Chemical Industry and Engineering Progress ›› 2024, Vol. 43 ›› Issue (S1): 189-208.DOI: 10.16085/j.issn.1000-6613.2024-1077
• Energy processes and technology • Previous Articles Next Articles
WANG Bo1(), WANG Bin1,2, GONG Xiang1,2(), YANG Fusheng1,2, FANG Tao1,2()
Received:
2024-07-05
Revised:
2024-08-24
Online:
2024-12-06
Published:
2024-11-20
Contact:
GONG Xiang, FANG Tao
王波1(), 王斌1,2, 龚翔1,2(), 杨福胜1,2, 方涛1,2()
通讯作者:
龚翔,方涛
作者简介:
王波(1999—),男,博士研究生,研究方向为有机液态储氢技术。E-mail:wb15281123670@stu.edu.cn。
基金资助:
CLC Number:
WANG Bo, WANG Bin, GONG Xiang, YANG Fusheng, FANG Tao. Enhancing dehydrogenation performance of liquid organic hydrogen carriers based on reactor design: Research progress[J]. Chemical Industry and Engineering Progress, 2024, 43(S1): 189-208.
王波, 王斌, 龚翔, 杨福胜, 方涛. 基于反应器设计的有机液态储氢载体脱氢反应强化研究进展[J]. 化工进展, 2024, 43(S1): 189-208.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2024-1077
序号 | LOHC-/LOHC+ | 储氢密度(质量分数)/% | 脱氢焓/kJ·mol-1 | LOHC-熔点/℃ | LOHC+沸点/℃ |
---|---|---|---|---|---|
1 | TOL/MCH | 6.2 | 68.3 | -95 | 101 |
2 | NEC/12H-NEC | 5.8 | 47.5 | 68 | 280 |
3 | NAP/十氢萘 | 7.3 | 63.9 | -37 | 189 |
4 | DBT/18H-DBT | 6.2 | 65.4 | -34 | 370 |
5 | BT/12H-BT | 6.2 | 63.5 | -30 | 270 |
6 | 1-MID/8H-1-MID | 5.8 | 51.9 | 95 | 180 |
序号 | LOHC-/LOHC+ | 储氢密度(质量分数)/% | 脱氢焓/kJ·mol-1 | LOHC-熔点/℃ | LOHC+沸点/℃ |
---|---|---|---|---|---|
1 | TOL/MCH | 6.2 | 68.3 | -95 | 101 |
2 | NEC/12H-NEC | 5.8 | 47.5 | 68 | 280 |
3 | NAP/十氢萘 | 7.3 | 63.9 | -37 | 189 |
4 | DBT/18H-DBT | 6.2 | 65.4 | -34 | 370 |
5 | BT/12H-BT | 6.2 | 63.5 | -30 | 270 |
6 | 1-MID/8H-1-MID | 5.8 | 51.9 | 95 | 180 |
序号 | 反应器 | LOHC体系 | 强化策略 | 温度,压力 | 脱氢性能 | 参考 文献 |
---|---|---|---|---|---|---|
1 | 批式反应釜 | DBT | 加氢/脱氢循环 | 加氢:140~200℃,3~4MPa 脱氢270℃,320℃ | 加氢率100%;脱氢率50%~80% | [ |
2 | 批式烧瓶 | DBT | 降低副产物 | 脱氢310℃,0.1MPa | 最大产氢能力4g/(gcat·min) 最低副产物2% | [ |
3 | 微分反应器 | DBT | 更准确的反应速率 | 脱氢250~340℃,0.1MPa, WHSV 0.5~67h-1 | 转化率范围30%~54% | [ |
4 | 列管式固定床 | BT | 均匀温度分布 | 脱氢348~364℃,0.1MPa, LHSV 0.6~1.2h-1 | 2.3m3/h(标准状况),脱氢程度大于90% | [ |
5 | 热管式固定床 | MCH | 传热强化 | 脱氢260~370℃,0.1MPa, LHSV 2~8h-1 | 脱氢程度100%,重整效率80% | [ |
6 | 交叉反向固定床 | BT | 传热强化 | 脱氢280~320℃,0.4MPa, 原料流率50mL/min | 脱氢程度小于70%,能量密度是传统反应器的2.3倍 | [ |
7 | 整体涂层式反应器 | NEC | 传热强化、传质强化 | 脱氢220~260℃,0.1MPa, 原料流率0.5~4mL/min | 最大氢气产率65%,最大生产能力为 1.27 | [ |
8 | “湿干”多相反应器 | 环己烷、MCH、萘 | 催化剂表面高温 | 脱氢250~400℃,0.1MPa, 环己烷1mL,萘0.75mL | 环己烷/MCH/萘最大反应速率常数分别为8mmol/min、6.5mmol/min和5.7mmol/min | [ |
9 | 微通道反应器 | DBT | 传热强化、传质强化 | 脱氢260~320℃,0.1MPa, 0.01mL/min | 最大氢气产率82%,氢气纯度99.99% | [ |
10 | 径向流动反应器 | DBT | 传热强化、反应动力学强化 | 脱氢340℃, 0.2MPa/0.3MPa/0.4MPa 0.38mL/min | 脱氢程度18%~24%。氢气纯度99.999%,1.15 | [ |
11 | 膜反应器 | MCH | 传质强化、反应动力学强化 | 脱氢350℃,0.9MPa 标准停留时间250kg·s/m3 | 转化率95%,H2/N2选择性大于85000 | [ |
12 | 反应精馏 | BT | 传热强化、反应动力学强化 | 脱氢300℃,0.1MPa 0.2~0.8g/min | 氢气流量280mL/min,脱氢程度80%,0.35 | [ |
13 | 加氢脱氢一体化反应器 | DBT | 加氢脱氢循环 | 加氢:300℃,3MPa 脱氢:290℃,0.2MPa | 脱氢率70% 1.2 | [ |
序号 | 反应器 | LOHC体系 | 强化策略 | 温度,压力 | 脱氢性能 | 参考 文献 |
---|---|---|---|---|---|---|
1 | 批式反应釜 | DBT | 加氢/脱氢循环 | 加氢:140~200℃,3~4MPa 脱氢270℃,320℃ | 加氢率100%;脱氢率50%~80% | [ |
2 | 批式烧瓶 | DBT | 降低副产物 | 脱氢310℃,0.1MPa | 最大产氢能力4g/(gcat·min) 最低副产物2% | [ |
3 | 微分反应器 | DBT | 更准确的反应速率 | 脱氢250~340℃,0.1MPa, WHSV 0.5~67h-1 | 转化率范围30%~54% | [ |
4 | 列管式固定床 | BT | 均匀温度分布 | 脱氢348~364℃,0.1MPa, LHSV 0.6~1.2h-1 | 2.3m3/h(标准状况),脱氢程度大于90% | [ |
5 | 热管式固定床 | MCH | 传热强化 | 脱氢260~370℃,0.1MPa, LHSV 2~8h-1 | 脱氢程度100%,重整效率80% | [ |
6 | 交叉反向固定床 | BT | 传热强化 | 脱氢280~320℃,0.4MPa, 原料流率50mL/min | 脱氢程度小于70%,能量密度是传统反应器的2.3倍 | [ |
7 | 整体涂层式反应器 | NEC | 传热强化、传质强化 | 脱氢220~260℃,0.1MPa, 原料流率0.5~4mL/min | 最大氢气产率65%,最大生产能力为 1.27 | [ |
8 | “湿干”多相反应器 | 环己烷、MCH、萘 | 催化剂表面高温 | 脱氢250~400℃,0.1MPa, 环己烷1mL,萘0.75mL | 环己烷/MCH/萘最大反应速率常数分别为8mmol/min、6.5mmol/min和5.7mmol/min | [ |
9 | 微通道反应器 | DBT | 传热强化、传质强化 | 脱氢260~320℃,0.1MPa, 0.01mL/min | 最大氢气产率82%,氢气纯度99.99% | [ |
10 | 径向流动反应器 | DBT | 传热强化、反应动力学强化 | 脱氢340℃, 0.2MPa/0.3MPa/0.4MPa 0.38mL/min | 脱氢程度18%~24%。氢气纯度99.999%,1.15 | [ |
11 | 膜反应器 | MCH | 传质强化、反应动力学强化 | 脱氢350℃,0.9MPa 标准停留时间250kg·s/m3 | 转化率95%,H2/N2选择性大于85000 | [ |
12 | 反应精馏 | BT | 传热强化、反应动力学强化 | 脱氢300℃,0.1MPa 0.2~0.8g/min | 氢气流量280mL/min,脱氢程度80%,0.35 | [ |
13 | 加氢脱氢一体化反应器 | DBT | 加氢脱氢循环 | 加氢:300℃,3MPa 脱氢:290℃,0.2MPa | 脱氢率70% 1.2 | [ |
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