Synthesis and application of chainlike MFI type zeolites

doi:10.16085/j.issn.1000-6613.2023-1140

Abstract

Abstract:

Chainlike MFI type zeolites were formed by the condensation of uniformly sized crystals along the b-axis direction through surface hydroxyl groups, which not only maintianed traditional zeolites' unique three-dimensional pore structure, acid resistance, hydrothermal stability, and high catalytic activity, but also showed higher shape selectivity, endowing them with unique properties in many fields such as adsorption, separation and catalysis. This paper systematically presented the current research development on the synthesis of chainlike MFI type zeolites and their application, focusing on the two synthesis methods of conventional hydrothermal and microwave-assisted hydrothermal synthesis. In addition, it analyzed the formation mechanism of chainlike MFI type zeolites in depth, elaborated on the various factors inducing the condensation of Si—OH groups, and then concluded the excellent catalytic and adsorptive performance of chainlike MFI type zeolites. Finally, an outlook on the green synthesis and potential application about chainlike MFI type zeolites was given, and the analysis on the evolution of silicon coordination environment was proposed as an important direction for further exploring their synthesis mechanism, which would lay an essential theoretical foundation for expanding the application of chainlike MFI type zeolites in the future.

Key words: chainlike morphology, MFI type zeolites, synthesis, catalysis

摘要：

链状MFI型分子筛是由大小均一的晶粒沿b轴方向通过表面羟基缩合而成，在保留传统分子筛独特的三维孔道结构、耐酸性、水热稳定性、高催化活性的同时，具有较高的孔道择形性，在吸附、分离、催化等领域展现出独特的性能。本文系统介绍了链状MFI型分子筛合成及其应用领域的最新研究进展，重点综述了常规水热合成与微波辅助水热合成两种方法，深入分析了链状MFI型分子筛的形成机理，对诱导表面羟基缩合的各种因素进行了详细阐述，总结了其在物理吸附及催化方面的优异性能。最后对链状MFI型分子筛的绿色合成及潜在应用进行了展望，提出硅配位环境的动态变化过程分析对于揭示其合成机理至关重要，将为拓展链状MFI型分子筛的应用奠定重要理论基础。

关键词: 链状, MFI型分子筛, 合成, 催化

CLC Number:

TQ426.65

ZHANG Yesu, QUAN Yanhong, DING Xinxin, REN Jun. Synthesis and application of chainlike MFI type zeolites[J]. Chemical Industry and Engineering Progress, 2024, 43(8): 4382-4392.

张叶素, 权燕红, 丁欣欣, 任军. 链状MFI型分子筛的合成与应用[J]. 化工进展, 2024, 43(8): 4382-4392.

Figures/Tables 9

References 61

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合成方法	MFI型分子筛	模板剂	Si/Al或Si/Ti	比表面积 /m²·g^-1	总孔容 /cm³·g^-1	特征与优势	应用	参考文献
水热合成法
模板法	ZSM-5	TPAOH	70	315	0.47	中空、介孔结构	催化裂解	[30]
		TPAOH	63	313	0.28	介孔结构	异构化	[59]
		TPAOH	83	398.8	—	链长适当	CO₂加氢制芳烃	[58]
助剂辅助法	ZSM-5	TPAOH、PDDA	90	470	0.27	介孔结构	甲醇制烯烃	[22]
		TPAOH、PDDA	50	538.7	0.77	介孔结构	催化裂解	[23]
		TPAOH、蔗糖	136	397	0.36	介孔结构	甲基化	[24]
		TPAOH、SA	16~64	410	0.25	—	—	[25]
		TPAOH、乙醇	50	370.7	0.63	—	—	[36]
微波合成法	TS-1	TPAOH	70~230	423	0.21	长而直的孔道、较强的疏水性	吸附分离	[42]
		TPAOH	71	329	0.23	适当的酸性	环氧化	[40]
	ZSM-5	TPAOH	70~90	451	0.37	—	—	[45]

合成方法	MFI型分子筛	模板剂	Si/Al或Si/Ti	比表面积 /m²·g^-1	总孔容 /cm³·g^-1	特征与优势	应用	参考文献
水热合成法
模板法	ZSM-5	TPAOH	70	315	0.47	中空、介孔结构	催化裂解	[30]
		TPAOH	63	313	0.28	介孔结构	异构化	[59]
		TPAOH	83	398.8	—	链长适当	CO₂加氢制芳烃	[58]
助剂辅助法	ZSM-5	TPAOH、PDDA	90	470	0.27	介孔结构	甲醇制烯烃	[22]
		TPAOH、PDDA	50	538.7	0.77	介孔结构	催化裂解	[23]
		TPAOH、蔗糖	136	397	0.36	介孔结构	甲基化	[24]
		TPAOH、SA	16~64	410	0.25	—	—	[25]
		TPAOH、乙醇	50	370.7	0.63	—	—	[36]
微波合成法	TS-1	TPAOH	70~230	423	0.21	长而直的孔道、较强的疏水性	吸附分离	[42]
		TPAOH	71	329	0.23	适当的酸性	环氧化	[40]
	ZSM-5	TPAOH	70~90	451	0.37	—	—	[45]

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