化工进展 ›› 2023, Vol. 42 ›› Issue (4): 1822-1831.DOI: 10.16085/j.issn.1000-6613.2022-1084
李玲1,2,3(), 马超峰1,2, 卢春山3, 于万金1,2, 石能富1,2, 金佳敏1,2, 张建君1,2, 刘武灿1,2(), 李小年3()
收稿日期:
2022-06-09
修回日期:
2022-07-27
出版日期:
2023-04-25
发布日期:
2023-05-08
通讯作者:
刘武灿,李小年
作者简介:
李玲(1986—),女,博士研究生,高级工程师,研究方向为工业催化技术与氟碳化学品。E-mail:liling7@sinochem.com。
LI Ling1,2,3(), MA Chaofeng1,2, LU Chunshan3, YU Wanjin1,2, SHI Nengfu1,2, JIN Jiamin1,2, ZHANG Jianjun1,2, LIU Wucan1,2(), LI Xiaonian3()
Received:
2022-06-09
Revised:
2022-07-27
Online:
2023-04-25
Published:
2023-05-08
Contact:
LIU Wucan, LI Xiaonian
摘要:
含氟烯烃(HFOs)具有ODP为零、GWP值极低的优点,其中1,1,2-三氟乙烯(TrFE)可作为新能源汽车热泵工质、含氟高聚材料的合成单体、高附加值卤代烯烃制备的关键原料,有望实现在新能源汽车空调系统、压电材料与电卡制冷材料、高端芯片蚀刻等领域的广泛应用。本文对TrFE合成工艺进行分类,并详述各路线的技术难点与解决策略;针对主要合成路线即1,1,1,2-四氟乙烷(HFC-134a)脱氟化氢、1,1,2-三氯-1,2,2-三氟乙烷(CFC-113)催化加氢制备TrFE路线,对催化剂进行总结与归纳,讨论催化剂配方、制备方法、结构等因素对反应的影响。如何提高1,1,2-三氟乙烯选择性与催化剂稳定性是该研究的重点与难点,也是制约其产业化与商品化的决定因素。
中图分类号:
李玲, 马超峰, 卢春山, 于万金, 石能富, 金佳敏, 张建君, 刘武灿, 李小年. 新型含氟替代品1,1,2-三氟乙烯的合成工艺与催化剂研究进展[J]. 化工进展, 2023, 42(4): 1822-1831.
LI Ling, MA Chaofeng, LU Chunshan, YU Wanjin, SHI Nengfu, JIN Jiamin, ZHANG Jianjun, LIU Wucan, LI Xiaonian. Progress on the synthesis of 1,1,2-trifluoroethene and the catalysts[J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1822-1831.
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