过一硫酸盐-高铁酸盐-FeS体系土柱淋洗修复邻二氯苯污染土壤

doi:10.16085/j.issn.1000-6613.2021-0941

化工进展 ›› 2022, Vol. 41 ›› Issue (5): 2743-2752.DOI: 10.16085/j.issn.1000-6613.2021-0941

过一硫酸盐-高铁酸盐-FeS体系土柱淋洗修复邻二氯苯污染土壤

何畅帆¹^,²^,³(), 赵小航⁴, 章雪莹¹^,²^,³, 何林¹^,²^,³(), 隋红¹^,², 李鑫钢¹^,²^,³

^1.天津大学化工学院，天津 300072
^2.精馏技术国家工程研究中心，天津 300072
^3.天津大学浙江研究院，浙江宁波 315211
^4.中国昆仑工程有限公司大连分公司，辽宁大连 116023

收稿日期:2021-05-05 修回日期:2021-05-20 出版日期:2022-05-05 发布日期:2022-05-24
通讯作者: 何林
作者简介:何畅帆（1996—），男，硕士研究生，研究方向为有机污染土壤氧化修复。E-mail：hechangfan@tju.edu.cn。
基金资助:
天津市自然科学基金(18JCQNJC06500)

Peroxymonosulfate-ferrate-FeS system soil column leaching to remediate o-dichlorobenzene contaminated soil

HE Changfan¹^,²^,³(), ZHAO Xiaohang⁴, ZHANG Xueying¹^,²^,³, HE Lin¹^,²^,³(), SUI Hong¹^,², LI Xingang¹^,²^,³

^1.School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
^2.National Engineering Research Centre of Distillation Technology, Tianjin 300072, China
^3.Zhejiang Institute of Tianjin University, Ningbo 315201, Zhejiang, China
^4.China Kunlun Contracting & Engineering Corporation Dalian Company, Dalian 116023, Liaoning, China

Received:2021-05-05 Revised:2021-05-20 Online:2022-05-05 Published:2022-05-24
Contact: HE Lin

摘要/Abstract

摘要：

有机氯污染土壤的修复是目前土壤修复的一个重点和难点。针对有机氯难降解的问题，本文采用土柱淋洗模拟异位淋洗修复的方式，利用过一硫酸盐-高铁酸盐-FeS（PFI）氧化体系对邻二氯苯污染土壤进行了修复。采用土柱实验测试了过一硫酸盐和高铁酸钾的复合溶液在土壤中的渗透系数（1.46×10^-4~2.46×10^-4cm/s），实验发现随氧化物浓度增大，渗透系数变小。使用PFI对污染土壤进行了土柱淋洗修复实验，结果表明，PFI可实现对深层土壤的氧化修复，在适中浓度下经过3.8h淋洗，可将深度为5cm、15cm、25cm处的土壤中的邻二氯苯最终残留率降低为17.5%、20.0%和30.3%。在改变土壤性质方面，土柱实验表明，PFI对土壤性质的改变与土壤深度呈负相关，即土壤越浅，改变得越彻底。综上所述，PFI氧化体系对含氯苯有机污染场地修复有良好的应用前景。

关键词: 土柱淋洗, 修复, 氧化, 降解, 过一硫酸盐, 高铁酸盐, 硫化亚铁

Abstract:

The remediation of organic chlorine contaminated soil is currently a significant and sticking point in soil remediation. For the trouble of hard degradation in organochlorine, soil column leaching was used to simulate in-situ remediation and peroxymonosulfate-ferrate-FeS (PFI) oxidation system was used to remediate o-dichlorobenzene contaminated soil. The soil column experiment was used to test the permeability coefficient (1.46×10^-4~2.46×10^-4cm/s) of the compound peroxymonosulfate and potassium ferrate solution in the soil. It was found through experiments that as the oxide concentration increased, the permeability coefficient became smaller. The PFI was used in soil column leaching remediation experiments on contaminated soil. It showed that the oxidation and remediation of deep soil could be achieved by PFI. The final residual ratio of o-dichlorobenzene in the soil at 5cm, 15cm and 25cm depth were reduced to 17.5%, 20.0% and 30.3% respectively by leaching at a middle concentration for 3.8h. In terms of changing soil properties, soil column experiments showed that the change of soil properties by PFI had a negative correlation with soil depth. The shallower the soil, the more thoroughly the soil properties changed. In summary, the PFI oxidation system has good prospects for the remediation of chlorobenzene-containing organic contaminated sites.

Key words: soil column leaching, remediation, oxidation, degradation, persulfate, ferrate, ferrous sulfide

中图分类号:

何畅帆, 赵小航, 章雪莹, 何林, 隋红, 李鑫钢. 过一硫酸盐-高铁酸盐-FeS体系土柱淋洗修复邻二氯苯污染土壤[J]. 化工进展, 2022, 41(5): 2743-2752.

HE Changfan, ZHAO Xiaohang, ZHANG Xueying, HE Lin, SUI Hong, LI Xingang. Peroxymonosulfate-ferrate-FeS system soil column leaching to remediate o-dichlorobenzene contaminated soil[J]. Chemical Industry and Engineering Progress, 2022, 41(5): 2743-2752.

图/表 22

参考文献 22

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参数	数值
有机质/g·kg^-1	10.7
pH（水土比=10）	7.94
平均粒径/μm	31.45
BET表面积/m²·g^-1	1.4446
砂粒/g·(100g)^-1	22.3
粉粒/g·(100g)^-1	74.6
黏粒/g·(100g)^-1	3.1
硅（Si）/g·(100g)^-1	40.55
氧（O）/g·(100g)^-1	47.48
铁（Fe）/g·kg^-1	6.2
铝（Al）/g·kg^-1	7.2
铬（Cr）/g·kg^-1	0.3
铜（Cu）/g·kg^-1	9.6
钙（Ca）/g·kg^-1	2.2
铅（Pb）/g·kg^-1	0.9

参数	数值
有机质/g·kg^-1	10.7
pH（水土比=10）	7.94
平均粒径/μm	31.45
BET表面积/m²·g^-1	1.4446
砂粒/g·(100g)^-1	22.3
粉粒/g·(100g)^-1	74.6
黏粒/g·(100g)^-1	3.1
硅（Si）/g·(100g)^-1	40.55
氧（O）/g·(100g)^-1	47.48
铁（Fe）/g·kg^-1	6.2
铝（Al）/g·kg^-1	7.2
铬（Cr）/g·kg^-1	0.3
铜（Cu）/g·kg^-1	9.6
钙（Ca）/g·kg^-1	2.2
铅（Pb）/g·kg^-1	0.9

实验序号	试剂用量
实验序号	PMS/mol·L^-1	K₂FeO₄/mol·L^-1	FeS/mol·kg^-1土壤
1	0.05	0.05	0.075
2	0.10	0.10	0.15
3	0.20	0.20	0.30

实验序号	试剂用量
实验序号	PMS/mol·L^-1	K₂FeO₄/mol·L^-1	FeS/mol·kg^-1土壤
1	0.05	0.05	0.075
2	0.10	0.10	0.15
3	0.20	0.20	0.30

名称	浓度/mol·L^-1	密度/g·L^-1	稳定渗透系数/10^-4cm·s^-1
去离子水	—	1	3.10
PMS溶液	0.05	1.02	4.22
PMS溶液	0.10	1.04	3.81
PMS溶液	0.20	1.07	3.18

过一硫酸盐-高铁酸盐-FeS体系土柱淋洗修复邻二氯苯污染土壤

Peroxymonosulfate-ferrate-FeS system soil column leaching to remediate o-dichlorobenzene contaminated soil

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参考文献 22

相关文章 15

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名称	浓度/mol?L^-1	黏度/mPa?s
去离子水	—	0.9248
PMS溶液	0.05	1.5738
PMS溶液	0.10	1.7414
PMS溶液	0.20	2.0688

名称	浓度/mol?L^-1	密度/g?L^-1	稳定渗透系数/10^-4cm?s^-1
PMS、K₂FeO₄复合溶液	0.05	1.03	2.46
PMS、K₂FeO₄复合溶液	0.10	1.06	1.98
PMS、K₂FeO₄复合溶液	0.20	1.12	1.46

土壤深度/cm	拟合参数
土壤深度/cm	A	k	b	R²
5	2.2042	0.9171	0.0011	0.9712
15	4.5777	1.3033	0.0809	0.9794
25	380.2093	2.6247	0.1365	0.9851

土壤深度/cm	拟合参数
土壤深度/cm	A	k	b	R²
5	0.8720	0.7461	0.1140	0.9839
15	2.3069	1.1640	0.1841	0.9976
25	3.7080	1.5177	0.2968	0.9975

土壤深度/cm	拟合参数
土壤深度/cm	A	k	b	R²
5	0.7463	0.9846	0.3112	0.9847
15	1.5917	1.2554	0.3917	0.9976
25	2.1723	1.4244	0.4756	0.9935

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