多孔有机聚合物催化二氧化碳合成环状碳酸酯研究进展

doi:10.16085/j.issn.1000-6613.2020-1502

化工进展 ›› 2021, Vol. 40 ›› Issue (7): 3564-3583.DOI: 10.16085/j.issn.1000-6613.2020-1502

多孔有机聚合物催化二氧化碳合成环状碳酸酯研究进展

陈亚举¹(), 任清刚², 周贤太³, 纪红兵¹^,³()

^1.广东石油化工学院化学学院，广东茂名 525000
^2.广东石油化工学院材料科学与工程学院，广东茂名 525000
^3.中山大学化学学院精细化工研究院，广东广州 510275

收稿日期:2020-07-31 修回日期:2020-08-31 出版日期:2021-07-06 发布日期:2021-07-19
通讯作者: 纪红兵
作者简介:陈亚举（1989—），男，博士，研究方向为绿色催化与合成、CO2捕集与转化。E-mail：chenyaju970@126.com。
基金资助:
国家自然科学基金(21938001);广东省基础与应用基础研究基金(2019A1515010612);广东省普通高校特色创新类项目(2019KTSCX107);广东石油化工学院科研基金(2019rc049);广东省“珠江人才计划”本土创新科研团队(2017BT01C102);广东省普通高校创新团队项目(2019KCXTD002);广东石油化工学院科研创新团队项目

Recent advances in porous organic polymers for the synthesis of cyclic carbonates from carbon dioxide

CHEN Yaju¹(), REN Qinggang², ZHOU Xiantai³, JI Hongbing¹^,³()

^1.School of Chemistry, Guangdong University of Petrochemical Technology, Maoming 525000, Guangdong, China
^2.School of Materials Science and Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, Guangdong, China
^3.Fine Chemical Industry Research Institute, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, Guangdong, China

Received:2020-07-31 Revised:2020-08-31 Online:2021-07-06 Published:2021-07-19
Contact: JI Hongbing

摘要/Abstract

摘要：

二氧化碳（CO₂）捕集、利用和储存（CCUS）在全球能源结构转型中是一种极具潜力的策略，能够实现能源供给、基础原料产出以及限制气候变化。多孔有机聚合物（POPs）具有高CO₂吸附容量和吸附选择性、突出的结构特性以及优异的化学可调控性，其作为极具潜力的材料广泛应用于催化CO₂参与的有机反应中。其中，CO₂与环氧化物环加成生成环状碳酸酯的反应具有100%的原子经济性，且其产物也极具工业价值。本文基于CO₂环加成反应催化机制，从催化剂的合成方法、结构性质与组成特性角度出发，综述了POPs在CO₂/环氧化物环加成反应的研究进展，包括金属配合物类、氢键供体类、离子液体类、金属配合物/离子液体和氢键供体/离子液体等有机多孔聚合物体系。通过阐述POPs在催化CO₂制备高附加值环状碳酸酯反应中的研究现状和发展趋势，为POPs的开发与应用以及CO₂综合利用的工业化探索提供具有建设性的指导意见。

关键词: 二氧化碳, 环状碳酸酯, 多孔有机聚合物, 多相催化, 离子液体, 金属配合物

Abstract:

Recently, carbon dioxide (CO₂) capture utilization and storage (CCUS) has been generally identified as a potential strategy in the global energy transition, enabling the provision of energy and the production of essential materials, while limiting climate change. Due to their large capacity and excellent selectivity for the adsorption of CO₂, outstanding structural properties, as well as their chemical tunability, porous organic polymers (POPs) have been widely employed as efficient catalysts in numerous CO₂-involved reactions. In particular, the insertion of CO₂ into epoxides for affording cyclic carbonates has been proposed as a promising strategy due to its 100% atom economy and the great industrial potential of products. Based on the reaction mechanism together with the synthetic methods, structural properties and component characteristics of catalysts, the progress in POPs for the CO₂/epoxides cycloaddition reaction was reviewed, including metal complexes-, hydrogen-bond donor-, ionic liquids (ILs)-, metal complexes/ILs- and hydrogen-bond donor/ILs-based POPs. The research status and development trend of POPs in the transformation of CO₂ into value-added cyclic carbonate were described, which provided constructive guidance for the development and application of POPs and the industrial exploration of comprehensive utilization of CO₂.

Key words: carbon dioxide, cyclic carbonate, porous organic polymers, heterogeneous catalysis, ionic liquids, metal complex

中图分类号:

O643.3

陈亚举, 任清刚, 周贤太, 纪红兵. 多孔有机聚合物催化二氧化碳合成环状碳酸酯研究进展[J]. 化工进展, 2021, 40(7): 3564-3583.

CHEN Yaju, REN Qinggang, ZHOU Xiantai, JI Hongbing. Recent advances in porous organic polymers for the synthesis of cyclic carbonates from carbon dioxide[J]. Chemical Industry and Engineering Progress, 2021, 40(7): 3564-3583.

图/表 20

图1 CO2参与的典型有机反应

图2 CO2与环氧化物环加成反应的酸碱协同反应机理

图3 几种金属卟啉配合物基多孔聚合物的结构示意图

图4 Friedel-Crafts反应合成M-HCPs（M=Al, Co, Fe, Mn）示意图[35]

图5 几种金属Salen配合物基多孔聚合物的结构示意图

图6 Bp-Zn@MA和Py-Zn@MA的结构示意图

图7 M/POP-Bpy的合成及其在CO2转化中的应用[44]

图8 T-IM和POM-IM的结构示意图

图9 HIPs的合成[47]

图10 季??盐类多孔有机聚合物的合成

图11 海绵状季铵盐类聚合物的合成及其在CO2/环氧化物环加成反应中的应用[57]

图12 HF-MOP和PRP-1的结构示意图

图13 Al-POP、Al-iPOP-1和Al-iPOP-2的合成[68]

图14 Mg-por/php@POP和ZnTPy-BIM4/CNTs的结构示意图

图15 Al-CPOP、DVB@ISA和DVB@ISZ的结构示意图

图16 pna/b（n=1~6）的结构示意图

图17 FIP-Im和FIP-Im@QA分别在CO2环加成反应和N-甲酰化反应中的应用[82]

图18 季??型多孔聚合物的结构

图19 PAD-3的合成路线图及其在CO2与环状碳酸酯的环加成反应中的应用[87]

图20 高度有序且可调控的咪唑基介孔聚合物IPMPs的合成[91]

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多孔有机聚合物催化二氧化碳合成环状碳酸酯研究进展

Recent advances in porous organic polymers for the synthesis of cyclic carbonates from carbon dioxide

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