石墨烯及其功能化石墨烯材料在储能领域中的应用

doi:10.16085/j.issn.1000-6613.2024-1222

化工进展 ›› 2025, Vol. 44 ›› Issue (9): 5055-5074.DOI: 10.16085/j.issn.1000-6613.2024-1222

• 材料科学与技术 • 上一篇

石墨烯及其功能化石墨烯材料在储能领域中的应用

胡亮¹(), 张开悦¹(), 高波², 张志彬¹, 刘状², 付海洋², 唐一巧¹, 杨媛媛¹

^1.沈阳理工大学材料科学与工程学院，辽宁沈阳 110159
^2.东北大学冶金学院，辽宁沈阳 110819

收稿日期:2024-07-26 修回日期:2024-12-03 出版日期:2025-09-25 发布日期:2025-09-30
通讯作者: 张开悦
作者简介:胡亮（1984—），男，博士，讲师，研究方向为石墨烯材料的制备及其应用以及金属表面处理。E-mail：huliang@sylu.edu.cn。
基金资助:
沈阳理工大学2023年引进高层次人才科研支持经费项目(1010147001218);国家自然科学基金(22309121);国家自然科学基金(51671052);中央高校基本科研业务费(N182502042);辽宁省兴辽英才项目(XLYC1902105)

Application of graphene and functionalized graphene in the field of energy storage

HU Liang¹(), ZHANG Kaiyue¹(), GAO Bo², ZHANG Zhibin¹, LIU Zhuang², FU Haiyang², TANG Yiqiao¹, YANG Yuanyuan¹

^1.School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, Liaoning, China
^2.School of Metallurgy, Northeastern University, Shenyang 110819, Liaoning, China

Received:2024-07-26 Revised:2024-12-03 Online:2025-09-25 Published:2025-09-30
Contact: ZHANG Kaiyue

摘要/Abstract

摘要：

石墨烯材料自2004年问世以来就备受材料科学界的广泛关注。在石墨烯的基础之上，各国科研人员陆续研发出性能优异的功能化石墨烯材料。石墨烯及功能化石墨烯材料凭借优异的导电、导热以及力学性能等特点，被广泛应用于电子信息、新能源、水处理、涂料工业、大健康等领域。本文重点总结了石墨烯及其功能化石墨烯材料在储能领域的研究进展及应用，包括材料的制备方法以及在各种储能器件的应用，并提出了石墨烯应用于储能器件的未来发展建议，认为应该继续深入研究石墨烯及其功能化石墨烯材料的结构、机理与性能，因石墨烯及其功能化石墨烯材料的形貌不同，直接影响了储能器件的电化学特性。本文旨在为石墨烯及其功能化石墨烯材料的研发以及在储能领域的应用提供一定的思路。

关键词: 石墨烯, 功能化石墨烯材料, 储能, 超级电容器, 锂硫电池

Abstract:

Graphene meterial has been widespread concern by the materials science community since its introduction in 2004. Researchers from various countries have successively developed functionalized graphene materials with excellent properties on the basis of graphene. Graphene and functionalized graphene materials are widely used in the fields of electronic information, new resources of energy, water treatment, coating industry and enlarged health due to their excellent electrical and thermal conductivity as well as mechanical properties. This paper focused on summarizing the research progress and applications of graphene and functionalized graphene materials in the field of energy storage, including the preparation methods of the materials as well as their applications in various energy storage devices, and proposed the future development of graphene applied to energy storage devices. It was believed that in-depth study of the structure, mechanism and properties of graphene and its functionalized graphene should be continued because the difference in the morphology of graphene and its functionalized graphene directly affected the electrochemical properties of energy storage devices. The review aimed to provide certain ideas for the research and development of graphene and functionalized graphene materials as well as their applications in the field of energy storage.

Key words: graphene, functionalized graphene materials, energy storage, supercapacitors, lithium-sulphur batteries

中图分类号:

TQ127.1

胡亮, 张开悦, 高波, 张志彬, 刘状, 付海洋, 唐一巧, 杨媛媛. 石墨烯及其功能化石墨烯材料在储能领域中的应用[J]. 化工进展, 2025, 44(9): 5055-5074.

HU Liang, ZHANG Kaiyue, GAO Bo, ZHANG Zhibin, LIU Zhuang, FU Haiyang, TANG Yiqiao, YANG Yuanyuan. Application of graphene and functionalized graphene in the field of energy storage[J]. Chemical Industry and Engineering Progress, 2025, 44(9): 5055-5074.

图/表 6

图1 流体剪切强化超临界CO2剥离法制备石墨烯

图2 化学氧化法制备还原氧化石墨烯（rGO）的合成路线示意图[28]

图3 SO42-离子插层剥离阳极石墨的反应机理示意图[40]

图4 阴极剥离法制备石墨烯的剥离机理示意图[43]

图5 不同质量分数聚苯胺的功能化石墨烯复合材料SEM图[83]

图6 FeNi-NCNT/rGO复合材料的形貌图及元素分布图[113]

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石墨烯及其功能化石墨烯材料在储能领域中的应用

Application of graphene and functionalized graphene in the field of energy storage

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