Gemini型表面活性剂在离子液体中构筑的溶致液晶

doi:10.16085/j.issn.1000-6613.2015.12.036

化工进展 ›› 2015, Vol. 34 ›› Issue (12): 4348-4355.DOI: 10.16085/j.issn.1000-6613.2015.12.036

Gemini型表面活性剂在离子液体中构筑的溶致液晶

宋冰蕾, 陈涛, 田金年, 裴晓梅, 孟丽

江南大学化学与材料工程学院, 江苏无锡 214122

收稿日期:2015-03-12 修回日期:2015-04-22 出版日期:2015-12-05 发布日期:2015-12-05
通讯作者: 宋冰蕾(1980—),男,博士,副教授,硕士生导师。E-mailccfsbl@126.com。
作者简介:宋冰蕾(1980—),男,博士,副教授,硕士生导师。E-mailccfsbl@126.com。
基金资助:
国家自然科学基金项目(21203078)。

Lyotropic liquid crystalline phases formed by Gemini surfactants in an ionic liquid

SONG Binglei, CHEN Tao, TIAN Jinnian, PEI Xiaomei, MENG Li

School of Chemical & Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu, China

Received:2015-03-12 Revised:2015-04-22 Online:2015-12-05 Published:2015-12-05

摘要/Abstract

摘要： 通过差示扫描量热仪(DSC)、X射线衍射仪(XRD)、热台偏光显微镜(POM)和红外光谱仪等手段研究了Gemini表面活性剂在硝酸乙基铵(EAN)中构筑的溶致液晶体系(lyotropic liquid crystal,LLc)的性质。结果表明,在液晶区内,所形成的溶致液晶均为层状介晶A相(SmA),且EAN主要存在于液晶相分子层的极性亚层中;液晶相稳定存在的温度区间随Gemini表面活性剂的浓度、尾链长度的增加而变大,随联接链的增加表现出先增大再减小的趋势;羟基削弱了离子头基与反离子间的相互作用,进而缩小了液晶相稳定存在的温度区间。

关键词: 溶致液晶, Gemini型表面活性剂, 离子液体, 自组织

Abstract: The lyotropic liquid crystals formed by Gemini surfactants in ethyl ammonium nitrate (EAN) were investigated by differential scanning calorimetry(DSC),X ray diffractometer(XRD),polarizing microscope(POM) equipped with a hot stage and FTIR. All the surfactants form smectic A phase(SmA) in liquid crystalline region. The EAN molecules mainly exist in the polar sublayers of liquid crystals. The temperature ranges of liquid crystal phase increase with increasing Gemini surfactant alkyl chain length while show maximum with the increase of spacer length. The hydroxyl groups decrease the interactions between the ionic head groups and counterions. The temperature range of liquid crystal state is thus narrowed.

Key words: lyotropic liquid crystal, Gemini surfactants, ionic liquids, self-assembly

中图分类号:

TQ423.9

宋冰蕾, 陈涛, 田金年, 裴晓梅, 孟丽. Gemini型表面活性剂在离子液体中构筑的溶致液晶[J]. 化工进展, 2015, 34(12): 4348-4355.

SONG Binglei, CHEN Tao, TIAN Jinnian, PEI Xiaomei, MENG Li. Lyotropic liquid crystalline phases formed by Gemini surfactants in an ionic liquid[J]. Chemical Industry and Engineering Progree, 2015, 34(12): 4348-4355.

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Gemini型表面活性剂在离子液体中构筑的溶致液晶

Lyotropic liquid crystalline phases formed by Gemini surfactants in an ionic liquid

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