聚己二酸丁二醇酯-共对苯二甲酸酯基可降解塑料改性研究进展

doi:10.16085/j.issn.1000-6613.2022-0194

摘要/Abstract

摘要：

随着人们环保意识的提高，可生物降解塑料逐步取代部分不可降解塑料，将成为一个趋势。目前，聚己二酸丁二醇酯-共对苯二甲酸酯（PBAT），作为最具商业潜力的可生物降解塑料，具有与低密度聚乙烯相当的延展性和柔韧性，被普遍认为是当代绿色材料制造中最有前途和最受欢迎的可持续材料之一。但PBAT在力学性能、热性能、阻隔性能及生产成本等方面存在不足，其应用范围受到限制。本文旨在系统性地简述近年来PBAT基复合材料的制备方法、回顾国内外研究人员在PBAT力学性能和阻隔性能等提升方面所做的工作、并详细介绍和讨论PBAT的降解原理和降解所带来的环境风险。开发低成本综合性能优异，兼顾良好降解性、抑菌性和耐久性能的PBAT基复合材料，应当予以重视和进一步研究。

关键词: 可降解塑料, 聚己二酸丁二醇酯-共对苯二甲酸酯, 共混改性, 降解

Abstract:

With awareness and highlights of environmental protection challenges, it is the trend for some non-biodegradable plastic to be gradually replaced by biodegradable ones. At present, polymer named as polybutylene adipate-co-terephthalate (PBAT), one of the most commercially promising biodegradable plastic with super ductility and flexibility compared favourably with low-density polyethylene, is considered to be one of the most attractive sustainable candidates for contemporary green material manufacturer. However, PBAT faces limitation of application cases, arising from its deficiencies in mechanical properties, thermal properties, barrier properties and production cost, etc.. This paper aimed to systematically review the development on preparation methods of PBAT-based composites in recent years and the work done by domestic and international researchers for improvement of the mechanical and barrier properties of PBAT, as well as the degradation principles and environmental risks associated with the PBAT degradation. Innovative research relevant to PBAT-based composites should be emphasized and further carried forward on topics such as excellent degradability, bacterial inhibition, durability and cost reduction.

Key words: degradable plastics, PBAT, blending modification, degradation

中图分类号:

TQ323.4

尹爽, 梁伟杰, 陈沛嘉, 张志聪, 葛建芳. 聚己二酸丁二醇酯-共对苯二甲酸酯基可降解塑料改性研究进展[J]. 化工进展, 2022, 41(S1): 307-317.

YIN Shuang, LIANG Weijie, CHEN Peijia, ZHANG Zhicong, GE Jianfang. Research progress on modification of PBAT-base biodegradable plastics[J]. Chemical Industry and Engineering Progress, 2022, 41(S1): 307-317.

图/表 8

参考文献 66

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标准号	标准名称
GB/T 18006.2—1999	一次性可降解餐饮具降解性能试验方法
GB/T 19275—2003	材料在特定微生物作用下潜在生物分解和崩解能力的评价
GB/T 19276.1—2003	水性培养液中材料最终需氧生物分解能力的测定采用测定密闭呼吸计中需氧量的方法
GB/T 19276.2—2003	水性培养液中材料最终需氧生物分解能力的测定采用测定释放的二氧化碳的方法
GB/T 19811—2005	在定义堆肥化中试条件下塑料材料崩解程度的测定
GB/T 22047—2008	土壤中塑料材料最终需氧生物分解能力的测定采用测定密闭呼吸计中需氧量或测定释放的二氧化碳的方法
GB/T 19277.1—2011	受控堆肥条件下材料最终需氧生物分解能力的测定采用测定释放的二氧化碳的方法第1部分：通用方法
GB/T 19277.2—2013	受控堆肥条件下材料最终需氧生物分解能力的测定采用测定释放的二氧化碳的方法第2部分：用重量分析法测定实验室条件下二氧化碳的释放量
GB/T 32106—2015	塑料在水性培养液中最终厌氧生物分解能力的测定通过测量生物气体产物的方法
GB/T 33797—2017	塑料在高固体份堆肥条件下最终厌氧生物分解能力的测定采用分析测定释放生物气体的方法
GB/T 17603—2017	光解性塑料户外暴露试验方法
GB/T 38737—2020	塑料受控污泥消化系统中材料最终厌氧生物分解率测定采用测量释放生物气体的方法

标准号	标准名称
GB/T 18006.2—1999	一次性可降解餐饮具降解性能试验方法
GB/T 19275—2003	材料在特定微生物作用下潜在生物分解和崩解能力的评价
GB/T 19276.1—2003	水性培养液中材料最终需氧生物分解能力的测定采用测定密闭呼吸计中需氧量的方法
GB/T 19276.2—2003	水性培养液中材料最终需氧生物分解能力的测定采用测定释放的二氧化碳的方法
GB/T 19811—2005	在定义堆肥化中试条件下塑料材料崩解程度的测定
GB/T 22047—2008	土壤中塑料材料最终需氧生物分解能力的测定采用测定密闭呼吸计中需氧量或测定释放的二氧化碳的方法
GB/T 19277.1—2011	受控堆肥条件下材料最终需氧生物分解能力的测定采用测定释放的二氧化碳的方法第1部分：通用方法
GB/T 19277.2—2013	受控堆肥条件下材料最终需氧生物分解能力的测定采用测定释放的二氧化碳的方法第2部分：用重量分析法测定实验室条件下二氧化碳的释放量
GB/T 32106—2015	塑料在水性培养液中最终厌氧生物分解能力的测定通过测量生物气体产物的方法
GB/T 33797—2017	塑料在高固体份堆肥条件下最终厌氧生物分解能力的测定采用分析测定释放生物气体的方法
GB/T 17603—2017	光解性塑料户外暴露试验方法
GB/T 38737—2020	塑料受控污泥消化系统中材料最终厌氧生物分解率测定采用测量释放生物气体的方法

颁布机构	标准号	标准名称
欧洲标准化委员会（CEN）	EN 13432	包装-堆肥和生物降解可回收的包装物要求-包装物最终的试验方法和评价标准
澳大利亚生物分解塑料协会	AS4736	生物降解塑料-适合堆肥化或者其他生物处理方式的生物降解塑料
德国标准化学会（DIN）	DINV54900	通过堆肥实验检测生物降解塑料生物降解性
美国试验与材料协会（ASTM）	ASTM D6400	可堆肥化塑料规范
全国塑料制品标准化技术委员会	GB/T 20197	降解塑料的定义、分类、标识和降解性能要求

颁布机构	标准号	标准名称
欧洲标准化委员会（CEN）	EN 13432	包装-堆肥和生物降解可回收的包装物要求-包装物最终的试验方法和评价标准
澳大利亚生物分解塑料协会	AS4736	生物降解塑料-适合堆肥化或者其他生物处理方式的生物降解塑料
德国标准化学会（DIN）	DINV54900	通过堆肥实验检测生物降解塑料生物降解性
美国试验与材料协会（ASTM）	ASTM D6400	可堆肥化塑料规范
全国塑料制品标准化技术委员会	GB/T 20197	降解塑料的定义、分类、标识和降解性能要求

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