化工进展

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以N,N-二甲基甲酰胺为溶剂萃取精馏制备高纯度甲缩醛

尹 琨,蒋建兰,白 鹏,唐 克,姜占坤   

  1. 天津大学化工学院,天津 300072
  • 出版日期:2011-07-05 发布日期:2011-07-05

Preparation of high purity methylal by extractive distillation using N,N-dimethylformamide (DMF) as solvent

YIN Kun,JIANG Jianlan,BAI Peng,TANG Ke,JIANG Zhankun   

  1. School of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China
  • Online:2011-07-05 Published:2011-07-05

摘要:

通过溶剂选择原理粗选出萃取精馏制备甲缩醛产品的溶剂,既而通过Chemcad软件模拟和汽液平衡实验确定合适的溶剂及溶剂比。结果表明,N,N-二甲基甲酰胺(DMF)能够消除甲缩醛-甲醇共沸物系的共沸点;采用UNIQUAC模型对常压下甲缩醛-甲醇物系和加入溶剂N,N-二甲基甲酰胺的汽液平衡进行模拟,模拟结果和实验数据吻合较好。用间歇萃取精馏实验对甲缩醛粗品进行了分离,在实验条件下,可以从塔顶得到质量浓度为99.9%的高纯度甲缩醛产品。

Abstract:

The solvent for methylal production by extractive distillation was chosen according to basic selection rules. The appropriate solvent and solvent ratio were determined with Chemcad simulation and vapor-liquid equilibrium experiment. The results showed that N,N-dimethylformamideDMFas a solvent could eliminate the azeotropic point of the azeotrope methylal-methanol. The simulation of vapor-liquid equilibrium using UNIQUAC model for methylal-methanol system with and without DMF under atmospheric pressure were performed and the simulation results agreed well with the experimental data. Finally the separation of crude product of methylal-methanol by batch extractive distillation was performed. Under the operation conditionsthe high purity product methyal of 99.9%mass percentagecould be obtained at the top of the column .

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