化工进展

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糠醛生产工艺及制备方法研究进展

张璐鑫,于宏兵   

  1. 南开大学环境科学与工程学院,天津 300071
  • 出版日期:2013-02-05 发布日期:2013-02-05

Research progress in the production and synthesis of furfural

ZHANG Luxin,YU Hongbing   

  1. College of Environmental Science & Engineering,Nankai University,Tianjin 300071,China
  • Online:2013-02-05 Published:2013-02-05

摘要: 糠醛是一种应用广泛的化工原料,其现有生产工艺在产率、能耗及环境污染等方面存在较大问题。本文介绍了现有的主流生产工艺如Quaker Oats工艺,Agrifuran工艺,Petrole-chimie工艺,Escher Wyss工艺及Rosenlew工艺存在的不足,分析了半纤维素生成糠醛的机理及水解动力学研究、糠醛生产设备的更新改造。从溶剂体系、催化剂体系、分离方法、加热方式等多方面探讨发展新的糠醛生产工艺。提出今后的研究重点要放在开发绿色的溶剂及催化剂上,以期对生态环境的危害降至最低。

关键词: 糠醛, 工艺, 制备, 催化剂, 溶剂体系

Abstract: Furfural is a highly versatile and key derivative used in the manufacture of a wide range of important chemicals. However,it is also associated with low yield,energy-intensive and negative environment impact in conventional process for producing furfural. Current mainstream techniques (Quaker Oats,Agrifuran,Petrole-chimie,Escher Wyss and Rosenlew) for furfural production are reviewed;the mechanism and kinetics of hydrolysis of hemicelluloses into furfural are analyzed. The equipment up to date and alteration for furfural production are also discussed. Besides,new furfural manufacturing-processes are analyzed by optimizing solvent,catalyst,separation and heat-up. In order to minimize the impact of furfural production to environment,the research on new green catalyst and solvent system should be more emphasized.

Key words: furfural, technology, synthesis, catalyst, reaction solvent

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