化工进展 ›› 2021, Vol. 40 ›› Issue (8): 4346-4359.DOI: 10.16085/j.issn.1000-6613.2020-1963

• 材料科学与技术 • 上一篇    下一篇

多孔液体:合成与应用

熊鑫坤1(), 宋华1,2, 苑彬彬3,4, 王园园1,2, 张浩瀚1,2, 陈彦广1,2, 苑丹丹1,2()   

  1. 1.东北石油大学化学化工学院, 黑龙江 大庆 163318
    2.东北石油大学石油与天然气化工省重点实验室,黑龙江 大庆 163318
    3.哈尔滨工业大学, 黑龙江 哈尔滨 150001
    4.哈尔滨锅炉厂有限责任公司, 黑龙江 哈尔滨 150046
  • 收稿日期:2020-09-25 出版日期:2021-08-05 发布日期:2021-08-12
  • 通讯作者: 苑丹丹
  • 作者简介:熊鑫坤(1997—),男,硕士研究生,研究方向为多孔液体。E-mail:2586189879@qq.com
  • 基金资助:
    国家自然科学基金(51674089);黑龙江省自然科学基金联合引导项目(LH2019B025)

Porous liquids: synthesis and application

XIONG Xinkun1(), SONG Hua1,2, YUAN Binbin3,4, WANG Yuanyuan1,2, ZHANG Haohan1,2, CHEN Yanguang1,2, YUAN Dandan1,2()   

  1. 1.School of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, Heilongjiang, China
    2.Provincial Key Laboratory of Petroleum and Natural Gas Chemical Engineering, Northeast Petroleum University, Daqing 163318, Heilongjiang, China
    3.Harbin Institute of Technology, Harbin 150001, Heilongjiang, China
    4.Harbin Boiler Company Limited, Harbin 150046, Heilongjiang, China
  • Received:2020-09-25 Online:2021-08-05 Published:2021-08-12
  • Contact: YUAN Dandan

摘要:

多孔液体是一类具有永久孔隙的新兴液体材料,它将多孔材料优异的性能和液体的流动性结合在一起。具有永久空腔的造孔器(pore generator),可以完全由无机砌块单元、有机配体和无机节点的组合单元或有机砌块单元构成。本文根据造孔器的结构综述了使用无机纳米材料、金属有机框架和多孔笼合成多孔液体的最新研究进展。文章指出作为新的研究领域,多孔液体化学正处于起步阶段,虽然面临着诸多挑战,但应用潜力巨大。目前在气体吸附、异构体识别、多孔液体膜的合成等方面都有研究,有望在气体捕捉和分离、催化、膜材料制备等领域得到应用。

关键词: 多孔液体, 无机纳米材料, 金属有机框架, 多孔笼, 分离

Abstract:

Porous liquids are an emerging class of liquid material with permanent pores that combine the excellent properties of porous materials with the fluidity of liquids. The permanently porous structures of pore generators can be made from inorganic building blocks or from a combination of organic ligands and inorganic nodes or from organic building blocks. According to the structure of pore generators, this review focused on recent advancements on the use of inorganic hollow nanomaterials, metal organic framework and porous cages as pore generators of porous liquids. This new research direction toward porous liquids chemistry was still in its early stages, which faced many challenges but had great application potential. Porous liquids had been studied in gas absorption, identification of isomers and synthesis of porous liquid separation membrane now, and they were expected to be used in areas of gas capture and separation, catalysis and synthesis membrane material etc.

Key words: porous liquid, inorganic nanomaterial, metal organic frameworks (MOFs), porous cage, separation

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