acetone/hexane(4∶96,volume ratio)was used as eluent and proper temperature was 35℃. After the separation,the purity of cholesterol was determined by HPLC to be 84.36% and the recovery was 85.67% when the column charge of cholesterol was 2.407% by weight. Additionally,the adsorbent was regenerated by the mixture solvent of acetone/ hexane(50∶50,volume ratio). The separation ability of silica gel remained almost unchanged after 7 cycles of usage and regeneration.

    Sterilization of circulating cooling water by ultrasound
    ZHANG Fan,Lü Xiaoping,HAN Pingfang,QIN Zhenbao
    2011, 30(7):  1431. 
    Abstract ( 2262 )  
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    The use of ultrasound in circulating cooling water sterilization is effective,moreover a long-term effect of bacteriostasis function exists. Several factors,including ultrasonic frequency and intensity,acoustic form which affect the treating result of cooling water were investigated. The optimum condition of sterilization:ultrasonic mixing frequency of 28/40kHz,ultrasonic intensity of 0.30W/cm2,sterilization time of 60min was obtained through orthogonal test. Under this condition 1000 mL circulating water was treated and the bactericidal rate was up to 94.6%. Bacteriostasis test showed that bacteriostasis rate was 82.1% after 72 h. Ultrasonic cavitation could influence the absorbance of KI solution,so the relationship between ultrasonic frequency,intensity with ultrasonic cavitation was obtained. Ultrasonic cavitation was one of the important reasons for ultrasonic sterilization by exploring the mechanism of ultrasonic sterilization. Ultrasound used for sterilization of circulation cooling water will be a new environment-friendly method for purification of industrial circulating cooling water .

    Batch extractive distillation for separation of ether-isopropanol-water azeotropic system
    YE Qing,HUANG Lu,LU Yeqian,DU Guangyao
    2011, 30(7):  1435. 
    Abstract ( 4281 )  
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    Batch extractive distillation for ether-isopropanol-water mixture was studied by using glycol as the extractant. The influence of solvent feeding rate,reflux ratio and solvent feeding temperature was investigated. Under the optimal operation conditions:solvent feeding location at the column top,reflux ratio was 2,solvent feeding rate 11.4g/min in the step of isopropyl ether collection and 8.08 g/min in the step of isopropanol collection,solvent feeding temperature 70.0 ℃ in the step of isopropyl ether collection and 100.0 ℃ in the step of isopropanol collection,the mass fraction of isopropyl ether at the column top could reach 0.95 and its yield was 0.985,the mass fraction of isopropanol at the column top could reach 0.97 and its yield was 0.968.

    Preparation of high purity methylal by extractive distillation using N,N-dimethylformamide (DMF) as solvent
    YIN Kun,JIANG Jianlan,BAI Peng,TANG Ke,JIANG Zhankun
    2011, 30(7):  1440. 
    Abstract ( 2175 )  
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    The solvent for methylal production by extractive distillation was chosen according to basic selection rules. The appropriate solvent and solvent ratio were determined with Chemcad simulation and vapor-liquid equilibrium experiment. The results showed that N,N-dimethylformamide(DMF)as a solvent could eliminate the azeotropic point of the azeotrope methylal-methanol. The simulation of vapor-liquid equilibrium using UNIQUAC model for methylal-methanol system with and without DMF under atmospheric pressure were performed and the simulation results agreed well with the experimental data. Finally the separation of crude product of methylal-methanol by batch extractive distillation was performed. Under the operation conditions,the high purity product methyal of 99.9%(mass percentage)could be obtained at the top of the column .

    Experimental investigation on bubbling behavior in anode channel of passive DMFC
    ZOU Xiaoyan,YAO Kejian
    2011, 30(7):  1444. 
    Abstract ( 2496 )  
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    The behavior of bubbling from anode diffusion layer into anode channel in passive DMFC was simplified as the formation and detachment of CO2 bubbles at orifices immersed in a stagnant liquid,and was experimentally investigated by using a visual system. The effects of as flux,orifice submergence,gas nozzle size,liquid concentration were investigated. The results showed that in the process of bubble growth,the contact angle decreased sharply at first and then increased rapidly,then was maintained at a constant value until detachment. With the increase of gas flux,bubble departure diameter changed little and the detaching time tended to be constant after the first rapid decline. Bubble departure diameter decreased and bubble frequency increased with the increase of submergence,and there was a fall in detaching time at first and then became constant in the process. The impact of gas flux on detaching time was weakened with the increase of submergence. As aperture increased,bubble departure diameter increased,resulting in decreasing bubble frequency,and bubble detachment time decreased. When the concentration of methanol was increased,the bubbles produced became smaller and the fluctuation of bubble size became significant,and bubble frequency grew faster. In addition,detaching time decreased first and then became constant especially at a low concentration.

    Analysis of structure and operating parameters of typical industrial vacuum transfer line
    CHEN Jianmin1,SUN Yuling2,JIANG Bin3,QIN Ya3
    2011, 30(7):  1450. 
    Abstract ( 2438 )  
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    The transfer line refers to a pipeline connection between furnace and vacuum column in the crude oil distillation unit. A well-designed transfer line can increase the evaporation rate of the feed in the vacuum distillation tower,improve oil product quality and save energy for the vacuum distillation tower. According to the existence of sudden enlargement,diffuser and T-connection,particularly to the connected mode of transition section and the low flow rate section,the typical vacuum transfer lines are divided into A,B type and C type. Using the one-dimensional,two-phase flow model developed on the basis of pressure drop model and the multi-stage flash model,the analysis of axial pressure,temperature,flow rate and evaporation rate of seven industrial transfer lines was made. The results showed that the pressure drop of Type A was the greatest because the transition section merged to the low flow rate section directly. The pressure in the transfer lines of Type B decreased gradually,and its pressure drop was the lowest. The pressure drop of Type C with two-stage enlargement structure decreased sharply twice and its pressure drop was lower.

    能源加工与技术
    Renewable biofuel production from thermal-chemical conversion of triglyceride
    XU Junming1,2,XIAO Guomin1,ZHOU Yonghong2,JIANG Jianchun2
    2011, 30(7):  1456. 
    Abstract ( 2138 )  
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    Although bio-diesel shows great promise as a renewable,alternate fuel,it is important to note that there are still disadvantages associated with its production and use. In this paper,the research advances by thermal chemical conversion,including thermal cracking and catalytic cracking processes for biofuel production are presented. The main problems are mentioned and the prospect of this research field is presented. Different catalysts used in catalytic cracking are compared and discussed. The catalyst with good selectivity for hydrocarbon products is a research priority.

    Analysis of current technologies and prospects of ethanediol produced from oil and coal
    HUANG Gesheng,LI Zhenyu,LI Dingjie,LIANG Chuan
    2011, 30(7):  1461. 
    Abstract ( 2677 )  
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    The recent technologies of ethanediol produced from oil and coal are introduced. Ethanediol production,market and prospects at home and abroad are analyzed. The demand of ethanediol in China is driven by the rapidly developing polyester industry,and the market prospect of ethanediol is broad. Although the coal to ethanediol technology has been taken as one of the key fields to be developed for the coal chemical industry of China,the resources and markets should be considered carefully the decision of building new production is made. China should focus on reducing cost and actively responding to the challenges of foreign imports,strengthening research and development,and expending the field of application.

    工业催化
    Advance in research on reaction mechanism and active sites for methanol synthesis
    BAI Shaofen,LIU Xinmei,YAN Zifeng
    2011, 30(7):  1466. 
    Abstract ( 3127 )  
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    Methanol is an important organic chemical and fuel for transportation and mobile devices. When used as a fuel,it is a cleaner energy compared with most other energy sources. Although methanol synthesis has attracted worldwide research interest in the past 40 years,the synthesis mechanism and the nature of active sites are yet to be fully understood. The current state of the reaction mechanism and active sites of methanol synthesis over Cu-based catalyst are reviewed in this paper. It will provide reference to the development of high-quality catalysts.

    Research progress of catalysts for selective hydrogenation of benzene to cyclohexene
    DONG Sen,FANG Chengxuan,WANG Yatao
    2011, 30(7):  1473. 
    Abstract ( 1980 )  
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    The catalysts for selective hydrogenation of benzene to cyclohexene have been widely used in synthetic fiber industry and other fields. The research status of the catalysts for this reaction is reviewed by focusing on the influence factors on catalytic activity and selectivity,such as active components,supports,promoters,additives and preparation methods. The reaction mechanism of the influence is analyzed and the key to improving cyclohexene selectivity is indicated. The development direction of the catalysts is prospected.

    Research advance in mechanism of low-temperature SCR of NO on carbon materials
    HUANG Huacun
    2011, 30(7):  1478. 
    Abstract ( 2603 )  
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    The behavior of the reactant molecules on carbon materials surface,formation of adsorbed NO2 ,dimer (NO)2,—NO2 or pyridine compounds from single component NO is reviewed. When NO and O2  coexists,NO is oxidized to NO2 by the adsorbed O2. When NO,O2 and NH3 coexists,the reaction occurs between adsorbed NH3 and adsorbed NO2. The mechanism of selective catalytic reduction(SCR)of NO on activated carbon fibers(ACF)catalyst is presented as follows. At a low temperature NH3-SCR follows the Langmuir-Hinshelwood mechanism. While at a high temperature NH3-SCR follows the Eley-Rideal mechanism. The catalyst pore structure characteristics and surface chemical functional groups are the main factors of the low temperature SCR of NO.

    Research progress of TiO2?Al2O3 composite support
    GUO Changyou,SHEN Zhiqi,ZHANG Zhimin
    2011, 30(7):  1482. 
    Abstract ( 2314 )  
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    Porous composite oxide of TiO2·Al2O3 is a new type of catalyst support,which has attract- ed increasing attention due to its capability to improve catalytic activity for hydrodesulfurization(HDS)and hydrodenitrogenation(HDN)of hydrotreating catalyst. This paper reviews the studies on the synthesis of porous TiO2·Al2O3 and analyzes influence factors of catalyst support properties,such as textural property and surface acidity etc,in the synthesis process.

    Preparation of Pt-based catalyst by reverse microemulsion and its selective hydrogenation performance
    LI Feng1,SONG Hua1,WANG Shuying1,CHENG Xiquan2
    2011, 30(7):  1489. 
    Abstract ( 2399 )  
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    A series of Pt-based catalysts were prepared by reverse microemulsion. The effects of synthesis parameters,such as composition of microemulsion,co-surfactant type,oil phase type,reducing agent dosage,and support type on the catalytic activity of Pt-based catalysts were studied by using m-chloronitrobenzene(m-CNB)selective hydrogenation as a probe reaction. The Pt particle and catalyst were characterized by TEM. The optimum preparation condition for Pt-based catalyst was as follows:microemulsion system of cetyltrimethylammonium bromide(CTAB)/n-butarol/cyclohexane/ H2PtCl6 solution with m(CTAB)∶m(n-butarol)=3∶7,m(CTAB+n-butarol)∶m(cyclohexane)=3∶7,H2PtCl6 solution content  of 3.6%,and N2H4·H2O dosage of 100 μL. Under this condition,the Pt/γ-Al2O3 catalyst exhibited the highest catalytic activity in selective hydrogenation of m-CNB. The result of TEM showed that Pt particles dispersed on the surface of support uniformly.

    Heteropolyacid salts catalysts supported on silylated attapulgite for cyclohexane oxidation
    LI Guixian1,SONG Weiwei1,MA Jianjun1,2,GAO Yunyan1,WANG Guang1,LI Yazhen1
    2011, 30(7):  1494. 
    Abstract ( 2593 )  
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    Heteropolyacid salts catalysts supported on silylated attapulgite were prepared by incipient wetness impregnation and characterized by XRD,BET,FTIR. The effects of the amount of H2O2,heteropolyacid salts catalysts loading and recycling times on cyclohexane oxidation was evaluated. The results show that the supported CoH7P2Mo15V3O62 enhanced cyclohexane oxidation. Recycle catalyst can be directly reused after drying,and catalytic activity was not significantly reduced. Under the optimal conditions,the conversion of cyclohxane was 35.28 % and the total yield of cyclohexanol and cyclohexanone was 12.48%. Experiments showed that the supported CoH7P2Mo15V3O62 heteropolyacid salts was one kind of promising catalyst,which could facilitate separation of products,require few pieces of equipment and cause less environmental pollution.

    Selective synthesis of p-xylene by alkylation of toluene with dimethyl carbonate over magnesium acetate-modified ZSM-5
    WANG Yongfei,XUE Bing,XU Jie,LI Yongxin
    2011, 30(7):  1498. 
    Abstract ( 2883 )  
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    MgO-modified ZSM-5 was prepared by impregnation of ZSM-5 with an aqueous solution of magnesium nitrate. Selective synthesis of p-xylene by alkylation of toluene with dimethyl carbonate(DMC)was carried out in a continuous flow fixed-bed rector over MgO-modified ZSM-5 zeolite. Physico-chemical properties of MgO/ZSM-5 catalysts were characterized by means of XRD,NH3-TPD,2,4-dimethylquinoline-IR and pyridine-IR.The results of experiments indicated that alkylation of toluene with DMC occurred mainly on Brønsted acid sites. With increasing MgO content,there was a decrease in toluene conversion and increase in selectivity for p-xylene. With further increase in MgO content from 9% to 12%,no significant change in toluene conversion and selectivity for p-xylene was observed. The results of FT-IR characterization with 2,4- dimethylquinoline adsorption indicated that the MgO was only dispersed over the external surface of ZSM-5 zeolite. With increasing MgO content,the amount of Brønsted acid sites decreased. When the amount of MgO was >9%,Brønsted acid sites on the external surface almost disappeared.

    Catalytic oxidation of NO over Ce-doped Mn/TiO2
    LI Xiaohai,ZHANG Shule,ZHONG Qin
    2011, 30(7):  1503. 
    Abstract ( 1995 )  
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    Mn-Ce/TiO2 catalyst was prepared by impregnating Mn-Ce on TiO2 and was characterized by XRD,BET and PL. The influences of Ce-doping concentration,loading,calcinations temperature,space velocity,inlet concentration of NO and volume fraction of oxygen on the performance of catalytic oxidation were examined. The results showed that the effect of doping Ce not only increased the surface area of MnOx/TiO2 but also enhanced the dispersion of active phase over TiO2. At Ce-doping concentration of [Ce]/[Mn]=1/3,10% loading Mn-Ce/TiO2 catalyst calcined at 300 ℃ for 3 h had high catalytic oxidation activity. When inlet concentration of NO was 300 μL/L,O2 10%,space velocity was 41000 h-1,oxidation rate of NO over Mn-Ce/TiO2 reached 58% at 200 ℃.

    材料科学与技术
    Research progress of non-covalent functionalization and applications of graphene
    FAN Yanru,ZHAO Zongbin,WAN Wubo,ZHOU Quan,HU Han,QIU Jieshan
    2011, 30(7):  1509. 
    Abstract ( 2729 )  
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    Graphene research develops dramatically in diverse fields,such as materials,physics,chemistry,biology and so on,and mainly concentrates on its synthesis,functionalization and applications. However,graphene also possesses some drawbacks,such as low solubility and poor dispersion that limit its performance,therefore functionalization of graphene-sheets is of crucial importance for making the best of their potential applications. Non-covalent functionalization is paid much attention due to its less damage and full maintenance of the intrinsic structure and properties of graphene. The recent research about non-covalent functionalization of graphene,including π-π interaction,hydrophobic attraction between surfactant and graphene,and hydrogen bonding interactions,is reviewed and applications of these functional graphene,such as electrode materials,electrocatalysis,field effect transistors and transparent conductors are outlined and prospected.

    Advance in polystyrene resins for catalytic aldol condensation
    WANG Jiexiang,WANG Qiang,LI Yunhua,CHEN Binghui
    2011, 30(7):  1521. 
    Abstract ( 2484 )  
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    Polystyrene resins have been paid attentions as a type of solid basic catalyst and significant progress has been made in its industrial application. The use of polystyrene resins to catalyze aldol condensation is reviewed. The effects of inherent properties and the modification of polystyrene resins on aldol reactions are summarized. The potential and research for polystyrene resins as catalysts are discussed.

    Progress of dissolution of cellulose with imidazolium ionic liquid
    ZHAO Dishun 1,LI He1,FU Linlin1,ZHANG Juan1,REN Peibing 1,2
    2011, 30(7):  1529. 
    Abstract ( 2317 )  
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    Cellulose is the most abundant renewable bio-material. Due to its hydrogen-bonded supramolecular structure,cellulose is insoluble in water and most common organic liquids,which limits its application. The emergence of ionic liquids provides a broad platform to the application of cellulose. The recent developments concerning imidazolium ionic liquids as cellulose solvents as well as the dissolution mechanism are reviewed. Ionic liquids,containing Cl-,CH3CHOO- and (MeO)RPO2- anions,appear to be the most effective solvents. A series of alkyl imidazolium ionic liquids containing alkyl phosphate was prepared by a one-pot procedure. Such ionic liquids have good thermal stability and are capable of solubilizing cellulose under mild conditions. The structure of imidazolium cation has an influence on the solubility as well. Future development of imidazolium ionic liquids is discussed.

    Technical options for production of chlorinated polypropylene under phaseout of carbon tetrachloride
    LU Yingzhou1,YANG Lirong2,WANG Kaixiang2,WANG Linhong2,LI Chunxi1
    2011, 30(7):  1537. 
    Abstract ( 2638 )  
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    This paper summarizes technologies of chlorinated polypropylene(CPP)production,and presents several new technologies for CPP production that do not use carbon tetrachloride(CTC). The feasibility and applicability of different technologies for CPP production are analyzed. Non-CTC solvent technology is the optimum process to produce CPP with low chlorinity which could be used for printing ink production. Water phase suspension technology is suitable for preparing CPP  for applied materials production. Despite its advantage of energy-saving and emission-reduction,solid-phase technology is still not mature and should be further improved. Finally,it is suggested that new varieties of CPP should be developed to meet the increasing demands of diversified production.

    Synthesis and properties of MDI-50 type polyurethane elastomer
    LI Wanjie,LIN Yinlei,ZHENG Yugang
    2011, 30(7):  1542. 
    Abstract ( 2680 )  
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    MDI-50 type polyurethane elastomer was prepared from a prepolymer system based on MDI-50,polyol and MOCA chain extender. The effects of mass fraction of —NCO in prepolymer on properties of the elastomer were studied. The structure and performance were analyzed by means of DSC,TG,FTIR and mechanical properties test. The results showed that hardness and glass transition temperature of MDI-50 type polyurethane elastomer increased with increasing molar ratio of NCO/OH in prepolymer reactive system. The tearing strength and tensile intensity increased at first and then declined with increasing mass content of —NCO. However,elongation at break of the elastomer and viscosity of prepolymer decreased with increasing —NCO mass content. It showed that better properties were obtained at 2.22 of the molar ratios of NCO/OH. —NCO mass content had little influence on thermal stability of the elastomer .The result provided data for the application of formula design of MDI-50 type polyurethane elastomer.

    Synergistic antioxidant performance of a new antioxidant for polyolefin
    WANG Jun,SHI Chunxia,Lü Chunsheng,LI Jie,ZHANG Rongming,GUO Yandong,QU Hongjie
    2011, 30(7):  1546. 
    Abstract ( 2632 )  
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    The synergistic antioxidant performance of a new antioxidant for polyolefin and phosphite antioxidant 168 was studied with PP and LLDPE resins by measurement of melt flow rate(MFI)and oxidation induction time(OIT). The results showed that the new antioxidant for polyolefin had excellent processing properties and oxidation resistance behavior with the two polyolefin resins,and the antioxidant performance of the antioxidant was superior to antioxidant 3114. The new antioxidant for polyolefin combined with a secondary antioxidant 168 had higher oxidation resistance behavior. The synergy effects on processing stability and thermal oxidation stability in PP resin were 274.62% and 59.90% respectively. The synergy effects on processing stability and thermal oxidation stability  with  LLDPE resin were 257.74% and 109.64% respectively. The mechanical properties of polyolefins could also be improved.

    Preparation of magnetic Fe3O4 nano-particles modified with oleic acid at low-temperature and washed with distilled water
    ZHU Chunshan,SONG Jia,QIU Li,ZHANG Qiang
    2011, 30(7):  1552. 
    Abstract ( 2781 )  
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    The magnetic Fe3O4 nano-particles modified with oleic acid were prepared at 60 ℃ reaction temperature and washed with distilled water. The modified Fe3O4 nano-particles were characterized by X-ray diffraction ,infrared ray spectrum and TEM. The results showed that the Fe3O4 nano-particles modified by oleic acid had better dispersibility,stronger magnetic response and average grain size of 18 nm.

    Preparation and characterization of XG-g-P(AA-co-AM)/AC composite super absorbent resin
    SU Xiuxia1,LI Yiyang1,LI Zhongjin1,LI Mingjie1,ZHAO Yan1,HAO Mingde2
    2011, 30(7):  1556. 
    Abstract ( 2902 )  
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    The composite super absorbent resin,xanthan gum-g-poly(acrylic acid-co-cryl amide)/ attapulgite clay with good salt tolerance was synthesized through inverse suspension copolymerization. The influence factors of preparing composite super absorbent resin were studied. FT-IR,XRD and TGA were used on characterization of the super absorbent resin. The results showed that:Si-OH and AM/AA participated in graft polymerization reaction with xanthan gum. The preparation of super absorbent resin under optimum conditions has good properties of water absorption and salt resistance,with the highest water absorption up to 871.2 g/g and 0.9% NaCl solution absorption up to 119.8 g/g. Degradation tests showed that super absorbent resin could be degraded by microbes,and the degradation degree was up to 26.1% within 90 days.

    生物化工
    Progress of asymmetric reduction with alcohol dehydrogenase for preparation of chiral alcohols
    CHEN Rong1,2,WANG Qiuyan1,YIN Xiaopu1,WEI Dongzhi2,XIE Tian1
    2011, 30(7):  1562. 
    Abstract ( 2044 )  
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    For preparative applications in asymmetric reduction with alcohol dehydrogenase,three issues have to be considered:An appropriate enzyme,an efficient coenzyme-regenerating method and a suitable in vitro evolution technique. Enzyme is the source of effective biocatalyst. The native or recombinational alcohol dehydrogenases from Rhodococcus sp.,Lactobacillus sp.,Leifsonia sp. and thermophilic microbiology,and their catalysis were analyzed. The advantages and disadvantages of coenzyme-regeneration methods were discussed. The efficient coenzyme-regeneration can decrease costs for large-scale application. In vitro evolution technique can improve the activity,stability and selectivity of target enzyme. The final aim is to establish effective and green ways to obtain chiral drug intermediates by enzymatic synthesis.

    Research progress of lipase-catalyzed synthesis of L-ascorbyl organic acid ester
    JIANG Xiangjun1,HU Yi1,2,LIU Weiming1,HUANG He1,2
    2011, 30(7):  1570. 
    Abstract ( 2300 )  
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    To broaden the applications of L-ascorbic acid,it is an economical and feasible way to convert L-ascorbic acid into L-ascorbyl organic acid ester. The recent research progress of enzymatic synthesis of L-ascorbyl organic acid ester is summarized,by focusing on enzymatic synthesis of L-ascorbyl saturated fatty acid ester,unsaturated fatty acid ester and mixed fatty acid ester in organic solvents. The types of lipase,organic solvents and methods of separation and purification in the synthesis are discussed. Furthermore,the prospect of enzymatic synthesis of L-ascorbyl organic acid ester is also presented.

    Solvent effect on catalytic synthesis of chiral compouds with lipase and penicillin G acylase
    XUE Ping,CAO Xuerong
    2011, 30(7):  1577. 
    Abstract ( 2471 )  
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    Synthesis of chiral drugs and intermediates catalyzed by enzyme has high efficiency,energy saving and environment-friendliness advantages. This paper reviews the solvent effect on the enzymatic reaction in non-aqueous media with lipases,namely,the activity and enantioselectivity of enzyme adjusted by solvent system to improve the efficiency of catalytic reaction. The kinetically controlled synthesis of β-lactam antibiotics with penicillin G acylase was introduced in different solvent systems,including the organic-water miscible solvents,organic-water immiscible solvents,reverse micelles and aqueous two-phase system. The yield of kinetically controlled synthesis of β-lactam antibiotics and synthesis/hydrolysis ratio(S/H)could be enhanced by designing an effective solvent system to better utilize the substrates.

    Immobilization of lipase on magnetic porous microspheres
    TAO Weihong,YANG Lirong,XU Gang,TAI Yulei,WANG Li,WU Jianping
    2011, 30(7):  1584. 
    Abstract ( 2415 )  
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    The immobilization of Arthrobacter sp. lipase on magnetic porous microspheres was investigated. The magnetic porous microspheres was characterized with FTIR,XRD,SEM,TEM,BET,TGA and VSM,and the effect of immobilization time,pH,and lipase amount on the catalytic performance of the immobilized lipase in an organic system was studied. The results showed that the core of microsphere was Fe3O4,the surface was porous,the surface area of microsphere was 12.16 m2/g,average pore diameter was 171.7 nm,its magnetic content was 38% and it was super-paramagnetic. The optimal immobilization conditions were determined to be pH 8.0 with the lipase/carrier ratio of 1 to 1(m/m)and immobilization time of 6 h. The activity recovery was as high as 2.4 fold of the free lipase in the resolution of 4-hydroxy-3-methyl-2-(2-propenyl)-2-cyclopenten-1-one. Furthermore,the operational stability of the immobilized enzyme was greatly enhanced compared to the free enzyme. The residual activity was kept at 74.5% after 30 batch reactions,while that of the free enzyme was just 37.1% after 7 batch reactions.

    Effect of metal ions on fermentation and metabolization of Actinobacillus Succinogenes NJ113
    ZHENG Xiaoyu,LI Jian,FANG Xiaojiang,CHEN Kequan,XI Yonglan,JIANG Min
    2011, 30(7):  1591. 
    Abstract ( 2120 )  
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    The effects of adding Mg2+,Mn2+,Co2+ on cell growth and succinic acid production was investigated. The metabolic flux of Actinobacillus succinogenes NJ113 was calculated. It was found that the flux of HMP increased by 445.38%,176.23 % and 171.67% after adding 6 mmol/L Mg2+,6 mmol/L Mn2+, 2 mmol/L Co2+ respectively,thus the reducing power was better balanced. The flux of C4 was 57.70%,15.94% and 2.91% higher respectively,which led to the improvement of succinic acid flux by 62.69%,18.91% and 5.01%. The key enzyme activity analysis showed that the specific activity of PEP carboxykinase(Pck)reached 568.732 U/mg,728.049 U/mg and 339.686 U/mg with 6 mmol/L Mg2+,6 mmol/L Mn2+,2 mmol/L Co2+ addition respectively. As a result,the concentration of succinc acid was 27.83 g/L,26.27 g/L,and 23.54 g/L,while the concentration of control was only 22.79 g/L.

    精细化工
    Synthesis and fluorescence performance of rare earth-amino acid complexes with Schiff base
    ZHANG Wenjun,ZHANG Jing,YUAN Zhizhong
    2011, 30(7):  1598. 
    Abstract ( 1861 )  
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    A Schiff base ligand,L-phenylalanine-o-vanillin,and its rare earth(Tb,Eu)complexes were synthesized. The complexes were characterized by elemental analysis,IR spectrometry,UV-vis as [Tb2(H2O)2(SL)4](NO3)2,[Eu2(H2O)2(SL)4](NO3)2(SL=C17H17O4N). The photophysical properties of the ligand and complexes were investigated by fluorescence spectroscopy. The result showed that the ligand and complexes exhibited good fluorescence,and complexes exhibited good thermal stability(decomposition temperatures reached 580 ℃).

    Synthesis of acrylpimaric acid under microwave irradiation
    WANG Hongxiao1,2,SHANG Shibin1,2,XU Xu1,2,TAN Weihong1,2
    2011, 30(7):  1602. 
    Abstract ( 2540 )  
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    Acrylpimaric acid was synthesized under microwave irradiation by using rosin and acrylic acid as raw materials. The effects of reaction time,microwave power,temperature,and mole ratio of acrylic acid to resin acids on the Diels-Alder addition were investigated. The optimum synthesis conditions were obtained as follows:reaction time 60 min,reaction temperature 180 ℃,microwave power 110 W,acrylic acid /resin acids ratio 1.2∶1(mole ratio). The results showed that microwave could accelerate the reaction rate significantly.

    资源与环境工程
    Research progress of removing mercury from coal-fired flue gas
    CUI Xia,MA Liping,DENG Chunling,XU Wenjuan,MAO Yu
    2011, 30(7):  1607. 
    Abstract ( 2780 )  
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    Mercury emissions from coal-?red power plants are believed to be the largest source of anthropogenic mercury emissions. This paper illustrates the form of mercury and the main factors which affect the elimination rate of mercury. Through the introduction of the air pollution control devices(APCDs),synergistic control is feasible by taking advantage of existing APCDs. The research progress of mercury emission control is summarized. The absorbents for mercury assorption,such as active carbon,activated carbon fiber,ash,polymeric chitosan,natural mineral sorbents,and new kinds of absorbents are summarized. Recent advances in non-injection mercury sorption technologies are reviewed. Future research directions are suggested.

    Progress of utilization of fly ash with high concentration alumina
    HU Qinhai1,ZHANG Hui1,BAI Guanghui2,XU Peng3,WANG Zhanxiu4,ZHU Jianhang1
    2011, 30(7):  1613. 
    Abstract ( 2672 )  
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    The research progress of the utilization of fly ash with high concentration alumina is reviewed. After a summary of properties of fly ash with high concentration alumina,the main methods of utilizationof sintering,acid,alkali,acid and alkali combination method are introduced. The processes,products of the four methods and the research status are described. Advantages and disadvantages of various methods are pointed out and corresponding solutions are proposed.

    Synthesis and characterization of PHA produced by acclimated activated sludge from acidified starchy wastewater
    LI Jinjuan,ZHAO Lin,TAN Xin,HUANG Yu,LIU Tingyi
    2011, 30(7):  1618. 
    Abstract ( 2611 )  
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    The synthesis and characterization of poly-β-hydroxyalkanoates(PHA)by activated sludge from acidified starchy wastewater were studied. The results showed that the acidification products of starchy were butyric,acetic,propionic,valeric acids and ethanol. These organic acids were used to feed activated sludge to produce PHA and 34.7% of PHA from sludge was obtained. The PHA in the sludge was extracted by CHCl3 and its structure and thermal properties were determined by nuclear magnetic resonance(NMR),themogravimetric(TG)and differential scanning calorimeter(DSC). The results of NMR showed that PHA was composed of HB and HV and PHA had HV content of 8.9%(mole ratio). The results of thermal analysis showed that melting point was 150 ℃ and thermal degradation temperature was 270 ℃.

    Processing conditions for preparation of polyol from beet pulp liquefied degradation
    YAN Xiaolin,WANG Kebing
    2011, 30(7):  1623. 
    Abstract ( 2238 )  
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    The catalyzed liquefied degradation of beet pulp(BP)in the system of solid phosphotungstic acid as catalyst and polyethyleneglycol 400(PEG 400)/ glycerol(GLY)as complex liquefier was studied,and the effect of processing conditions of BP liquefaction such as liquefaction temperature,catalyst amount,liquid-to-solid ratio,liquefaction time on the liquefaction reaction and properties of liquefaction product were investigated. The results showed that BP had good liquefaction effect,the optimum liquefaction processing conditions were determined as follows:PEG 400/glycerol mass ratio 4∶1,liquefaction temperature 160 ℃,catalyst amount 4%,liquid-to-solid mass ratio 12∶1 and liquefaction time 160min,the liquefaction rate would reach 99.0%. Hydroxyl value and acid value of liquefaction mixtures were 45—86 mg/g and 0.61—0.75 mg/g respectively,which was a low hydroxyl value plant-based polyol.

    应用技术
    Simultanous removal of high concentration nitrogen and phosphorus from abattoir wastewater by using a sequencing batch reactor
    JIA Yanping 1,2,WANG Ying1,ZHANG Lanhe1,LI Jun1
    2011, 30(7):  1627. 
    Abstract ( 2376 )  
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    A sequencing batch reactor(SBR)was used to remove high concentration nitrogen,phosphorus and COD in the abattoir wastewater. The results showed that step-feed could avoid high-level build-up of nitrate and nitrite during the nitrification and create anaerobic conditions for biological phosphorus removal. Two types of abattoir wastewater were used as raw wastewater,one was the effluent from abattoir wastewater and the other was the pre-fermentor wastewater. After a 3-month start-up,removal efficiencies of total phosphorus,total nitrogen and COD were higher than 96%,95% and 95.5%,respectively,when total phosphate,total nitrogen and COD in the influent were 36.5 mg/L,226 mg/L and 2615 mg/L,respectively,under the condition of a sludge age of 14 days at 35 ℃.The concentrations of total phosphate,total nitrogen and COD in the effluent were lower than 1.4 mg/L,10.8 mg/L and 95 mg/L,respectively.

    Research on purifying wet-process phosphoric acid by membrane dispersion extraction
    ZHANG Zeguang,MA Yanlong,YE Shichao,LI Jun,ZHONG Benhe
    2011, 30(7):  1632. 
    Abstract ( 1932 )  
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    The membrane dispersion extraction process was used to purify wet-process phosphoric acid with stainless steel fiber sintered membrane as dispersion media. The system of water/phosphoric acid/ TBP + kerosene was used to study the effects of flow rate,membrane diameter,kerosene content ,phase ratio,phosphate content and extraction cell volume and residence time on the extraction. When flow rate increased,extraction efficiency increased first and then decreased.,When pore diameter decreased and phosphoric acid concentration of water increased,extraction efficiency increased. When extraction cell volume was enlarged and residence time was increased,extraction efficiency increased. With 10 μm stainless steel fiber sintered membrane,at dispersed phase flow rate of 1000 mL/min,kerosene volume fraction of 20%,phase ratio of 1∶1,phosphoric acid content of 30%—70%,extraction cell volume of 30 mL,single-stage efficiency could  reach 96%.

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