Research progress of charge polarized photocatalysts in photoconversion carbon dioxide into multi-carbon chemicals

doi:10.16085/j.issn.1000-6613.2023-2064

Abstract

Abstract:

Photosynthesis of high-value multi-carbon chemicals from carbon dioxide (CO₂) represents an exceptionally promising avenue for green technology development, offering a dual solution to the challenges of greenhouse gas accumulation and the looming energy crisis. Designing photocatalysts with charge-polarized active sites can effectively lower the energy barriers for C-C coupling reaction, which significantly boosts the selectivity and efficiency of multi-carbon chemical synthesis. This paper provides a comprehensive review of the latest advances in the photocatalytic reduction of CO₂ to C₂ chemicals, exploring the pivotal strategies for engineering charge asymmetry at active sites. It also elucidates the activity and selectivity of C₂ products regulatory mechanisms at the microscopic level influenced by charge polarization effects. This paper summarizes the most promising approach for the design and development of efficient photocatalysts, providing theoretical and practical guidance for the actual application of photocatalytic technology. Moving forward, it is imperative to concentrate on the precise control at the atomic level of catalysts, and to develop more efficient and specific multi-carbon product preparation systems, thereby supporting the low-carbon transformation of the energy industry structure.

Key words: carbon neutral, carbon dioxide, photocatalysis, C-C coupling reaction, charge polarization

摘要：

二氧化碳（CO₂）光合成高附加值多碳化学品是缓解温室效应和能源危机的极具前景的绿色发展新技术。设计具有电荷极化活性位点的光催化剂能够有效降低C-C偶联反应能垒，进而提高光合成多碳化学品催化选择性和活性。本文综述了光催化CO₂还原制C₂化学品的相关研究，深入研究电荷不对称位点构筑的主要策略，阐明微观层面上电荷极化效应对C₂产物活性和选择性的影响机制，总结出极具前景的高效光催化剂的设计与开发思路，为光催化技术的实际应用提供重要的理论和实践指导。展望未来，应更加注重催化剂在原子层面上的精准调控，开发出更高效、更专一的多碳产物制备系统，助力能源产业结构的低碳转型。

关键词: 碳中和, 二氧化碳, 光催化, C-C偶联反应, 电荷极化

CLC Number:

O643.36

XIE Zhongkai, SHI Weidong. Research progress of charge polarized photocatalysts in photoconversion carbon dioxide into multi-carbon chemicals[J]. Chemical Industry and Engineering Progress, 2024, 43(5): 2714-2722.

解仲凯, 施伟东. 电荷极化光催化剂光转化二氧化碳制多碳化学品的研究进展[J]. 化工进展, 2024, 43(5): 2714-2722.

Figures/Tables 8

References 59

4	JIANG Xiao, NIE Xiaowa, GUO Xinwen, et al. Recent advances in carbon dioxide hydrogenation to methanol via heterogeneous catalysis[J]. Chemical Reviews, 2020, 120(15): 7984-8034.
5	SHARMA Yogeshkumar, SINGH Bhaskar, UPADHYAY Siddhnath. Advancements in development and characterization of biodieset: A review[J]. Fuel, 2008, 87(12): 2355-2373.
6	KOSARI Mohammadreza, Alvin M H LIM, SHAO Yu, et al. Thermocatalytic CO₂ conversion by siliceous matter: A review[J]. Journal of Materials Chemistry A, 2023, 11(4): 1593-1633.
7	LU Tianrui, XU Ting, ZHU Shaojun, et al. Electrocatalytic CO₂ reduction to ethylene: From advanced catalyst design to industrial applications[J]. Advanced Materials, 2023, 35(52): e2310433.
8	SAKIMOTO Kelsey K, WONG Andrew Barnabas, YANG Peidong. Self-photosensitization of nonphotosynthetic bacteria for solar-to-chemical production[J]. Science, 2016, 351(6268): 74-77.
9	Inwhan ROH, YU Sunmoon, LIN Chung-Kuan, et al. Photoelectrochemical CO₂ reduction toward multicarbon products with silicon nanowire photocathodes interfaced with copper nanoparticles[J]. Journal of the American Chemical Society, 2022, 144(18): 8002-8006.
10	Honghui OU, LI Guosheng, REN Wei, et al. Atomically dispersed Au-assisted C-C coupling on red phosphorus for CO₂ photoreduction to C₂H₆ [J]. Journal of the American Chemical Society, 2022, 144(48): 22075-22082.
11	XIONG Xuyang, MAO Chengliang, YANG Zhaojun, et al. Photocatalytic CO₂ reduction to CO over Ni single atoms supported on defect-rich zirconia[J]. Advanced Energy Materials, 2020, 10(46): 2002928.
12	XU Jiaqi, JU Zhengyu, ZHANG Wei, et al. Efficient infrared-light-driven CO₂ reduction over ultrathin metallic Ni-doped CoS₂ nanosheets[J]. Angewandte Chemie International Edition, 2021, 60(16): 8705-8709.
13	WANG Xianyi, WANG Yingshuo, GAO Meichao, et al. BiVO₄/Bi₄Ti₃O₁₂ heterojunction enabling efficient photocatalytic reduction of CO₂ with H₂O to CH₃OH and CO[J]. Applied Catalysis B: Environmental, 2020, 270: 118876.
14	WANG Ying, SHANG Xiaotong, SHEN Jinni, et al. Direct and indirect Z-scheme heterostructure-coupled photosystem enabling cooperation of CO₂ reduction and H₂O oxidation[J]. Nature Communications, 2020, 11(1): 3043.
15	DOKANIA Abhay, RAMIREZ Adrian, BAVYKINA Anastasiya, et al. Heterogeneous catalysis for the valorization of CO₂: Role of bifunctional processes in the production of chemicals[J]. ACS Energy Letters, 2019, 4(1): 167-176.
16	MENG Dongli, ZHANG Mengdi, SI Duanhui, et al. Highly selective tandem electroreduction of CO₂ to ethylene over atomically isolated nickel-nitrogen site/copper nanoparticle catalysts[J]. Angewandte Chemie International Edition, 2021, 60(48): 25485-25492.
17	Kousik DAS, Risov DAS, RIYAZ Mohd, et al. Intrinsic charge polarization in Bi₁₉S₂₇Cl₃ nanorods promotes selective C-C coupling reaction during photoreduction of CO₂ to ethanol[J]. Advanced Materials, 2023, 35(5): 2205994.
18	SHI Hainan, WANG Haozhi, ZHOU Yichen, et al. Atomically dispersed indium-copper dual-metal active sites promoting C-C coupling for CO₂ photoreduction to ethanol[J]. Angewandte Chemie International Edition, 2022, 61(40): e202208904.
19	WANG Gang, HE Chunting, HUANG Rong, et al. Photoinduction of Cu single atoms decorated on UiO-66-NH₂ for enhanced photocatalytic reduction of CO₂ to liquid fuels[J]. Journal of the American Chemical Society, 2020, 142(45): 19339-19345.
20	ZHENG Tingting, JIANG Kun, Na TA, et al. Large-scale and highly selective CO₂ electrocatalytic reduction on nickel single-atom catalyst[J]. Joule, 2019, 3(1): 265-278.
21	FENG Manman, WU Xuemei, CHENG Huiyuan, et al. Well-defined Fe-Cu diatomic sites for efficient catalysis of CO₂ electroreduction[J]. Journal of Materials Chemistry A, 2021, 9(42): 23817-23827.
22	CHAKRABORTY Subhajit, Risov DAS, RIYAZ Mohd, et al. Wurtzite CuGaS₂ with an in-situ-formed CuO layer photocatalyzes CO₂ conversion to ethylene with high selectivity[J]. Angewandte Chemie International Edition, 2023, 62(9): e202216613.
23	WU Yang, HU Qinyuan, CHEN Qingxia, et al. Fundamentals and challenges of engineering charge polarized active sites for CO₂ photoreduction toward C₂ products[J]. Accounts of Chemical Research, 2023, 56(18): 2500-2513.
24	ALBERO Josep, PENG Yong, GARCIA Hermenegildo. Photocatalytic CO₂ reduction to C₂₊ products[J]. ACS Catalysis, 2020, 10(10): 5734-5749.
25	WU Yang, CHEN Qingxia, ZHU Juncheng, et al. Selective CO₂-to-C₂H₄photoconversion enabled by oxygen-mediated triatomic sites in partially oxidized bimetallic sulfide[J]. Angewandte Chemie International Edition, 2023, 62(15): 2301075.
26	SHAO Weiwei, LI Xiaodong, ZHU Juncheng, et al. Metal ⁿ ⁺-metal ^δ ⁺ pair sites steer C-C coupling for selective CO₂ photoreduction to C₂ hydrocarbons[J]. Nano Research, 2022, 15(3): 1882-1891.
27	WANG Gang, CHEN Zhe, WANG Tao, et al. P and Cu dual sites on graphitic carbon nitride for photocatalytic CO₂ reduction to hydrocarbon fuels with high C₂H₆ evolution[J]. Angewandte Chemie International Edition, 2022, 61(40): e202210789.
1	PETER Sebastian C. Reduction of CO₂ to chemicals and fuels: A solution to global warming and energy crisis[J]. ACS Energy Letters, 2018, 3(7): 1557-1561.
2	GAO Wanlin, LIANG Shuyu, WANG Rujie, et al. Industrial carbon dioxide capture and utilization: State of the art and future challenges[J]. Chemical Society Reviews, 2020, 49(23): 8584-8686.
3	ZHOU Yansong, WANG Zhitong, HUANG Lei, et al. Engineering 2D photocatalysts toward carbon dioxide reduction[J]. Advanced Energy Materials, 2021, 11(8): 2003159.
28	XIE Wenke, LI Kuangjun, LIU Xuanhe, et al. P-mediated Cu-N₄ sites in carbon nitride realizing CO₂ photoreduction to C₂H₄ with selectivity modulation[J]. Advanced Materials, 2023, 35(3): e2208132.
29	YU Hongjian, CHEN Fang, LI Xiaowei, et al. Synergy of ferroelectric polarization and oxygen vacancy to promote CO₂ photoreduction[J]. Nature Communications, 2021, 12(1): 4594.
30	CAO Yuehan, GUO Lan, DAN Meng, et al. Modulating electron density of vacancy site by single Au atom for effective CO₂ photoreduction[J]. Nature Communications, 2021, 12(1): 1675.
31	GAO Wa, LI Shi, HE Huichao, et al. Vacancy-defect modulated pathway of photoreduction of CO₂ on single atomically thin AgInP₂S₆ sheets into olefiant gas[J]. Nature Communications, 2021, 12(1): 4747.
32	WANG Junyan, YANG Chen, MAO Liang, et al. Regulating the metallic Cu-Ga bond by S vacancy for improved photocatalytic CO₂ reduction to C₂H₄ [J]. Advanced Functional Materials, 2023, 33(28): 2213901.
33	LU Changhai, LI Juan, YAN Jiahao, et al. Surface plasmon resonance and defects on tungsten oxides synergistically boost high-selective CO₂ reduction for ethylene[J]. Applied Materials Today, 2020, 20: 100744.
34	YU Yangyang, DONG Xing’an, CHEN Peng, et al. Synergistic effect of Cu single atoms and Au-Cu alloy nanoparticles on TiO₂ for efficient CO₂ photoreduction[J]. ACS Nano, 2021, 15(9): 14453-14464.
35	YU Yangyang, HE Ye, YAN Ping, et al. Boosted C-C coupling with Cu-Ag alloy sub-nanoclusters for CO₂-to-C₂H₄ photosynthesis[J]. Proceedings of the National Academy of Sciences of the United States of America, 2023, 120(44): e2307320120.
36	SORCAR Saurav, HWANG Yunju, LEE Jaewoong, et al. CO₂, water, and sunlight to hydrocarbon fuels: A sustained sunlight to fuel (Joule-to-Joule) photoconversion efficiency of 1%[J]. Energy & Environmental Science, 2019, 12(9): 2685-2696.
37	ZENG Di, WANG Haipeng, ZHU Xiaodi, et al. Photocatalytic conversion of CO₂ to acetic acid by CuPt/WO₃: Chloride enhanced C-C coupling mechanism[J]. Applied Catalysis B: Environmental, 2023, 323: 122177.
38	GONG Shuaiqi, NI Baoxin, HE Xiaoyang, et al. Electronic modulation of a single-atom-based tandem catalyst boosts CO₂ photoreduction to ethanol[J]. Energy & Environmental Science, 2023, 16(12): 5956-5969.
39	WANG Ting, CHEN Liang, CHEN Cong, et al. Engineering catalytic interfaces in Cu ^δ ⁺/CeO₂-TiO₂ photocatalysts for synergistically boosting CO₂ reduction to ethylene[J]. ACS Nano, 2022, 16(2): 2306-2318.
40	WANG Wei, DENG Chaoyuan, XIE Shijie, et al. Photocatalytic C-C coupling from carbon dioxide reduction on copper oxide with mixed-valence copper(Ⅰ)/copper(Ⅱ)[J]. Journal of the American Chemical Society, 2021, 143(7): 2984-2993.
41	GONG Shuaiqi, NIU Yanli, LIU Xuan, et al. Selective CO₂ photoreduction to acetate at asymmetric ternary bridging sites[J]. ACS Nano, 2023, 17(5): 4922-4932.
42	Risov DAS, PAUL Ratul, PARUI Arko, et al. Engineering the charge density on an In_2.77S₄/porous organic polymer hybrid photocatalyst for CO₂-to-ethylene conversion reaction[J]. Journal of the American Chemical Society, 2023, 145(1): 422-435.
43	YAN Ke, WU Donghai, WANG Ting, et al. Highly selective ethylene production from solar-driven CO₂ reduction on the Bi₂S₃@In₂S₃ catalyst with In-S_V-Bi active sites[J]. ACS Catalysis, 2023, 13(4): 2302-2312.
44	DI Jun, ZHU Xingwang, HAO Gazi, et al. Vacancy pair-induced charge rebalancing with surface and interfacial dual polarization for CO₂ photoreduction[J]. ACS Catalysis, 2022, 12(24): 15728-15736.
45	DI Jun, CHEN Chao, ZHU Chao, et al. Surface local polarization induced by bismuth-oxygen vacancy pairs tuning non-covalent interaction for CO₂ photoreduction[J]. Advanced Energy Materials, 2021, 11(41): 2102389.
46	WANG Yinghui, HU Jingcong, GE Teng, et al. Gradient cationic vacancies enabling inner-to-outer tandem homojunctions: Strong local internal electric field and reformed basic sites boosting CO₂ photoreduction[J]. Advanced Materials, 2023, 35(31): e2302538.
47	SHI Xian, DAI Weidong, DONG Xing’an, et al. Dual Cu and S vacancies boost CO₂ photomethanation on Cu_1.95S_1- _x : Vacancy-regulated selective photocatalysis[J]. Applied Catalysis B: Environmental, 2023, 339: 123147.
48	WANG Jin, XIA Tong, WANG Lei, et al. Enabling visible-light-driven selective CO₂ reduction by doping quantum dots: Trapping electrons and suppressing H₂ evolution[J]. Angewandte Chemie International Edition, 2018, 57(50): 16447-16451.
49	LIN Cheng-Chieh, LIU Tingran, LIN Sin-Rong, et al. Spin-polarized photocatalytic CO₂ reduction of Mn-doped perovskite nanoplates[J]. Journal of the American Chemical Society, 2022, 144(34): 15718-15726.
50	FENG Shuaijun, ZHAO Jie, BAI Yujie, et al. Facile synthesis of Mo-doped TiO₂ for selective photocatalytic CO₂ reduction to methane: Promoted H₂O dissociation by Mo doping[J]. Journal of CO₂ Utilization, 2020, 38: 1-9.
51	WANG Yiqiao, XIE Yu, YU Shuohan, et al. Ni doping in unit cell of BiOBr to increase dipole moment and induce spin polarization for promoting CO₂ photoreduction via enhanced build-in electric field[J]. Applied Catalysis B: Environmental, 2023, 327: 122420.
52	WEI Yuechang, WU Xingxing, ZHAO Yilong, et al. Efficient photocatalysts of TiO₂ nanocrystals-supported PtRu alloy nanoparticles for CO₂ reduction with H₂O: Synergistic effect of Pt-Ru[J]. Applied Catalysis B: Environmental, 2018, 236: 445-457.
53	YIN Shikang, LIU Yun, ZHOU Weiqiang, et al. Nanocluster-mediated electron-hole separation for efficient CO₂ photoreduction[J]. Chemical Engineering Journal, 2023, 477: 147292.
54	LIU Qian, CHEN Qin, LI Tianyu, et al. Vacancy engineering of AuCu cocatalysts for improving the photocatalytic conversion of CO₂ to CH₄ [J]. Journal of Materials Chemistry A, 2019, 7(47): 27007-27015.
55	LONG Ran, LI Yu, LIU Yan, et al. Isolation of Cu atoms in Pd lattice: Forming highly selective sites for photocatalytic conversion of CO₂ to CH₄ [J]. Journal of the American Chemical Society, 2017, 139(12): 4486-4492.
56	ZHU Yuzhen, XU Zaixiang, JIANG Wenya, et al. Engineering on the edge of Pd nanosheet cocatalysts for enhanced photocatalytic reduction of CO₂ to fuels[J]. Journal of Materials Chemistry A, 2017, 5(6): 2619-2628.
57	WANG Rui, SHEN Jun, SUN Kouhua, et al. Enhancement in photocatalytic activity of CO₂ reduction to CH₄ by 0D/2D Au/TiO₂ plasmon heterojunction[J]. Applied Surface Science, 2019, 493: 1142-1149.
58	LIU Zhiguo, CHEN Ziyu, LI Mingyang, et al. Construction of single Ni atom-immobilized ZIF-8 with ordered hierarchical pore structures for selective CO₂ photoreduction[J]. ACS Catalysis, 2023, 13(10): 6630-6640.
59	MA Zhentao, WANG Qingyu, LIU Limin, et al. Low-coordination environment design of single Co atoms for efficient CO₂ photoreduction[J]. Nano Research, 2024. 17(5): 3745-3751.

光催化剂	光催化测试条件	光源及光强	C₂化学品产率/μmol·g^-1·h^-1	参考文献
Au₁/RP	50mg光催化剂，0.5g KHCO₃, 1~2mL 6mol/L的HCl	300W氙灯，300mW·cm^-2	1.32 (C₂H₆)	[10]
Bi₁₉S₂₇Cl₃	10mg光催化剂，20mL水，0.4mg Na₂S，2.9mg Na₂SO₃，CO₂	420W氙灯，未提及光强	5.19 (CH₃CH₂OH)	[17]
Cu SAs/UiO-66-NH₂	100mg光催化剂，50mL水，100µL TEOA，100kPa CO₂	300W氙灯，未提及光强	4.22 (CH₃CH₂OH)	[19]
Co-doped NiS₂	10mg光催化剂，10kPa CO₂	300W氙灯，100mW·cm^-2	2.3 (C₂H₄)	[26]
P/Cu SAs@CN	0.5mg光催化剂，25mL水，3.0mL TEOA，65kPa CO₂	300W氙灯，未提及光强	616.6 (C₂H₆)	[27]
CuACs/PCNs	5mg光催化剂，45mL水，5mL TEOA，100kPa CO₂，C₃₀H₂₄Cl₂N₆Ru·6H₂O	300W氙灯，未提及光强	10.2 (C₂H₄)	[28]
WO_3-_x -2	5mg光催化剂，0.2mL水，100kPa CO₂	300W氙灯，未提及光强	61.6 (C₂H₄)	[33]
CuO _X @p-ZnO	5mg光催化剂，水，50kPa CO₂	300W氙灯，100mW·cm^-2	2.7 (C₂H₄)	[40]
In_2.77S₄(P6)	3mg光催化剂，20mL水，100kPa CO₂	300W氙灯，110mW·cm^-2	67.65 (C₂H₄)	[42]

光催化剂	光催化测试条件	光源及光强	C₂化学品产率/μmol·g^-1·h^-1	参考文献
Au₁/RP	50mg光催化剂，0.5g KHCO₃, 1~2mL 6mol/L的HCl	300W氙灯，300mW·cm^-2	1.32 (C₂H₆)	[10]
Bi₁₉S₂₇Cl₃	10mg光催化剂，20mL水，0.4mg Na₂S，2.9mg Na₂SO₃，CO₂	420W氙灯，未提及光强	5.19 (CH₃CH₂OH)	[17]
Cu SAs/UiO-66-NH₂	100mg光催化剂，50mL水，100µL TEOA，100kPa CO₂	300W氙灯，未提及光强	4.22 (CH₃CH₂OH)	[19]
Co-doped NiS₂	10mg光催化剂，10kPa CO₂	300W氙灯，100mW·cm^-2	2.3 (C₂H₄)	[26]
P/Cu SAs@CN	0.5mg光催化剂，25mL水，3.0mL TEOA，65kPa CO₂	300W氙灯，未提及光强	616.6 (C₂H₆)	[27]
CuACs/PCNs	5mg光催化剂，45mL水，5mL TEOA，100kPa CO₂，C₃₀H₂₄Cl₂N₆Ru·6H₂O	300W氙灯，未提及光强	10.2 (C₂H₄)	[28]
WO_3-_x -2	5mg光催化剂，0.2mL水，100kPa CO₂	300W氙灯，未提及光强	61.6 (C₂H₄)	[33]
CuO _X @p-ZnO	5mg光催化剂，水，50kPa CO₂	300W氙灯，100mW·cm^-2	2.7 (C₂H₄)	[40]
In_2.77S₄(P6)	3mg光催化剂，20mL水，100kPa CO₂	300W氙灯，110mW·cm^-2	67.65 (C₂H₄)	[42]

光催化剂	光催化测试条件	光源及光强	C₂化学品产率/μmol·g^-1·h^-1	参考文献
InCu/PCN	50mg光催化剂，3mL水，21mL DMF，80kPa CO₂	300W氙灯，1000mW·cm^-2	28.5 (CH₃CH₂OH)	[18]
CuGaS₂	5mg光催化剂，20mL水，100kPa CO₂，pH=12	450W氙灯，未提及光强	20.6 (C₂H₄)	[22]
FeCoS₂	10mg光催化剂，100kPa CO₂	300W氙灯，100mW·cm^-2	20.1 (C₂H₄)	[25]
V_S-AgInP₂S₆	4~5mg光催化剂，0.4mL水，100kPa CO₂	300W氙灯，未提及光强	44.3 (C₂H₄)	[31]
CuGaS₂/Ga₂S₃	20mg光催化剂，3mL水，TEOA，70kPa CO₂	300W氙灯，未提及光强	335.7 (C₂H₄)	[32]
Cu_0.8Au_0.2/TiO₂	2.0mg光催化剂，0.15mL水，90kPa CO₂	300W氙灯，500mW·cm^-2	369.8 (C₂H₄)	[34]
Cu_0.8Ag_0.2/TiO₂	2.0mg光催化剂，0.15mL水，90kPa CO₂	300W氙灯，500mW·cm^-2	1110.6 (C₂H₄)	[35]
Pt_0.35%-Cu_1.00%-BT	40mg光催化剂，水，CO₂	300W氙灯，100mW·cm^-2	25 (C₂H₆)	[36]
CuPt/WO₃	40mg光催化剂，20mL水，HCl，90kPa CO₂	300W氙灯，未提及光强	19.41 (CH₃COOH)	[37]
In₂O₃/Cu-O₃	10mg光催化剂，10mL水，CO₂	300W氙灯，未提及光强	20.7 (CH₃CH₂OH)	[38]
Cu ^δ⁺/CeO₂-TiO₂	10mg光催化剂，30mL水，100kPa CO₂	300W氙灯，200mW·cm^-2	4.51 (C₂H₄)	[39]
r-In₂O₃/InP	50mg光催化剂，100mL水，80kPa CO₂	300W氙灯，未提及光强	9.67 (CH₃COOH)	[41]
Bi₂S₃@In₂S₃	5mg光催化剂，1mL水，100kPa CO₂	300W氙灯，1150mW·cm^-2	11.81 (C₂H₄)	[43]

光催化剂	光催化测试条件	光源及光强	C₂化学品产率/μmol·g^-1·h^-1	参考文献
InCu/PCN	50mg光催化剂，3mL水，21mL DMF，80kPa CO₂	300W氙灯，1000mW·cm^-2	28.5 (CH₃CH₂OH)	[18]
CuGaS₂	5mg光催化剂，20mL水，100kPa CO₂，pH=12	450W氙灯，未提及光强	20.6 (C₂H₄)	[22]
FeCoS₂	10mg光催化剂，100kPa CO₂	300W氙灯，100mW·cm^-2	20.1 (C₂H₄)	[25]
V_S-AgInP₂S₆	4~5mg光催化剂，0.4mL水，100kPa CO₂	300W氙灯，未提及光强	44.3 (C₂H₄)	[31]
CuGaS₂/Ga₂S₃	20mg光催化剂，3mL水，TEOA，70kPa CO₂	300W氙灯，未提及光强	335.7 (C₂H₄)	[32]
Cu_0.8Au_0.2/TiO₂	2.0mg光催化剂，0.15mL水，90kPa CO₂	300W氙灯，500mW·cm^-2	369.8 (C₂H₄)	[34]
Cu_0.8Ag_0.2/TiO₂	2.0mg光催化剂，0.15mL水，90kPa CO₂	300W氙灯，500mW·cm^-2	1110.6 (C₂H₄)	[35]
Pt_0.35%-Cu_1.00%-BT	40mg光催化剂，水，CO₂	300W氙灯，100mW·cm^-2	25 (C₂H₆)	[36]
CuPt/WO₃	40mg光催化剂，20mL水，HCl，90kPa CO₂	300W氙灯，未提及光强	19.41 (CH₃COOH)	[37]
In₂O₃/Cu-O₃	10mg光催化剂，10mL水，CO₂	300W氙灯，未提及光强	20.7 (CH₃CH₂OH)	[38]
Cu ^δ⁺/CeO₂-TiO₂	10mg光催化剂，30mL水，100kPa CO₂	300W氙灯，200mW·cm^-2	4.51 (C₂H₄)	[39]
r-In₂O₃/InP	50mg光催化剂，100mL水，80kPa CO₂	300W氙灯，未提及光强	9.67 (CH₃COOH)	[41]
Bi₂S₃@In₂S₃	5mg光催化剂，1mL水，100kPa CO₂	300W氙灯，1150mW·cm^-2	11.81 (C₂H₄)	[43]

光催化剂	光催化测试条件	光源及光强	C₁化学品产率/μmol·g^-1·h^-1	参考文献
BP-Bi₂₄O₃₁Br₁₀	30mg光催化剂，50mL水，80kPa CO₂	300W氙灯，未提及光强	39.8 (CO)	[44]
V_BiO-Bi₂₄O₃₁Br₁₀	30mg光催化剂，50mL水，80kPa CO₂	300W氙灯，300mW·cm^-2	24.9 (CO)	[45]
V_W-Bi₂WO₆	10mg光催化剂，1.7g NaHCO₃，15mL 4mol/L的H₂SO₄	300W氙灯，未提及光强	30.62 (CO)	[46]
Cu_1.95S_1-_x	10mg光催化剂，10mL水，100kPa CO₂	300W氙灯，未提及光强	13.63 (CH₄)	[47]
Ni:CdS	催化剂，5mL水，1mL三乙醇胺，100kPa CO₂	300W氙灯，未提及光强	9.5 (CO)	[48]
Mn-CsPbBr₃	2mg光催化剂，10mL水，100kPa CO₂	300W氙灯，100mW·cm^-2	45.4 (CO)/约3.5 (CH₄)	[49]
Mo/TiO₂	光催化剂，20uL水，20mL CO₂	300W氙灯，未提及光强	8.2 (CO)/约9.8 (CH₄)	[50]
Ni-BiOBr	5mg光催化剂，1mL水，5mg [Ru(bpy)₃]Cl₂·6H₂O，1mL三乙醇胺，4mL CH₃CN，100kPa CO₂	300W氙灯，未提及光强	378.7 (CO) μ	[51]
PtRu/TiO₂	100mg光催化剂，2mL水，CO₂	300W氙灯，80mW·cm^-2	38.7 (CH₄)	[52]
SnS₂/Pt₃Co	20mg光催化剂，100mL水，140kPa CO₂	300W氙灯，未提及光强	27.34 (CO)/约14.02 (CH₄)	[53]
TiO₂-AuCu-V	15mg光催化剂，1mL水，150kPa CO₂	300W氙灯，未提及光强	3.4 (CO)/约33.5 (CH₄)	[54]
Pd₇Cu₁-TiO₂	5mg光催化剂，1mL水，200kPa CO₂	300W氙灯，未提及光强	19.6 (CH₄)	[55]
TiO₂-Pd	15mg光催化剂，2mL水，150kPa CO₂	300W氙灯，未提及光强	12.6 (CO)/约3.0 (CH₄)	[56]
Au-TiO₂	50mg光催化剂，0.084g NaHCO₃，0.6mL 4mol/L的HCl	300W氙灯，未提及光强	70.34 (CO)/约19.75 (CH₄)	[57]
Ni/SOM-ZIF-8	3mg光催化剂，2mL水，10mg [Ru(bpy)₃]Cl₂·6H₂O，2mL三乙醇胺，6mL CH₃CN，100kPa CO₂	300W氙灯，未提及光强	4.2 (CO) mmol/(g·h)	[58]
Co₁/ZnO	1mg光催化剂，4mL水，10mg [Ru(bpy)₃]Cl₂·6H₂O，4mL三乙醇胺，16mL CH₃CN，100kPa CO₂	300W氙灯，未提及光强	22.5 (CO) mmol/(g·h)	[59]