多孔液体：合成与应用

doi:10.16085/j.issn.1000-6613.2020-1963

摘要/Abstract

摘要：

多孔液体是一类具有永久孔隙的新兴液体材料，它将多孔材料优异的性能和液体的流动性结合在一起。具有永久空腔的造孔器（pore generator），可以完全由无机砌块单元、有机配体和无机节点的组合单元或有机砌块单元构成。本文根据造孔器的结构综述了使用无机纳米材料、金属有机框架和多孔笼合成多孔液体的最新研究进展。文章指出作为新的研究领域，多孔液体化学正处于起步阶段，虽然面临着诸多挑战，但应用潜力巨大。目前在气体吸附、异构体识别、多孔液体膜的合成等方面都有研究，有望在气体捕捉和分离、催化、膜材料制备等领域得到应用。

关键词: 多孔液体, 无机纳米材料, 金属有机框架, 多孔笼, 分离

Abstract:

Porous liquids are an emerging class of liquid material with permanent pores that combine the excellent properties of porous materials with the fluidity of liquids. The permanently porous structures of pore generators can be made from inorganic building blocks or from a combination of organic ligands and inorganic nodes or from organic building blocks. According to the structure of pore generators, this review focused on recent advancements on the use of inorganic hollow nanomaterials, metal organic framework and porous cages as pore generators of porous liquids. This new research direction toward porous liquids chemistry was still in its early stages, which faced many challenges but had great application potential. Porous liquids had been studied in gas absorption, identification of isomers and synthesis of porous liquid separation membrane now, and they were expected to be used in areas of gas capture and separation, catalysis and synthesis membrane material etc.

Key words: porous liquid, inorganic nanomaterial, metal organic frameworks (MOFs), porous cage, separation

中图分类号:

O641.3

熊鑫坤, 宋华, 苑彬彬, 王园园, 张浩瀚, 陈彦广, 苑丹丹. 多孔液体：合成与应用[J]. 化工进展, 2021, 40(8): 4346-4359.

XIONG Xinkun, SONG Hua, YUAN Binbin, WANG Yuanyuan, ZHANG Haohan, CHEN Yanguang, YUAN Dandan. Porous liquids: synthesis and application[J]. Chemical Industry and Engineering Progress, 2021, 40(8): 4346-4359.

图/表 2

参考文献 76

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