Catalytic hydrogenation of carbonate minerals: A promising pathway to carbon neutrality for industries with intensive carbon emissions

doi:10.16085/j.issn.1000-6613.2024-0783

Abstract

Abstract:

Intensive carbon emissions and energy consumptions are the technical bottleneck for sustainable developments of traditional industries, such as the cement, steel and metallurgy, which are mainly caused by the thermal decomposition of various carbonate minerals. The technology of hydrogen-driven carbonate catalytic reduction integrates metal oxide production and high-value-added conversion of carbon resources processes to overturn the inevitable CO₂ emission in conventional thermal decomposition pathway. In this process, the resource of hydrogen can be widely referred to various hydrogen donors (e.g., H₂, alkane or other substances containing hydrogen), and the high-value-added products can be C₁-products or C₂₊ hydrocarbon, thus significantly reducing the overall costs of the reduction of carbon emissions. Furthermore, the novel technology was expected to provide technical supports for the goal of carbon neutrality in intensive-carbon-emission industrial sectors using carbonate minerals as raw materials. This review presented the developments and progresses of the carbonate hydrogenation technology. Along with the clue of various value-added products, the characteristics of processes, reaction mechanisms, catalysts design and the key bottlenecks of the technologies were introduced, respectively. Based on the analysis of state-of-the-art works of catalytic carbonate hydrogenation, the challenges as well as the potential applications of the technologies in these energy-intensive industries with carbonate minerals as raw materials were proposed, which provided promising new pathways for carbon neutrality.

Key words: carbon neutrality, carbonate minerals, hydrogenation, catalysis, reduction of CO₂ emission

摘要：

碳酸盐矿物高温炼制过程高碳排和高能耗是建材、钢铁、有色冶金等传统工业发展面临的巨大挑战，碳酸盐催化加氢转化技术通过将金属氧化物的生产过程与碳资源的高附加值转化过程耦合，有望从生产源头颠覆传统碳酸盐热分解必产二氧化碳的途径。在该过程中，利用供氢分子（如氢气、低碳烷烃、液态有机富含氢物质等）直接将碳酸盐矿物中的碳物种原位转化为高值含碳化学品，从而有望大幅降低减排成本，有望成为基于碳酸盐矿物为原料的高碳排工业“碳中和”创新技术。本文以碳酸盐催化加氢转化技术制备不同产品为出发点，从过程特点、反应机理、催化剂设计和关键技术瓶颈等方面进行了综述，分析了碳酸盐加氢转化技术制备不同产品的研究现状和现存问题；结合近期关于碳酸盐催化加氢的最新研究进展，提出了基于碳酸盐矿物原料加氢转化在建材、钢铁、耐材等重排放工业过程碳减排的应用展望，为实现CO₂的高效转化和减排增效提供了思路。

关键词: 碳中和, 碳酸盐矿物, 加氢, 催化, 二氧化碳减排

CLC Number:

TQ115

SHAO Bin, LI Su, MA Rongting, XIE Zhicheng, GAO Zihao, JIA Zhonghao, WANG Wenhui, SUN Zheyi, HU Jun. Catalytic hydrogenation of carbonate minerals: A promising pathway to carbon neutrality for industries with intensive carbon emissions[J]. Chemical Industry and Engineering Progress, 2024, 43(11): 5995-6009.

邵斌, 栗粟, 马榕廷, 谢志成, 高梓皓, 贾中昊, 王文慧, 孙哲毅, 胡军. 高碳排工业“碳中和”潜在途径[J]. 化工进展, 2024, 43(11): 5995-6009.

Figures/Tables 10

References 79

1	张锁江, 张香平, 葛蔚, 等. 工业过程绿色低碳技术[J]. 中国科学院院刊, 2022, 37(4): 511-521.
	ZHANG Suojiang, ZHANG Xiangping, GE Wei, et al. Carbon neutral transformative technologies for industrial process[J]. Bulletin of Chinese Academy of Sciences, 2022, 37(4): 511-521.
2	LIU Zhu, DENG Zhu, HE Gang, et al. Challenges and opportunities for carbon neutrality in China[J]. Nature Reviews Earth and Environment, 2022, 3(2): 141-155.
3	HAN Rui, WANG Yang, XING Shuang, et al. Progress in reducing calcination reaction temperature of calcium-looping CO₂ capture technology: A critical review[J]. Chemical Engineering Journal, 2022, 450: 137952.
4	NHUCHHEN Daya R, Song P SIT, LAYZELL David B. Decarbonization of cement production in a hydrogen economy[J]. Applied Energy, 2022, 317: 119180.
5	FENNELL Paul S, DAVIS Steven J, MOHAMMED Aseel. Decarbonizing cement production[J]. Joule, 2021, 5(6): 1305-1311.
6	FAN Jingli, LI Zezheng, HUANG Xi, et al. A net-zero emissions strategy for China’s power sector using carbon-capture utilization and storage[J]. Nature Communications, 2023, 14: 5972.
7	邵斌, 孙哲毅, 章云, 等. 二氧化碳转化为合成气及高附加值产品的研究进展[J]. 化工进展, 2022, 41(3): 1136-1151.
	SHAO Bin, SUN Zheyi, ZHANG Yun, et al. Recent progresses in CO₂ to syngas and high value-added products[J]. Chemical Industry and Engineering Progress, 2022, 41(3): 1136-1151.
8	周红军, 周颖, 徐春明. 中国碳中和目标下CO₂转化的思考与实践[J]. 化工进展, 2022, 41(6): 3381-3385.
	ZHOU Hongjun, ZHOU Ying, XU Chunming. Exploration of the CO₂ conversion under China’s carbon neutrality goal[J]. Chemical Industry and Engineering Progress, 2022, 41(6): 3381-3385.
9	CASTELVECCHI Davide. How the hydrogen revolution can help save the planet-and how it can’t[J]. Nature, 2022, 611: 440-443.
10	自然资源保护协会（NRDC）. 面向碳中和的氢冶金发展战略研究[R].
	(2023-06-25). .
	The Natural Resources Defense Council(NRDC).Research on the development strategy of hydrogen metallurgy for carbon neutrality[R]. (2023-06-25). http://www.nrdc.cn/Public/uploads/2023-06-25/6497aa6685787.pdf.
11	United States Department of Energy (DOE), Industrial decarbonization of energy intensive sector[R]. (2022-09-12). https://www.energy.gov/eere/amo/articles/industrial-decarbonization-energy-intensive-sectors.
12	GIARDINI A A, SALOTTI C A, LAKNER J F. Synthesis of graphite and hydrocarbons by reaction between calcite and hydrogen[J]. Science, 1968, 159(3812): 317-319.
13	RELLER A, PADESTE C, HUG P. Formation of organic carbon compounds from metal carbonates[J]. Nature, 1987, 329: 527-529.
14	SUN Shuzhuang, CHEN Zheng, XU Yikai, et al. Potassium-promoted limestone for preferential direct hydrogenation of carbonates in integrated CO₂ capture and utilization[J]. JACS Au, 2023, 4(1): 72-79.
15	SUN Shuzhuang, WANG Yuanyuan, ZHAO Xiaotong, et al. One step upcycling CO₂ from flue gas into CO using natural stone in an integrated CO₂ capture and utilisation system[J]. Carbon Capture Science & Technology, 2022, 5: 100078.
16	SHAO Bin, ZHU Yuanming, HU Jun, et al. Chemical engineering solution for carbon neutrality in cement industry: Tailor a pathway from inevitable CO₂ emission into syngas[J]. Chemical Engineering Journal, 2024, 483: 149098.
17	WANG Iwei, LI Dan, WANG Shihui, et al. Limestone hydrogenation combined with reverse water-gas shift reaction under fluidized and iso-thermal conditions using MFB-TGA-MS[J]. Chemical Engineering Journal, 2023, 472: 144822.
18	徐明, 邵明飞, 刘清雅, 等. 电解水制氢耦合碳酸盐还原展望[J]. 化工进展, 2022, 41(3): 1121-1124.
	XU Ming, SHAO Mingfei, LIU Qingya, et al. Hydrogen generation from electrochemical water splitting coupling carbonate reduction[J]. Chemical Industry and Engineering Progress, 2022, 41(3): 1121-1124.
19	HALMANN M, STEINFELD A. Thermoneutral coproduction of calcium oxide and syngas by combined decomposition of calcium carbonate and partial oxidation/CO₂-reforming of methane[J]. Energy & Fuels, 2003, 17(3): 774-778.
20	STEINFELD A. Solar combined thermochemical processes for CO₂ mitigation in the iron, cement, and syngas industries[J]. Energy, 1994, 19(10): 1077-1081.
21	尹倩, 宋慧婷, 徐明, 等. 碳酸盐炼制共热耦合甲烷干重整制高附加值化学品发展展望[J]. 物理化学学报, 2023, 39(3): 7-15.
	YIN Qian, SONG Huiting, XU Ming, et al. Thermal decomposition of carbonates coupled with dry reforming of methane to synthesize high-value products: A perspective[J]. Acta Physico-Chimica Sinica, 2023, 39(3): 7-15.
22	JIANG Peng, LI Lin, ZHAO Guanhan, et al. Reductive calcination of calcium carbonate in hydrogen and methane: A thermodynamic analysis on different reaction routes and evaluation of carbon dioxide mitigation potential[J]. Chemical Engineering Science, 2023, 276: 118823.
23	SAEIDI Samrand, NAJARI Sara, HESSEL Volker, et al. Recent advances in CO₂ hydrogenation to value-added products—Current challenges and future directions[J]. Progress in Energy and Combustion Science, 2021, 85: 100905.
24	LUX S, BALDAUF-Sommerbauer G, SIEBENHOFER M. Hydrogenation of inorganic metal carbonates: A review on its potential for carbon dioxide utilization and emission reduction[J]. ChemSusChem, 2018, 11(19): 3357-3375.
25	Georg BALDAUF-SOMMERBAUER, Susanne LUX, ANISER Wolfgang, et al. Reductive calcination of mineral magnesite: Hydrogenation of carbon dioxide without catalysts[J]. Chemical Engineering & Technology, 2016, 39(11): 2035-2041.
26	SHI Sulong, YU Jiachen, PAN Yue, et al. Hydrogenation of calcium carbonate to carbon monoxide and methane[J]. Fuel, 2023, 354: 129385.
27	JAGADEESAN D, ESWARAMOORTHY M, RAO C N R. Investigations of the conversion of inorganic carbonates to Methane[J]. ChemSusChem. 2009, 2(9): 878-882.
28	YOSHIDA Noritetsu, HATTORI Takeshi, KOMAI Eiji, et al. Methane formation by metal-catalyzed hydrogenation of solid calcium carbonate[J]. Catalysis Letters, 1999, 58(2): 119-122.
29	LV Zongze, DENG Tao, GAO Chang, et al. Promotion of active H-assisted CaCO₃ conversion for integrated CO₂ capture and methanation[J]. Chemical Engineering Journal, 2024, 489: 151427.
30	MESTERS Carl, RAHIMI Nazanin, VAN DER SLOOT Dennis, et al. Direct reduction of magnesium carbonate to methane[J]. ACS Sustainable Chemistry & Engineering, 2021, 9(33): 10977-10989.
31	GIARDINI A A, SALOTTI C A. Kinetics and relations in the calcite-hydrogen reaction and relations in the dolomite-hydrogen and siderite-hydrogen systems[J]. 1969, 54(7/8): 1151-1172.
32	TSUNETO Akira, KUDO Akihiko, SAITO Nobuhiro, et al. Hydrogenation of solid state carbonates[J]. Chemistry Letters, 1992, 21(5): 831-834.
33	SHEN Tao, WU Jiawen, LIU Qingya, et al. Hydrogenation of CaCO₃ for methane by a liquid organic hydrogen carrier in the presence of the catalyst precursor NiCO₃ [J]. Industrial & Engineering Chemistry Research, 2023, 62(27): 10721-10728.
34	GUNASEKAR Gunniya Hariyanandam, PARK Kwangho, JUNG Kwang-Deog, et al. Recent developments in the catalytic hydrogenation of CO₂ to formic acid/formate using heterogeneous catalysts[J]. Inorganic Chemistry Frontiers, 2016, 3(7): 882-895.
35	YOUNAS Mohammad, REZAKAZEMI Mashallah, ARBAB Muhammad Saddique, et al. Green hydrogen storage and delivery: Utilizing highly active homogeneous and heterogeneous catalysts for formic acid dehydrogenation[J]. International Journal of Hydrogen Energy, 2022, 47(22): 11694-11724.
36	AINEMBABAZI Diana, WANG Kai, FINN Matthew, et al. Efficient transfer hydrogenation of carbonate salts from glycerol using water-soluble iridium N-heterocyclic carbene catalysts[J]. Green Chemistry, 2020, 22(18): 6093-6104.
37	WEI Duo, SHI Xinzhe, Sponholz Peter, et al. Manganese promoted (Bi)carbonate hydrogenation and formate dehydrogenation: Toward a circular carbon and hydrogen economy[J]. ACS Central Science, 2022, 8(10): 1457-1463.
38	COUFOURIER S, GAILLARD S, CLET G, et al. A MOF-assisted phosphine free bifunctional iron complex for the hydrogenation of carbon dioxide, sodium bicarbonate and carbonate to formate[J]. Chemical Communications, 2019, 55(34): 4977-4980.
39	WANG Tian, REN Dezhang, HUO Zhibao, et al. A nanoporous nickel catalyst for selective hydrogenation of carbonates into formic acid in water[J]. Green Chemistry, 2017, 19(3): 716-721.
40	ZHANG Xiaochen, LI Aowen, TANG Haoyi, et al. Carbonate hydrogenated to formate in the aqueous phase over nickel/TiO₂ catalysts[J]. Angewandte Chemie International Edition, 2023, 62(41): e202307061.
41	LIANG Xuan, WANG Meng, MA Ding. One-pot conversion of polyester and carbonate into formate without external H₂ [J]. Journal of the American Chemical Society, 2024, 146(4): 2711-2717.
42	WANG Yixuan, BAN Hongyan, WANG Yugao, et al. Unraveling the role of basic sites in the hydrogenation of CO₂ to formic acid over Ni-based catalysts[J]. Journal of Catalysis, 2024, 430: 115357.
43	MAHDI Hilman Ibnu, RAMLEE Nurfadhila Nasya, DA SILVA SANTOS Danilo Henrique, et al. Formaldehyde production using methanol and heterogeneous solid catalysts: A comprehensive review[J]. Molecular Catalysis, 2023, 537: 112944.
44	KALCK Philippe, LE BERRE Carole, SERP Philippe. Recent advances in the methanol carbonylation reaction into acetic acid[J]. Coordination Chemistry Reviews, 2020, 402: 213078.
45	SUN Jian, YANG Guohui, YONEYAMA Yoshiharu, et al. Catalysis chemistry of dimethyl ether synthesis[J]. ACS Catalysis, 2014, 4(10): 3346-3356.
46	TIAN Peng, WEI Yingxu, YE Mao, et al. Methanol to olefins (MTO): From fundamentals to commercialization[J]. ACS Catalysis, 2015, 5(3): 1922-1938.
47	LI Teng, SHOINKHOROVA Tuiana, GASCON Jorge, et al. Aromatics production via methanol-mediated transformation routes[J]. ACS Catalysis, 2021, 11(13): 7780-7819.
48	周芳, 曾纪龙, 姜波. 气和煤合成甲醇的原料路线探讨[J]. 化工设计, 2011, 21(5): 3-6.
	ZHOU Fang, ZENG Jilong, JIANG Bo, et al. Probe on feedstock route of methanol production from natural gas and coal[J]. Chemical Engineering Design, 2011, 21(5): 3-6.
49	PONTZEN Florian, LIEBNER Waldemar, GRONEMANN Veronika, et al. CO₂-based methanol and DME-Efficient technologies for industrial scale production[J]. Catalysis Today, 2011, 171(1): 242-250.
50	G K Surya PRAKASH, OLAH George A, GOEPPERT Alain. Beyond oil and gas: The methanol economy[J]. ECS Transactions, 2011, 35(11): 31-40.
51	NEBEL Bernd A, BREUER Michael, SCHNEIDER Andreas, et al. A career in catalysis: Bernhard hauer[J]. ACS Catalysis, 2023, 13(13): 8861-8889.
52	JIANG Xiao, NIE Xiaowa, GUO Xinwen, et al. Recent advances in carbon dioxide hydrogenation to methanol via heterogeneous catalysis[J]. Chemical Reviews, 2020, 120(15): 7984-8034.
53	WANG Mengheng, ZHENG Lanling, WANG Genyuan, et al. Spinel nanostructures for the hydrogenation of CO₂ to methanol and hydrocarbon chemicals[J]. Journal of the American Chemical Society, 2024, 146(21): 14528-14538.
54	RUI Ning, ZHANG Feng, SUN Kaihang, et al. Hydrogenation of CO₂ to methanol on a Au ^δ ⁺-In₂O₃-x catalyst[J]. ACS Catalysis 2020, 10 (19): 11307-11317.
55	SUN Kaihang, ZHANG Zhitao, SHEN Chenyang, et al. The feasibility study of the indium oxide supported silver catalyst for selective hydrogenation of CO₂ to methanol[J]. Green Energy & Environment, 2022, 7(4): 807-817.
56	RUI Ning, WANG Zongyuan, SUN Kaihang, et al. CO₂ hydrogenation to methanol over Pd/In₂O₃: Effects of Pd and oxygen vacancy[J]. Applied Catalysis B: Environmental, 2017, 218: 488-497.
57	SHEN Chenyang, SUN Kaihang, ZOU Rui, et al. CO₂ hydrogenation to methanol on indium oxide-supported rhenium catalysts: The effects of size[J]. ACS Catalysis, 2022, 12(20): 12658-12669.
58	WIRNER Luca C, KOSAKA Fumihiko, SASAYAMA Tomone, et al. Combined capture and reduction of CO₂ to methanol using a dual-bed packed reactor[J]. Chemical Engineering Journal, 2023, 470: 144227.
59	Chae JEONG-POTTER, ARELLANO-TREVIÑO Martha A, Wilson MCNEARY W, et al. Modified Cu-Zn-Al mixed oxide dual function materials enable reactive carbon capture to methanol[J]. EES Catalysis, 2024, 2(1): 253-261.
60	何聂燕，李学琴，刘鹏，等. 二氧化碳加氢合成甲醇技术现状及催化剂研究进展[J/OL]. 洁净煤技术. .
	HE Nieyan, LI Xueqin, LIU Peng, et al. Technical status of carbon dioxide hydrogenation to methanol and research progress of catalysts[J]. Clean Coal Technology. .
61	TORRES GALVIS Hirsa M, DE JONG Krijn P. Catalysts for production of lower olefins from synthesis gas: A review[J]. ACS Catalysis, 2013, 3(9): 2130-2149.
62	JAGADEESAN D, SUNDARAYYA Y, MADRAS Giridhar, et al. Direct conversion of calcium carbonate to C₁—C₃ hydrocarbons[J]. RSC Advances, 2013, 3(20): 7224-7229.
63	Ahmed AL-MAMOORI, LAWSON Shane, ROWNAGHI Ali A, et al. Oxidative dehydrogenation of ethane to ethylene in an integrated CO₂ capture-utilization process[J]. Applied Catalysis B: Environmental, 2020, 278: 119329.
64	LAWSON S, BAAMRAN K, NEWPORT K, et al. Screening of adsorbent/catalyst composite monoliths for carbon capture-utilization and ethylene production[J]. ACS Applied Materials & Interfaces, 2021, 13(46): 55198-55207.
65	BAAMRAN Khaled, LAWSON Shane, ROWNAGHI Ali A, et al. Process evaluation and kinetic analysis of 3D-printed monoliths comprised of CaO and Cr/H-ZSM-5 in combined CO₂ Capture-C₂H₆ oxidative dehydrogenation to C₂H₄ [J]. Chemical Engineering Journal, 2022, 435: 134706.
66	ZHANG Xiaoyu, LIU Wenqiang, PENG Peng, et al. A dual functional sorbent/catalyst material for in situ CO₂ capture and conversion to ethylene production[J]. Fuel, 2023, 351: 128701.
67	XUE Zhen, GUO Jingyi, WU Shasha, et al. Co-thermal in situ reduction of inorganic carbonates to reduce carbon-dioxide emission[J]. Science China Chemistry, 2023, 66(4): 1201-1210.
68	张琦, 沈佳林, 籍杨梅. 典型钢铁制造流程碳排放及碳中和实施路径[J]. 钢铁, 2023, 58(2): 173-187.
	ZHANG Qi, SHEN Jialin, JI Yangmei. Analysis of carbon emissions in typical iron- and steelmaking process and implementation path research of carbon neutrality[J]. Iron & Steel, 2023, 58(2): 173-187.
69	LUO Y H, ZHU D Q, PAN J, et al. Thermal decomposition behaviour and kinetics of Xinjiang siderite ore[J]. Mineral Processing and Extractive Metallurgy, 2016, 125(1): 17-25.
70	FENG Yong, WU Deli, LI Hailong, et al. Activation of persulfates using siderite as a source of ferrous ions: Sulfate radical production, stoichiometric efficiency, and implications[J]. ACS Sustainable Chemistry & Engineering, 2018, 6(3): 3624-3631.
71	YU Jianwen, HAN Yuexin, LI Yanjun, et al. Recent advances in magnetization roasting of refractory iron ores: A technological review in the past decade[J]. Mineral Processing and Extractive Metallurgy Review, 2020, 41(5): 349-359.
72	CHEN Dong, GUO Hongwei, LV Yanan, et al. Green technology-based utilization of refractory siderite ores to prepare electric arc furnace burden[J]. Steel Research International, 2021, 92(9).
73	BALDAUF-SOMMERBAUER G, LUX S, SIEBENHOFER M. Sustainable iron production from mineral iron carbonate and hydrogen[J]. Green Chemistry, 2016, 18(23): 6255-6265.
74	ZHANG Dongliang, LI Hanke, YANG Guangxing, et al. Hydrogen-driven routes to steel from siderite with low CO₂ emissions: A modeling study[J]. Chemical Engineering Science, 2024, 287: 119702.
75	AN Jing, LI Yingnan, MIDDLETON Richard S. Reducing energy consumption and carbon emissions of magnesia refractory products: A life-cycle perspective[J]. Journal of Cleaner Production, 2018, 182: 363-371.
76	AN Jing, XUE Xiangxin. Life-cycle carbon footprint analysis of magnesia products[J]. Resources, Conservation and Recycling, 2017, 119: 4-11.
77	LI Yongquan. Production and running status of China’s refractories and main downstream industries in 2021[J]. China’s Refractories, 2022, 31(3): 1-4.
78	WANG Xiu, ZHAO Liang, ZHANG Lihui, et al. A novel combined system for LNG cold energy utilization to capture carbon dioxide in the flue gas from the magnesite processing industry[J]. Energy, 2019, 187: 115963.
79	XIE Zhicheng, SUN Zheyi, SHAO Bin, et al. Highly efficient hydrogenation of carbonate to methanol for boating CO₂ mitigation[J]. Chemical Engineering Journal, 2024, 495: 153465.

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