固相钴基催化剂活化过一硫酸盐在水处理中的研究进展

doi:10.16085/j.issn.1000-6613.2021-0489

摘要/Abstract

摘要：

固相钴基催化剂驱动的过一硫酸盐（PMS）高级氧化技术，由于其高催化活性和易于从水中分离的优势，近年来受到了研究人员的广泛关注。本文回顾了近年来用于过一硫酸盐活化的固相钴基催化剂的研究进展，总结了钴基催化剂的种类和催化剂开发过程中采取的改性措施，汇总了钴基过一硫酸盐高级氧化技术在难降解有机污染物削减方面的应用，并分析了多种水质环境因素对削减效能的影响作用，同时阐述了钴基催化剂活化过一硫酸盐的氧化机理。最后，展望了固相钴基催化剂在未来研究中有望往大尺度、低泄漏、高循环、低能耗、具有磁效应或与膜反应器相结合的方向进一步发展。

关键词: 固相钴基催化剂, 过一硫酸盐, 改性策略, 活化机理, 有机污染物降解

Abstract:

Advanced oxidation technology using peroxymonosulfate driven by solid-phase cobalt-based catalysts has received extensive attention from researchers in recent years due to its high catalytic activity and easy separation from water. This article reviewed the research progress of the solid-phase cobalt-based catalysts for peroxymonosulfate activation in recent years, and summarized the types of the cobalt-based catalysts and their modification methods. The applications of advanced oxidation technology with cobalt-based persulfate in the reduction of refractory organic pollutants were introduced, and the effects of various water quality environmental factors on the reduction efficiency were analyzed. Further, the oxidation mechanism of the cobalt-based catalyst activated peroxymonosulfate was explained. Finally, the future development of solid-phase cobalt-based catalysts is expected to move towards large-scale, low leakage, high circulation, low energy consumption, having magnetic effects, or integration with membrane reactors.

Key words: solid-phase cobalt-based catalyst, peroxymonosulfate, modification strategy, activation mechanism, degradation of organic pollutants

中图分类号:

许泽涛, 曹怡婷, 王俏, 王志红. 固相钴基催化剂活化过一硫酸盐在水处理中的研究进展[J]. 化工进展, 2022, 41(2): 730-739.

XU Zetao, CAO Yiting, WANG Qiao, WANG Zhihong. Research progress of peroxymonosulfate activated by solid-phase cobalt-based catalyst in water treatment[J]. Chemical Industry and Engineering Progress, 2022, 41(2): 730-739.

图/表 4

参考文献 45

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污染物	污染物浓度	PMS浓度	催化剂	浓度/g·L^-1	pH	温度/℃	时间/min	去除率/%	动力学常数/min^-1	参考文献
罗丹明B	40mg/L	0.1mol/L	Co-HAP-2	0.2	5.5	25	12	93.30	0.0332	［27］
罗丹明B	10mg/L	0.05mg/L	Co₃O₄-Bi₂O₃	0.05	6	25	30	100	—	［25］
亮红3BF	0.1mmol/L	0.4mmol/L	AC-CuCo₂O₄	0.2	10	25	10	98	0.476	［18］
双酚A	20mg/L	0.3mmol/L	CoS	0.05	7	25	10	90	0.37	［28］
双酚A	20mg/L	0.3g/L	Co@NC-ZS-700	0.1	6.2	25	20	95	—	［21］
双酚A	80mg/L	0.3g/L	Co-N-C-900	0.5	—	30	3	100	2.81	［29］
2，4-二氯苯氧基乙酸	20mg/L	1mmol/L	CuO-Co₃O₄@CeO₂	0.07	6	25	45	97.50	0.1344	［15］
2，4-二氯苯酚	50mg/L	6mmol/L	CoOOH	0.20	7	25	120	100	0.0462	［4］
2，4-二氯苯酚	50mg/L	1.26g/L	Co₃Fe₇-CoFe₂O₄	0.05	7.7	30	30	97.10	0.119	［30］
阿特拉津	10μmol/L	1mmol/L	CoBC500	0.1	5.3	25	10	99	0.76	［17］
阿特拉津	23μmol/L	0.3mmol/L	3Co@Ⅰ	0.2	7	25	30	96	0.1034	［32］
二氢呋喃	10mg/L	0.65mmol/L	Co-S@NC	0.1	4.8	25	90	100.00	0.054	［22］
喹克洛拉克	50mg/L	20mmol/L	Co/NAC	0.08	—	25	30	93	0.0022	［20］
氯霉素	30mg/L	10mmol/L	Co₃O₄-BC	0.2	7	26	10	100	0.3361	［16］
环丙沙星	10mg/L	1.62mmol/L	Co-Fe/SiO₂LC	0.2	7	25	60	99.60	0.686	［14］
环丙沙星	10mg/L	1.3mmol/L	CoS₂（HNSs）	0.08	8	25	3	100.00	0.1209	［31］
萘普生	0.043mmol/L	2.5mmol/L	CoCN_x/SBA-15	0.0375	6.4	25	55	100	0.0877	［33］
5-磺基水杨酸	20mg/L	150mg/L	CoTS	0.1	7	30	60	100	0.0784	［34］
四环素	30mg/L	0.4g/L	ALCo-LDH	0.2	—	25	30	96.10	0.980	［5］
四环素	30mg/L	0.3g/L	CoS_x	0.2	5	25	30	100	0.151	［26］
三氯生	10mg/L	0.05g/L	Co₂Mn₁O₄	0.02	6.8	25	30	96.40	0.112	［3］

污染物	污染物浓度	PMS浓度	催化剂	浓度/g·L^-1	pH	温度/℃	时间/min	去除率/%	动力学常数/min^-1	参考文献
罗丹明B	40mg/L	0.1mol/L	Co-HAP-2	0.2	5.5	25	12	93.30	0.0332	［27］
罗丹明B	10mg/L	0.05mg/L	Co₃O₄-Bi₂O₃	0.05	6	25	30	100	—	［25］
亮红3BF	0.1mmol/L	0.4mmol/L	AC-CuCo₂O₄	0.2	10	25	10	98	0.476	［18］
双酚A	20mg/L	0.3mmol/L	CoS	0.05	7	25	10	90	0.37	［28］
双酚A	20mg/L	0.3g/L	Co@NC-ZS-700	0.1	6.2	25	20	95	—	［21］
双酚A	80mg/L	0.3g/L	Co-N-C-900	0.5	—	30	3	100	2.81	［29］
2，4-二氯苯氧基乙酸	20mg/L	1mmol/L	CuO-Co₃O₄@CeO₂	0.07	6	25	45	97.50	0.1344	［15］
2，4-二氯苯酚	50mg/L	6mmol/L	CoOOH	0.20	7	25	120	100	0.0462	［4］
2，4-二氯苯酚	50mg/L	1.26g/L	Co₃Fe₇-CoFe₂O₄	0.05	7.7	30	30	97.10	0.119	［30］
阿特拉津	10μmol/L	1mmol/L	CoBC500	0.1	5.3	25	10	99	0.76	［17］
阿特拉津	23μmol/L	0.3mmol/L	3Co@Ⅰ	0.2	7	25	30	96	0.1034	［32］
二氢呋喃	10mg/L	0.65mmol/L	Co-S@NC	0.1	4.8	25	90	100.00	0.054	［22］
喹克洛拉克	50mg/L	20mmol/L	Co/NAC	0.08	—	25	30	93	0.0022	［20］
氯霉素	30mg/L	10mmol/L	Co₃O₄-BC	0.2	7	26	10	100	0.3361	［16］
环丙沙星	10mg/L	1.62mmol/L	Co-Fe/SiO₂LC	0.2	7	25	60	99.60	0.686	［14］
环丙沙星	10mg/L	1.3mmol/L	CoS₂（HNSs）	0.08	8	25	3	100.00	0.1209	［31］
萘普生	0.043mmol/L	2.5mmol/L	CoCN_x/SBA-15	0.0375	6.4	25	55	100	0.0877	［33］
5-磺基水杨酸	20mg/L	150mg/L	CoTS	0.1	7	30	60	100	0.0784	［34］
四环素	30mg/L	0.4g/L	ALCo-LDH	0.2	—	25	30	96.10	0.980	［5］
四环素	30mg/L	0.3g/L	CoS_x	0.2	5	25	30	100	0.151	［26］
三氯生	10mg/L	0.05g/L	Co₂Mn₁O₄	0.02	6.8	25	30	96.40	0.112	［3］

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