碳纤维类材料用于电芬顿体系电极的研究现状

doi:10.16085/j.issn.1000-6613.2021-1779

摘要/Abstract

摘要：

电芬顿技术作为先进氧化技术的一种，基于电化学原理间接性地产生·OH自由基，可以高效快速地去除水中的有机污染物。碳纤维类材料因其比表面积大、密度低、耐腐蚀等优点而被常用作电芬顿体系的电极材料。本文首先介绍了电芬顿技术的基本原理，对近年来碳纤维类材料用于电芬顿电极的研究现状进行了归纳总结，分析了碳纤维材料用于电芬顿电极时的改性手段及应用方式。着重分析了其用于电芬顿阴极时的改性机理与改性方式，并指出了其应用优势与局限性。同时也对碳纤维类材料在电芬顿阳极的应用进行了总结。最后，针对碳纤维类材料用于电芬顿体系时的产业化问题、能耗问题、电极的多功能化等问题进行了分析和展望，为碳纤维类材料应用于电芬顿体系的深入研究提供参考。

关键词: 碳纤维, 电芬顿技术, 电极材料, 有机污染物

Abstract:

As a kind of advanced oxidation processes based on the electrochemistry method, electro-Fenton technology can indirectly generated ·OH radicals that can efficiently remove the organic pollution in water. Carbon fiber materials have the advantages of high volumetric area, low-density, corrosion-resistant, and so on. Motivated by these outstanding advantages, it has been employed for the electrode of Electro-Fenton system. This review primarily introduces the mechanism of electro-Fenton reaction, and then reviews the current situation of carbon fiber materials used for the electrode of electro-Fenton technology. The summary and analysis of the modification mechanism and forms of carbon fiber materials are the emphasis of this review, and the application advantage and limitation are point out. Meanwhile, the application of carbon fiber materials employed for anode is summarized. Finally, the industrialization problems, energy consumption problems and multi-functional electrode of carbon fiber materials used in the electro-Fenton system are analyzed and prospected, providing reference for the further study of this subject.

Key words: carbon fiber, electro-Fenton technology, electrode materials, organic pollution

中图分类号:

TQ342⁺.74

徐虎, 郭泓凯, 柴昌盛, 郝相忠, 杨子元, 徐卫军. 碳纤维类材料用于电芬顿体系电极的研究现状[J]. 化工进展, 2022, 41(7): 3707-3718.

XU Hu, GUO Hongkai, CHAI Changsheng, HAO Xiangzhong, YANG Ziyuan, XU Weijun. Carbon fiber materials used for the electrode of electro-Fenton system: a critical review[J]. Chemical Industry and Engineering Progress, 2022, 41(7): 3707-3718.

图/表 8

图1 电芬顿反应降解有机污染物物机理

图2 三种处理方法对氮、磷在CSCF上可能存在的表面基团的引入机理[32]

图3 不同氧官能团的氧还原活性的第一性原理计算结果[35]

图4 改性碳毡的相关表征[53]

图5 石墨毡/氧化石墨烯/蒽醌磺酸盐阴极体系的反应机理[51]

图6 采用石墨烯改性石墨毡阴极和氮掺杂石墨烯改性石墨毡阴极的原位无金属EAOPs的原理示意图[59]

图7 碳纤维材料的SEM图[62]

图8 改性阴极的循环性能[82]（二次改性条件为180mL反应器，50mmol/L Na2SO4，未搅拌，pH=7，范围1440C/g（200mA，30min）；H2O2电解生成条件为180mL反应器，50mmol/L Na2SO4，pH=7，电解电流100mA，搅拌速度350r/min）

参考文献 82

1	CHENG N, WANG B, WU P, et al. Adsorption of emerging contaminants from water and wastewater by modified biochar: a review[J]. Environmental Pollution, 2021, 273: 116448.
2	MIKLOS D B, REMY C, JEKEL M, et al. Evaluation of advanced oxidation processes for water and wastewater treatment—A critical review[J]. Water Research, 2018, 139: 118-131.
3	GANIYU S O, ZHOU M H, MARTÍNEZ-HUITLE C A. Heterogeneous electro-Fenton and photoelectro-Fenton processes: a critical review of fundamental principles and application for water/wastewater treatment[J]. Applied Catalysis B: Environmental, 2018, 235: 103-129.
4	HU Z Z, CAI J J, SONG G, et al. anodic oxidation of organic pollutants: anode fabrication, process hybrid and environmental applications[J]. Current Opinion in Electrochemistry, 2021, 26: 100659.
5	LOFRANO G, PEDRAZZANI R, LIBRALATO G, et al. Advanced oxidation processes for antibiotics removal: a review[J]. Current Organic Chemistry, 2017, 21(12): 1054-1067.
6	贺福. 碳纤维及石墨纤维[M]. 北京: 化学工业出版社, 2010.
	HE Fu. Carbon fibre and graphite fibre[M]. Beijing: Chemical Industry Press, 2010.
7	高爱君. PAN基碳纤维成分、结构及性能的高温演变机理[D]. 北京: 北京化工大学, 2012.
	GAO Aijun. Evolution mechanism of composition, structure and mechanical properties of carbon fiber during high temperature heat treatment[D]. Beijing: Beijing University of Chemical Technology, 2012.
8	YUAN X M, ZHU B, CAI X, et al. Influence of different surface treatments on the interfacial adhesion of graphene oxide/carbon fiber/epoxy composites[J]. Applied Surface Science, 2018, 458: 996-1005.
9	MENG L H, FAN D P, ZHANG C H, et al. The effect of oxidation treatment by KClO₃/H₂SO₄ system on intersurface performance of carbon fibers[J]. Applied Surface Science, 2013, 268: 225-230.
10	ZHENG X R, PARK C W. Thermal and mechanical properties of carbon fiber-reinforced resin composites with copper/boron nitride coating[J]. Composite Structures, 2019, 220: 494-501.
11	龚明. 轨道车辆用碳纤维复合材料电磁屏蔽结构设计及仿真与试验研究[D]. 北京: 北京交通大学, 2019.
	GONG Ming. Design, simulation and experimental study on electromagnetic shielding structure of carbon fiber reinforced composites for railway vehicles[D]. Beijing: Beijing Jiaotong University, 2019.
12	燕吉强. 基于电-磁双重损耗效应的回收碳纤维取向毡复合材料制备及其电磁屏蔽性能研究[D]. 北京: 北京化工大学, 2020.
	YAN Jiqiang. Preparation and electromagnetic shielding properties of recycled carbon fiber oriented felt composites based on electro-magnetic double loss effect[D]. Beijing: Beijing University of Chemical Technology, 2020.
13	MUKHOPADHYAY A, YANG Y, LI Y F, et al. Mass transfer and reaction kinetic enhanced electrode for high-performance aqueous flow batteries[J]. Advanced Functional Materials, 2019, 29(43): 1903192.
14	陈悦, 赵永欢, 褚朱丹, 等. 基于碳纤维及其织物的柔性锂电池电极研究进展[J]. 纺织学报, 2019, 40(2): 173-180.
	CHEN Yue, ZHAO Yonghuan, CHU Zhudan, et al. Research progress of flexible lithium battery electrodes based on carbon fibers and their fabrics[J]. Journal of Textile Research, 2019, 40(2): 173-180.
15	LIU Y M, QUAN X, FAN X F, et al. High-yield electrosynthesis of hydrogen peroxide from oxygen reduction by hierarchically porous carbon[J]. Angewandte Chemie International Edition, 2015, 54(23): 6837-6841.
16	KATSOUNAROS I, SCHNEIDER W B, MEIER J C, et al. Hydrogen peroxide electrochemistry on platinum: towards understanding the oxygen reduction reaction mechanism[J]. Physical Chemistry Chemical Physics, 2012, 14(20): 7384-7391.
17	SIRÉS I, BRILLAS E, OTURAN M A, et al. Electrochemical advanced oxidation processes: today and tomorrow. A review[J]. Environmental Science and Pollution Research, 2014, 21(14): 8336-8367.
18	AKERDI A G, ES’HAGHZADE Z, BAHRAMI S H, et al. Comparative study of GO and reduced GO coated graphite electrodes for decolorization of acidic and basic dyes from aqueous solutions through heterogeneous electro-Fenton process[J]. Journal of Environmental Chemical Engineering, 2017, 5(3): 2313-2324.
19	LI Q, BATCHELOR-MCAULEY C, LAWRENCE N S, et al. A flow system for hydrogen peroxide production at reticulated vitreous carbon via electroreduction of oxygen[J]. Journal of Solid State Electrochemistry, 2014, 18(5): 1215-1221.
20	ZHOU W, RAJIC L, ZHAO Y W, et al. Rates of H₂O₂ electrogeneration by reduction of anodic O₂ at RVC foam cathodes in batch and flow-through cells[J]. Electrochimica Acta, 2018, 277: 185-196.
21	FRIEDRICH J M, PONCE-DE-LEÓN C, READE G W, et al. Reticulated vitreous carbon as an electrode material[J]. Journal of Electroanalytical Chemistry, 2004, 561: 203-217.
22	LE T X H, BECHELANY M, LACOUR S, et al. High removal efficiency of dye pollutants by electron-Fenton process using a graphene based cathode[J]. Carbon, 2015, 94: 1003-1011.
23	YANG Y R, HE F, SHEN Y F, et al. A biomass derived N/C-catalyst for the electrochemical production of hydrogen peroxide[J]. Chemical Communications, 2017, 53(72): 9994-9997.
24	ZHOU W, RAJIC L, CHEN L, et al. Activated carbon as effective cathode material in iron-free electro-Fenton process: integrated H₂O₂ electrogeneration, activation, and pollutants adsorption[J]. Electrochimica Acta, 2019, 296: 317-326.
25	PANIZZA M, OTURAN M A. Degradation of Alizarin Red by electro-Fenton process using a graphite-felt cathode[J]. Electrochimica Acta, 2011, 56(20): 7084-7087.
26	XIA G S, LU Y H, XU H B. Electrogeneration of hydrogen peroxide for electro-Fenton via oxygen reduction using polyacrylonitrile-based carbon fiber brush cathode[J]. Electrochimica Acta, 2015, 158: 390-396.
27	贺福, 王茂章. 碳纤维及其复合材料[M]. 北京: 科学出版社, 1995.
	HE Fu, WANG Maozhang. Carbon fiber and its composite materials[M]. Beijing: Science Press, 1995.
28	LAN H C, HE W J, WANG A M, et al. An activated carbon fiber cathode for the degradation of glyphosate in aqueous solutions by the electro-Fenton mode: optimal operational conditions and the deposition of iron on cathode on electrode reusability[J]. Water Research, 2016, 105: 575-582.
29	ZHANG Y Y, WANG A M, REN S Y, et al. Effect of surface properties of activated carbon fiber cathode on mineralization of antibiotic cefalexin by electro-Fenton and photoelectro-Fenton treatments: mineralization, kinetics and oxidation products[J]. Chemosphere, 2019, 221: 423-432.
30	YU F K, WANG Y, MA H R. Enhancing the yield of H₂O₂ from oxygen reduction reaction performance by hierarchically porous carbon modified active carbon fiber as an effective cathode used in electro-Fenton[J]. Journal of Electroanalytical Chemistry, 2019, 838: 57-65.
31	YU F K, WANG L N, MA H R, et al. Zeolitic imidazolate framework-8 modified active carbon fiber as an efficient cathode in electro-Fenton for tetracycline degradation[J]. Separation and Purification Technology, 2020, 237: 116342.
32	LI K Q, LIU J M, LI J, et al. Effects of N mono- and N/P dual-doping on H₂O₂, OH generation, and MB electrochemical degradation efficiency of activated carbon fiber electrodes[J]. Chemosphere, 2018, 193: 800-810.
33	陈俞. 氯改性活性炭纤维电极制备及电芬顿降解酸性橙Ⅱ[D]. 杭州: 浙江工业大学, 2019.
	CHEN Yu. Preparation of chlorine modified activated carbon fiber electrode for electro-Fenton degradation of orange Ⅱ[D]. Hangzhou: Zhejiang University of Technology, 2019.
34	SU D S, WEN G D, WU S C, et al. Carbocatalysis in liquid-phase reactions[J]. Angewandte Chemie International Edition, 2017, 56(4): 936-964.
35	LU Z Y, CHEN G X, SIAHROSTAMI S, et al. High-efficiency oxygen reduction to hydrogen peroxide catalysed by oxidized carbon materials[J]. Nature Catalysis, 2018, 1(2): 156-162.
36	DUAN X G, KANG J, TIAN W J, et al. Interfacial-engineered cobalt@carbon hybrids for synergistically boosted evolution of sulfate radicals toward green oxidation[J]. Applied Catalysis B: Environmental, 2019, 256: 117795.
37	WANG Z N, LIU M Y, XIAO F, et al. Recent advances and trends of heterogeneous electro-Fenton process for wastewater treatment-review[J]. Chinese Chemical Letters, 2022, 33(2): 653-662.
38	YEAGER E. Oxygen electrodes for electrochemical energy storage systems[M]//Energy Storage. Amsterdam: Elsevier, 1980: 201-211.
39	KIM H, LEE K, WOO S I, et al. On the mechanism of enhanced oxygen reduction reaction in nitrogen-doped graphene nanoribbons[J]. Physical Chemistry Chemical Physics, 2011, 13(39): 17505.
40	ZHOU W, MENG X X, GAO J H, et al. Hydrogen peroxide generation from O₂ electroreduction for environmental remediation: a state-of-the-art review[J]. Chemosphere, 2019, 225: 588-607.
41	MIAO J, ZHU H, TANG Y, et al. Graphite felt electrochemically modified in H₂SO₄ solution used as a cathode to produce H₂O₂ for pre-oxidation of drinking water[J]. Chemical Engineering Journal, 2014, 250: 312-318.
42	XU H, ZHANG Z, GUO H K, et al. Electrogeneration of hydrogen peroxide by oxygen reduction using anodized graphite felt[J]. Journal of the Taiwan Institute of Chemical Engineers, 2021, 125: 387-393.
43	XIA G S, LU Y H, XU H B. An energy-saving production of hydrogen peroxide via oxygen reduction for electro-Fenton using electrochemically modified polyacrylonitrile-based carbon fiber brush cathode[J]. Separation and Purification Technology, 2015, 156: 553-560.
44	ZHOU L, ZHOU M H, HU Z X, et al. Chemically modified graphite felt as an efficient cathode in electro-Fenton for p-nitrophenol degradation[J]. Electrochimica Acta, 2014, 140: 376-383.
45	OU B, WANG J X, WU Y, et al. A highly efficient cathode based on modified graphite felt for aniline degradation by electro-Fenton[J]. Chemosphere, 2019, 235: 49-57.
46	LAI W K, XIE G Y, DAI R Z, et al. Kinetics and mechanisms of oxytetracycline degradation in an electro-Fenton system with a modified graphite felt cathode[J]. Journal of Environmental Management, 2020, 257: 109968.
47	WANG Y, LIU Y H, WANG K, et al. Preparation and characterization of a novel KOH activated graphite felt cathode for the electro-Fenton process[J]. Applied Catalysis B: Environmental, 2015, 165: 360-368.
48	KIM H W, ROSS M B, KORNIENKO N, et al. Efficient hydrogen peroxide generation using reduced graphene oxide-based oxygen reduction electrocatalysts[J]. Nature Catalysis, 2018, 1(4): 282-290.
49	ZHANG H C, LI Y J, ZHAO Y S, et al. Carbon black oxidized by air calcination for enhanced H₂O₂ generation and effective organics degradation[J]. ACS Applied Materials & Interfaces, 2019, 11(31): 27846-27853.
50	DIVYAPRIYA G, NAMBI I M, SENTHILNATHAN J. An innate quinone functionalized electrochemically exfoliated graphene/Fe₃O₄ composite electrode for the continuous generation of reactive oxygen species[J]. Chemical Engineering Journal, 2017, 316: 964-977.
51	GAO Y, ZHU W H, WANG C G, et al. Enhancement of oxygen reduction on a newly fabricated cathode and its application in the electro-Fenton process[J]. Electrochimica Acta, 2020, 330: 135206.
52	WANG Y, ZHOU W, GAO J H, et al. Oxidative modification of graphite felts for efficient H₂O₂ electrogeneration: enhancement mechanism and long-term stability[J]. Journal of Electroanalytical Chemistry, 2019, 833: 258-268.
53	ZHANG Q Z, ZHOU M H, REN G B, et al. Highly efficient electrosynthesis of hydrogen peroxide on a superhydrophobic three-phase interface by natural air diffusion[J]. Nature Communications, 2020, 11: 1731.
54	ZHANG Q Z, ZHOU M H, LANG Z C, et al. Dual strategies to enhance mineralization efficiency in innovative electrochemical advanced oxidation processes using natural air diffusion electrode: improving both H₂O₂ production and utilization efficiency[J]. Chemical Engineering Journal, 2021, 413: 127564.
55	ZHOU L, ZHOU M H, ZHANG C, et al. Electro-Fenton degradation of p-nitrophenol using the anodized graphite felts[J]. Chemical Engineering Journal, 2013, 233: 185-192.
56	LI D, ZHENG T, LIU Y L, et al. A novel electro-Fenton process characterized by aeration from inside a graphite felt electrode with enhanced electrogeneration of H₂O₂ and cycle of Fe³⁺/Fe²⁺ [J]. Journal of Hazardous Materials, 2020, 396: 122591.
57	YU X M, ZHOU M H, REN G B, et al. A novel dual gas diffusion electrodes system for efficient hydrogen peroxide generation used in electro-Fenton[J]. Chemical Engineering Journal, 2015, 263: 92-100.
58	KUBO D C, KAWASE Y. Hydroxyl radical generation in electro-Fenton process with in situ electro-chemical production of Fenton reagents by gas-diffusion-electrode cathode and sacrificial iron anode[J]. Journal of Cleaner Production, 2018, 203: 685-695.
59	YANG W L, ZHOU M H, LIANG L. Highly efficient in situ metal-free electrochemical advanced oxidation process using graphite felt modified with N-doped graphene[J]. Chemical Engineering Journal, 2018, 338: 700-708.
60	GANIYU S O, HUONG LE T X, BECHELANY M, et al. A hierarchical CoFe-layered double hydroxide modified carbon-felt cathode for heterogeneous electro-Fenton process[J]. Journal of Materials Chemistry A, 2017, 5(7): 3655-3666.
61	QI H Q, SUN X P, SUN Z R. Porous graphite felt electrode with catalytic defects for enhanced degradation of pollutants by electro-Fenton process[J]. Chemical Engineering Journal, 2021, 403: 126270.
62	LE T X H, CHARMETTE C, BECHELANY M, et al. Facile preparation of porous carbon cathode to eliminate paracetamol in aqueous medium using electro-Fenton system[J]. Electrochimica Acta, 2016, 188: 378-384.
63	HUANG H L, HAN C L, WANG G W, et al. Lignin combined with polypyrrole as a renewable cathode material for H₂O₂ generation and its application in the electro-Fenton process for azo dye removal[J]. Electrochimica Acta, 2018, 259: 637-646.
64	VALIM R B, REIS R M, CASTRO P S, et al. Electrogeneration of hydrogen peroxide in gas diffusion electrodes modified with tert-butyl-anthraquinone on carbon black support[J]. Carbon, 2013, 61: 236-244.
65	YANG W L, ZHOU M H, CAI J J, et al. Ultrahigh yield of hydrogen peroxide on graphite felt cathode modified with electrochemically exfoliated graphene[J]. Journal of Materials Chemistry A, 2017, 5(17): 8070-8080.
66	阮炽, 刘长军, 岳海荣, 等. 聚吡咯改性石墨毡电极的氧还原性能及应用[J]. 精细化工, 2020, 37(9): 1896-1903, 1917.
	RUAN Chi, LIU Changjun, YUE Hairong, et al. Oxygen reduction performance and application of polypyrrole-modified graphite felt electrode[J]. Fine Chemicals, 2020, 37(9): 1896-1903, 1917.
67	ZHU X P, NI J R. Simultaneous processes of electricity generation and p-nitrophenol degradation in a microbial fuel cell[J]. Electrochemistry Communications, 2009, 11(2): 274-277.
68	陈诗雨, 许志成, 杨婧, 等. 微生物燃料电池在废水处理中的研究进展[J]. 化工进展, 2022, 41(2): 951-963.
	CHEN Shiyu, XU Zhicheng, YANG Jing, et al. Research progress of microbial fuel cell in wastewater treatment[J]. Chemical Industry and Engineering Progress, 2022, 41(2): 951-963.
69	HASSAN M, OLVERA-VARGAS H, ZHU X P, et al. Microbial electro-Fenton: an emerging and energy-efficient platform for environmental remediation[J]. Journal of Power Sources, 2019, 424: 220-244.
70	ZHAO H H, ZHANG Q H. Performance of electro-Fenton process coupling with microbial fuel cell for simultaneous removal of herbicide mesotrione[J]. Bioresource Technology, 2021, 319: 124244.
71	NADAIS H, LI X H, ALVES N, et al. Bio-electro-Fenton process for the degradation of non-steroidal anti-inflammatory drugs in wastewater[J]. Chemical Engineering Journal, 2018, 338: 401-410.
72	YANG X Y, ZOU R S, TANG K, et al. Degradation of metoprolol from wastewater in a bio-electro-Fenton system[J]. Science of the Total Environment, 2021, 771: 145385.
73	LI S N, LIU Y, GE R L, et al. Microbial electro-Fenton: a promising system for antibiotics resistance genes degradation and energy generation[J]. Science of the Total Environment, 2020, 699: 134160.
74	LI X H, JIN X D, ZHAO N N, et al. Novel bio-electro-Fenton technology for azo dye wastewater treatment using microbial reverse-electrodialysis electrolysis cell[J]. Bioresource Technology, 2017, 228: 322-329.
75	ZOU R S, ANGELIDAKI I, JIN B, et al. Feasibility and applicability of the scaling-up of bio-electro-Fenton system for textile wastewater treatment[J]. Environment International, 2020, 134: 105352.
76	HIDALGO D, TOMMASI T, BOCCHINI S, et al. Surface modification of commercial carbon felt used as anode for microbial fuel cells[J]. Energy, 2016, 99: 193-201.
77	MIER A A, OLVERA-VARGAS H, MEJÍA-LÓPEZ M, et al. A review of recent advances in electrode materials for emerging bioelectrochemical systems: from biofilm-bearing anodes to specialized cathodes[J]. Chemosphere, 2021, 283: 131138.
78	FENG C H, LI F B, LIU H Y, et al. A dual-chamber microbial fuel cell with conductive film-modified anode and cathode and its application for the neutral electro-Fenton process[J]. Electrochimica Acta, 2010, 55(6): 2048-2054.
79	XU P, XU H, SHI Z. A novel bio-electro-Fenton process with FeVO₄/CF cathode on advanced treatment of coal gasification wastewater[J]. Separation and Purification Technology, 2018, 194: 457-461.
80	SOPAJ F, OTURAN N, PINSON J, et al. Effect of the anode materials on the efficiency of the electro-Fenton process for the mineralization of the antibiotic sulfamethazine[J]. Applied Catalysis B: Environmental, 2016, 199: 331-341.
81	SONG D B, LI J F, WANG Z Y, et al. Performance of graphite felt as anodes in the electro-Fenton oxidation systems: changes in catalysis, conductivity and adsorption properties[J]. Applied Surface Science, 2020, 532: 147450.
82	ZHOU W, RAJIC L, MENG X X, et al. Efficient H₂O₂ electrogeneration at graphite felt modified via electrode polarity reversal: utilization for organic pollutants degradation[J]. Chemical Engineering Journal, 2019, 364: 428-439.

[1]	葛全倩, 徐迈, 梁铣, 王凤武. MOFs材料在光电催化领域应用的研究进展[J]. 化工进展, 2023, 42(9): 4692-4705.
[2]	王帅晴, 杨思文, 李娜, 孙占英, 安浩然. 元素掺杂生物质炭材料在电化学储能中的研究进展[J]. 化工进展, 2023, 42(8): 4296-4306.
[3]	徐伟, 李凯军, 宋林烨, 张兴惠, 姚舜华. 光催化及其协同电化学降解VOCs的研究进展[J]. 化工进展, 2023, 42(7): 3520-3531.
[4]	陈飞, 刘成宝, 陈丰, 钱君超, 邱永斌, 孟宪荣, 陈志刚. g-C₃N₄基超级电容器用电极材料的研究进展[J]. 化工进展, 2023, 42(5): 2566-2576.
[5]	蔡江涛, 候刘华, 兰雨金, 张晨陈, 刘国阳, 朱由余, 张建兰, 赵世永, 张亚婷. 沥青基多孔炭材料的制备及在超级电容器中的应用进展[J]. 化工进展, 2023, 42(4): 1895-1906.
[6]	刘静, 林琳, 张健, 赵峰. 生物质基炭材料孔径调控及电化学性能研究进展[J]. 化工进展, 2023, 42(4): 1907-1916.
[7]	卓祖优, 宋生南, 黄明堦, 杨旋, 卢贝丽, 陈燕丹. 草酸钾-尿素协同活化法制备超大比表面积面粉基多级孔炭及其电化学储能应用[J]. 化工进展, 2023, 42(2): 925-933.
[8]	田甜, 雷西萍, 于婷, 樊凯, 宋晓琪, 朱航. 碳材料在柔性超级电容器中的研究进展[J]. 化工进展, 2023, 42(2): 884-896.
[9]	章萍萍, 丁书海, 高晶晶, 赵敏, 俞海祥, 刘玥宏, 谷麟. 碳量子点修饰半导体复合光催化剂降解水中有机污染物[J]. 化工进展, 2023, 42(10): 5487-5500.
[10]	祁元, 徐欣蓉, 阮玮, 吴昊, 吴科, 周亚明, 杨宏旻. 改性活性碳纤维对苯胺吸附特性分析[J]. 化工进展, 2022, 41(S1): 622-630.
[11]	刘怡璇, 林跃朝, 马伟芳. 可见光催化降解水中卤代有机污染物的研究进展[J]. 化工进展, 2022, 41(S1): 571-579.
[12]	张辛亥, 赵思琛, 朱辉, 张首石, 王凯. 多种碳材料与碳酸钠复合后脱硫性能对比[J]. 化工进展, 2022, 41(S1): 424-435.
[13]	张辛亥, 赵思琛, 朱辉, 王凯, 张首石. 活性碳纤维负载型脱硫剂在矿井气体环境条件下的应用[J]. 化工进展, 2022, 41(S1): 415-423.
[14]	龙垠荧, 杨健, 管敏, 杨怡洛, 程正柏, 曹海兵, 刘洪斌, 安兴业. 木质素基材料在混合型超级电容器电极材料中的研究进展[J]. 化工进展, 2022, 41(9): 4855-4865.
[15]	段毅, 邹烨, 周书葵, 杨柳. 过渡金属单原子催化剂活化H₂O₂/PMS/PDS降解有机污染物的研究进展[J]. 化工进展, 2022, 41(8): 4147-4158.